Adhesion is one of the significant parameter which leads to mechanical wear. This presemntation gives brief information about adhesion, molecular interaction between two mating surfaces and factors affecting adhesion. Study of interfacial forces between mating surfaces helps in selection of surface materials to prevent adhesion. Failure of lubricant’s basic function relates to failure of separation of two surfaces which results in adhesion between sliding surfaces. Adhesion is not observed between two surfaces casually placed together due to existing oxide film and contaminants. Surface energy, reduced roughness, high hardness can depress adhesion.
2. Contents
1. Introduction
2. Mechanism of Adhesion
3. Friction Due to Adhesion
4. Formation of wear particles
5. Reducing adhesion
6. Example: Mechanical Seal
7. Conclusion
8. Reference
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3. 1. Introduction
Definition: The state in
which two surfaces are
held together by
interfacial forces which
consist of valence forces
or interlocking actions
or both.
ASTM Definition of Term Relating to Adhesion D907-70, ASTM, Philadelphia, PA, 1970. Advanced Techniques for
Surface Engineering
Figure 1: Relative bond strengths for a range of potential
interfacial binding forces.
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4. 2. Mechanism of Adhesion
Energy of adhesion
– energy necessary
to separate 1cm2 of
interface
Hexagonal close
packed
The highest
adhesion occurs
between identical
metals
FIGURE 2 Adhesion coefficient of various metals versus hardness
M.E. Sikorski, Correlation of the Coefficient of Adhesion With Various Physical and Mechanical Properties of Metals,
Transactions ASME, Series D - Journal of Basic Engineering, Vol. 85, 1963, pp. 279-285.4
5. 3. Friction Due to Adhesion
FIGURE 3 Schematic diagram of the apparatus for FIGURE 4 Effect of oxygen on the friction
measurements of friction in a vacuum of clean iron
J.S. McFarlane and D. Tabor, Relation Between Friction and Adhesion, Proc. Roy. Soc., London,
Series A, Vol. 202, 1950, pp. 244-253.5
6. 4. Formation of wear particles
Tangential Shear under
compression
Formation of shear band
Koji Kato & Koshi Adachi , Modern Tribology Handbook, Tokohu University, Chapter 7
FIGURE 5: Experimental apparatus to study adhesive wear
processes
FIGURE 6 Deformation in adhesive asperity contact FIGURE 7 Formation of an adhesive transfer particle
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7. 5. Reducing adhesion
Increasing Hardness[hardness
is most dominant parameter]
Combination of dissimilar
materials
Surface roughness
Use of lubricant
Material with high melting
point
To limit the size of contact
Risk of disappearance of
natural oxide layers
FIGURE 9 Surface roughness comparison
FIGURE 8 Dendrites of zinc electrodeposited onto a zinc surface
David E Pakham,Ch 2, Theories of Fundamental Adhesion, Handbook of Adhesion Technology, Vol 2, Springer
Publication, Pg 22-23
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8. 6. Example: Mechanical Seal
Mechanical Seal
FIGURE 10 Centrifugal pump FIGURE 11 Mechanical Seal major components
FIGURE 12 Mechanical Seal Faces FIGURE 13 Metal to metal adhesion
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9. Material Properties for seal faces
Michael Huebner, Material Selection for Mechanical Seal, Flowserve corporation, Deer Park, Texas.
FIGURE 14 Material comparison for mechanical seal faces
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10. 7. Conclusion
All materials has the tendency to adhere when brought into
close contact. Contaminants and lubricants can reduce the
tendency to adhere but adhesion can never be entirely
eliminated. Adhesion is the root cause of failure between
metal sliding.
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11. 8. Reference
Gwidon W. Stachowiak and Andrew W. Batchelor, Engineering Tribology,
Butterworth Heinmann Publication, Pg 533-550.
HEF Groupe, Handbook of Surface Treatments and coatings.
W. Gissler and H. A. Jehn, Advanced Techniques for Surface Engineering, Kluwer
Academic Publishers, Vol 1, Pg 31-41.
M.E. Sikorski, Correlation of the Coefficient of Adhesion With Various Physical and
Mechanical Properties of Metals, Transactions ASME, Series D - Journal of Basic
Engineering, Vol. 85, 1963, pp. 279-285.
J.S. McFarlane and D. Tabor, Relation Between Friction and Adhesion, Proc. Roy.
Soc., London, Series A, Vol. 202, 1950, pp. 244-253.
Koji Kato & Koshi Adachi , Modern Tribology Handbook, Tokohu University,
Chapter 7
David E Pakham,Ch 2, Theories of Fundamental Adhesion, Handbook of Adhesion
Technology, Vol 2, Springer Publication, Pg 22-23
Michael Huebner, Material Selection for Mechanical Seal, Flowserve corporation,
Deer Park, Texas.
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