Point of zero charge related to the adsorption phenomenon I surface chemistry. Here it is the point if achievement of zero charge density on a surface. If pHzpc is 8.5 that means at this pH solid submerged in electrolyte will show zero electrical charge on the surface. P sorption refers to binding of phosphates in other forms to soil particles. At high pH, P availability is low because of reaction of phosphates to calcium which result in formation of apatite. At low pH, phosphate reacts with aluminum, iron etc and results in formation of various other minerals. Solution Point of zero charge related to the adsorption phenomenon I surface chemistry. Here it is the point if achievement of zero charge density on a surface. If pHzpc is 8.5 that means at this pH solid submerged in electrolyte will show zero electrical charge on the surface. P sorption refers to binding of phosphates in other forms to soil particles. At high pH, P availability is low because of reaction of phosphates to calcium which result in formation of apatite. At low pH, phosphate reacts with aluminum, iron etc and results in formation of various other minerals..