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International Journal of Trend in Scientific Research and Development (IJTSRD)
Volume 5 Issue 4, May-June 2021 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470
@ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1014
Sanganer Textile and Dye Industries
Causing Serious Environmental Pollution
Madhu Sharma1, Dr. Tripti Yadav2
1Associate Professor, Department of Home Science, RD Girls College, Bharatpur, Rajasthan, India
2Assistant Professor, Department of Botany,
SS Jain Subodh College of Global Excellence, Jaipur, Rajasthan, India
ABSTRACT
Sanganer town, district Jaipur (Rajasthan, India), is famous worldwide for its
dyeing and printing industries. There are about 400 industries involved in
textile printing processes, which discharge effluents into nearby ponds and
drains, without any treatment. These effluents contain highly toxic dyes,
bleaching agents, salts, acids, and alkalis. Heavy metals like cadmium, copper,
zinc, chromium, and iron are also found in the dye effluents. Textile workers
are exposed to such waters with no control over the length and frequency of
exposure. Further, as the untreated effluents are discharged into the
environment theycancauseseverecontaminationofsurfaceandunderground
water. Dyeing and textile printing industries of Sanganer houses about 400
small scales and one large scale industry [1]. These industries use a variety of
chemicals and azo dyes (direct,reactive, rapid,mordantandpremetalised etc.)
during processing and finishing of raw materials. The workers in those
industries are exposed to such dyes with no control over the length and
frequency of exposure. Further, a huge volume of mostly untreatedtextiledye
wastewater (10,000 - 15,000 Kl/day) is released into surface watersofAmani
Shah drainage or through the drainage systems, seeps into the groundwater
and adjoining water bodies flowing through Sanaganer. The untreated waste
water is discharged directly into the drains that connect the industry to the
main drainage network through the nullas in the town. The effluentsdisposed
in open drains are directly used for crops cultivation which affects the nearby
agricultural land also. The study deals with the collection of effluent from one
of the large scale printing and dyeing industry in Sanganer town and
physicochemical characterization of these samples in order to find out the
physio-chemical load put in by the effluent on the wastewater stream.
Environmental pollution caused by such textile effluents results in adverse
effects on flora, fauna, and the general health of not only the textile workers,
but also the residents of Sanganer town. Therefore, to assess the possible
genotoxic health risk and environmental genotoxicity due to the textile
industry effluents, this study was carried out using the Ames
Salmonella/microsome mutagenicity assay. The results clearly indicate that
the effluents and the surface water of Amani Shah drainage have high
mutagenic activity. Further, the drainage water and the dry bed of the
drainage (during summer months) are not fit for agricultural or other
recreational purposes. Wastewater and groundwater samples of Sanganer
were studied to find out the pollution load of wastewater generated from
dyeing and printing units and itsimpactonthequalityof domesticwastewater
of the Amanishah Nallah and groundwater. The wastewateroftheseunitswas
found to have high concentrations of sodium, chloride, and sulfate. It has
remarkable concentrations of copper, chromium, and iron with low chemical
oxygen demand and nearly 7-fold biochemical oxygen demand. The
wastewater of these units, discharged on land without any treatment, comes
into the Amanishah Nallah through small watercourses. The quality of the
domestic wastewater of Nallah deteriorates with the mixing of wastewater
from these units. Maximum concentrations of physicochemical parameters
were found at the Sanganer Road bridge sampling point. Eleven groundwater
samples, collected from various locations of Sanganer, were found polluted
due to percolation of wastewater into the ground.Copperandchromium were
recorded from some groundwater sources while iron was recorded from
almost all sources. Sodium and chloride are the major cation and anion in the
groundwater, which is identical to the wastewater of dyeing and printing
units.[2]
How to cite this paper: Madhu Sharma |
Dr. Tripti Yadav "Sanganer Textile and
Dye Industries Causing Serious
Environmental
Pollution" Published
in International
Journal of Trend in
Scientific Research
and Development
(ijtsrd), ISSN: 2456-
6470, Volume-5 |
Issue-4, June 2021, pp.1014-1016, URL:
www.ijtsrd.com/papers/ijtsrd42509.pdf
Copyright © 2021 by author (s) and
International Journal ofTrendinScientific
Research and Development Journal. This
is an Open Access article distributed
under the terms of
the Creative
Commons Attribution
License (CC BY 4.0)
(http://creativecommons.org/licenses/by/4.0)
INTRODUCTION
Dye production in India is estimated to be
around 64,000 tonnes, which is about
6.6% of the world production. There are
around 700 varieties of dyes and dye
intermediates produced in India, mainly
direct dyes, acid dyes, reactive dyes and
pigments. Most of these dyes have not
been characterized regarding their
chemical nature, purity, possible toxicity
or their impact on health and the
environment. Yet, they are widelyused by
textile, leather, paint and even the food
industry. The textile industry in India
alone consumes up to 80% of the total
dyestuffs produced. In Rajasthan state
particularly, textile mills represent an
important economic sector. Sanganer is
famous for dyeing and printing of colorful
dresses, bed sheets, curtains, dress
material and variety of other textiles.Bulk
of the textile products of these industries
is exported. It is located about 15 km
south of Jaipur, the State capital that has a
population of more than two million
people. The total area ofSanganerisabout
635.5 Sq. km out of which, 12.9 Sq. km
comprises the urban area. Most of the
textile industries of Sanganer are
IJTSRD42509
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1015
concentrated in this urban area. There are estimated to be
around 500 block and screen printing units in Sanganer. Of
all dyes produced across the world, 11% goes out as
effluents, 2% from manufacturing and as much as 9% from
coloring. The effluents from dyeing and textile industries
contain chemicals with intense colors and the release of
these effluents to receiving streamsmaybeobjectionablefor
various aesthetic reasons. Besides a number of dyes used by
these textile industries are not degradable. Further, these
colored dye wastes contain compounds that are difficult to
treat biologically due to their resistance against
biodegradation. The dye effluents may contain some
components or moieties that could be toxic, carcinogenic or
mutagenic to aquatic life. Central Pollution Control Board
has listed the dye and dye intermediates industry as one of
the heavily polluting industries (CPCB, 1990). Theyarethus,
a potent hazard to the natural sources like soil, water, flora,
fauna, livestock and human population. Ecological and
toxicological problems due to the discharge of wastewaters
from Sanganer textile industries in local drainage (Amani
Shah Ka Nallah) have been one of the most important water
pollution problems in this area. Studies have clearly
indicated that the industrial effluents, which are directly
discharged into the Amani Shah Ka Nallah, drainage contain
highly mutagenic compounds. These compounds are also
contaminating the surface and even underground water,
thereby, making it unfit for irrigation and drinking [1] High
concentrations of heavy metals like Cu, Cd, Zn, Pb, Ni, etc.
have also been reported in this area [2] Dyes and heavy
metals have been considered to be the possible source of
genotoxic activity in dyeing and textile effluents. Several
dyes have been investigated andfoundtobecarcinogenic [3]
Since large quantities of dyes are used, such pollution due to
dyes may occur on a significant scale. Assessment of
genotoxicity of dyes is therefore of utmost importance.Most
of the dyes, being openly sold in Sanganer markets have no
information regarding their chemical nature, purity or
possible mutagenicity or toxicity. This study was thus
planned to investigate the mutagenic potential of the dyes
available in markets of Sanganer.
DISCUSSION
Textile finishing processes (Yarns, fabrics, nonwovens,knits
and rugs) such as dyeing and printing. These dyes are
reactive, direct, dispersed, indigo, sulphur and vats. Such
that their presence in the liquid effluents resulting from the
textile washing constitutes a serious risk, in the absence of
their purification, for the quality of receiving aquatic
environments.[4] Indeed, the presence of these dyes and
pigments can cause a significant alteration in the ecological
conditions of the aquatic fauna and flora, because of the lack
of their biodegradability. This has a negative impact on the
equilibrium of the aquatic environment by causing serious
dangers, namely the obvious dangers (Eutrophication,
under-oxygenation, color, turbidity andodor),thelong-term
dangers (Persistence, bioaccumulation of carcinogenic
aromatic products and formation of by-products of
chlorination), mutagenicity and carcinogenicity. The textile
finishing dyes are organic compounds capable of absorbing
the light radiation in the visible range of the spectrumandof
reflecting or diffusing complementary radiation on the one
hand, and dyeing a substance in a sustainable manneronthe
other hand [5]. They consist of chromophoric groups,
auxochromes and conjugated aromatic structures. These
groups have specific independent properties, i.e., the color
and the ability to be fixed on such a textile support, during
dyeing and/or printing [6]. Chromophoric groups are
unsaturated groups consisting of atoms or groups of atoms,
in which the arrangement of successive single and double
bonds resonates with the unstable mesomeric form thus
allowing the absorption of light rays gathers the
mainchromophoricandauxochromicgroupsclassifiedby the
increasing intensity.
These dye waste waters can produce several dangerous
problems, namely aesthetic and health problems such as
changes in the quality (color and odor) of water and make it
toxic, as they can cause allergies, dermatitis, skin irritations,
cancers and mutations inhumans[7].Furthermore,between
60 and 70% of azo dyes are toxic, carcinogenic and are
refractory to conventional treatment processes because of
their resistancetoconventional physicochemical destruction
and the absence of their biodegradability [8]. This
interrupted the phenomenon of photosynthesis in marine
plants by triggering the phenomenon of eutrophication,
under the effect of the release of mineral elements such as
nitrates, nitrites and phosphates in an uncontrolledmanner,
and produced the long-term hazards of persistence,
bioaccumulation, by products of chlorination, mutagenicity
and carcinogenicity [9]. In terms of toxicity, the most toxic
synthetic organic dyes are azo dyes and more particularly
diazo and cationic dyes [9]. These types of dyes have
carcinogenic effects on humansandanimalsprimarily,asthe
electron-withdrawing character of azo groups generates
electronic deficiencies. This makes azo compounds
uncomfortable with oxidative catabolism under aerobic
environmental conditions.
RESULTS
In the light of this review, we can conclude that synthetic
dyes and pigments applied to textile finishing processes are
numerous and diverse in termsofchromophoregroups(Azo
groups, anthraquinone groups, indigoids, xanthenes,
phthalocyanines, nitroseds, triphenylmethanes and
polymethines) and application techniques (Water-soluble
dyes (Acidic, basic, metalliferous, reactive and direct dyes)
and water-insoluble dyes (Vat dyes, sulfur dyes and
dispersible)). The majority of these dyes are azo (60–70 %)
characterized by high chemical stability with respect to
chemicals and products due to the combination of azo
groups with aromatic rings. The presence of these dyes and
its residues in the effluents discharged into aquatic
environments, as well astheirrelativebiodegradability,have
a negative impact on the environment and moreparticularly
on aquatic ecosystems because of their toxic and
carcinogenic effects as they occur. Accumulate throughout
the food chain of aquatic fauna, on the one hand and
dysfunctional physiological processes of aquatic flora
(Plants, diatoms and algae) by disrupting their
photosynthesis mechanisms by the lack of circulation of the
oxygen and absorption of light in aquatic environments, on
the other hand. Besides, these textile dyes must eliminate
according to processes, which will be the interest of a future
review, of biological, chemical,physical andphysicochemical
treatment before their evacuation in aquatic
environments.[10]
CONCLUSION
Among the textile industries, one of the most extensively
used as dyes are synthetic chemicals. Approximately 10,000
different dyes and pigments are used industrially and 0.7
million tonnes of synthetic dyes produced annually,
worldwide [11] India’s dye industry produces differenttype
International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470
@ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1016
of dyes and pigments. Nearly 7,00,000 tonnes of dyes are
produced annually Worldwide [12] Production of dye stuffs
and pigments in India is close to 80,000 tonnes. India is the
second large exporter of dye stuffs and intermediates after
China [13] Azo dyes being the large group of synthetic dyes
constitute up to 70% of all known commercial dyes
produced [14] Synthetic dyes generally classified in to
reactive, acidic, vat, dispersing, direct and sulphur etc.
During the dyeing process, approximately 10-15% of the
dyes are released in to the wastewaters, causing serious
environmental and health hazards [15] Disposal of these
dyes into the environment causes serious threat, since they
may significantly affect the photosynthetic activity of
hydrophtes by reducing light penetration and also toxic to
aquatic organisms due to their breakdown products [16]
Dyes may also be toxic to some aquatic life due to the
presence of aromatics and metals, chlorides etc [16] The
textile finishing generates a large amount of waste water
containing dyes and represents one of the largest causes of
water pollution .Considerable attention has been given in
evaluating the capability ofmicroorganismsindecolourizing
and degrading the azo dyes. Many studies on the
decolourizing capability of microorganisms especially fungi
and bacteria have been reported. Various physical and
chemical methods have been used for the removal of dyes
from wastewater effluent. However, implementation of
physical and chemical methods have inherent drawbacks of
being economically unfeasible, unabletocompletelyremove
the recalcitrant azo dyes and organic metabolites maycause
pollution problems and involving complicated procedures .
REFERENCES
[1] Ajay kumar Pandey and Vinay Dubey.Biodegradation
of Azo dye reactive red BL by Alcaligenes sp. AA09.
International Journal of Engineering and Science
2012; 1: 54-60.
[2] Aksu Z, Kilic N, Ertugrul V and Donmez G. Inhibitory
effects of chromium (Vl) and Remazol black
onchromium (Vl) and dye stuff removals by
Trametesversicolor. Enzyme and Microbial
Technology 2007;40: 1167-1174.
[3] Carliell C M, Barclay S J, Shaw C, Wheatley A D and
Buckley C A. The effect of salts used in textile dyeing
on microbial decolourization of a reactive azo dye.
Environmental Technology1998;19(11):1133–1137.
[4] Cetin D and DonmezG. “Decolourization of reactive
dyes by mixed cultures isolated from textile effluent
under anaerobic conditions” Enzymes and Microbial
Technology 2006; 38: 926-930.
[5] Chen K C, Hung W T, Wu J Y and Houng J Y. Microbial
decolourization of azo dyes by Proteus mirabilis.
Journal of Industrial Microbiology and Biotechnology
1999; 23: 686- 690.
[6] Chen K C, Jane Y W, Liou D J and Sz-Chwun J
Decolourization textile dyes by newly isolated
bacterial strain. Journal of Biotechnology 2003; 101:
57-68.
[7] Dawkar V V, Jadhav U U, Jadhav S U and Govindwar S
P. Biodegradation of disperse textile dyeBrown3REL
by newly isolated Bacillus sp. VUS. Journal of Applied
Microbiology 2008; 105: 14-24.
[8] Dykes G A, Timm R G and Von Holy A. Azoreductase
activity in bacteria associated with the greening of
instant chocolate puddings. Applied Environmental
Microbiology 1994; 60: 3027-3029.
[9] EI-Sersy N A. bioremediation of methylene blue by
Bacillus thuringiensis 4G 1: application of statistical
designs and surface plots for optimization.
Biotechnology 2007; 6 (1): 34-39.
[10] Feng J, Cerniglia C E and Chen H. Toxicological
significance of azo dye metabolism by human
intestinal microbiota. Front Biosciences (Elite Ed)
2012; 4: 568-586.
[11] Forgacs E, Cserhati T and Oros G. Removal of
synthetic dyes from wastewaters: Review on
Environmental International 2004; 30: 953–971.
[12] Gupta R, Gigras P, Mohapatra H, Goswami V K and
Chauhan B. Microbial α-amylases: a biotechnological
perspective. Process Biochemistry2003; 38:1599-
1616.
[13] Hao O J, Kim H and Chaing P C. Decolourization of
wastewater critical reviews. Environmental and
Science Technology 2000; 30:449-505.
[14] Jacob Thomson. Impact of Industries on the Ground
Water Quality ofTiruppuranditsEthical implications,
Ph.D. Thesis, Dept. of Zoology, University of Madras,
Chennai 1998.
[15] Jadhav S U, Kalme S D and Govindwar S P.
Biodegradation of methyl red by Galactomyces
geotrichum MTCC 1360. Intenational Bio
deterioration and Biodegradation 2008;62:135-142.
[16] Joshni T Chacko and Subramaniam K. Enzymatic
degradation of Azo dyes- A Review. International
Journal of Environmental Sciences 2011; 1:6.

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Sanganer Textile Dye Industries Causing Environmental Pollution

  • 1. International Journal of Trend in Scientific Research and Development (IJTSRD) Volume 5 Issue 4, May-June 2021 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470 @ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1014 Sanganer Textile and Dye Industries Causing Serious Environmental Pollution Madhu Sharma1, Dr. Tripti Yadav2 1Associate Professor, Department of Home Science, RD Girls College, Bharatpur, Rajasthan, India 2Assistant Professor, Department of Botany, SS Jain Subodh College of Global Excellence, Jaipur, Rajasthan, India ABSTRACT Sanganer town, district Jaipur (Rajasthan, India), is famous worldwide for its dyeing and printing industries. There are about 400 industries involved in textile printing processes, which discharge effluents into nearby ponds and drains, without any treatment. These effluents contain highly toxic dyes, bleaching agents, salts, acids, and alkalis. Heavy metals like cadmium, copper, zinc, chromium, and iron are also found in the dye effluents. Textile workers are exposed to such waters with no control over the length and frequency of exposure. Further, as the untreated effluents are discharged into the environment theycancauseseverecontaminationofsurfaceandunderground water. Dyeing and textile printing industries of Sanganer houses about 400 small scales and one large scale industry [1]. These industries use a variety of chemicals and azo dyes (direct,reactive, rapid,mordantandpremetalised etc.) during processing and finishing of raw materials. The workers in those industries are exposed to such dyes with no control over the length and frequency of exposure. Further, a huge volume of mostly untreatedtextiledye wastewater (10,000 - 15,000 Kl/day) is released into surface watersofAmani Shah drainage or through the drainage systems, seeps into the groundwater and adjoining water bodies flowing through Sanaganer. The untreated waste water is discharged directly into the drains that connect the industry to the main drainage network through the nullas in the town. The effluentsdisposed in open drains are directly used for crops cultivation which affects the nearby agricultural land also. The study deals with the collection of effluent from one of the large scale printing and dyeing industry in Sanganer town and physicochemical characterization of these samples in order to find out the physio-chemical load put in by the effluent on the wastewater stream. Environmental pollution caused by such textile effluents results in adverse effects on flora, fauna, and the general health of not only the textile workers, but also the residents of Sanganer town. Therefore, to assess the possible genotoxic health risk and environmental genotoxicity due to the textile industry effluents, this study was carried out using the Ames Salmonella/microsome mutagenicity assay. The results clearly indicate that the effluents and the surface water of Amani Shah drainage have high mutagenic activity. Further, the drainage water and the dry bed of the drainage (during summer months) are not fit for agricultural or other recreational purposes. Wastewater and groundwater samples of Sanganer were studied to find out the pollution load of wastewater generated from dyeing and printing units and itsimpactonthequalityof domesticwastewater of the Amanishah Nallah and groundwater. The wastewateroftheseunitswas found to have high concentrations of sodium, chloride, and sulfate. It has remarkable concentrations of copper, chromium, and iron with low chemical oxygen demand and nearly 7-fold biochemical oxygen demand. The wastewater of these units, discharged on land without any treatment, comes into the Amanishah Nallah through small watercourses. The quality of the domestic wastewater of Nallah deteriorates with the mixing of wastewater from these units. Maximum concentrations of physicochemical parameters were found at the Sanganer Road bridge sampling point. Eleven groundwater samples, collected from various locations of Sanganer, were found polluted due to percolation of wastewater into the ground.Copperandchromium were recorded from some groundwater sources while iron was recorded from almost all sources. Sodium and chloride are the major cation and anion in the groundwater, which is identical to the wastewater of dyeing and printing units.[2] How to cite this paper: Madhu Sharma | Dr. Tripti Yadav "Sanganer Textile and Dye Industries Causing Serious Environmental Pollution" Published in International Journal of Trend in Scientific Research and Development (ijtsrd), ISSN: 2456- 6470, Volume-5 | Issue-4, June 2021, pp.1014-1016, URL: www.ijtsrd.com/papers/ijtsrd42509.pdf Copyright © 2021 by author (s) and International Journal ofTrendinScientific Research and Development Journal. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (CC BY 4.0) (http://creativecommons.org/licenses/by/4.0) INTRODUCTION Dye production in India is estimated to be around 64,000 tonnes, which is about 6.6% of the world production. There are around 700 varieties of dyes and dye intermediates produced in India, mainly direct dyes, acid dyes, reactive dyes and pigments. Most of these dyes have not been characterized regarding their chemical nature, purity, possible toxicity or their impact on health and the environment. Yet, they are widelyused by textile, leather, paint and even the food industry. The textile industry in India alone consumes up to 80% of the total dyestuffs produced. In Rajasthan state particularly, textile mills represent an important economic sector. Sanganer is famous for dyeing and printing of colorful dresses, bed sheets, curtains, dress material and variety of other textiles.Bulk of the textile products of these industries is exported. It is located about 15 km south of Jaipur, the State capital that has a population of more than two million people. The total area ofSanganerisabout 635.5 Sq. km out of which, 12.9 Sq. km comprises the urban area. Most of the textile industries of Sanganer are IJTSRD42509
  • 2. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1015 concentrated in this urban area. There are estimated to be around 500 block and screen printing units in Sanganer. Of all dyes produced across the world, 11% goes out as effluents, 2% from manufacturing and as much as 9% from coloring. The effluents from dyeing and textile industries contain chemicals with intense colors and the release of these effluents to receiving streamsmaybeobjectionablefor various aesthetic reasons. Besides a number of dyes used by these textile industries are not degradable. Further, these colored dye wastes contain compounds that are difficult to treat biologically due to their resistance against biodegradation. The dye effluents may contain some components or moieties that could be toxic, carcinogenic or mutagenic to aquatic life. Central Pollution Control Board has listed the dye and dye intermediates industry as one of the heavily polluting industries (CPCB, 1990). Theyarethus, a potent hazard to the natural sources like soil, water, flora, fauna, livestock and human population. Ecological and toxicological problems due to the discharge of wastewaters from Sanganer textile industries in local drainage (Amani Shah Ka Nallah) have been one of the most important water pollution problems in this area. Studies have clearly indicated that the industrial effluents, which are directly discharged into the Amani Shah Ka Nallah, drainage contain highly mutagenic compounds. These compounds are also contaminating the surface and even underground water, thereby, making it unfit for irrigation and drinking [1] High concentrations of heavy metals like Cu, Cd, Zn, Pb, Ni, etc. have also been reported in this area [2] Dyes and heavy metals have been considered to be the possible source of genotoxic activity in dyeing and textile effluents. Several dyes have been investigated andfoundtobecarcinogenic [3] Since large quantities of dyes are used, such pollution due to dyes may occur on a significant scale. Assessment of genotoxicity of dyes is therefore of utmost importance.Most of the dyes, being openly sold in Sanganer markets have no information regarding their chemical nature, purity or possible mutagenicity or toxicity. This study was thus planned to investigate the mutagenic potential of the dyes available in markets of Sanganer. DISCUSSION Textile finishing processes (Yarns, fabrics, nonwovens,knits and rugs) such as dyeing and printing. These dyes are reactive, direct, dispersed, indigo, sulphur and vats. Such that their presence in the liquid effluents resulting from the textile washing constitutes a serious risk, in the absence of their purification, for the quality of receiving aquatic environments.[4] Indeed, the presence of these dyes and pigments can cause a significant alteration in the ecological conditions of the aquatic fauna and flora, because of the lack of their biodegradability. This has a negative impact on the equilibrium of the aquatic environment by causing serious dangers, namely the obvious dangers (Eutrophication, under-oxygenation, color, turbidity andodor),thelong-term dangers (Persistence, bioaccumulation of carcinogenic aromatic products and formation of by-products of chlorination), mutagenicity and carcinogenicity. The textile finishing dyes are organic compounds capable of absorbing the light radiation in the visible range of the spectrumandof reflecting or diffusing complementary radiation on the one hand, and dyeing a substance in a sustainable manneronthe other hand [5]. They consist of chromophoric groups, auxochromes and conjugated aromatic structures. These groups have specific independent properties, i.e., the color and the ability to be fixed on such a textile support, during dyeing and/or printing [6]. Chromophoric groups are unsaturated groups consisting of atoms or groups of atoms, in which the arrangement of successive single and double bonds resonates with the unstable mesomeric form thus allowing the absorption of light rays gathers the mainchromophoricandauxochromicgroupsclassifiedby the increasing intensity. These dye waste waters can produce several dangerous problems, namely aesthetic and health problems such as changes in the quality (color and odor) of water and make it toxic, as they can cause allergies, dermatitis, skin irritations, cancers and mutations inhumans[7].Furthermore,between 60 and 70% of azo dyes are toxic, carcinogenic and are refractory to conventional treatment processes because of their resistancetoconventional physicochemical destruction and the absence of their biodegradability [8]. This interrupted the phenomenon of photosynthesis in marine plants by triggering the phenomenon of eutrophication, under the effect of the release of mineral elements such as nitrates, nitrites and phosphates in an uncontrolledmanner, and produced the long-term hazards of persistence, bioaccumulation, by products of chlorination, mutagenicity and carcinogenicity [9]. In terms of toxicity, the most toxic synthetic organic dyes are azo dyes and more particularly diazo and cationic dyes [9]. These types of dyes have carcinogenic effects on humansandanimalsprimarily,asthe electron-withdrawing character of azo groups generates electronic deficiencies. This makes azo compounds uncomfortable with oxidative catabolism under aerobic environmental conditions. RESULTS In the light of this review, we can conclude that synthetic dyes and pigments applied to textile finishing processes are numerous and diverse in termsofchromophoregroups(Azo groups, anthraquinone groups, indigoids, xanthenes, phthalocyanines, nitroseds, triphenylmethanes and polymethines) and application techniques (Water-soluble dyes (Acidic, basic, metalliferous, reactive and direct dyes) and water-insoluble dyes (Vat dyes, sulfur dyes and dispersible)). The majority of these dyes are azo (60–70 %) characterized by high chemical stability with respect to chemicals and products due to the combination of azo groups with aromatic rings. The presence of these dyes and its residues in the effluents discharged into aquatic environments, as well astheirrelativebiodegradability,have a negative impact on the environment and moreparticularly on aquatic ecosystems because of their toxic and carcinogenic effects as they occur. Accumulate throughout the food chain of aquatic fauna, on the one hand and dysfunctional physiological processes of aquatic flora (Plants, diatoms and algae) by disrupting their photosynthesis mechanisms by the lack of circulation of the oxygen and absorption of light in aquatic environments, on the other hand. Besides, these textile dyes must eliminate according to processes, which will be the interest of a future review, of biological, chemical,physical andphysicochemical treatment before their evacuation in aquatic environments.[10] CONCLUSION Among the textile industries, one of the most extensively used as dyes are synthetic chemicals. Approximately 10,000 different dyes and pigments are used industrially and 0.7 million tonnes of synthetic dyes produced annually, worldwide [11] India’s dye industry produces differenttype
  • 3. International Journal of Trend in Scientific Research and Development (IJTSRD) @ www.ijtsrd.com eISSN: 2456-6470 @ IJTSRD | Unique Paper ID – IJTSRD42509 | Volume – 5 | Issue – 4 | May-June 2021 Page 1016 of dyes and pigments. Nearly 7,00,000 tonnes of dyes are produced annually Worldwide [12] Production of dye stuffs and pigments in India is close to 80,000 tonnes. India is the second large exporter of dye stuffs and intermediates after China [13] Azo dyes being the large group of synthetic dyes constitute up to 70% of all known commercial dyes produced [14] Synthetic dyes generally classified in to reactive, acidic, vat, dispersing, direct and sulphur etc. During the dyeing process, approximately 10-15% of the dyes are released in to the wastewaters, causing serious environmental and health hazards [15] Disposal of these dyes into the environment causes serious threat, since they may significantly affect the photosynthetic activity of hydrophtes by reducing light penetration and also toxic to aquatic organisms due to their breakdown products [16] Dyes may also be toxic to some aquatic life due to the presence of aromatics and metals, chlorides etc [16] The textile finishing generates a large amount of waste water containing dyes and represents one of the largest causes of water pollution .Considerable attention has been given in evaluating the capability ofmicroorganismsindecolourizing and degrading the azo dyes. Many studies on the decolourizing capability of microorganisms especially fungi and bacteria have been reported. Various physical and chemical methods have been used for the removal of dyes from wastewater effluent. However, implementation of physical and chemical methods have inherent drawbacks of being economically unfeasible, unabletocompletelyremove the recalcitrant azo dyes and organic metabolites maycause pollution problems and involving complicated procedures . REFERENCES [1] Ajay kumar Pandey and Vinay Dubey.Biodegradation of Azo dye reactive red BL by Alcaligenes sp. AA09. International Journal of Engineering and Science 2012; 1: 54-60. [2] Aksu Z, Kilic N, Ertugrul V and Donmez G. Inhibitory effects of chromium (Vl) and Remazol black onchromium (Vl) and dye stuff removals by Trametesversicolor. Enzyme and Microbial Technology 2007;40: 1167-1174. [3] Carliell C M, Barclay S J, Shaw C, Wheatley A D and Buckley C A. The effect of salts used in textile dyeing on microbial decolourization of a reactive azo dye. Environmental Technology1998;19(11):1133–1137. [4] Cetin D and DonmezG. “Decolourization of reactive dyes by mixed cultures isolated from textile effluent under anaerobic conditions” Enzymes and Microbial Technology 2006; 38: 926-930. [5] Chen K C, Hung W T, Wu J Y and Houng J Y. Microbial decolourization of azo dyes by Proteus mirabilis. Journal of Industrial Microbiology and Biotechnology 1999; 23: 686- 690. [6] Chen K C, Jane Y W, Liou D J and Sz-Chwun J Decolourization textile dyes by newly isolated bacterial strain. Journal of Biotechnology 2003; 101: 57-68. [7] Dawkar V V, Jadhav U U, Jadhav S U and Govindwar S P. Biodegradation of disperse textile dyeBrown3REL by newly isolated Bacillus sp. VUS. Journal of Applied Microbiology 2008; 105: 14-24. [8] Dykes G A, Timm R G and Von Holy A. Azoreductase activity in bacteria associated with the greening of instant chocolate puddings. Applied Environmental Microbiology 1994; 60: 3027-3029. [9] EI-Sersy N A. bioremediation of methylene blue by Bacillus thuringiensis 4G 1: application of statistical designs and surface plots for optimization. Biotechnology 2007; 6 (1): 34-39. [10] Feng J, Cerniglia C E and Chen H. Toxicological significance of azo dye metabolism by human intestinal microbiota. Front Biosciences (Elite Ed) 2012; 4: 568-586. [11] Forgacs E, Cserhati T and Oros G. Removal of synthetic dyes from wastewaters: Review on Environmental International 2004; 30: 953–971. [12] Gupta R, Gigras P, Mohapatra H, Goswami V K and Chauhan B. Microbial α-amylases: a biotechnological perspective. Process Biochemistry2003; 38:1599- 1616. [13] Hao O J, Kim H and Chaing P C. Decolourization of wastewater critical reviews. Environmental and Science Technology 2000; 30:449-505. [14] Jacob Thomson. Impact of Industries on the Ground Water Quality ofTiruppuranditsEthical implications, Ph.D. Thesis, Dept. of Zoology, University of Madras, Chennai 1998. [15] Jadhav S U, Kalme S D and Govindwar S P. Biodegradation of methyl red by Galactomyces geotrichum MTCC 1360. Intenational Bio deterioration and Biodegradation 2008;62:135-142. [16] Joshni T Chacko and Subramaniam K. Enzymatic degradation of Azo dyes- A Review. International Journal of Environmental Sciences 2011; 1:6.