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Pre-treatment of lignocellulosic
           biomass
             Jiby Kurian
            Ph. D. Student
       Bioresource Engineering
Lignocellulosic biomass

                Others 2-5%
Minerals 2-5%




     Lignin 10-20%            Cellulose
                              40-50 %


        Hemicellulose
          25-30%


                                          brae.calpoly.edu
Value addition to lignocellulosic biomass
Pre-treatment of lignocelluloses




                         Mosier et al., 2006
Types of pre-treatment processes
                                          Average
Pre-treatment     Catalyst(s) used      Temperature Final Treatment (s)
                                          & Time

                  Acid, Alkali, H2O,      1500C,      Enzymatic hydrolysis
Thermo-chemical       Solvents           2-60 min.     and fermentation

  Biochemical     Microorganisms,          300C,         Fermentation
                     enzymes             24-72 hrs.

   Thermal         ------------------     10000C,        FT synthesis,
 (Gasification)                          2-30 min.       Fermentation
Biofuel production: Today


 Feedstock                  Harvesting   Transporting




                                           Storing
Pre-treatment and final processing
                                                     brae.calpoly.edu
The problems
• Low density of the resource (0.1-0.2 kg/m3)

• Scarcity and variability

• Environmental issues

• Not economical



                                                Biomasshub.com
The solution: On-the-site Pre-treatment (OP)


     Minerals
                                  Energy
                    Cellulose
 Lignin                                    Biofuels

                                  Bio-refinery
On-the-site Pre-treatment
                                Bioproducts

          Hemicellulose


                                Industry
            Farm
The benefits of OP for farmers

• Additional jobs

• Rural development

• Sustainable biomass production




"Not mass production, but production by the masses." – M. K. Gandhi
The benefits of OP for industries


• Compact, purified and specific raw materials

• Availability of raw materials

• Less capital investment
My research work
                        Cellulose
                                        Biofuels, &
                                        biomaterials
                        Hemicellulose

Biomass   On-the-site
          pre-          Lignin          Solid fuel
          treatment
                                        Fertilizer
                        Minerals
References
• http://afdelingen.kiviniria.net/media-
  afdelingen/DOM100000178/Presentaties/2011/Kersten_19-05-2011.pdf
• Eranki et al., (2011) Advanced regional biomass processing depots: A key
  to the logistical challenges to the cellulosic biofuel industry.
  Biofuels, Bioproducts and Biorefining, Vol 5(6), pp 621-630.
• http://www.businesschemistry.org/article/?article=121
• Carolan et al., (2007) Technical and Financial Feasibility Analysis of
  Distributed Bioprocessing Using Regional Biomass Pre-Processing Centers.
  Journal of Agricultural & Food Industrial Organization Vol. 5 [2007], Article
  10
Acknowledgement
• Supervisor:

• Course instructor:

• Reviewers
• Friends
Pre-treatment of Lignocellulosic Biomass

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Pre-treatment of Lignocellulosic Biomass

  • 1. Pre-treatment of lignocellulosic biomass Jiby Kurian Ph. D. Student Bioresource Engineering
  • 2. Lignocellulosic biomass Others 2-5% Minerals 2-5% Lignin 10-20% Cellulose 40-50 % Hemicellulose 25-30% brae.calpoly.edu
  • 3. Value addition to lignocellulosic biomass
  • 4. Pre-treatment of lignocelluloses Mosier et al., 2006
  • 5. Types of pre-treatment processes Average Pre-treatment Catalyst(s) used Temperature Final Treatment (s) & Time Acid, Alkali, H2O, 1500C, Enzymatic hydrolysis Thermo-chemical Solvents 2-60 min. and fermentation Biochemical Microorganisms, 300C, Fermentation enzymes 24-72 hrs. Thermal ------------------ 10000C, FT synthesis, (Gasification) 2-30 min. Fermentation
  • 6. Biofuel production: Today Feedstock Harvesting Transporting Storing Pre-treatment and final processing brae.calpoly.edu
  • 7. The problems • Low density of the resource (0.1-0.2 kg/m3) • Scarcity and variability • Environmental issues • Not economical Biomasshub.com
  • 8. The solution: On-the-site Pre-treatment (OP) Minerals Energy Cellulose Lignin Biofuels Bio-refinery On-the-site Pre-treatment Bioproducts Hemicellulose Industry Farm
  • 9. The benefits of OP for farmers • Additional jobs • Rural development • Sustainable biomass production "Not mass production, but production by the masses." – M. K. Gandhi
  • 10. The benefits of OP for industries • Compact, purified and specific raw materials • Availability of raw materials • Less capital investment
  • 11. My research work Cellulose Biofuels, & biomaterials Hemicellulose Biomass On-the-site pre- Lignin Solid fuel treatment Fertilizer Minerals
  • 12. References • http://afdelingen.kiviniria.net/media- afdelingen/DOM100000178/Presentaties/2011/Kersten_19-05-2011.pdf • Eranki et al., (2011) Advanced regional biomass processing depots: A key to the logistical challenges to the cellulosic biofuel industry. Biofuels, Bioproducts and Biorefining, Vol 5(6), pp 621-630. • http://www.businesschemistry.org/article/?article=121 • Carolan et al., (2007) Technical and Financial Feasibility Analysis of Distributed Bioprocessing Using Regional Biomass Pre-Processing Centers. Journal of Agricultural & Food Industrial Organization Vol. 5 [2007], Article 10
  • 13. Acknowledgement • Supervisor: • Course instructor: • Reviewers • Friends