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ELECTRON CONFIGURATIONS
and
QUANTUM NUMBERS
Tony Coloma
Gr. 8
Memory Device to Remember the Order of Orbitals
1s,
2s, 2p,
3s, 3p,
4s, 3d, 4p,
5s, 4d, 5p, 6s,
4f, 5d, 6p, 7s, 5f…
Remember this!
Guide
• THE AUFBAU
PRINCIPLE (Building
up principle): Electrons
are added to atomic
orbitals starting with the
lowest energy orbital and
building up to higher
energy orbitals.
Guide
• PAULI
EXCLUSION
PRINCIPLE: Only 2
electrons can
occupy an orbital
and they must have
opposite spins.
Guide
• HUND’S RULE:
Electrons occupy
orbitals in a
sublevel one at a
time until each
orbital has 1 e-.
They will not
double up until
each orbital has
at least one
electron
Main Energy Level
(n)
(sometimes called
a “Shell”)
Sub-shells*
are
represente
d by:
Number of
orbitals**
per sub-
shell
Max Number of
e-
per
sub-shell
1 (K-Shell) s s = 1 s = 2 e-
2 (L-Shell) s, p s = 1
p = 3
s = 2 e-
p = 6 e-
3 (M-Shell) s, p, d s = 1
p = 3
d = 5
s = 2 e-
p = 6 e-
d = 10 e-
4 (N-Shell) s, p, d, f s = 1
p = 3
d = 5
f = 7
s = 2 e-
p = 6 e-
d = 10 e-
f = 14 e-
*sub-shells
s = Sharp
p = Principal
d = Diffuse
f = Fundamental
**The 3-dimensional region
around the nucleus where the
probability of finding electrons are
maximum are called orbitals.
2
1
3
4
K
L
M
N
s s s s
p p
d
p
d
f
2
1
3
4
K
L
M
N
s s s s
p p
d
p
d
f
QUANTUM NUMBERS
1- PRINCIPAL QUANTUM NUMBER (n).
Designates the main energy level or shell.
2- ANGULAR MOMENTUM QUANTUM
NUMBER (l). Designates the sub-level
where the electron can be found.
Gives the SHAPE OF THE ORBITALS
3- MAGNETIC QUANTUM NUMBER (ml). Specifies to
which orbital within a subshell the electron is
assigned
s subshell: ml = 0
p subshell: ml = -1, 0, 1
d subshell: ml = -2, -1, 0, 1, 2
f subshell: ml = -3, -2, -1, 0, 1, 2, 3
4- SPIN QUANTUM NUMBER (ms). Designates the
SPIN OF THE ELECTRON (describes the behavior of
the e-, not the location).
 Values: +½ , -½
 Arrow up ↑ is +½, arrow down ↓ is –½
17Cl: 1s22s22p63s23p5
Condense: [Ne] 3s² 3p⁵
-1 0 1
-1 0 1
-1 0 1
-2 -1 0 1 2
-2 -1 0 1 2 -3 -2 -1 0 1 2 3
0
0
0
0
YOUR TURN
YOUR TURN
ELEMENT:
CONDENSED ELECTRON CONFIGURATION:
QUANTUM
NUMBERS
n
l
m
l
ms
ORBITAL
ENERGY
TEMPLATE

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e- Configuration & Quantum Num- Gr. 8.pptx

  • 2.
  • 3.
  • 4.
  • 5. Memory Device to Remember the Order of Orbitals 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f… Remember this!
  • 6. Guide • THE AUFBAU PRINCIPLE (Building up principle): Electrons are added to atomic orbitals starting with the lowest energy orbital and building up to higher energy orbitals.
  • 7. Guide • PAULI EXCLUSION PRINCIPLE: Only 2 electrons can occupy an orbital and they must have opposite spins.
  • 8. Guide • HUND’S RULE: Electrons occupy orbitals in a sublevel one at a time until each orbital has 1 e-. They will not double up until each orbital has at least one electron
  • 9. Main Energy Level (n) (sometimes called a “Shell”) Sub-shells* are represente d by: Number of orbitals** per sub- shell Max Number of e- per sub-shell 1 (K-Shell) s s = 1 s = 2 e- 2 (L-Shell) s, p s = 1 p = 3 s = 2 e- p = 6 e- 3 (M-Shell) s, p, d s = 1 p = 3 d = 5 s = 2 e- p = 6 e- d = 10 e- 4 (N-Shell) s, p, d, f s = 1 p = 3 d = 5 f = 7 s = 2 e- p = 6 e- d = 10 e- f = 14 e- *sub-shells s = Sharp p = Principal d = Diffuse f = Fundamental **The 3-dimensional region around the nucleus where the probability of finding electrons are maximum are called orbitals. 2 1 3 4 K L M N s s s s p p d p d f
  • 10.
  • 11. 2 1 3 4 K L M N s s s s p p d p d f
  • 12.
  • 13. QUANTUM NUMBERS 1- PRINCIPAL QUANTUM NUMBER (n). Designates the main energy level or shell. 2- ANGULAR MOMENTUM QUANTUM NUMBER (l). Designates the sub-level where the electron can be found. Gives the SHAPE OF THE ORBITALS 3- MAGNETIC QUANTUM NUMBER (ml). Specifies to which orbital within a subshell the electron is assigned s subshell: ml = 0 p subshell: ml = -1, 0, 1 d subshell: ml = -2, -1, 0, 1, 2 f subshell: ml = -3, -2, -1, 0, 1, 2, 3 4- SPIN QUANTUM NUMBER (ms). Designates the SPIN OF THE ELECTRON (describes the behavior of the e-, not the location).  Values: +½ , -½  Arrow up ↑ is +½, arrow down ↓ is –½
  • 15. -1 0 1 -1 0 1 -1 0 1 -2 -1 0 1 2 -2 -1 0 1 2 -3 -2 -1 0 1 2 3 0 0 0 0 YOUR TURN
  • 16.
  • 17.
  • 18.
  • 19.

Editor's Notes

  1. The s, p, d, and f, respectively stand for sharp, primary, diffuse and fundamental. The letters and words refer to the visual impression left by the spectral lines’ fine structure that occurs because of the first relativistic corrections, particularly the spin-orbital interaction.