nitro methane is a polar compound plus it has nit.pdf

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nipuns1983

nitro methane is a polar compound plus it has nitrogen and oxygen atoms which can easily do hydrogen bonding with the hydrogen atoms of water. this greatly increases the solubility of this compound in water. Hope this will do..:) Solution nitro methane is a polar compound plus it has nitrogen and oxygen atoms which can easily do hydrogen bonding with the hydrogen atoms of water. this greatly increases the solubility of this compound in water. Hope this will do..:).

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Solution : This encryption scheme is not considered to be a secure one as the key used for encryption is very weak. It will be easy for Eve to crack the key and decrypt the message. The security provided here is very limited and it would not be possible for Alice to implement other elements of security to her encryption method. It would not be possible to add digital signatures to the encrypted message due to which it lacks repudiation. Authentication problem is also there with this weak encryption method. There is no surity of message integrity. Before reaching the destination it is possible that message gets modified to some extent or fully, of which the receiver or the sender will not be able to know. Sharing the key is also very dangerous as using any of electronic medium or magnetic medium is not safe. Due to insecure network the sender or the receiver may never know that the messages are being tapped. Sharing it in personal is only a safer method, but here distance and time becomes an obstacle in many cases. Alice used a method which have very limited security and thus insecure to send any message over the network. By modifying her method of encryption she could easily convert it into a healthy communication process.Strong keys will help her a lot and transferring it to the sender in a secure manner will add to it..

SolutionThis encryption scheme is not considered to be a secure o.pdf

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Smart Beta ia a rather elusive term in modern finance sometimes known as advanced beta,alternate beta or startegy indices.firstly theorized by Harry Markowitz , the first smart beta ETF was launched in 2003.A smart Beta ETF is a type of exchange-traded fund that uses alternative index construction rules instead of the typical cap-weighted index strategy, in a transparent way. It takes into account factors such as size, value and volatility. It utilizes both passive and active methods of investing ... passive because it follows an index, but active because it considers alternative factors. Smart Beta ETFs are ideal for investors hoping to maximize their income and returns and minimize risk. \"Smart\" refers to the use of an alternative methodology rather than following an index\'s size- based (market-cap) allocations.Its Evolution began with its namer\' Professional services firm Towers Watson .\"Smart beta strategies have seen huge inflows in recent years. According to ETF provider Invesco Powershares, from 2010 to 2017, Smart Beta ETFs took in more than 21% of U.S. equity ETF inflows, representing 12% of total ETF industry assets. Shifting On to the barriers for allocating smart beta in a investor`s portfolio investors have consistently reported that \"determining the best strategy or combination of strategies and managing unintended factor biases\" are the biggest concerns relating to implementation of a smart beta strategy.Finding the best variation is the issue of major concern for investors. Stating that excess returns mean extra risks for a smart beta strategy is not really a criticism of smart beta. Rather, it is a criticism of smart beta systems that claim to produce excess returns without assuming extra risks Smart beta is no different, regardless of how it is marketed. smart beta managers don\'t investigate the underlying economic logic behind performance, which can lead to problematic allocations.A smart beta construction is likely to be focused on past performance, because that is how factors are identified. Factors that show the strongest correlation with active management performance tend to be favored. That is as deep as the diagnosis goes with many smart beta mutual funds and exchange-traded funds (ETFs). One of the glorious things about market-cap-weighted indexes is that they\'re comparatively easy to run. Once you own all the stocks you want in their market weights, you generally don\'t need to touch the portfolio except to reinvest dividends, handle corporate actions and deal with index changes. Smart-beta strategies are holding securities in different weights, adjusting their portfolios to match their \"smart\" strategies, and often rebalancing regularly. All of that means that ETFs tracking smart-beta indexes often have a much more difficult time than their vanilla brethren. Apart from these short comings, investors need to have a deep insight of these matters while adding advanced beta to their portfolios. 1.. Not all s.

Smart Beta ia a rather elusive term in modern finance sometimes know.pdf

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Ques-1: What is the differential diagnosis of this patients infecting organism? Germ Tube Test is a screening diagnostic test. The differential diagnosis of this patient is obtain some urine samples for laboratory cultures in carbohydrate medium as \"pathogenic organism can reproduce by budding\" means it is \"pathogenic fungi\" infected at the surgical region of cervix. Therefore, it will produce germ tube with fungal spores upon cell cultures & culture will produce \"yellow precipitate\" when examined with I2-KI & NaOH (iodoform test) due to alcohol formation as a metabolic byproduct. The morphology of diagnostic samples with infected pathogen can be observed under the microscope. Ques-2. The organism was subsequently shown to form germ tubes. What is the organism? The organism was subsequently shown to form germ tubes depicting that the infected pathogen is “Candida albicans\", a fungal pathogen Ques-3. Is this organism part of the normal flora in humans? Yes, this species in humans mainly located normal commensual in the regions of mouth, gut and vagina. However, in the above surgical procedures of cervix, transition of the organism has occurred from commensalism to virulence by germ tube formation with hyperthermia (increased temperature). Solution Ques-1: What is the differential diagnosis of this patients infecting organism? Germ Tube Test is a screening diagnostic test. The differential diagnosis of this patient is obtain some urine samples for laboratory cultures in carbohydrate medium as \"pathogenic organism can reproduce by budding\" means it is \"pathogenic fungi\" infected at the surgical region of cervix. Therefore, it will produce germ tube with fungal spores upon cell cultures & culture will produce \"yellow precipitate\" when examined with I2-KI & NaOH (iodoform test) due to alcohol formation as a metabolic byproduct. The morphology of diagnostic samples with infected pathogen can be observed under the microscope. Ques-2. The organism was subsequently shown to form germ tubes. What is the organism? The organism was subsequently shown to form germ tubes depicting that the infected pathogen is “Candida albicans\", a fungal pathogen Ques-3. Is this organism part of the normal flora in humans? Yes, this species in humans mainly located normal commensual in the regions of mouth, gut and vagina. However, in the above surgical procedures of cervix, transition of the organism has occurred from commensalism to virulence by germ tube formation with hyperthermia (increased temperature)..

Ques-1 What is the differential diagnosis of this patients infectin.pdf

nipuns1983

package employeeType.employee; public abstract class Employee { private String firstName; private String lastName; private char middleInitial; private boolean fulltime; private char gender; private int employeeNum; public Employee(String firstName, String lastName, char middleInitial, char gender, int employeeNum, boolean fulltime) { super(); this.firstName = firstName; this.lastName = lastName; this.middleInitial = middleInitial; this.fulltime = fulltime; this.gender = gender; this.employeeNum = employeeNum; } public int getEmployeeNumber() { return this.employeeNum; } public void setEmployeeNumber(int empNum) { this.employeeNum = empNum; } public String getFirstName() { return firstName; } String getLastName() { return lastName; } char getMiddleInitial() { return middleInitial; } public char getGender() { return gender; } public void setFirstName(String fn) { this.firstName = fn; } public void setLastName(String ln) { this.lastName = ln; } public void setMiddleI(char m) { this.middleInitial = m; } public void setGender(char g) { this.gender = g; } public boolean equals(Object obj) { // TODO Auto-generated method stub if (obj instanceof Employee) { Employee employee = (Employee) obj; if (employee.getEmployeeNumber() == this.getEmployeeNumber()) return true; else return false; } else return false; } public String toString() { // TODO Auto-generated method stub return getEmployeeNumber() + \"\ \" + getFirstName() + \" \" + getLastName() + \"\ Gender:\" + getGender() + \"\ Status:\" + ((fulltime) ? \"Full Time\" : \"Part Time\"); } public abstract double calculateWeeklyPay(); public abstract void annualRaise(); public abstract double holidayBonus(); public abstract void resetWeek(); } package employeeType.subTypes; import java.text.DecimalFormat; import employeeType.employee.Employee; public class HourlyEmployee extends Employee { private double wage; private double hoursWorked; public HourlyEmployee(String firstName, String lastName, char middleInitial, char gender, int employeeNum, boolean fulltime, double wage) { super(firstName, lastName, middleInitial, gender, employeeNum, fulltime); // TODO Auto-generated constructor stub this.wage = wage; this.hoursWorked = 0.0d; } public void increaseHours(double hours) { if (hours > 0) this.hoursWorked += hours; else System.out.println(\"Error! Invalid hours\"); } public String toString() { // TODO Auto-generated method stub return super.toString() + \"\ Wage: \" + wage + \"\ Hours Worked: \" + hoursWorked; } public double calculateWeeklyPay() { double pay; if (hoursWorked > 40) { pay = (40 * wage) + (2 * (hoursWorked - 40) * wage); } else { pay = wage * hoursWorked; } return pay; } public void annualRaise() { DecimalFormat decimalFormat = new DecimalFormat(\"#.##\"); wage = Double.valueOf(decimalFormat.format(wage * 0.05)); } public double holidayBonus() { return 40 * wage; } public void resetWeek() { this.hoursWorked = 0; } } package employeeType.subTypes; import java.text.DecimalFormat; import emplo.

package employeeType.employee;public abstract class Employee { .pdf

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Option 1Project management software Project management software .pdf

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import java.util.Scanner; public class InputIntegers { public static void main(String args[]) { Scanner s=new Scanner(System.in); System.out.println(\"enter n :\"); int n=s.nextInt(); int a[]=new int[n]; System.out.println(\"enter n integers :\"); for(int i=0;i Solution import java.util.Scanner; public class InputIntegers { public static void main(String args[]) { Scanner s=new Scanner(System.in); System.out.println(\"enter n :\"); int n=s.nextInt(); int a[]=new int[n]; System.out.println(\"enter n integers :\"); for(int i=0;i.

import java.util.Scanner;public class InputIntegers{public sta.pdf

nipuns1983

The main drawback of Trouton\'s rule is that it is not applied for the liquids that contains \"hydrogen bonding\" . In the given molecules HF and CH3OH both have the hydrogen bonding in their solutions. Therefore - Toulene (C6H5CH3) only contains the value that is closely related to Troutons value. Hence answer is C6H5CH2 Solution The main drawback of Trouton\'s rule is that it is not applied for the liquids that contains \"hydrogen bonding\" . In the given molecules HF and CH3OH both have the hydrogen bonding in their solutions. Therefore - Toulene (C6H5CH3) only contains the value that is closely related to Troutons value. Hence answer is C6H5CH2.

The main drawback of Troutons rule is that it i.pdf

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Solid to liquid, or liquid to gas change absorbs .pdf

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RNase P catalyzes the Mg2+-dependent 5\'-maturation of precursor tRNAs. Biochemical studies on the bacterial holoenzyme, composed of one catalytic RNase P RNA (RPR) and one RNase P protein (RPP), have helped understand the pleiotropic roles (including substrate/Mg2+ binding) by which a protein could facilitate RNA catalysis. As a model for uncovering the functional coordination among multiple proteins that aid an RNA catalyst, we use archaeal RNase P, which comprises one catalytic RPR and at least four RPPs. Exploiting our previous finding that these archaeal RPPs function as two binary RPP complexes (POP5•RPP30 and RPP21•RPP29), we prepared recombinant RPP pairs from three archaea and established interchangeability of subunits through homologous/heterologous assemblies. Our finding that archaeal POP5•RPP30 reconstituted with bacterial and organellar RPRs suggests functional overlap of this binary complex with the bacterial RPP and highlights their shared recognition of a phylogenetically-conserved RPR catalytic core, whose minimal attributes we further defined through deletion mutagenesis. Moreover, single-turnover kinetic studies revealed that while POP5•RPP30 is solely responsible for enhancing the RPR’s rate of precursor tRNA cleavage (by 60-fold), RPP21•RPP29 contributes to increased substrate affinity (by 16-fold). Collectively, these studies provide new perspectives on the functioning and evolution of an ancient, catalytic ribonucleoprotein. INTRODUCTION RNase P, a ribonucleoprotein (RNP), is the endoribonuclease that catalyzes the removal of 5\'-leaders in precursor tRNAs (pre-tRNAs) in all three domains of life (1–4). The bacterial variant is composed of 1 catalytic RNase P RNA (RPR) and 1 RNase P protein (RPP) cofactor. Eukaryal (nuclear) RNase P from yeast and human contain 1 RPR with 9 and 10 RPPs, respectively. Intermediate in complexity, the archaeal holoenzyme is associated with 1 RPR and at least 4 RPPs (POP5, RPP30, RPP21 and RPP29), which are homologous to eukaryal RPPs. Several years after the remarkable finding that the bacterial RPR is a true RNA enzyme in the presence of Mg2+ and monovalent ions (5), archaeal and eukaryal RPRs were also shown to be catalytically active in vitro (6,7). This common attribute of evolutionarily divergent RPRs was anticipated from their shared ancestry, attested by sequence and structural similarity of their putative catalytic core (8–15). However, dramatic variations (106-fold) in catalytic potential indicate that not all RPRs are equal: activity of RPRs from bacteria?>?archaea?>?eukarya (5–7). Although RPRs display activity in vitro without RPPs, they are dependent on their cognate protein cofactors for cellular function. Interestingly, there is an inverse relationship between RPR activity and RNP composition—the protein:RNA mass ratio is 70% in eukaryal and 50% in archaeal RNase P compared to 10% in their bacterial counterpart. Thus, elucidating the intimate cooperation between the RNA and.

RNase P catalyzes the Mg2+-dependent 5-maturati.pdf

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pH of a solution is directly proportional to mola.pdf

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Option - D is correct !! .pdf

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n = number present before orbital =3 l= 0 for s, .pdf

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Molar solubility = moles of solute volume of so.pdf

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ionic bonds .pdf

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in the equation E=Eo-RTln(M) since u r getting -0.pdf

nipuns1983

Hückel Theory This theory was originally introduced to permit qualitative study of the p-electron systems in planar, conjugated hydrocarbon molecules (i.e. in \"flat\" hydrocarbon molecules which possess a mirror plane of symmetry containing all the carbon atoms, and in which the atoms of the carbon skeleton are linked by alternating double and single carbon-carbon bonds when the bonding is represented in a localised fashion). It is thus most appropriate for molecules such as benzene or butadiene, but the approach and concepts have wider applicability. Basic Assumptions 1. the atomic orbitals contributing to the p-bonding in a planar molecule (e.g. the so-called pp orbitals in a molecule such as benzene) are antisymmetric with respect to reflection in the molecular plane; they are therefore of a different symmetry to the atomic orbitals contributing to the s-bonding and may be treated independently. 2. the Coulomb integrals for all the carbon atoms are assumed to be identical. i.e. small differences in a-values due to the different chemical environment of C atoms in a molecule such as are neglected. 3. all resonance integrals between directly-bonded atoms are assumed to be the same; whilst those between atoms that are not directly bonded are neglected. i.e. ?f Hf dt i j . ˆ = ß : if atoms i and j are directly s-bonded. = 0 : if atoms i and j are non-bonded. 4. all overlap integrals representing the overlap of atomic orbitals centred on different atoms are neglected. i.e. ?f f dt i j . = 0 : if i ? j (note - if i = j then ?f f dt i j . = 1 since it is assumed that the atomic orbitals are normalized) Mirror plane (of molecule) pp orbital s or ps orbital6.2 A Closer Look at the Secular Determinant The basic form of the secular determinant for the bonding arising from the overlap of two orbitals (from 4.9) is reproduced below. 12 2 1 12 E E - - ß a a ß For three overlapping orbitals the approach outlined in Chapter 4 leads to a secular determinant of the form: E E E - - - 13 23 3 12 2 23 1 12 13 ß ß a ß a ß a ß ß From a comparison of the two secular determinants given above, it is becoming clear that all such secular determinants have a characteristic structure: 1. each row and column may be associated with one of the atomic orbitals; thus the first row and first column contain information about the nature of orbital 1 and its interactions with the other orbitals, the second row and second column contain information about the nature of orbital 2 and its interactions with the other orbitals. 2. The diagonal set of elements (comprised of those elements where row 1 intersects column 1, row 2 intersects column 2, ….. and so on) include the values of the relevant Coulomb integrals (a1 , a2 etc.). 3. The off-diagonal elements (comprised of those elements having different row numbers and column numbers) are equal to the relevant resonance integrals (e.g. ß12 at the intersection of row 1 and column 2) This structure is summarised below, where the rows an.

Hückel Theory This theory was originally introduc.pdf

nipuns1983

Experimenters had noticed that sparks travel through rarefied (i.e. low pressure) air since the time of Franklin. The basic setup was to have two metal plates inside a glass tube. The air was removed from the glass container with a pump. One plate (called the cathode) was connected to the negative side of an electrical supply and the other (called the anode) was connected to the positive side of the electrical supply. As pump technology improved, the appearance of the “spark” within the tube changed. A jumpy purplish stream replaced the spark, and in the 1830s Faraday noticed that a dark spot opened up in the beam near the cathode. By 1870, pump technology had improved considerably and the dark spot had expanded to fill the entire tube and experimentalists noticed that the glass glowed where the “cathode rays” (as they were being called at that time) hit the glass. In the last half of the 19th century, scientists did many experiments with cathode ray tubes and tried to use the results to determine the nature of cathode rays. In 1879, Sir William Crookes demonstrated that cathode rays travel in straight lines by using the tube shown at the right. Crookes also demonstrated that magnetic fields could deflect cathode rays. He found that the properties of cathode rays did not depend on the metal used to make the cathode and anode. According to Crookes, the current in the tube consisted of negatively charged gas molecules repelled from the cathode and traveling to the anode. Heinrich Hertz, a leading German experimentalist, tried to deflect cathode rays with an electric field, but was not able to do so. Since he knew that charged particles are deflected by electric fields, Hertz concluded that cathode rays were not charged particles, but waves that could be deflected with magnetic fields. In 1894, J.J. Thomson, an English physicist, began a series of experiments that would resolve the controversy about cathode rays and lead to the discovery of the first subatomic particle. By constructing a cathode ray tube with the deflector plates inside the glass tube (at right), Thomson discovered --in direct contradiction with Hertz-- that cathode rays could be deflected by an electric field. Thomson’s tube design allowed him to determine the ratio of the cathode ray particle’s charge to its mass. The clever experiment exploits two ideas that were known about the interaction between electromagnetic fields and charged particles: Use the below link for clear diagrammatic explanation http://www.dartmouth.edu/~phys1/labs/lab3.pdf Solution Experimenters had noticed that sparks travel through rarefied (i.e. low pressure) air since the time of Franklin. The basic setup was to have two metal plates inside a glass tube. The air was removed from the glass container with a pump. One plate (called the cathode) was connected to the negative side of an electrical supply and the other (called the anode) was connected to the positive side of the electrical supply. As pump tec.

Experimenters had noticed that sparks travel thro.pdf

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Density = PMRT = 0.4168.314112 = 0.007 gml .pdf

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D.) Solu.pdf

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