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UAIPD #: 13-0017
Decaboronate Salts To Induce Hypergolicity
Dr. Robin Rogers
Dr. Parker McCrary
Current Technology
• Industry currently uses hypergolic solutions
for propellant or fuel in rocket propulsion
systems.
• Hypergolic solutions do not need an
ignition source
– Hydrazine, MMH, UDMH, RP-1
• Hydrazine and other hypergolic solutions
are extremely toxic and/or difficult to store
in liquid form.
• RP-1 uses liquid oxygen which is inefficient
to pressurize and store.
• Growing demand for greener, safer and
more cost effective propulsion systems.
• Hypergolic propellants components
spontaneously ignite when they come into
contact with each other.
• Hypergolic propellants eliminate the need for
an ignition source and rely only on a
fuel/oxidizer mix to combust.
Hypergolicity
Only the fuel and the oxidizer are
needed to create combustion.
• Decaboronate salt has a hypergolic
relationship with nitric acid.
• Salts can be dissolved into other ionic
fuel solutions and cause them to
become hypergolic.
• Any solution that can dissolve the
salts can become hypergolic and thus
used as a fuel source.
• Less toxic than hydrazine and more
efficient than liquid oxygen methods.
Decaboronate Salt Technology
Ionic liquid containing dissolved
decaboronate salts interacting with nitric
acid
• Salts can be used as primary, solid bipropellants
• Can be used to induce hypergolicity when dissolved in other solutions
• Can be used as an additive to reduce ignition delay times in known propellants
– Decaboronate ignition delay: < 3 ms
– Hydrazine: ~15 ms
• Salts can be suspended in ionic liquids
– Not sensitive to water
• Will ignite on contact with safer and benign oxidizers such as 99% or 70% nitric
acid which can replace liquid oxygen in RP-1 bipropellant.
– Reduces inefficiencies of storing liquid oxygen
– Lowers toxicity and hazardousness of propellant storage.
Advantages
Dr. Robin Rogers
• Ph.D. Chemistry
• Adjunct Professor at The University of
Alabama
• Canada Excellence Research Chair at McGill
University
• Over 100 patents filed
Inventor
Office for Technology Transfer
720 2nd Ct E
Tuscaloosa, AL 35401
OTT@UA.edu
www.OTT.UA.edu

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UAIPD 13-0017

  • 1. UAIPD #: 13-0017 Decaboronate Salts To Induce Hypergolicity Dr. Robin Rogers Dr. Parker McCrary
  • 2. Current Technology • Industry currently uses hypergolic solutions for propellant or fuel in rocket propulsion systems. • Hypergolic solutions do not need an ignition source – Hydrazine, MMH, UDMH, RP-1 • Hydrazine and other hypergolic solutions are extremely toxic and/or difficult to store in liquid form. • RP-1 uses liquid oxygen which is inefficient to pressurize and store. • Growing demand for greener, safer and more cost effective propulsion systems.
  • 3. • Hypergolic propellants components spontaneously ignite when they come into contact with each other. • Hypergolic propellants eliminate the need for an ignition source and rely only on a fuel/oxidizer mix to combust. Hypergolicity Only the fuel and the oxidizer are needed to create combustion.
  • 4. • Decaboronate salt has a hypergolic relationship with nitric acid. • Salts can be dissolved into other ionic fuel solutions and cause them to become hypergolic. • Any solution that can dissolve the salts can become hypergolic and thus used as a fuel source. • Less toxic than hydrazine and more efficient than liquid oxygen methods. Decaboronate Salt Technology Ionic liquid containing dissolved decaboronate salts interacting with nitric acid
  • 5. • Salts can be used as primary, solid bipropellants • Can be used to induce hypergolicity when dissolved in other solutions • Can be used as an additive to reduce ignition delay times in known propellants – Decaboronate ignition delay: < 3 ms – Hydrazine: ~15 ms • Salts can be suspended in ionic liquids – Not sensitive to water • Will ignite on contact with safer and benign oxidizers such as 99% or 70% nitric acid which can replace liquid oxygen in RP-1 bipropellant. – Reduces inefficiencies of storing liquid oxygen – Lowers toxicity and hazardousness of propellant storage. Advantages
  • 6. Dr. Robin Rogers • Ph.D. Chemistry • Adjunct Professor at The University of Alabama • Canada Excellence Research Chair at McGill University • Over 100 patents filed Inventor
  • 7. Office for Technology Transfer 720 2nd Ct E Tuscaloosa, AL 35401 OTT@UA.edu www.OTT.UA.edu

Editor's Notes

  1. Make sure to list references for all numbers, trends, etc. on each slide. Many inventors like to see exactly where the data comes from.
  2. Should read like Wikipedia entry. Try to focus on the high points.
  3. Make sure to list references for all numbers, trends, etc. on each slide. Many inventors like to see exactly where the data comes from.