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General Idea of ETP
Know Basic Words.
BY- KANHAYA LAL KUMAWAT
2
1) Effluent in Different
processes
2) Basic terms used in waste water
treatment
3) Definition / Impact on
Environment
4) How to Reduce it
Contents
Sections of ETP
3
Preliminary Treatment
Primary Treatment
Biological Treatment
Tertiary Treatment
Advance Treatment
(Advance Filtration, Advance oxidation)
Effluent in Processing Unit
4
Desizing
Sizes (starch),
enzymes, waxes
Scouring
NaOH, surfactants,
soaps, fats, waxes
water softeners
FinishingDyeing
Colour, metals, salts,
surfactants, sulphide,
acidity/alkalinity,
formaldehyde , water
softeners
Printing
Urea, solvents,
colour, metals
Bleaching/Mercerisation
H2O2, AOX, organic stabiliser,
NaOH & high pH
Resins, waxes, chlorinated
solvents, spent
solvents, softeners
Let us know the terms used in effluent treatment
BASIC TERMS IN ETP
5
pH
• Measure of acidity or alkalinity
MLSS
• Mixed Liquor Suspended solids
MLVSS
• Mixed Liquor Volatile Suspended Solids
BASIC TERMS IN ETP
6
DO
• Dissolved Oxygen in water
COD
• Oxygen required to oxidise organic material by
chemical means in waste water
BOD
• Oxygen required to oxidise organic material by
biological means in waste water
BASIC TERMS IN ETP
7
Treatability study
• It is a study or test that tells us how the
wastewater might be treated.
Retention Time
• It is a measure at an average length
of time holding the wastewater in a tank.
Grab sample
• It is a sampling method in which a
single sample is taken at a specific time
BASIC TERMS IN ETP
8
Composite Sample
• It is a collection of several individual
samples taken at regular intervals over a period
of time, usually 24 hours. & combined testing is
done
Bio Mass
• It is a colony of living Bacteria, which digest
many organic and inorganic substances. An
essential part of the ecosystem including within
human beings
BASIC TERMS IN ETP
9
Activated Sludge
• Sludge that has undergone flocculation forming a
bacterial culture typically carried out in tanks.
Can be extended with aeration.
Clarifier
• A section of ETP equipment used to "clarify" the
wastewater, It is a holding tank that allows
settling. Used when solids have a specific gravity
greater than 1.00
BASIC TERMS IN ETP
10
Anaerobic Digester
• The breaking down of organic material and other
waste biologically by microorganisms in absence
of Oxygen. Results in by-products such as
methane gas, carbon dioxide, sludge solids and
water
Grit Chamber
• Usually in ETP, a chamber or tank in which
primary influent is slowed down so heavy
typically inorganic solids can drop out, such as
metals and plastics.
BASIC TERMS IN ETP
11
Flocculation
• The process whereby a chemical or other
substance is added to wastewater to trap or
attract the particulate suspended solids into
clusters -woolly looking mass
Sludge
• The solid waste material which settles out in the
wastewater treatment process, sometimes
biosolids. Can be dewatered and reused or
disposed.
pH
12
In chemistry, pH is the measure of acidity or alkalinity of
an aqueous solution.
The pH is equal to − log10 C, where c is the hydrogen ion
concentration in moles/ltr.
Solutions with pH less than 7 are acidic whereas above 7
are alkaline. pH of 7 is termed as neutral.
Impact of pH value
13
 Affects the aquatic life if the pH is not in 6-9 range.
 The bacteria involved in biological treatment will
not perform effectively outside 6-9 pH range.
 When pH is not neutral it increases the
consumption of chemicals for coagulation and
flocculation.
How To Control pH value
14
 Maintain pH as desired by dosing acid/alkali
 Use Dilute Sulphuric Acid if the pH is alkaline
 Use Lime if the pH is acidic.
TDS - Total Dissolved Solids
15
In textiles,
generally common
salt increases TDS
of water and
harmful to aquatic
life.
It also affects the
fertility of soil.
Fertile
land
Non
Fertile
land
Mixed Liquor Suspended Solids (MLSS)
16
 Mixed liquor is a combination of raw or unsettled
wastewater or pre-settled wastewater and activated
sludge within an aeration tank.
 Mixed liquor suspended solids (MLSS) is the
concentration of suspended solids, in an aeration
tank during the activated sludge process, which
occurs during the treatment of waste water. ...
MLSS - Mixed Liquor Suspended Solids
17
• The activity of bio mass
is measured by MLSS &
should be maintained
approximate 30% by
volume.
How to maintain MLSS
18
 MLSS should be maintained in 30% range.
 MLSS > 30% : Reduce and Dispose the sludge.
 MLSS < 30% : Grow biomass, feed concentrated active
mass from Secondary Clarifier
 Frequency of the test analysis : Once in a Day.
 MLSS can depend upon effluent quality, Health of Bio-
mass & Retention time.
 Take liquor, filter & dry at 105 °C & find Suspended
solids
Mixed Liquor Volatile Suspended Solids
(MLVSS)
19
 MLVSS is generally defined as the microbiological
suspension in the aeration tank of an activated-
sludge biological wastewater treatment plant.
 The biomass solids in a biological waste water
reactor are usually indicated as total suspended
solids (TSS) and volatile (at 550°C for 30 min.)
suspended solids (VSS).
 MLSS is used to indicate the concentration of
suspended solids in activated sludge. MLVSS
represents the concentration of biomass in activated
sludge.
MLVSS
20
 MLVSS should be maintained between 60% to 70%
of MLSS
 Frequency of the test analysis : Once in a Day
Chemical Oxygen Demand (COD)
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 Definition
 Chemical oxygen demand (COD) is a measure of
the capacity of sample to consume oxygen during
the decomposition of organic matter and the
oxidation of inorganic chemicals.
Impact of COD
22
 Higher COD values affect land fertility.
 Higher COD level will reduce DO levels.
 Which affects the aquatic life.
 Higher COD gives higher TDS
 Sunlight cannot reach the below levels of sea water which
affects the aquatic plants.
COD : Chemical Oxygen Demand
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Organic pollutant
Inorganic pollutant
Reducing chemicals
Definition:- Amount of oxygen needed to oxidize organic
and inorganic materials in a waste water effluent
mg/L
How to reduce COD
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 Optimisation of Process.
 Recover and reuse of the chemical.
 Coagulation and flocculation process.
 Biological treatment.
 Tertiary treatment.
Biochemical Oxygen Demand (BOD)
25
Definition:
• Biochemical oxygen demand (BOD) is a measure of
the amount of oxygen that bacteria will consume for
decomposition of organic material and oxidation of
inorganic material under aerobic conditions.
BOD - Biological Oxygen Demand
26
Organic pollutant
Inorganic pollutant
Microbes
Definition:- Amount of dissolved oxygen needed by
bacteria in ETP to break down organic material
present in the Effluent
If BOD level in effluent is not controlled, the rate of Oxygen
consumption > Oxygen replenishment from the atmosphere, thus
affecting the marine species in the water-body where the
effluent is discharged.
How to control BOD
27
 Use Biodegradable chemicals in the process
 If Non-Biodegradable
Reduce, Recover & Reuse
Focus on Primary Treatment To reduce Load
Advanced Oxidation/H2O2 Oxidation
Biological treatment
Dissolved Oxygen (DO)
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 It is the amount of oxygen
present in water.
 DO is measured in ppm
 DO levels can be increased
by surface aerators or
diffusion technique.
Desired DO levels for fish to
remain healthy & alive is >3
ppm
Impact of DO on Aquatic Life
29
 Desired DO levels for fish to remain healthy & alive is
>3 ppm
 When BOD levels are high, dissolved oxygen (DO)
levels decrease because the bacteria are consuming
the oxygen that is available in the water. Since less
dissolved oxygen is available in the water, fish and
other aquatic organisms may not survive.
How to maintain DO
30
 Maintain BOD level.
 Aeration of water.
 Maintain the Temperature.
 Remove dead bio-mass as Bio-sludge.
Treatability Study
31
It is a study or test that tells us how the wastewater might
be treated with some of the following tests:
pH
Colour
Odour
Chemical Oxygen Demand
Biochemical Oxygen Demand
Total Dissolved Solids
Total Suspended Solids
It also gives
The performance of treatment in ETP
Efficiency of dosing
Retention time
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It is a measure at an average length of time holding
the wastewater in a tank.
• Primary Collection tank
• Flash mixing
• Flocculation
• Clarifier
• Aeration tank
Grab Sample, Composite Sample
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It is a sampling method in which a single sample is taken at a
specific time.
It is a collection of several individual samples taken at regular
intervals over a period of time, usually 24 hours. &
combined testing is done
Effluent Treatment Plant
34
ETP (Effluent Treatment Plant) is a process design
for treating the industrial waste water for its
reuse or safe disposal to the environment.
 Influent: Untreated industrial waste water.
 Effluent: Treated industrial waste water.
 Sludge: Solid part separated from waste water
by ETP.
1)
Quality Requirements of Effluent
Contents
35
Parameters for
Dyehouse
Untreated
waste water
Treated
waste water
pH 4.0 to 9.5 6 to 9
Colour Dark, offensive
No Colour,
not offensive
Foam Persistent
No foam or
dissipates
Heavy metals 10 to 15 ppm 0.01 to 1.5 ppm
Suspended solids 200 to 300 ppm 30 To 45 ppm
Total Dissolved Solids 3500 to 6000 ppm 2100 ppm
Chemical Oxygen Demand 900 to 1500 ppm 250 ppm
Biochemical Oxygen Demand 300 to 500 ppm 30 ppm
36
Quality requirements of effluent
36
One must follow the discharge norms as per Consent to operate issued by SPCB
2
Various Processes used in ETP
Content
37
Physical Chemical Biological Physico-
chemical
Sedimentation Neutralization Stabilization ponds Coagulation
Filtration reduction Aerated lagoons Reverse Osmosis
Oil removal Oxidation Trickling filters Solvent extraction
Ionizing radiation Catalysis Activated sludge Electrolysis
Adsorption Ion Exchange Anaerobic digestion Foam fractionation
Classification of methods of
Effluent treatment
38
Treatment Levels &
Mechanisms involved
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 Preliminary (Physical Separation)
 Primary (Physical & Chemical method used )
 Secondary (Biological)
 Tertiary /Advanced (Physical & Chemical)
Preliminary Treatment
40
Solid Waste
Removal
Rags
Floatables Grit & grease
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Preliminary Treatment
Screening-
Removal of large particles.
Screens- opening with uniform size
 Screen element- parallel bars,
rods, grating or wire meshes or
perforated plates
Requires periodic cleaning
Set in channel at 600
•Removal of wastewater constituents such as rags, suspended
and floatable yarns, fibres.
•Removes 20-30% solids
Screening Unit
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Preliminary Treatment
Sedimentation
Use of gravity as settlable solids separate out as a watery sludge.
Flotation
 Suitable for low-density solids
 Facilitates separation of suspended matter from the waste
liquor and isolation of the sludge
The waste flow is pressurized ( 3 – 5 bar) in the presence of air
The pressurized waste flow is passed into the flotation unit
 Minute air bubbles are formed; simultaneously sludge flocs and
suspended matter floats which can be skimmed off.
42
Grit Chamber
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Usually in ETP, a chamber or tank in which primary influent
is slowed down so heavy typically inorganic solids can drop
out, such as metals and plastics.
Flocculation
45
The process whereby a chemical or other substance is added
to wastewater to trap or attract the particulate suspended
solids into clusters -woolly looking mass
46
Primary Treatment
Removal of part of suspended solids and organic matters from
wastewater treatment.
Equalization-
Application- Temporary storage of effluent to equalize flow rates,
mass loading of BOD and suspended solids
Advantage- shock loadings are eliminated
Device- Equalization tank
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Primary Treatment
Chemical neutralization-
 Removal of excess of acidity or alkalinity using suitable
chemical.
 Polyester processing generates acidic effluent
 Cotton processing generates alkaline effluent.
pH adjustment –
Alkaline waste water is neutralized with dil. Sulphuric acid
Acidic waste water is neutralized with NaOH and Lime.
Lime is more cheaper than NaOH.
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Coagulation
• A reasonable and economical method of lowering BOD and COD
and of reducing colour.
• The contaminants are in colloidal form having particle size in the
range of 10-7 to 10-9 m.
• The stability of non-gelatinous colloid is primarily due to
electrostatic forces.
• The degree of stability can be determined by measuring zeta
potential.
48
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Coagulation
 Coagulants are used to reduce the zeta potential thereby
facilitate aggregation of particles
 Lime, aluminum sulfate, iron(III) chloride are the most popular
coagulants
 Aids to coagulant include silica and polyelectrolyte
Concerns:
 Coagulation process is time consuming, tests are necessary to
optimize the coagulant concentration
 Coagulation process produces large amount of sludge.
 Running costs are high
49
 It uses chemical precipitation to cause separation
 The solids in the waste adhere to the coagulant particles and the
resulting bulky gelatinous material, known as floc, can be
removed by direct filtration, sedimentation or flotation.
 Coagulation results due to lowering of the zeta potential at the
particle surface to permit closer approach followed by
association of the particles to form larger flocculated
agglomerates.
 Lime, either alone or with ferric salts is the most popular
coagulant. It is often able to remove 90% of the colour present.
Flocculation
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Coagulation and Flocculation
Steps-
• Addition of coagulant with flash mixing
•Charge particle come closer to form clump
•Large particles removed by gravity sedimentation
•Device- Flash mixer, Flocculator, Primary Clarifier
51
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In primary treatment,
Color, colloidal, suspended and settling solids are removed
For getting better results, the reaction time during each process should
be maintained. (This time is known as Retention time)
Reaction of chemicals with effluent - 60 to 90 sec
Flocks generation - 5 to 10 minutes
Retention time in Primary Clarifier : 240 min
During primary treatment,
BOD and COD reduction: 45 to 65 %
Primary Treatment
52
Clarifier
53
• A section of ETP to "clarify" the wastewater.
• It is a holding tank, that allows settling & removes
solids from bottom having specific gravity greater
than 1.00 .
• It also removes solids have Specific gravity lesser
than 1.00 from top by scrubber.
• Solids from Top & bottom are transferred to Sludge
tank or recycled back to aeration tank.Conventional Clarifier
Slanting
plate
Clarifier
Anaerobic Digester
54
• The breaking down of organic material and other
waste biologically by micro-organisms in absence
of Oxygen.
• Results in by-products such as methane gas,
carbon dioxide, sludge solids and water
Anaerobic
Treatment
55
Aeration tank
TRICKLING FILTRATIONOXIDATION DITCH / POND
ANAEROBIC
DIGESTER
Aerobic Treatment
Secondary Treatment
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Secondary Treatment
 Removal of biodegradable organic matter and suspended
solids.
 Soluble organic matter converted to simple substances by
microorganisms.
Org.C+O2 CO2
Org.H+O2 H2O
Org.N+O2 NO2
-
Org.S+O2 SO2
Org.P+O2 PO4
2-
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Secondary Treatment Important points
Aerobic Treatment-
 Oxidative continuous reaction
 Reaction depend on,
 Microbial population
 Oxygen availability
 Nutrients
Anaerobic Treatment
 Reductive reaction
 Absence of oxygen
57
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Aerated Lagoon
 Earthen basin provided with mechanical aerators.
 Longer residence time require to achieve same effluent quality.
 Microorganisms are more resistant than ASP.
 Settling tank and sludge recirculation absent.
Types of Aerated Lagoon
 Suspended growth aerated Lagoon- Fully aerobic from top to
bottom
 Facultative aerated lagoon- lower part anaerobic, upper part
aerobic
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Membrane Biological Reactor
Biological reactor with suspended biomass
Solid separation by membrane (pore size 0.1µm -0.4µm)
59
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Attached Growth Processes
 Microorganisms attached to inert packing material- biofilm.
 Packing material – rock, gravel, plastic and other synthetic
material
 Operated as aerobic or anaerobic processes.
 Commonly used in Trickling Filter
Rotating Biological Contactor
60
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Attached Growth Processes
61
Trickling Filter Rotating Biological Contactor
Biomass
62
It is a colony of living Bacteria, which digest many organic
and inorganic substances. An essential part of the
ecosystem including within human beings
Activated Sludge
63
• Sludge that has undergone flocculation forming a
bacterial culture typically carried out in tanks.
• Can be extended with aeration.
64
Activated Sludge Process
 Production of activated mass of microorganisms capable of
stabilizing waste under aerobic condition.
 Aerobic condition is achieved by using surface aerators or
diffused aeration system
64
Sludge
65
• The solid waste material which settles out in the wastewater
treatment process,
• Sometimes bio-solids can be dewatered and reused or
disposed.
• These solid waste may contain hazardous pollutants & may
be harmful. It must be disposed as per regulatory
guidelines .
Sludge Treatment and Disposal
66
Sludge filter press
Sludge separated for discharge
Sludge dewateringSludge drying beds
Sludge disposal area
66
Summary - ETP-Process
67
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Anaerobic Lagoon
 Suspended growth anaerobic processes
 Treatment of high strength organic wastewaters and high quantity
of solids
 Employed in textile wastewater treatment.
 Degradation of organic matter by anaerobic bacteria, in two
stages, involves
 First Stage- nonmethanogenic bacteria- hydrolyze wastes in
short chain organic compounds, organic acids and ammonia
 Second Stage- methanogenic bacteria involves conversion of
intermediate products in to methane and carbon dioxide.
68
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Up flow Anaerobic sludge blanket
69
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 Wastewater enters from bottom and flow upward.
 Microorganisms in sludge layer degrade organic compounds.
 Methane and CO2 released
 Clarified effluent is extracted from top.
 Methane gas collected in gas collection dome
 Up flow velocity maintained- 0.6 to 0.9m/s
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Oxidation Techniques
Electro chemical Oxidation
PROCESS
Activated carbon UV peroxide / NaOCl
Various
Techniques used
To be selected
depending upon
effluent
characteristics after
secondary treatment
Tertiary treatment
71
Adsorption
 The adsorption process is used to removes colour and other
soluble organic pollutants from effluent.
 The process also removes toxic chemicals such as pesticides,
phenols, cyanides and organic dyes
 Dissolved organics are adsorbed on surface as waste water
containing these is made to pass through adsorbent.
 Most commonly used adsorbent for treatment is activated
carbon.
72
Activated Carbon
 It is manufactured from carbonaceous material such as wood,
coal, petroleum products etc.
 A char is made by burning the material in the absence of air. The
char is then oxidized at higher temperatures to create a porous
solid mass which has large surface area per unit mass.
 The pores need to be large enough for soluble organics
compounds to diffuse in order to reach the abundant surface
area.
 Colour removal is effective for non-ionic and cationic dyes
73
Limitations of Activated Carbon
 Very expensive
 For reuse, solvent treatment is necessary which puts heavy
economical burden
Alternate Adsorption Techniques
 Clays
 Ion-exchange resins
74
Oxidation
 Chlorination
 Hydrogen peroxide
 Fenton’s Reagent
 Electrochemical Oxidation
 Advanced Oxidation
75
Chlorination
 Use of sodium hypochlorite (NaOCl) for decolorizing waste.
 Sodium hypochlorite is a powerful oxidizing agent and will
readily break down most dye molecules to smaller fragments.
 If a dye is somewhat resistant to biological degradation, then
pre-treatment with hypochlorite can improve the total
mineralization
Disadvantages:
 Disperse dyes are not discolored
 Production of hazardous chlorinated organic compounds (AOX)
76
Hydrogen peroxide
 By itself can be used for de-colorization
 Can generate lower COD
 Longer reaction times
 Works effectively with activator
77
Fenton’s Reagent
 Hydrogen peroxide, alone, is insufficiently powerful to
decolorize dye waste at a normal temperature and pH.
 In acid solution, however, with iron(II) as a catalyst, the
peroxide forms the vigorous hydroxyl radicals and may be used
to decolorize dye wastes.
Fenton’s Reagent Reaction
78
Process Flow
with
Fenton’s
reagent
79
Advantages of Fenton’s Reagent
 Capable of treating both soluble dyes, such as reactive dyes, and
insoluble dyes, such as vat and disperse dyes
 The vigorous oxidation also reduces the COD of the effluent.
 Neutralisation of the effluents after treatment causes
precipitation of the iron oxide and hydroxide, which removes any
remaining insoluble dye from the effluent by absorption and/or
flocculation.
 Other reagents that can be used are manganese dioxide, ferrous
sulphate, ferric sulphate, ferric chloride or cupric nitrate
80
Electrochemical Oxidation
 The process involves the use of a sacrificial iron electrode, the
anode dissolving to form ferrous hydroxide.
 The typical electrochemical cell consists of two electronically
conducting materials put into an electrolyte solution. When iron
electrodes are used as both the cathode and anode, and
electricity is applied, the following reaction takes place:
 At the anode (oxidation):
Fe Fe2+ + 2e–
 At the cathode (reduction)
2H2O + 2e– H2 + 2OH–
Suitable for acid dyes and the maximum colour removal takes place
in acidic conditions.
81
Advanced Oxidation
 UV/ peroxide
 UV/ozone
 Peroxide/ozone
 Electron beam/ozone
 UV/ozone/peroxide
82
Tertiary Treatment (B)
Advanced Filtration techniques
83
Water
Microfiltration &
Ultrafiltration
Nanofiltration
Reverse Osmosis
Monovalent
ions
Multivalent
Ions
Bacteria Suspended
particles
83
Membrane Filtration
84
Principle -
The process of reverse osmosis is based on the ability of certain specific
polymeric membranes, usually cellulose acetate or nylon to pass pure water at
fairly high rates and to reject salts.
Waste water stream is passed at high pressures through the
membrane.
The applied pressures has to be high enough to overcome the osmotic pressure
of the stream, and to provide a pressure driving force for water to flow from the
reject compartment through the membrane into the clear water compartment.
85
Working of Reverse Osmosis System
 The feed water is pumped through a pre-treatment section
which removes suspended solids and if necessary, ions such as
iron and magnesium which may foul the system.
 The feed water is then pressurised and sent through the
reverse osmosis modules.
 Clear water permeates through the membrane under the
pressure driving force, emerging at atmospheric pressure.
 The pressure of reject stream is reduced by a power recovery,
which helps drive the high pressure pump and then is
discharged.
86
Characteristics of Reverse Osmosis
 Reverse osmosis can be used as end-of-pipe treatment and
recycling system for effluent.
 After primary, secondary and/or tertiary treatment, further
purification by removal of organics and dissolved salts is possible
by use of reverse osmosis.
 RO membranes are susceptible to fouling due to organics,
colloids and microorganism.
 scale causing constituents like hardness, carbonate. Silica, heavy
metals, oil etc has to be removed from the feed.
 As the membranes are sensitive to oxidizing agents like chlorine
or ozone, they should also be absent.
87
Tertiary Treatment
88
Process Examples of removal
Microfiltration Bacteria, pigments , oils etc.
Ultrafiltration Colloids, virus, protein etc.
Nano-filtration Dyes, pesticides, divalent ions etc.
Reverse Osmosis Salts and ions
 Nano-filtration
 Reverse Osmosis
 Microfiltration
 Ultrafiltration
ETP Management
89
• How to monitor compliance,
• Sampling
• Testing requirements & frequency
• In-house monitoring daily checkpoints
• Formats for maintaining data.
Daily Monitoring of ETP
90
• The pH at flocculation tank should
be maintained between 8.5 to 9.5
as maximum flocculation takes
place at pH 9
• The optimum biological activity of
the microorganisms for the
treatment process is in the pH
range from 6.0 to 8.0.
pH of aeration and
flocculation tank
pH-meter
Daily Monitoring of ETP
91
 Test helps to
decide the recipe
of coagulating
agents in primary
settling tank
 Gives an
indication of how
settling occurs in
the clarifier
Settleability test
Test
 Collect 1 liter
effluent from
Equalization tank
 Dose required Alum,
lime, FeSO4 & PAC
 Check Flocculation
time & volume of
sludge
 Confirm the
required daily
dosage
Checkpoints
o Quantity of
clear water
o Settling time
o Volume of
sludge
Testing Frequency for plant operator
92
pH
Colour
Temperature
Once in Shift
TDS
BOD
COD
Once in a Day
Heavy metals
Toxic
substances
Random
check
Based on the parameters mentioned in the
‘Consent to Operate’
the testing requirements will vary from industry
to industry
Reporting system
 Daily volume of effluent generated & discharged
 Daily Power consumption in ETP
 Daily chemical consumption
 Daily test reports of effluent discharged
 Daily volume of recycling of effluent
 Weekly once “treatability study”
 Record of random testing reports for heavy metals
& other parameters
Sampling & Testing
How do we know the characteristics of the waste
water?
93
sampling and further
testing
Sampling Methods
94
Water samples collected at
equal time intervals.
All the collected samples are
then mixed.
The representative sample is
known as composite sample.
Water samples collected at a
specific location, where
sample composition remains
constant over long period.
Grab Sampling Composite sampling
Systematic way of sampling
Parameters
Volume
Required
(ml)
Preserving
Method
Type of
Container
Temperature 100
On site
Plastic or
Glass
pH 25
Colour 500
Cool to 4 0C
TSS 50
Metals
100 per
metal pH <2 with
nitric acid
Mercury 500
BOD 1000 Chill to near freezing
Glass
COD 50
pH 2 with sulphuric
acid, maintain at 4 0C
95
Criteria for sampling
96
Automatic SamplingManual Sampling
pH meter DO meter
Plastic or Glass
bottle
Automatic sampler
Temp. Meter
Summary
97
Inlet clean
water
Industri
al
Activity
Untreate
d Effluent
E.T.P
.
Treated Effluent
Recycle
Industry can Save
fresh water for
drinking
.
Contact +91 7768883361
harane27@gmail.com
Design Sustainability
ForFutureGrowth
Join Hands with Environment
98
Sustainable Development
Take care of mother
earth with social
responsibility and
environmental
protection.
This is our contribution to
a better future for us
and for coming
generations
It simply means: Give back what you take!
99
Thank you
.
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ETP Effluent Treatment Processes

  • 1. 1 General Idea of ETP Know Basic Words. BY- KANHAYA LAL KUMAWAT
  • 2. 2 1) Effluent in Different processes 2) Basic terms used in waste water treatment 3) Definition / Impact on Environment 4) How to Reduce it Contents
  • 3. Sections of ETP 3 Preliminary Treatment Primary Treatment Biological Treatment Tertiary Treatment Advance Treatment (Advance Filtration, Advance oxidation)
  • 4. Effluent in Processing Unit 4 Desizing Sizes (starch), enzymes, waxes Scouring NaOH, surfactants, soaps, fats, waxes water softeners FinishingDyeing Colour, metals, salts, surfactants, sulphide, acidity/alkalinity, formaldehyde , water softeners Printing Urea, solvents, colour, metals Bleaching/Mercerisation H2O2, AOX, organic stabiliser, NaOH & high pH Resins, waxes, chlorinated solvents, spent solvents, softeners Let us know the terms used in effluent treatment
  • 5. BASIC TERMS IN ETP 5 pH • Measure of acidity or alkalinity MLSS • Mixed Liquor Suspended solids MLVSS • Mixed Liquor Volatile Suspended Solids
  • 6. BASIC TERMS IN ETP 6 DO • Dissolved Oxygen in water COD • Oxygen required to oxidise organic material by chemical means in waste water BOD • Oxygen required to oxidise organic material by biological means in waste water
  • 7. BASIC TERMS IN ETP 7 Treatability study • It is a study or test that tells us how the wastewater might be treated. Retention Time • It is a measure at an average length of time holding the wastewater in a tank. Grab sample • It is a sampling method in which a single sample is taken at a specific time
  • 8. BASIC TERMS IN ETP 8 Composite Sample • It is a collection of several individual samples taken at regular intervals over a period of time, usually 24 hours. & combined testing is done Bio Mass • It is a colony of living Bacteria, which digest many organic and inorganic substances. An essential part of the ecosystem including within human beings
  • 9. BASIC TERMS IN ETP 9 Activated Sludge • Sludge that has undergone flocculation forming a bacterial culture typically carried out in tanks. Can be extended with aeration. Clarifier • A section of ETP equipment used to "clarify" the wastewater, It is a holding tank that allows settling. Used when solids have a specific gravity greater than 1.00
  • 10. BASIC TERMS IN ETP 10 Anaerobic Digester • The breaking down of organic material and other waste biologically by microorganisms in absence of Oxygen. Results in by-products such as methane gas, carbon dioxide, sludge solids and water Grit Chamber • Usually in ETP, a chamber or tank in which primary influent is slowed down so heavy typically inorganic solids can drop out, such as metals and plastics.
  • 11. BASIC TERMS IN ETP 11 Flocculation • The process whereby a chemical or other substance is added to wastewater to trap or attract the particulate suspended solids into clusters -woolly looking mass Sludge • The solid waste material which settles out in the wastewater treatment process, sometimes biosolids. Can be dewatered and reused or disposed.
  • 12. pH 12 In chemistry, pH is the measure of acidity or alkalinity of an aqueous solution. The pH is equal to − log10 C, where c is the hydrogen ion concentration in moles/ltr. Solutions with pH less than 7 are acidic whereas above 7 are alkaline. pH of 7 is termed as neutral.
  • 13. Impact of pH value 13  Affects the aquatic life if the pH is not in 6-9 range.  The bacteria involved in biological treatment will not perform effectively outside 6-9 pH range.  When pH is not neutral it increases the consumption of chemicals for coagulation and flocculation.
  • 14. How To Control pH value 14  Maintain pH as desired by dosing acid/alkali  Use Dilute Sulphuric Acid if the pH is alkaline  Use Lime if the pH is acidic.
  • 15. TDS - Total Dissolved Solids 15 In textiles, generally common salt increases TDS of water and harmful to aquatic life. It also affects the fertility of soil. Fertile land Non Fertile land
  • 16. Mixed Liquor Suspended Solids (MLSS) 16  Mixed liquor is a combination of raw or unsettled wastewater or pre-settled wastewater and activated sludge within an aeration tank.  Mixed liquor suspended solids (MLSS) is the concentration of suspended solids, in an aeration tank during the activated sludge process, which occurs during the treatment of waste water. ...
  • 17. MLSS - Mixed Liquor Suspended Solids 17 • The activity of bio mass is measured by MLSS & should be maintained approximate 30% by volume.
  • 18. How to maintain MLSS 18  MLSS should be maintained in 30% range.  MLSS > 30% : Reduce and Dispose the sludge.  MLSS < 30% : Grow biomass, feed concentrated active mass from Secondary Clarifier  Frequency of the test analysis : Once in a Day.  MLSS can depend upon effluent quality, Health of Bio- mass & Retention time.  Take liquor, filter & dry at 105 °C & find Suspended solids
  • 19. Mixed Liquor Volatile Suspended Solids (MLVSS) 19  MLVSS is generally defined as the microbiological suspension in the aeration tank of an activated- sludge biological wastewater treatment plant.  The biomass solids in a biological waste water reactor are usually indicated as total suspended solids (TSS) and volatile (at 550°C for 30 min.) suspended solids (VSS).  MLSS is used to indicate the concentration of suspended solids in activated sludge. MLVSS represents the concentration of biomass in activated sludge.
  • 20. MLVSS 20  MLVSS should be maintained between 60% to 70% of MLSS  Frequency of the test analysis : Once in a Day
  • 21. Chemical Oxygen Demand (COD) 21  Definition  Chemical oxygen demand (COD) is a measure of the capacity of sample to consume oxygen during the decomposition of organic matter and the oxidation of inorganic chemicals.
  • 22. Impact of COD 22  Higher COD values affect land fertility.  Higher COD level will reduce DO levels.  Which affects the aquatic life.  Higher COD gives higher TDS  Sunlight cannot reach the below levels of sea water which affects the aquatic plants.
  • 23. COD : Chemical Oxygen Demand 23 Organic pollutant Inorganic pollutant Reducing chemicals Definition:- Amount of oxygen needed to oxidize organic and inorganic materials in a waste water effluent mg/L
  • 24. How to reduce COD 24  Optimisation of Process.  Recover and reuse of the chemical.  Coagulation and flocculation process.  Biological treatment.  Tertiary treatment.
  • 25. Biochemical Oxygen Demand (BOD) 25 Definition: • Biochemical oxygen demand (BOD) is a measure of the amount of oxygen that bacteria will consume for decomposition of organic material and oxidation of inorganic material under aerobic conditions.
  • 26. BOD - Biological Oxygen Demand 26 Organic pollutant Inorganic pollutant Microbes Definition:- Amount of dissolved oxygen needed by bacteria in ETP to break down organic material present in the Effluent If BOD level in effluent is not controlled, the rate of Oxygen consumption > Oxygen replenishment from the atmosphere, thus affecting the marine species in the water-body where the effluent is discharged.
  • 27. How to control BOD 27  Use Biodegradable chemicals in the process  If Non-Biodegradable Reduce, Recover & Reuse Focus on Primary Treatment To reduce Load Advanced Oxidation/H2O2 Oxidation Biological treatment
  • 28. Dissolved Oxygen (DO) 28  It is the amount of oxygen present in water.  DO is measured in ppm  DO levels can be increased by surface aerators or diffusion technique. Desired DO levels for fish to remain healthy & alive is >3 ppm
  • 29. Impact of DO on Aquatic Life 29  Desired DO levels for fish to remain healthy & alive is >3 ppm  When BOD levels are high, dissolved oxygen (DO) levels decrease because the bacteria are consuming the oxygen that is available in the water. Since less dissolved oxygen is available in the water, fish and other aquatic organisms may not survive.
  • 30. How to maintain DO 30  Maintain BOD level.  Aeration of water.  Maintain the Temperature.  Remove dead bio-mass as Bio-sludge.
  • 31. Treatability Study 31 It is a study or test that tells us how the wastewater might be treated with some of the following tests: pH Colour Odour Chemical Oxygen Demand Biochemical Oxygen Demand Total Dissolved Solids Total Suspended Solids It also gives The performance of treatment in ETP Efficiency of dosing
  • 32. Retention time 32 It is a measure at an average length of time holding the wastewater in a tank. • Primary Collection tank • Flash mixing • Flocculation • Clarifier • Aeration tank
  • 33. Grab Sample, Composite Sample 33 It is a sampling method in which a single sample is taken at a specific time. It is a collection of several individual samples taken at regular intervals over a period of time, usually 24 hours. & combined testing is done
  • 34. Effluent Treatment Plant 34 ETP (Effluent Treatment Plant) is a process design for treating the industrial waste water for its reuse or safe disposal to the environment.  Influent: Untreated industrial waste water.  Effluent: Treated industrial waste water.  Sludge: Solid part separated from waste water by ETP.
  • 35. 1) Quality Requirements of Effluent Contents 35
  • 36. Parameters for Dyehouse Untreated waste water Treated waste water pH 4.0 to 9.5 6 to 9 Colour Dark, offensive No Colour, not offensive Foam Persistent No foam or dissipates Heavy metals 10 to 15 ppm 0.01 to 1.5 ppm Suspended solids 200 to 300 ppm 30 To 45 ppm Total Dissolved Solids 3500 to 6000 ppm 2100 ppm Chemical Oxygen Demand 900 to 1500 ppm 250 ppm Biochemical Oxygen Demand 300 to 500 ppm 30 ppm 36 Quality requirements of effluent 36 One must follow the discharge norms as per Consent to operate issued by SPCB
  • 37. 2 Various Processes used in ETP Content 37
  • 38. Physical Chemical Biological Physico- chemical Sedimentation Neutralization Stabilization ponds Coagulation Filtration reduction Aerated lagoons Reverse Osmosis Oil removal Oxidation Trickling filters Solvent extraction Ionizing radiation Catalysis Activated sludge Electrolysis Adsorption Ion Exchange Anaerobic digestion Foam fractionation Classification of methods of Effluent treatment 38
  • 39. Treatment Levels & Mechanisms involved 39  Preliminary (Physical Separation)  Primary (Physical & Chemical method used )  Secondary (Biological)  Tertiary /Advanced (Physical & Chemical)
  • 41. 41 Preliminary Treatment Screening- Removal of large particles. Screens- opening with uniform size  Screen element- parallel bars, rods, grating or wire meshes or perforated plates Requires periodic cleaning Set in channel at 600 •Removal of wastewater constituents such as rags, suspended and floatable yarns, fibres. •Removes 20-30% solids Screening Unit 41
  • 42. 42 Preliminary Treatment Sedimentation Use of gravity as settlable solids separate out as a watery sludge. Flotation  Suitable for low-density solids  Facilitates separation of suspended matter from the waste liquor and isolation of the sludge The waste flow is pressurized ( 3 – 5 bar) in the presence of air The pressurized waste flow is passed into the flotation unit  Minute air bubbles are formed; simultaneously sludge flocs and suspended matter floats which can be skimmed off. 42
  • 43. Grit Chamber 44 Usually in ETP, a chamber or tank in which primary influent is slowed down so heavy typically inorganic solids can drop out, such as metals and plastics.
  • 44. Flocculation 45 The process whereby a chemical or other substance is added to wastewater to trap or attract the particulate suspended solids into clusters -woolly looking mass
  • 45. 46 Primary Treatment Removal of part of suspended solids and organic matters from wastewater treatment. Equalization- Application- Temporary storage of effluent to equalize flow rates, mass loading of BOD and suspended solids Advantage- shock loadings are eliminated Device- Equalization tank 46
  • 46. 47 Primary Treatment Chemical neutralization-  Removal of excess of acidity or alkalinity using suitable chemical.  Polyester processing generates acidic effluent  Cotton processing generates alkaline effluent. pH adjustment – Alkaline waste water is neutralized with dil. Sulphuric acid Acidic waste water is neutralized with NaOH and Lime. Lime is more cheaper than NaOH. 47
  • 47. 48 Coagulation • A reasonable and economical method of lowering BOD and COD and of reducing colour. • The contaminants are in colloidal form having particle size in the range of 10-7 to 10-9 m. • The stability of non-gelatinous colloid is primarily due to electrostatic forces. • The degree of stability can be determined by measuring zeta potential. 48
  • 48. 49 Coagulation  Coagulants are used to reduce the zeta potential thereby facilitate aggregation of particles  Lime, aluminum sulfate, iron(III) chloride are the most popular coagulants  Aids to coagulant include silica and polyelectrolyte Concerns:  Coagulation process is time consuming, tests are necessary to optimize the coagulant concentration  Coagulation process produces large amount of sludge.  Running costs are high 49
  • 49.  It uses chemical precipitation to cause separation  The solids in the waste adhere to the coagulant particles and the resulting bulky gelatinous material, known as floc, can be removed by direct filtration, sedimentation or flotation.  Coagulation results due to lowering of the zeta potential at the particle surface to permit closer approach followed by association of the particles to form larger flocculated agglomerates.  Lime, either alone or with ferric salts is the most popular coagulant. It is often able to remove 90% of the colour present. Flocculation 50
  • 50. 51 Coagulation and Flocculation Steps- • Addition of coagulant with flash mixing •Charge particle come closer to form clump •Large particles removed by gravity sedimentation •Device- Flash mixer, Flocculator, Primary Clarifier 51
  • 51. 52 In primary treatment, Color, colloidal, suspended and settling solids are removed For getting better results, the reaction time during each process should be maintained. (This time is known as Retention time) Reaction of chemicals with effluent - 60 to 90 sec Flocks generation - 5 to 10 minutes Retention time in Primary Clarifier : 240 min During primary treatment, BOD and COD reduction: 45 to 65 % Primary Treatment 52
  • 52. Clarifier 53 • A section of ETP to "clarify" the wastewater. • It is a holding tank, that allows settling & removes solids from bottom having specific gravity greater than 1.00 . • It also removes solids have Specific gravity lesser than 1.00 from top by scrubber. • Solids from Top & bottom are transferred to Sludge tank or recycled back to aeration tank.Conventional Clarifier Slanting plate Clarifier
  • 53. Anaerobic Digester 54 • The breaking down of organic material and other waste biologically by micro-organisms in absence of Oxygen. • Results in by-products such as methane gas, carbon dioxide, sludge solids and water
  • 54. Anaerobic Treatment 55 Aeration tank TRICKLING FILTRATIONOXIDATION DITCH / POND ANAEROBIC DIGESTER Aerobic Treatment Secondary Treatment 55
  • 55. 56 Secondary Treatment  Removal of biodegradable organic matter and suspended solids.  Soluble organic matter converted to simple substances by microorganisms. Org.C+O2 CO2 Org.H+O2 H2O Org.N+O2 NO2 - Org.S+O2 SO2 Org.P+O2 PO4 2- 56
  • 56. 57 Secondary Treatment Important points Aerobic Treatment-  Oxidative continuous reaction  Reaction depend on,  Microbial population  Oxygen availability  Nutrients Anaerobic Treatment  Reductive reaction  Absence of oxygen 57
  • 57. 58 Aerated Lagoon  Earthen basin provided with mechanical aerators.  Longer residence time require to achieve same effluent quality.  Microorganisms are more resistant than ASP.  Settling tank and sludge recirculation absent. Types of Aerated Lagoon  Suspended growth aerated Lagoon- Fully aerobic from top to bottom  Facultative aerated lagoon- lower part anaerobic, upper part aerobic 58
  • 58. 59 Membrane Biological Reactor Biological reactor with suspended biomass Solid separation by membrane (pore size 0.1µm -0.4µm) 59
  • 59. 60 Attached Growth Processes  Microorganisms attached to inert packing material- biofilm.  Packing material – rock, gravel, plastic and other synthetic material  Operated as aerobic or anaerobic processes.  Commonly used in Trickling Filter Rotating Biological Contactor 60
  • 60. 61 Attached Growth Processes 61 Trickling Filter Rotating Biological Contactor
  • 61. Biomass 62 It is a colony of living Bacteria, which digest many organic and inorganic substances. An essential part of the ecosystem including within human beings
  • 62. Activated Sludge 63 • Sludge that has undergone flocculation forming a bacterial culture typically carried out in tanks. • Can be extended with aeration.
  • 63. 64 Activated Sludge Process  Production of activated mass of microorganisms capable of stabilizing waste under aerobic condition.  Aerobic condition is achieved by using surface aerators or diffused aeration system 64
  • 64. Sludge 65 • The solid waste material which settles out in the wastewater treatment process, • Sometimes bio-solids can be dewatered and reused or disposed. • These solid waste may contain hazardous pollutants & may be harmful. It must be disposed as per regulatory guidelines .
  • 65. Sludge Treatment and Disposal 66 Sludge filter press Sludge separated for discharge Sludge dewateringSludge drying beds Sludge disposal area 66
  • 67. 68 Anaerobic Lagoon  Suspended growth anaerobic processes  Treatment of high strength organic wastewaters and high quantity of solids  Employed in textile wastewater treatment.  Degradation of organic matter by anaerobic bacteria, in two stages, involves  First Stage- nonmethanogenic bacteria- hydrolyze wastes in short chain organic compounds, organic acids and ammonia  Second Stage- methanogenic bacteria involves conversion of intermediate products in to methane and carbon dioxide. 68
  • 68. 69 Up flow Anaerobic sludge blanket 69
  • 69. 70  Wastewater enters from bottom and flow upward.  Microorganisms in sludge layer degrade organic compounds.  Methane and CO2 released  Clarified effluent is extracted from top.  Methane gas collected in gas collection dome  Up flow velocity maintained- 0.6 to 0.9m/s 70
  • 70. 71 Oxidation Techniques Electro chemical Oxidation PROCESS Activated carbon UV peroxide / NaOCl Various Techniques used To be selected depending upon effluent characteristics after secondary treatment Tertiary treatment 71
  • 71. Adsorption  The adsorption process is used to removes colour and other soluble organic pollutants from effluent.  The process also removes toxic chemicals such as pesticides, phenols, cyanides and organic dyes  Dissolved organics are adsorbed on surface as waste water containing these is made to pass through adsorbent.  Most commonly used adsorbent for treatment is activated carbon. 72
  • 72. Activated Carbon  It is manufactured from carbonaceous material such as wood, coal, petroleum products etc.  A char is made by burning the material in the absence of air. The char is then oxidized at higher temperatures to create a porous solid mass which has large surface area per unit mass.  The pores need to be large enough for soluble organics compounds to diffuse in order to reach the abundant surface area.  Colour removal is effective for non-ionic and cationic dyes 73
  • 73. Limitations of Activated Carbon  Very expensive  For reuse, solvent treatment is necessary which puts heavy economical burden Alternate Adsorption Techniques  Clays  Ion-exchange resins 74
  • 74. Oxidation  Chlorination  Hydrogen peroxide  Fenton’s Reagent  Electrochemical Oxidation  Advanced Oxidation 75
  • 75. Chlorination  Use of sodium hypochlorite (NaOCl) for decolorizing waste.  Sodium hypochlorite is a powerful oxidizing agent and will readily break down most dye molecules to smaller fragments.  If a dye is somewhat resistant to biological degradation, then pre-treatment with hypochlorite can improve the total mineralization Disadvantages:  Disperse dyes are not discolored  Production of hazardous chlorinated organic compounds (AOX) 76
  • 76. Hydrogen peroxide  By itself can be used for de-colorization  Can generate lower COD  Longer reaction times  Works effectively with activator 77
  • 77. Fenton’s Reagent  Hydrogen peroxide, alone, is insufficiently powerful to decolorize dye waste at a normal temperature and pH.  In acid solution, however, with iron(II) as a catalyst, the peroxide forms the vigorous hydroxyl radicals and may be used to decolorize dye wastes. Fenton’s Reagent Reaction 78
  • 79. Advantages of Fenton’s Reagent  Capable of treating both soluble dyes, such as reactive dyes, and insoluble dyes, such as vat and disperse dyes  The vigorous oxidation also reduces the COD of the effluent.  Neutralisation of the effluents after treatment causes precipitation of the iron oxide and hydroxide, which removes any remaining insoluble dye from the effluent by absorption and/or flocculation.  Other reagents that can be used are manganese dioxide, ferrous sulphate, ferric sulphate, ferric chloride or cupric nitrate 80
  • 80. Electrochemical Oxidation  The process involves the use of a sacrificial iron electrode, the anode dissolving to form ferrous hydroxide.  The typical electrochemical cell consists of two electronically conducting materials put into an electrolyte solution. When iron electrodes are used as both the cathode and anode, and electricity is applied, the following reaction takes place:  At the anode (oxidation): Fe Fe2+ + 2e–  At the cathode (reduction) 2H2O + 2e– H2 + 2OH– Suitable for acid dyes and the maximum colour removal takes place in acidic conditions. 81
  • 81. Advanced Oxidation  UV/ peroxide  UV/ozone  Peroxide/ozone  Electron beam/ozone  UV/ozone/peroxide 82
  • 82. Tertiary Treatment (B) Advanced Filtration techniques 83 Water Microfiltration & Ultrafiltration Nanofiltration Reverse Osmosis Monovalent ions Multivalent Ions Bacteria Suspended particles 83
  • 84. Principle - The process of reverse osmosis is based on the ability of certain specific polymeric membranes, usually cellulose acetate or nylon to pass pure water at fairly high rates and to reject salts. Waste water stream is passed at high pressures through the membrane. The applied pressures has to be high enough to overcome the osmotic pressure of the stream, and to provide a pressure driving force for water to flow from the reject compartment through the membrane into the clear water compartment. 85
  • 85. Working of Reverse Osmosis System  The feed water is pumped through a pre-treatment section which removes suspended solids and if necessary, ions such as iron and magnesium which may foul the system.  The feed water is then pressurised and sent through the reverse osmosis modules.  Clear water permeates through the membrane under the pressure driving force, emerging at atmospheric pressure.  The pressure of reject stream is reduced by a power recovery, which helps drive the high pressure pump and then is discharged. 86
  • 86. Characteristics of Reverse Osmosis  Reverse osmosis can be used as end-of-pipe treatment and recycling system for effluent.  After primary, secondary and/or tertiary treatment, further purification by removal of organics and dissolved salts is possible by use of reverse osmosis.  RO membranes are susceptible to fouling due to organics, colloids and microorganism.  scale causing constituents like hardness, carbonate. Silica, heavy metals, oil etc has to be removed from the feed.  As the membranes are sensitive to oxidizing agents like chlorine or ozone, they should also be absent. 87
  • 87. Tertiary Treatment 88 Process Examples of removal Microfiltration Bacteria, pigments , oils etc. Ultrafiltration Colloids, virus, protein etc. Nano-filtration Dyes, pesticides, divalent ions etc. Reverse Osmosis Salts and ions  Nano-filtration  Reverse Osmosis  Microfiltration  Ultrafiltration
  • 88. ETP Management 89 • How to monitor compliance, • Sampling • Testing requirements & frequency • In-house monitoring daily checkpoints • Formats for maintaining data.
  • 89. Daily Monitoring of ETP 90 • The pH at flocculation tank should be maintained between 8.5 to 9.5 as maximum flocculation takes place at pH 9 • The optimum biological activity of the microorganisms for the treatment process is in the pH range from 6.0 to 8.0. pH of aeration and flocculation tank pH-meter
  • 90. Daily Monitoring of ETP 91  Test helps to decide the recipe of coagulating agents in primary settling tank  Gives an indication of how settling occurs in the clarifier Settleability test Test  Collect 1 liter effluent from Equalization tank  Dose required Alum, lime, FeSO4 & PAC  Check Flocculation time & volume of sludge  Confirm the required daily dosage Checkpoints o Quantity of clear water o Settling time o Volume of sludge
  • 91. Testing Frequency for plant operator 92 pH Colour Temperature Once in Shift TDS BOD COD Once in a Day Heavy metals Toxic substances Random check Based on the parameters mentioned in the ‘Consent to Operate’ the testing requirements will vary from industry to industry Reporting system  Daily volume of effluent generated & discharged  Daily Power consumption in ETP  Daily chemical consumption  Daily test reports of effluent discharged  Daily volume of recycling of effluent  Weekly once “treatability study”  Record of random testing reports for heavy metals & other parameters
  • 92. Sampling & Testing How do we know the characteristics of the waste water? 93 sampling and further testing
  • 93. Sampling Methods 94 Water samples collected at equal time intervals. All the collected samples are then mixed. The representative sample is known as composite sample. Water samples collected at a specific location, where sample composition remains constant over long period. Grab Sampling Composite sampling
  • 94. Systematic way of sampling Parameters Volume Required (ml) Preserving Method Type of Container Temperature 100 On site Plastic or Glass pH 25 Colour 500 Cool to 4 0C TSS 50 Metals 100 per metal pH <2 with nitric acid Mercury 500 BOD 1000 Chill to near freezing Glass COD 50 pH 2 with sulphuric acid, maintain at 4 0C 95
  • 95. Criteria for sampling 96 Automatic SamplingManual Sampling pH meter DO meter Plastic or Glass bottle Automatic sampler Temp. Meter
  • 96. Summary 97 Inlet clean water Industri al Activity Untreate d Effluent E.T.P . Treated Effluent Recycle Industry can Save fresh water for drinking
  • 97. . Contact +91 7768883361 harane27@gmail.com Design Sustainability ForFutureGrowth Join Hands with Environment 98
  • 98. Sustainable Development Take care of mother earth with social responsibility and environmental protection. This is our contribution to a better future for us and for coming generations It simply means: Give back what you take! 99