CCl4 molecule can give IR and Raman spectroscopy. Selection rule of IR spectra: During the vibration dipolemoment change. Selection rule of Raman spectra: During the vibration polarizibility change. CCl4 molecule centrosymmetric molecule, so it can exibit Raman spectroscopy According to mutual exclusion principle, IR inactive modes are raman active Raman inactive modes are IR active modes. Therefore, CCl4 molecule can give multiple peaks. Solution CCl4 molecule can give IR and Raman spectroscopy. Selection rule of IR spectra: During the vibration dipolemoment change. Selection rule of Raman spectra: During the vibration polarizibility change. CCl4 molecule centrosymmetric molecule, so it can exibit Raman spectroscopy According to mutual exclusion principle, IR inactive modes are raman active Raman inactive modes are IR active modes. Therefore, CCl4 molecule can give multiple peaks..