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Fundamentals and Applications
of Bainitic Steels
Thermodynamics
Simulation of kinetics
“Superbainite”
Mechanical properties
Future
1 µm
upper
bainite
lower
bainite
Surface 1 Surface 2
Srinivasan & Wayman, 1968
50 µm
c
r
d
s
1
50 µm
UPPER BAINITE
(High Temperature)
LOWER BAINITE
(Low Temperature)
Carbon supersaturated plate
Carbon diffusion into
austenite
Carbon diffusion into
austenite and carbide
precipitation in ferrite
Carbide precipitation
from austenite
500
400
300
0
1
2
Temperature / °C
Decarburisation
time
/
s
Fe-0.4C wt%
Ae3'
T'
o
x
Carbon in austenite
Temperature
Growth is diffusionless.
Strain energy must be
accounted for.
UPPER BAINITE
(High Temperature)
LOWER BAINITE
(Low Temperature)
Carbon supersaturated plate
Carbon diffusion into
austenite
Carbon diffusion into
austenite and carbide
precipitation in ferrite
Carbide precipitation
from austenite
Takahashi and Bhadeshia
Oka and
Okamoto
Ohmori and
Honeycombe
Th
GN
Bhadeshia, 1981
Each point
represents a
different
steel
Nucleation
function GN
The nucleation of bainite
must involve the partitioning
of carbon
Why does the required free
energy vary linearly with T?
hexagonal close-packed cubic close-packed
Christian, 1951
Brooks, Loretto and Smallman, 1979
Olson & Cohen, 1976
Nucleation of bainite must involve
the partitioning of carbon.
Mechanism of nucleation is
otherwise identical to that of
martensite.
0
200
400
600
800
0 0.2 0.4 0.6 0.8 1 1.2 1.4
Carbon / wt%
Temperature
/
K Fe-2Si-3Mn-C wt%
BS
MS
1.E+00
1.E+04
1.E+08
0 0.5 1 1.5
Carbon / wt%
Time
/
s
Fe-2Si-3Mn-C wt%
1 month
1 year
wt%
Low transformation temperature
Bainitic hardenability
Reasonable transformation time
Elimination of cementite
Austenite grain size control
Avoidance of temper embrittlement
Time
1200 oC
2 days
1000 o
C
15 min
Isothermal
transformation
125 oC-
325 oC
hours-
months
slow
cooling
Air
cooling
Quench
Austenitisation
Homogenisation
200 Å
g
g
a
a
a
Caballero,
Mateo,
Bhadeshia
Low temperature transformation: 0.25 T/Tm
Fine microstructure: 20-40 nm thick plates
Harder than most martensites (710 HV)
Carbide-free
Designed using theory alone
200 Å
g
g
a
a
a
Very strong
Huge uniform ductility
No deformation
No rapid cooling
No residual stresses
Cheap
Uniform in very large sections
Hammond and Cross, 2004
Velocity km s-1
Stress
/
GPa
“more serious battlefield threats”
ballistic mass efficiency
consider unit area of armour
Caballero, Mateo,
Bhadeshia
Caballero, Mateo,
Bhadeshia
Sherif, 2005, Ph.D.
thesis, Cambridge
Above
percolation
threshold
Below
percolation
threshold
Geometrical percolation threshold of
overlapping ellipsoids
1 µm
0.4 C
2 Si
3 Mn
wt%
Very poor toughness!
50 µm
Fe-1C-1.5Si…… wt%
periodic cracking
stress transfer length
Chatterjee & Bhadeshia, 2005
Carbide-free alloys
wt %
0.4C-3Mn-2Si
0.4C-4Ni -2Si
0.2C-3Mn-2Si
Impact Energy
200
100
0
-100
-200
0
10
20
30
40
50
60
70
Test temperature / °C
Charpy
impact
/
J
Temperature / °C
1200
1000
800
600
400
200
0
Pearlite
Martensite
Bainite
kilocycles to Crack Initiation
Yates, Jerath
Yates, Jerath
U.K.

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