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Reinforced Plastics
Composites
• Metals are isometric materials
• Composites can cut weight by not being
isometric and still maintain the strength in
the desired directions
• Composites are, by definition, solid
materials composed of more than one
substance in more than one phase
Composites
Processes
• Thermoplastic processes –Very short fibers
• Matched die/compression molding
• RTM
• Spray-up
• Hand lay-up for wet and prepreg materials
• Filament winding and fiber placement
• Pultrusion
Advanced Composites
• Long (continuous) fibers
• Very high performance reinforcements
– Carbon and aramid
• Resins are also very high performance
• Typically aerospace applications
Engineering Composites
• Shorter fibers/fiberglass
• Lower mechanical properties (stiffness)
• Lower performance resins
Matrix Materials
• Resins
– Both thermosets and thermoplastics can be
used
– Short fibers are generally used in
thermoplastics
– Long fibers are generally used with
thermosets
Matrix Materials
• Short fiber composites
– Less than 0.2 inches (whiskers)
– Processed through standard thermoplastic
processes
• Must pass through gates, runners, and gap
between processing screw and barrel walls
– Thermoplastics generally benefit greatly from
even the short reinforcement materials
Matrix Materials – FRP
• Intermediate length fiber reinforcement
– The longer the fibers, the more difficult it is to
coat the fibers enough to reap strength
benefits
– Low viscosity thermosets “wet-out” the
materials better than high viscosity
thermoplastics
– Generally use unsaturated polyester and
vinylester resins for FRP
Matrix Materials – Advanced
• Very long fibers or continuous fibers
– Typically used with thermosets, also for “wet-
out” reasons
– Used generally in advanced composite parts
and have greater material property
requirements
– Generally use epoxy resins
Reinforcements
• Three main types of fibers
– Fiberglass
– Carbon fiber or Graphite
– Organic fibers, aramids (kevlar)
Fiberglass
• Spin molten glass
• Different types of glass can be made
– E-glass (improved electrical resistance)
– S-glass (high strength)
– C-glass (high chemical resistance)
Carbon or Graphite Fiber
• Originally some distinction was made—
now the two refer to the same material
• Made from PAN fibers, pitch or rayon
fibers
• Through heating, raw material looses most
non-carbon atoms in the chain
• Processing also aligns carbon chains
• Carbon fibers have very high modulus
(stiffness)
Organic Reinforcement Fibers
• Aramid fibers have greatest strength and
modulus properties of organic fibers
• Kevlar is the most commonly used aramid
fiber
• Aramids are strong and stiff but their
greatest value is in impact applications
– Front of airplane wings
– Armor applications
Reinforcement Forms
• Fiber manufacturers package the fibers on
spools called tows
• Fibers are generally converted to other
forms after manufacturing
– Chopped fibers (including whiskers)
– Mat (random)
– Woven fibers
– Tapes
– Prepregs
Manufacturing Methods
• Thermoplastic processes using short
fibers
– Injection molding
– Extrusion
– Minor changes are made to accommodate the
fiber reinforcements
• All gaps in flow path should be increased
• A resin viscosity decrease may be necessary
Manufacturing Methods
• Matched die or Compression molding
– Reduced flow path over injection or extrusion
– SMC compression molding allows for
continuous fibers, mats or weaves
– These processes offer parts that are finished
on both sides where most other composite
processes do not
Manufacturing Methods
• Resin transfer molding
– Fiber preform is placed in the mold cavity
– Preform doesn’t move—resin is pulled/pushed
in
Manufacturing Methods
• Spray-up
– Fibers are chopped, coated with resin and
sprayed onto the mold
Manufacturing Methods
• Hand Lay-up (wet and prepreg)
Prepreg
Wet
Fiber Orientations
• Isometric materials have equal strength in
all directions
• Composites can be lighter weight by not
having strength in the directions that it is
not needed
• Lay-up still has to have some balance and
symmetry
Vacuum Bagging
• Provides for increased part consolidation
• Reduces matched die mold costs
Manufacturing Methods
• Filament winding and fiber placement
– Fiber placement has greater accuracy
– Fiber placement can wind on less symmetrical
and even partially concave mandrels
• Tubes, tanks, wind turbine blades and
rockets
Manufacturing Methods
• Roll wrapping
– Faster than filament winding
– Limited to symmetrical mandrels
Manufacturing Methods
• Pultrusion
– High volume production
– Comparable to extrusion but the main
processing force is tension
– Profile is pulled from the machine
Plant Concepts
• Many of the processes require
considerable space
• Curing equipment for large parts can be
very large (and expensive)
• Controlling volatiles (solvents and resins)
must be taken care of
• Molds can be both expensive and fragile
Thank You

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12572654.ppt

  • 2. Composites • Metals are isometric materials • Composites can cut weight by not being isometric and still maintain the strength in the desired directions • Composites are, by definition, solid materials composed of more than one substance in more than one phase
  • 4. Processes • Thermoplastic processes –Very short fibers • Matched die/compression molding • RTM • Spray-up • Hand lay-up for wet and prepreg materials • Filament winding and fiber placement • Pultrusion
  • 5. Advanced Composites • Long (continuous) fibers • Very high performance reinforcements – Carbon and aramid • Resins are also very high performance • Typically aerospace applications
  • 6. Engineering Composites • Shorter fibers/fiberglass • Lower mechanical properties (stiffness) • Lower performance resins
  • 7. Matrix Materials • Resins – Both thermosets and thermoplastics can be used – Short fibers are generally used in thermoplastics – Long fibers are generally used with thermosets
  • 8. Matrix Materials • Short fiber composites – Less than 0.2 inches (whiskers) – Processed through standard thermoplastic processes • Must pass through gates, runners, and gap between processing screw and barrel walls – Thermoplastics generally benefit greatly from even the short reinforcement materials
  • 9. Matrix Materials – FRP • Intermediate length fiber reinforcement – The longer the fibers, the more difficult it is to coat the fibers enough to reap strength benefits – Low viscosity thermosets “wet-out” the materials better than high viscosity thermoplastics – Generally use unsaturated polyester and vinylester resins for FRP
  • 10. Matrix Materials – Advanced • Very long fibers or continuous fibers – Typically used with thermosets, also for “wet- out” reasons – Used generally in advanced composite parts and have greater material property requirements – Generally use epoxy resins
  • 11. Reinforcements • Three main types of fibers – Fiberglass – Carbon fiber or Graphite – Organic fibers, aramids (kevlar)
  • 12. Fiberglass • Spin molten glass • Different types of glass can be made – E-glass (improved electrical resistance) – S-glass (high strength) – C-glass (high chemical resistance)
  • 13. Carbon or Graphite Fiber • Originally some distinction was made— now the two refer to the same material • Made from PAN fibers, pitch or rayon fibers • Through heating, raw material looses most non-carbon atoms in the chain • Processing also aligns carbon chains • Carbon fibers have very high modulus (stiffness)
  • 14. Organic Reinforcement Fibers • Aramid fibers have greatest strength and modulus properties of organic fibers • Kevlar is the most commonly used aramid fiber • Aramids are strong and stiff but their greatest value is in impact applications – Front of airplane wings – Armor applications
  • 15. Reinforcement Forms • Fiber manufacturers package the fibers on spools called tows • Fibers are generally converted to other forms after manufacturing – Chopped fibers (including whiskers) – Mat (random) – Woven fibers – Tapes – Prepregs
  • 16. Manufacturing Methods • Thermoplastic processes using short fibers – Injection molding – Extrusion – Minor changes are made to accommodate the fiber reinforcements • All gaps in flow path should be increased • A resin viscosity decrease may be necessary
  • 17. Manufacturing Methods • Matched die or Compression molding – Reduced flow path over injection or extrusion – SMC compression molding allows for continuous fibers, mats or weaves – These processes offer parts that are finished on both sides where most other composite processes do not
  • 18. Manufacturing Methods • Resin transfer molding – Fiber preform is placed in the mold cavity – Preform doesn’t move—resin is pulled/pushed in
  • 19. Manufacturing Methods • Spray-up – Fibers are chopped, coated with resin and sprayed onto the mold
  • 20. Manufacturing Methods • Hand Lay-up (wet and prepreg) Prepreg Wet
  • 21. Fiber Orientations • Isometric materials have equal strength in all directions • Composites can be lighter weight by not having strength in the directions that it is not needed • Lay-up still has to have some balance and symmetry
  • 22. Vacuum Bagging • Provides for increased part consolidation • Reduces matched die mold costs
  • 23. Manufacturing Methods • Filament winding and fiber placement – Fiber placement has greater accuracy – Fiber placement can wind on less symmetrical and even partially concave mandrels • Tubes, tanks, wind turbine blades and rockets
  • 24. Manufacturing Methods • Roll wrapping – Faster than filament winding – Limited to symmetrical mandrels
  • 25. Manufacturing Methods • Pultrusion – High volume production – Comparable to extrusion but the main processing force is tension – Profile is pulled from the machine
  • 26. Plant Concepts • Many of the processes require considerable space • Curing equipment for large parts can be very large (and expensive) • Controlling volatiles (solvents and resins) must be taken care of • Molds can be both expensive and fragile