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Sparkling Wine Forum | Reims - June 2023
New materials for
barrels in a climate
change scenario Luca Risso
Research
Clayver srl, ITALY
Sparkling Wine Forum | Reims - June 2023 3
Some data about last 22 harvests in Champagne
Alcol
Harvest date
Acidity
Sparkling Wine Forum | Reims – 20 June 2023 4
Huglin Index
Only if Tav.>10°
Winkler
Index
Winkler, A.J.; et al. (1974). General viticulture.
University of California Press. ISBN 978-0520025912.
Pierre Huglin: Biologie et écologie de la vigne.
Lavoisier (Edition Tec & Doc), Paris 1986, ISBN 2-
60103-019-4. S. 292 (371 S.).
Sparkling Wine Forum | Reims – 20 June 2023 5
Huglin
Winkler
Sparkling Wine Forum | Reims – 20 June 2023 6
Sparkling Wine Forum | Reims – 20 June 2023 7
Tm and TM and are two arbitrary temperatures defining the
limits of normal ripening temperatures, f.e. 10° and 30°. Ti is
a temperature for each hour of the day from 1/4 to 30/4
CWI= X+iY is a complex number with a
real part and an imaginary part. The first
takes into account what happens in normal
ripening days. The latter only what happens
when temperature are abnormal.
Complex Winkler Index
Sparkling Wine Forum | Reims – 20 June 2023 8
Real Part
Imaginary Part
Sparkling Wine Forum | Reims – 20 June 2023 9
● Increase the size of containers
● Limit the amount of oxygen given to wine
● Limit tannins others than the ones in the grapes
● Limit racking and other sources of extra oxygen
● Limit sulfur and other sources of reduction
● Limit contaminations (Hygiene)
● Change ampelographic base (if possible)
● New materials for wine containers
CURRENT TRENDS
Sparkling Wine Forum | Reims – 20 June 2023 10
Der Winzer Betonei, Steinfass, Tonamphore
& Co. Vergleich zu herkömmlichen
Weinbehältern Ein Artikel von OSR Ing. Herbert
Schödl u.a. | 09.10.2017 - 00:10
Sparkling Wine Forum | Reims – 20 June 2023 11
Sparkling Wine Forum | Reims – 20 June 2023 12
Sparkling Wine Forum | Reims – 20 June 2023 13
Pinot Noir, Champagne 24 months
Sparkling Wine Forum | Reims – 20 June 2023 14
Parametres
Contenat
Moût fin FA + FML 4 mois élevage 7 mois élevage
Inox Fût Ogive
beton
Ogive
terre
cuite
Ogive
grès
Inox Fût Ogive
beton
Ogive
terre
cuite
Ogive
grès
Inox Fût Ogive
beton
Ogive
terre
cuite
Ogive
grès
TAP/TAV (% vol) 10,27 10,25 10,2 10,3 10,25 10,3 10,3 10,35 10,3 10,25 10,3 10,25 10,3 10,3 10,2 10,25
pH 3,04 3,19 3,21 3,24 3,3 3,2 3,19 3,21 3,23 3,3 3,2 3,18 3,21 3,23 3,3 3,19
Acidité totale (g/l) 7,95 5,05 5,25 4,75 4,55 5 4,95 5,05 4,65 4,4 4,9 4,8 5,1 4,55 4,3 4,8
SO2 libre (mg/l) 12 10 13 11 12 11 12 13 12 12 10 11 12 11 10
SO2 total (mg/l) 21 41 32 42 52 35 39 36 39 49 35 38 45 36 47 33
Acide tartrique
(g/l)
3,3 3,1 2,9 2,8 3,2 2,8 3 2,6 2,3 2,8
Acide malique (g/l) < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1
Acide lactique (g/l) 3,02 3,22 3,08 3,08 3,3 3,02 3,22 3,08 3,08 3,3
Acide acétique
(g/l)
0,27 0,32 0,23 0,22 0,24 0,33 0,42 0,28 0,26 0,3
Turbidité (ntu) 18,7 8,3 6,3 6,9 7,8 7,8
Sparkling Wine Forum | Reims – 20 June 2023 15
Clayver is a ceramic container designed
specifically for winemaking, including
fermentation, conservation and ageing of the
product. It is the result of a long process of
research and experimentation
Sparkling Wine Forum | Reims – 20 June 2023 16
https://tinyurl.com/bdfmyebc
“Characterization of the Oxygen Transmission
Rate of New‐Ancient Natural Materials for
Wine Maturation Containers”, Ignacio
Nevares and Maria del Alamo‐Sanza, Foods
2021, 10, 140
Sparkling Wine Forum | Reims – 20 June 2023 17
● 5 mg/L.year for a
standard vat
● 13 mg/L.year for a O+
(high porosity) vat
Experiments on a 250L Clayver
Sparkling Wine Forum | Reims – 20 June 2023 18
● Any acid or basic solutions in normal
concentrations up to 100 °C.
● Steam, paying attention to let the container
cool down afterwards naturally, without
forcing things.
● High pressure water jet cleaner.
● Enzymatic solutions.
Cleaning… Which solution to adopt?
Sparkling Wine Forum | Reims – 20 June 2023 19
250L and 400L Clayver can be
rotated on their stand and turned
upside down for an easier cleansing
650L has a wide bottom
manhole to drain out
everything is scum, peels and
stems
Sparkling Wine Forum | Reims – 20 June 2023 20
Sparkling Wine Forum | Reims – 20 June 2023 21
Mandatory: no lead nor cadmium can be present
(Regolamento CE 1935/2004 - Direttiva 84/500
attuata con D.M. 4/4/85 e Direttiva 2005/31/CE
attuata con D.M. 1/2/2007)
Other elements such as Al, Si, Fe, Ca, Ti, Na, K could
be allowed under certain concentrations, but they are
not welcome
Food grade certification
Sparkling Wine Forum | Reims – 20 June 2023 22
THANK YOU!

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New materials for barrels in a climate change scenario

  • 1. 1 Sparkling Wine Forum | Reims - June 2023
  • 2. New materials for barrels in a climate change scenario Luca Risso Research Clayver srl, ITALY
  • 3. Sparkling Wine Forum | Reims - June 2023 3 Some data about last 22 harvests in Champagne Alcol Harvest date Acidity
  • 4. Sparkling Wine Forum | Reims – 20 June 2023 4 Huglin Index Only if Tav.>10° Winkler Index Winkler, A.J.; et al. (1974). General viticulture. University of California Press. ISBN 978-0520025912. Pierre Huglin: Biologie et écologie de la vigne. Lavoisier (Edition Tec & Doc), Paris 1986, ISBN 2- 60103-019-4. S. 292 (371 S.).
  • 5. Sparkling Wine Forum | Reims – 20 June 2023 5 Huglin Winkler
  • 6. Sparkling Wine Forum | Reims – 20 June 2023 6
  • 7. Sparkling Wine Forum | Reims – 20 June 2023 7 Tm and TM and are two arbitrary temperatures defining the limits of normal ripening temperatures, f.e. 10° and 30°. Ti is a temperature for each hour of the day from 1/4 to 30/4 CWI= X+iY is a complex number with a real part and an imaginary part. The first takes into account what happens in normal ripening days. The latter only what happens when temperature are abnormal. Complex Winkler Index
  • 8. Sparkling Wine Forum | Reims – 20 June 2023 8 Real Part Imaginary Part
  • 9. Sparkling Wine Forum | Reims – 20 June 2023 9 ● Increase the size of containers ● Limit the amount of oxygen given to wine ● Limit tannins others than the ones in the grapes ● Limit racking and other sources of extra oxygen ● Limit sulfur and other sources of reduction ● Limit contaminations (Hygiene) ● Change ampelographic base (if possible) ● New materials for wine containers CURRENT TRENDS
  • 10. Sparkling Wine Forum | Reims – 20 June 2023 10 Der Winzer Betonei, Steinfass, Tonamphore & Co. Vergleich zu herkömmlichen Weinbehältern Ein Artikel von OSR Ing. Herbert Schödl u.a. | 09.10.2017 - 00:10
  • 11. Sparkling Wine Forum | Reims – 20 June 2023 11
  • 12. Sparkling Wine Forum | Reims – 20 June 2023 12
  • 13. Sparkling Wine Forum | Reims – 20 June 2023 13 Pinot Noir, Champagne 24 months
  • 14. Sparkling Wine Forum | Reims – 20 June 2023 14 Parametres Contenat Moût fin FA + FML 4 mois élevage 7 mois élevage Inox Fût Ogive beton Ogive terre cuite Ogive grès Inox Fût Ogive beton Ogive terre cuite Ogive grès Inox Fût Ogive beton Ogive terre cuite Ogive grès TAP/TAV (% vol) 10,27 10,25 10,2 10,3 10,25 10,3 10,3 10,35 10,3 10,25 10,3 10,25 10,3 10,3 10,2 10,25 pH 3,04 3,19 3,21 3,24 3,3 3,2 3,19 3,21 3,23 3,3 3,2 3,18 3,21 3,23 3,3 3,19 Acidité totale (g/l) 7,95 5,05 5,25 4,75 4,55 5 4,95 5,05 4,65 4,4 4,9 4,8 5,1 4,55 4,3 4,8 SO2 libre (mg/l) 12 10 13 11 12 11 12 13 12 12 10 11 12 11 10 SO2 total (mg/l) 21 41 32 42 52 35 39 36 39 49 35 38 45 36 47 33 Acide tartrique (g/l) 3,3 3,1 2,9 2,8 3,2 2,8 3 2,6 2,3 2,8 Acide malique (g/l) < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 < 0,1 Acide lactique (g/l) 3,02 3,22 3,08 3,08 3,3 3,02 3,22 3,08 3,08 3,3 Acide acétique (g/l) 0,27 0,32 0,23 0,22 0,24 0,33 0,42 0,28 0,26 0,3 Turbidité (ntu) 18,7 8,3 6,3 6,9 7,8 7,8
  • 15. Sparkling Wine Forum | Reims – 20 June 2023 15 Clayver is a ceramic container designed specifically for winemaking, including fermentation, conservation and ageing of the product. It is the result of a long process of research and experimentation
  • 16. Sparkling Wine Forum | Reims – 20 June 2023 16 https://tinyurl.com/bdfmyebc “Characterization of the Oxygen Transmission Rate of New‐Ancient Natural Materials for Wine Maturation Containers”, Ignacio Nevares and Maria del Alamo‐Sanza, Foods 2021, 10, 140
  • 17. Sparkling Wine Forum | Reims – 20 June 2023 17 ● 5 mg/L.year for a standard vat ● 13 mg/L.year for a O+ (high porosity) vat Experiments on a 250L Clayver
  • 18. Sparkling Wine Forum | Reims – 20 June 2023 18 ● Any acid or basic solutions in normal concentrations up to 100 °C. ● Steam, paying attention to let the container cool down afterwards naturally, without forcing things. ● High pressure water jet cleaner. ● Enzymatic solutions. Cleaning… Which solution to adopt?
  • 19. Sparkling Wine Forum | Reims – 20 June 2023 19 250L and 400L Clayver can be rotated on their stand and turned upside down for an easier cleansing 650L has a wide bottom manhole to drain out everything is scum, peels and stems
  • 20. Sparkling Wine Forum | Reims – 20 June 2023 20
  • 21. Sparkling Wine Forum | Reims – 20 June 2023 21 Mandatory: no lead nor cadmium can be present (Regolamento CE 1935/2004 - Direttiva 84/500 attuata con D.M. 4/4/85 e Direttiva 2005/31/CE attuata con D.M. 1/2/2007) Other elements such as Al, Si, Fe, Ca, Ti, Na, K could be allowed under certain concentrations, but they are not welcome Food grade certification
  • 22. Sparkling Wine Forum | Reims – 20 June 2023 22 THANK YOU!