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O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 67|P a g e
Mathematical modelling and analysis of the mushroom drying
process at the optimal temperature
O. Kubaychuk*, O. Mazurenko**, T. Roman***
* (Department of Computer Science, National University of Food Technologies, Kyiv, Ukraine)
** (Department of Electrical Engineering, National University of Food Technologies, Kyiv, Ukraine)
*** (Department of Electrical Engineering, National University of Food Technologies, Kyiv, Ukraine)
ABSTRACT
To preserve food is used drying method. It was found experimentally that drying mushroom caps and legs should
be conducted at temperatures close to 52,5°C and 55,5°C, accordingly. In this case, we can get the product of the
highest quality. Statistically, we proved that the drying processes of mushroom caps are different for fixed levels
of temperature (from 40° C to 80° C, by step 10° C). At the same time, at higher temperatures, the nature of the
process changes abruptly. Based on the experimental data, the polynomial regression model was built. This
model can used for estimating and forecasting a specific evaporation heat at the optimal temperature.
Keywords – drying process, humidity, mushroom, optimal temperature, polynomial model, specific evaporation
heat
I. INTRODUCTION
There are many ways to preserve a food. One of
the most important is the drying. It is important that
products are harvested kept its taste and usefulness.
For example, some problems of drying are studied in
[1]. Mushrooms are the very delicious product, but
contain only 10% of dry matter and the remaining
90% is water. Nutritional value of mushrooms bodies
determined by the content of essential and
conditionally essential amino acids: lysine, threonine,
valine, leucine, isoleucine, tryptophan, cysteine,
methionine, phenylalanine and tyrosine. The
biological value of mushroom mycelium index is
determined by essential amino acids, is ranged from
72,9-98,6 (according to EAA index). There are some
limiting amino acids: methionine, tsystin, leucine,
isoleucine. The biological value is 67,8-95,8
(according BV FAO). Amino acid index ranges 36,0-
90,0. Index nutritional 22.2 (according to N FAO).
The fruit body chemical composition includes
vitamins: thiamine (B1), riboflavin (B2), niacin (PP),
pyridoxine (B6), biotin (H), ascorbic acid (C), folic
acid (B9). The content of macro - and microelements
that fully satisfy the needs of the human body
provides the great value of fruiting bodies. Especially
important and scarce micronutrients in mushrooms
bodies consider the presence of selenium (Se).
Dried mushrooms are part of many delicious
dishes. When the process parameters are chosen
properly (drying temperature and final product
humidity) a high quality products are achieved
(nutrients are stored, they have a pleasant flavor and
taste). The drying process is a heat and mass transfer
phenomenon where water migrates from the interior
of the drying product on to the surface from which it
evaporates. In [2] was established there exist a
significant difference between caps and legs of
mushroom body. Drying processes of mushrooms
legs are studied in [3].
II. MATERIALS AND METHODS
One of the modern methods for determining
specific evaporation heat is a method of simultaneous
thermal analysis (STA), which combines the
calorimeter and thermo-grav analysis [4,5].
Laboratory facility DMKV-1 (Fig. 1, Fig. 2) was
developed at the Institute of Technical Thermal
Physics NAS Ukraine specially for this kind of
research [6] and combines the functionality of
calorimetry and thermogravimetry.
For experiments was used thin (about 1 mm
thick) pileus tissue slices of the mushroom fruit body
"Champignon". Drying of the samples was carried
out at 40 ° C, 50 ° C, 60 ° C, 70 ° C, 80 ° C, air
velocity of 0.8 cm / s and its initial moisture content
of 8.5 g / kg. Registration of heat flows and changes
in the mass of the sample drying process was carried
out continuously. Drying specimens finished when
they reach equilibrium moisture. The mass of dry
matter was determined by final drying samples
calorimeter at 105 ° C to constant weight.
Symbols:
r- specific evaporation heat, kJ / kg * K
t- time from the beginning to the end of the
experiment, s
w - moisture,%
T- temperature, ° C
RESEARCH ARTICLE OPEN ACCESS
O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 68|P a g e
Fig. 1. Structural schema DMKV-1.
Fig. 2. Fundamental thermal unit schema DMKV-1.
1, 2 - top and bottom thermostatted blocks;
3 - calorimeter platform with the main electroheater;
4, 5 - heat flow meters;
6 - cell with the sample of research material;
7 - cell with the standard; 8 - working chamber.
III. RESULTS AND DISCUSSION
It was found experimentally that drying
mushroom caps should be conducted at temperatures
close to 52,5°C. In this case, we can get the product
of the highest quality. Based on the data of the
experiment it is important to build and explore the
specific evaporation heat ( r ) dependence of
humidity ( w ) at the optimum temperature
52.5optT  for the constant pressure condition.
During the experiment, five temperature levels
were fixed at 40° C, 50° C, 60° C, 70° C, 80°C.
Accordingly, we have five different drying processes.
A specific evaporation heat at a given level of
humidity w , was measured for each process (Table
1). The null hypothesis is that the data for each
drying temperature have identical distributions.
Since, the amounts of samples small ( 9n  ) and
there is no reason to believe that data is normally
distributed, non-parametric tests were used
(Wilcoxon test and sign-test). Both tests yielded
similar results: the hypothesis is rejected at
significance level 0,05  for all pairs of variables,
besides the pair of variables, which corresponds to
the value of 60 ° C and 70 ° C, where type I error
slightly higher. Thus, statistically, we also have to
deal with five different processes.
We can assume that for adequate regression
model, it is possible to make the conversion
dependent variable:
, 0
log , 0
w
w
w



 



by scatter diagram visualization in STATISTICA.
Using the program Boxtidwell, we estimate
maximum likelihood parameter conversion  and
accordingly, it is desirable to consider transformation
2
w w . Even better results can be achieved by
approximation using the polynomial regression as
2
0 1 2y b b x b x   . A regression curve and its
analytical appearance, 95% confidence interval
(dotted line) is shown on each of the (Fig. 3-7).
Quality of the models can be estimated on the Table
2.
As seen from Table 2, all of the coefficients 0b
and 2b are significant at the level 0,05  , but the
coefficient 1b is not at 70°C. Therefore, the equation
for 70° C is better to take without the appropriate
member: 2
2527,752 0,004y x  , and estimation
error will decrease from 3.59 to 3.43.
Since Fig. 7, we can see that the nature of the
drying process changes dramatically. There is no
sense to use the experimental data at 80°C,
considering that 52.5optT  (Table 3).
Then, using the results (Table 3) a linear
dependence 0 0( )b f T , 1 1( )b f T and 2 2( )b f T
is build:
0 2855,862 247,317b T   ,
52.5optT  , hence 0 2608,545b  .
1 6,423 4,628b T   ,
52.5optT  , hence 1 1,795b  .
2 0,111 0,076b T    ,
52.5optT  , hence 2 0,035b   . Finally, the model is:
2
2608,545 1,795 0,035r w w   , and the
corresponding 95% confidence intervals for
coefficients, are: 0 [2603,801; 2613,288]b  ,
1 [1,037, 2,552]b  , 2 [ 0,052; 0,017]b    .
O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 69|P a g e
Table 1: observation data
w
T=40°C T=50°C T=60°C T=70°C T=80°C
№ r № r № r № r № r
90 1 2462,00632 10 2500,27542 19 2421,51408 28 2486,82968 37 2497,86484
80 2 2594,44269 11 2574,30108 20 2472,96711 29 2504,08285 38 2498,1502
70 3 2613,68588 12 2605,46985 21 2513,30813 30 2509,72037 39 2490,06305
60 4 2652,21084 13 2616,01081 22 2539,48108 31 2514,26749 40 2499,64728
50 5 2664,11301 14 2626,14557 23 2553,54145 32 2516,70095 41 2499,80394
40 6 2677,59847 15 2647,04263 24 2570,54635 33 2517,43496 42 2500,39347
30 7 2689,49413 16 2648,88333 25 2576,40635 34 2522,34935 43 2501,35014
20 8 2698,80949 17 2650,12242 26 2586,75565 35 2524,93564 44 2506,25214
15 9 2714,35886 18 2650,77995 27 2589,05379 36 2528,43252 45 2509,20498
Table 2: quality of the models
Model 2
R p-value 0b p-value 1b p-value 2b Residuals normality
40°C 0,925 0,000 0,150 0,017 yes
50°C 0,954 0,000 0,035 0,003 yes
60°C 0,992 0,000 0,012 0,000 yes
70°C 0,938 0,000 0,560 0,046 yes
80°C 0,920 0,000 0,005 0,018 yes
Тable 3: estimations of the coefficients
Model 0b 1b 2b
40°C 2668,3331 2,6648 -0,0510
50°C 2620,1616 2,2275 -0,0376
60°C 2570,8244 1,4056 -0,0333
70°C 2527,7520 0 -0,0040
Fig. 3: Drying at 40°С
O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 70|P a g e
Fig. 4: Drying at 50°С
Fig. 5: Drying at 60°С
O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 71|P a g e
Fig. 6: Drying at 70°С
Fig. 7: Drying at 80°С
IV. CONCLUSION
The results obtained in this paper allow one to
see the drying behaviour of mushrooms caps in case
of five fixed levels. Statistically proved, that we have
a sample from a mixture of distributions. We built the
polynomial regression for each temperature level.
Furthermore, using the regression coefficients, we
build the estimator for specific evaporation heat in
case the optimal temperature. All equations holds
under constant pressure condition. This is another
important step to solving the problem of effective
drying process for mushrooms. Future research will
be devoted to the simulation drying processes with an
arbitrary pressure.
REFERENCES
[1] S Sharadai, Mathematical Models for drying
behaviour of green beans, International
O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com
ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72
www.ijera.com 72|P a g e
Journal of Engineering Research and
Applications, 3(3), 2013, 845-851.
[2] T. Roman, O. Masurenko, A. Dubyvko, A.
Bybych, V. Zakharov, Physical and
biochemical changes at mushroom cells,
Harchova Promyslovist, 15, 2014, 32-35.
[3] T. Roman, O. Mazurenko, O. Kubaychuk,
N. Vovkodav, Modeling of champignon
stipe drying process, Scientific Works of
National University of Food Technologies,
21(6), 2015, 147-153.
[4] Simatos D., Faure М., Bonjour E., Couach
M., Differential thermal analysis and
differential scanning calorimetry in the
study of water in foods: Water relation of
foods, Proc. Int. Symp. London - N.Y.:
Acad. Press, 1975, 193-209.
[5] Dmytrenko N., Dubovikova N., Sniezhkin
Yu., Mykhailyk V., Dekusha L., Vorobyov
L., Vyvchennya vplyvu stanu vody v
kharchovykh roslynnykh materialakh na
teplotu vyparovuvannya, Naukovi pratsi
ONAKhT, 40, 2011, 71-75.
[6] Sniezhkin Yu. F., Dekusha L. V.,
Dubovikova N. S., Hryshchenko T. H.,
Vorobyov L. I., Boryak L. A., Patent
Ukrainy № 84075 МПК G01N 25/26,
G01N25/28. Kalorymetrychniy prystriy dlya
vyznachennya pytomoi teploty
vyparovuvannya vology i organichnykh
ridyn z materialiv, Kyiv, 2006.

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Mathematical modelling and analysis of the mushroom drying process at the optimal temperature

  • 1. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 67|P a g e Mathematical modelling and analysis of the mushroom drying process at the optimal temperature O. Kubaychuk*, O. Mazurenko**, T. Roman*** * (Department of Computer Science, National University of Food Technologies, Kyiv, Ukraine) ** (Department of Electrical Engineering, National University of Food Technologies, Kyiv, Ukraine) *** (Department of Electrical Engineering, National University of Food Technologies, Kyiv, Ukraine) ABSTRACT To preserve food is used drying method. It was found experimentally that drying mushroom caps and legs should be conducted at temperatures close to 52,5°C and 55,5°C, accordingly. In this case, we can get the product of the highest quality. Statistically, we proved that the drying processes of mushroom caps are different for fixed levels of temperature (from 40° C to 80° C, by step 10° C). At the same time, at higher temperatures, the nature of the process changes abruptly. Based on the experimental data, the polynomial regression model was built. This model can used for estimating and forecasting a specific evaporation heat at the optimal temperature. Keywords – drying process, humidity, mushroom, optimal temperature, polynomial model, specific evaporation heat I. INTRODUCTION There are many ways to preserve a food. One of the most important is the drying. It is important that products are harvested kept its taste and usefulness. For example, some problems of drying are studied in [1]. Mushrooms are the very delicious product, but contain only 10% of dry matter and the remaining 90% is water. Nutritional value of mushrooms bodies determined by the content of essential and conditionally essential amino acids: lysine, threonine, valine, leucine, isoleucine, tryptophan, cysteine, methionine, phenylalanine and tyrosine. The biological value of mushroom mycelium index is determined by essential amino acids, is ranged from 72,9-98,6 (according to EAA index). There are some limiting amino acids: methionine, tsystin, leucine, isoleucine. The biological value is 67,8-95,8 (according BV FAO). Amino acid index ranges 36,0- 90,0. Index nutritional 22.2 (according to N FAO). The fruit body chemical composition includes vitamins: thiamine (B1), riboflavin (B2), niacin (PP), pyridoxine (B6), biotin (H), ascorbic acid (C), folic acid (B9). The content of macro - and microelements that fully satisfy the needs of the human body provides the great value of fruiting bodies. Especially important and scarce micronutrients in mushrooms bodies consider the presence of selenium (Se). Dried mushrooms are part of many delicious dishes. When the process parameters are chosen properly (drying temperature and final product humidity) a high quality products are achieved (nutrients are stored, they have a pleasant flavor and taste). The drying process is a heat and mass transfer phenomenon where water migrates from the interior of the drying product on to the surface from which it evaporates. In [2] was established there exist a significant difference between caps and legs of mushroom body. Drying processes of mushrooms legs are studied in [3]. II. MATERIALS AND METHODS One of the modern methods for determining specific evaporation heat is a method of simultaneous thermal analysis (STA), which combines the calorimeter and thermo-grav analysis [4,5]. Laboratory facility DMKV-1 (Fig. 1, Fig. 2) was developed at the Institute of Technical Thermal Physics NAS Ukraine specially for this kind of research [6] and combines the functionality of calorimetry and thermogravimetry. For experiments was used thin (about 1 mm thick) pileus tissue slices of the mushroom fruit body "Champignon". Drying of the samples was carried out at 40 ° C, 50 ° C, 60 ° C, 70 ° C, 80 ° C, air velocity of 0.8 cm / s and its initial moisture content of 8.5 g / kg. Registration of heat flows and changes in the mass of the sample drying process was carried out continuously. Drying specimens finished when they reach equilibrium moisture. The mass of dry matter was determined by final drying samples calorimeter at 105 ° C to constant weight. Symbols: r- specific evaporation heat, kJ / kg * K t- time from the beginning to the end of the experiment, s w - moisture,% T- temperature, ° C RESEARCH ARTICLE OPEN ACCESS
  • 2. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 68|P a g e Fig. 1. Structural schema DMKV-1. Fig. 2. Fundamental thermal unit schema DMKV-1. 1, 2 - top and bottom thermostatted blocks; 3 - calorimeter platform with the main electroheater; 4, 5 - heat flow meters; 6 - cell with the sample of research material; 7 - cell with the standard; 8 - working chamber. III. RESULTS AND DISCUSSION It was found experimentally that drying mushroom caps should be conducted at temperatures close to 52,5°C. In this case, we can get the product of the highest quality. Based on the data of the experiment it is important to build and explore the specific evaporation heat ( r ) dependence of humidity ( w ) at the optimum temperature 52.5optT  for the constant pressure condition. During the experiment, five temperature levels were fixed at 40° C, 50° C, 60° C, 70° C, 80°C. Accordingly, we have five different drying processes. A specific evaporation heat at a given level of humidity w , was measured for each process (Table 1). The null hypothesis is that the data for each drying temperature have identical distributions. Since, the amounts of samples small ( 9n  ) and there is no reason to believe that data is normally distributed, non-parametric tests were used (Wilcoxon test and sign-test). Both tests yielded similar results: the hypothesis is rejected at significance level 0,05  for all pairs of variables, besides the pair of variables, which corresponds to the value of 60 ° C and 70 ° C, where type I error slightly higher. Thus, statistically, we also have to deal with five different processes. We can assume that for adequate regression model, it is possible to make the conversion dependent variable: , 0 log , 0 w w w         by scatter diagram visualization in STATISTICA. Using the program Boxtidwell, we estimate maximum likelihood parameter conversion  and accordingly, it is desirable to consider transformation 2 w w . Even better results can be achieved by approximation using the polynomial regression as 2 0 1 2y b b x b x   . A regression curve and its analytical appearance, 95% confidence interval (dotted line) is shown on each of the (Fig. 3-7). Quality of the models can be estimated on the Table 2. As seen from Table 2, all of the coefficients 0b and 2b are significant at the level 0,05  , but the coefficient 1b is not at 70°C. Therefore, the equation for 70° C is better to take without the appropriate member: 2 2527,752 0,004y x  , and estimation error will decrease from 3.59 to 3.43. Since Fig. 7, we can see that the nature of the drying process changes dramatically. There is no sense to use the experimental data at 80°C, considering that 52.5optT  (Table 3). Then, using the results (Table 3) a linear dependence 0 0( )b f T , 1 1( )b f T and 2 2( )b f T is build: 0 2855,862 247,317b T   , 52.5optT  , hence 0 2608,545b  . 1 6,423 4,628b T   , 52.5optT  , hence 1 1,795b  . 2 0,111 0,076b T    , 52.5optT  , hence 2 0,035b   . Finally, the model is: 2 2608,545 1,795 0,035r w w   , and the corresponding 95% confidence intervals for coefficients, are: 0 [2603,801; 2613,288]b  , 1 [1,037, 2,552]b  , 2 [ 0,052; 0,017]b    .
  • 3. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 69|P a g e Table 1: observation data w T=40°C T=50°C T=60°C T=70°C T=80°C № r № r № r № r № r 90 1 2462,00632 10 2500,27542 19 2421,51408 28 2486,82968 37 2497,86484 80 2 2594,44269 11 2574,30108 20 2472,96711 29 2504,08285 38 2498,1502 70 3 2613,68588 12 2605,46985 21 2513,30813 30 2509,72037 39 2490,06305 60 4 2652,21084 13 2616,01081 22 2539,48108 31 2514,26749 40 2499,64728 50 5 2664,11301 14 2626,14557 23 2553,54145 32 2516,70095 41 2499,80394 40 6 2677,59847 15 2647,04263 24 2570,54635 33 2517,43496 42 2500,39347 30 7 2689,49413 16 2648,88333 25 2576,40635 34 2522,34935 43 2501,35014 20 8 2698,80949 17 2650,12242 26 2586,75565 35 2524,93564 44 2506,25214 15 9 2714,35886 18 2650,77995 27 2589,05379 36 2528,43252 45 2509,20498 Table 2: quality of the models Model 2 R p-value 0b p-value 1b p-value 2b Residuals normality 40°C 0,925 0,000 0,150 0,017 yes 50°C 0,954 0,000 0,035 0,003 yes 60°C 0,992 0,000 0,012 0,000 yes 70°C 0,938 0,000 0,560 0,046 yes 80°C 0,920 0,000 0,005 0,018 yes Тable 3: estimations of the coefficients Model 0b 1b 2b 40°C 2668,3331 2,6648 -0,0510 50°C 2620,1616 2,2275 -0,0376 60°C 2570,8244 1,4056 -0,0333 70°C 2527,7520 0 -0,0040 Fig. 3: Drying at 40°С
  • 4. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 70|P a g e Fig. 4: Drying at 50°С Fig. 5: Drying at 60°С
  • 5. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 71|P a g e Fig. 6: Drying at 70°С Fig. 7: Drying at 80°С IV. CONCLUSION The results obtained in this paper allow one to see the drying behaviour of mushrooms caps in case of five fixed levels. Statistically proved, that we have a sample from a mixture of distributions. We built the polynomial regression for each temperature level. Furthermore, using the regression coefficients, we build the estimator for specific evaporation heat in case the optimal temperature. All equations holds under constant pressure condition. This is another important step to solving the problem of effective drying process for mushrooms. Future research will be devoted to the simulation drying processes with an arbitrary pressure. REFERENCES [1] S Sharadai, Mathematical Models for drying behaviour of green beans, International
  • 6. O. Kubaychuk et al. Int. Journal of Engineering Research and Applications www.ijera.com ISSN: 2248-9622, Vol. 6, Issue 2, (Part - 3) February 2016, pp.67-72 www.ijera.com 72|P a g e Journal of Engineering Research and Applications, 3(3), 2013, 845-851. [2] T. Roman, O. Masurenko, A. Dubyvko, A. Bybych, V. Zakharov, Physical and biochemical changes at mushroom cells, Harchova Promyslovist, 15, 2014, 32-35. [3] T. Roman, O. Mazurenko, O. Kubaychuk, N. Vovkodav, Modeling of champignon stipe drying process, Scientific Works of National University of Food Technologies, 21(6), 2015, 147-153. [4] Simatos D., Faure М., Bonjour E., Couach M., Differential thermal analysis and differential scanning calorimetry in the study of water in foods: Water relation of foods, Proc. Int. Symp. London - N.Y.: Acad. Press, 1975, 193-209. [5] Dmytrenko N., Dubovikova N., Sniezhkin Yu., Mykhailyk V., Dekusha L., Vorobyov L., Vyvchennya vplyvu stanu vody v kharchovykh roslynnykh materialakh na teplotu vyparovuvannya, Naukovi pratsi ONAKhT, 40, 2011, 71-75. [6] Sniezhkin Yu. F., Dekusha L. V., Dubovikova N. S., Hryshchenko T. H., Vorobyov L. I., Boryak L. A., Patent Ukrainy № 84075 МПК G01N 25/26, G01N25/28. Kalorymetrychniy prystriy dlya vyznachennya pytomoi teploty vyparovuvannya vology i organichnykh ridyn z materialiv, Kyiv, 2006.