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( © F U N D A M E N TA L S O F M O D E R N M A N U FA C T U R I N G ;
M AT E R I A L S , P R O C E S S E S A N D S Y S T E M S ,
B Y M . P. G R O O V E R )
SHAPING
PROCESSES FOR
PLASTICS
CHAPTER 13
- PROPERTIES OF POLYMER MELTS
- EXTRUSION
-INJECTION MOLDING
-BLOW MOLDING
SHAPING PROCESSES FOR PLASTICS
 Properties of Polymer Melts
 Extrusion
 Production of Sheet, Film, and Filaments
 Coating Processes
 Injection Molding
 Other Molding Processes
 Thermoforming
 Casting
 Polymer Foam Processing and Forming
 Product Design Considerations
2
PLASTIC PRODUCTS
• Plastics can be shaped into a wide variety of
products:
• Molded parts, Extruded sections, Films, Sheets,
Insulation coatings on electrical wires, Fibers for
textiles
• In addition, plastics are often the principal
ingredient in other materials, such as
• Paints and varnishes, Adhesives, Various
polymer matrix composites
3
PLASTIC SHAPING PROCESSES ARE
IMPORTANT
 Almost unlimited variety of part geometries
 Plastic molding is a net shape process
• Further shaping is not needed
 Less energy is required than for metals due to much
lower processing temperatures
• Handling of product is simplified during production
because of lower temperatures
 Painting or plating is usually not required
4
POLYMER MELTS
• To shape a thermoplastic polymer it must be heated
so that it softens to the consistency of a liquid
• In this form, it is called a polymer melt
• Important properties of polymer melts:
• Viscosity
• Viscoelasticity
5
VISCOSITY OF
POLYMER MELTS
• Fluid property that relates shear stress to shear
rate during flow.
• Shear stress=viscosity times shear rate
• Due to its high molecular weight, a polymer melt
is a thick fluid with high viscosity.
• Most polymer shaping processes involve flow
through small channels or die openings.
• Flow rates are often large, leading to high
shear rates and shear stresses, so significant
pressures are required to accomplish the
processes.
6
 

Ketchup, a highly
viscoelastic fluid (like
the polymer melt)
NEWTONIAN AND
NON-NEWTONIAN FLUIDS
7
• Newtonian Material: Viscosity changes by
temperature (not by time or shear rate)
Examples: Air, water, honey, glycerine,
Kerosene.
• Non-Newtonian Material: Viscosity changes by
temperature, time and shear rate). Examples:
Polymer melt, ketchup, custard, toothpaste,
starch suspensions, paint, shampoo, cream,
etc
VISCOSITY AND
TEMPERATURE
• Viscosity decreases with temperature, thus the fluid becomes
thinner at higher temperatures
Figure 13.2 Viscosity as a function of temperature
for selected polymers at a shear rate of 103 s-1. 8
Temperature Viscosity
VISCOSITY AND
SHEAR RATE
Viscosity of a polymer melt
“usually” decreases with shear
rate, thus the fluid becomes thinner
at higher shear rates.
9
Shear rate Viscosity
Figure 13.1 Viscosity relationships for
Newtonian fluid and typical
polymer melt.
VISCOELASTIC BEHAVIOR
• Material property that determines the strain that the material
experiences when subjected to combinations of stress and
temperature over time
 Combination of viscosity and elasticity
10
VISCOELASTICITY
• Combination of viscosity and elasticity.
• Examples: Shampoo, hand cream,
mayonnaise, toothpaste, yoghurt.
• Temperature, time and shear rate are
important and affect the properties of
viscoelastic materials (here the polymer
melts).
• Example: die swell in extrusion, in which the
hot plastic expands when exiting the die
opening.
11
VISCOELASTIC MATERIAL
12
Viscoelastic Material:
Exhibits both viscous and elastic
material properties. Deformation of the
material is dependent on the strain rate.
Examples:
Paint, polymer melt, bread dough, soft
tissue, shampoo, toothpaste,
mayonnaise, etc.
Polymer pellets
13
EXTRUSION
13.2
EXTRUSION
 Compression process in which material is forced to flow
through a die orifice to provide long continuous product whose
cross-sectional shape is determined by the shape of the
orifice.
 Widely used for thermoplastics and elastomers to mass
produce items such as tubing, pipes, hose, structural shapes,
sheet and film, continuous filaments, and coated electrical
wire.
14
Extrudate
EXTRUDER
Figure 13.4
Components
and features of
a (single-screw)
extruder for
plastics and
elastomers.
15
Feedstock is
moved from
hopper and
preheated.
Polymer is
transformed
into fluid, air
mixed is
extracted, and
material is
compressed.
Melt is
homogenized
and sufficient
pressure
developed to
pump it through
die opening.
RHEOLOGICAL EFFECTS
 A problem in extrusion of polymers is die swell, in which the
profile of extruded material grows in size, reflecting its tendency
to return to its previously larger cross section in the extruder
barrel immediately after being squeezed through the smaller die
opening
16
 Shape memory:
Extruded polymer
"remembers" its
previous shape when in
the larger cross section
of the extruder, tries to
return to it after leaving
the die orifice.
RHEOLOGICAL EFFECTS
• Die swell can be most
easily measured for a
circular cross section by
means of the swell
ratio, defined as
𝑟𝑥 =
𝐷𝑥
𝐷𝑑
EXTRUDER SCREW
• Divided into sections to serve
several functions:
•
• Feed section - feedstock is
moved from hopper and
preheated.
• Compression section - polymer is
transformed into fluid, air mixed
with pellets is extracted from
melt, and material is
compressed.
• Metering section - melt is
homogenized and sufficient
pressure developed to pump it
through die opening.
18
Figure 13.5 Details of an extruder
screw inside the barrel.
Pressure is largely determined by
dc.
MAIN COMPONENTS
OF AN EXTRUDER
• Barrel
• Screw
19
Die - not an extruder component
Special tool that must be fabricated for
particular profile to be produced.
EXTRUSION OF
SOLID PROFILES
• Regular shapes such as
• Rounds
• Squares
• Irregular cross sections such as
• Structural shapes
• Door and window moldings
• Automobile trim
• House siding
20
EXTRUSION DIE FOR SOLID CROSS SECTION
Figure 13.8 (a) Side view cross-section of an extrusion die for
solid regular shapes, such as round stock; (b) front view of die,
with profile of extrudate. Die swell is evident in both views.
21
HOLLOW PROFILES
 Examples: tubes, pipes, hoses, and other cross-sections
containing holes
 Hollow profiles require mandrel to form the shape
 Mandrel held in place using a spider. Polymer melt flows
around legs supporting the mandrel to reunite into a monolithic
tube wall
 Mandrel often includes an air channel through which air is
blown to maintain hollow form of extrudate during hardening
22
FYI: Extrusion bridge die making
a hollow section product. Note
that in the picture the die has
been split to show the material
passing through it. In reality, the
die and the ring fit together, with
a gap for the extruded material to
flow through.
EXTRUSION DIE FOR
HOLLOW SHAPES
Figure 13.10 Side view cross-section of extrusion die for shaping hollow
cross-sections such as tubes and pipes; Section A-A is a front view
cross-section showing how the mandrel is held in place; Section B-B
shows the tubular cross-section just prior to exiting the die; die swell
causes an enlargement of the diameter.
23
WIRE AND CABLE COATING
• Polymer melt is applied to bare wire as it is pulled at high
speed through a die
• A slight vacuum is drawn between wire and polymer to
promote adhesion of coating
• Wire provides rigidity during cooling - usually aided by
passing coated wire through a water trough
• Product is wound onto large spools at speeds up to 50
m/s (10,000 ft/min)
24
EXTRUSION DIE FOR
COATING WIRE
Figure 13.11 Side view
cross-section of die for coating of
electrical wire by extrusion. 25
EXTRUSION DIE FOR
COATING WIRE
26
29
INJECTION MOLDING
13.6
INJECTION MOLDING
 Polymer is heated to a highly
plastic state and forced to
flow under high pressure into
a mold cavity where it
solidifies and the molding is
then removed from cavity.
 Produces discrete
components almost always
to net shape.
 Typical cycle time 10 to 30
sec, but cycles of one minute
or more are not uncommon.
Similar to hot-chamber die casting.
• Pellets fed into heated chamber.
• Melt forced into split die chamber.
• 10,000 to 50,000 psi.
• Mold is water cooled.
• Part is ejected. 30
INJECTION MOLDED PARTS
 Complex and intricate shapes are possible
 Shape limitations:
• Capability to fabricate a mold whose cavity is the
same geometry as part
• Shape must allow for part removal from mold
 Part size from  50 g (2 oz) up to  25 kg (more
than 50 lb), e.g., automobile bumpers
 Injection molding is economical only for large
production quantities due to high cost of mold
31
POLYMERS FOR INJECTION MOLDING
 Injection molding is the most widely used molding process for
thermoplastics.
 Some thermosets and elastomers are injection molded
• Modifications in equipment and operating parameters must be made to
avoid premature cross-linking of these materials before injection.
Parts manufactured by
injection molding
32
Injection Molding Machine
Figure 13.21 Diagram of an injection molding machine, reciprocating
screw type (some mechanical details are simplified).
- Melts and delivers
polymer melt
- Operates much like
an extruder Two principal components
- Opens and
closes mold
each injection
cycle
33
INJECTION MOLDING PROCESS
INJECTION MOLDING MACHINES
• Injection molding machines differ in both injection unit
and clamping unit
• Name of injection molding machine is based on the
type of injection unit used
• Reciprocating-screw injection molding machine
• Plunger-type injection molding machine
• Several clamping designs
• Mechanical (toggle)
• Hydraulic
35
INJECTION MOLDING MACHINES
36
SHRINKAGE
• Reduction in linear size during cooling from molding to room
temperature.
• Polymers have high thermal expansion coefficients, so significant
shrinkage occurs during solidification and cooling in mold.
37
SHRINKAGE FACTORS
Fillers in the plastic tend to reduce shrinkage
Injection pressure – higher pressures force more
material into mold cavity to reduce shrinkage
Compaction time - similar effect – longer time forces
more material into cavity to reduce shrinkage
Molding temperature - higher temperatures lower
polymer melt viscosity, allowing more material to be
packed into mold to reduce shrinkage
Shrinkage decreases if the following quantities increase:
38
REACTION INJECTION MOLDING (RIM)
• A processing technique for the
formation of polymer parts by
direct polymerization in the
mold through a mixing
activated reaction.
• Two highly reactive liquid
ingredients are mixed and
immediately injected into a
mold cavity where chemical
reactions leading to
solidification occur
39
REACTION INJECTION MOLDING (RIM)
• RIM was developed
with polyurethane to
produce large
automotive parts such
as bumpers and
fenders.
• RIM polyurethane
parts possess a foam
internal structure
surrounded by a dense
outer skin.
40
41
COMPRESSION MOLDING
• A widely used molding process for thermosetting plastics.
• Also used for rubber tires and polymer matrix composite parts.
• Molding compound available in several forms: powders or pellets,
or liquid.
42
BLOW MOLDING
• Molding process in which air pressure is used to inflate soft
plastic into a mold cavity
• Important for making one-piece hollow plastic parts with
thin walls, such as bottles
• Because these items are used for consumer beverages in
mass markets, production is typically organized for very
high quantities
43
BLOW MOLDING
44
MATERIALS AND PRODUCTS IN BLOW
MOLDING
• Blow molding is limited to thermoplastics
• Materials: high density polyethylene, polypropylene
(PP), polyvinylchloride (PVC), and polyethylene
terephthalate (PET)
Products: disposable containers
for beverages and other liquid
consumer goods, large shipping
drums (55 gallon) for liquids
and powders, large storage
tanks (2000 gallon), gasoline
tanks, toys, and hulls for sail
boards and small boats
45
BLOW MOLDING PROCESS
• Accomplished in two steps:
1. Fabrication of a starting
tube, called a parison
2. Inflation of the tube to
desired final shape
• Forming the parison is accomplished
by either
• Extrusion or
• Injection molding
parison
Final
product
46

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ch13.pptx

  • 1. 1 ( © F U N D A M E N TA L S O F M O D E R N M A N U FA C T U R I N G ; M AT E R I A L S , P R O C E S S E S A N D S Y S T E M S , B Y M . P. G R O O V E R ) SHAPING PROCESSES FOR PLASTICS CHAPTER 13 - PROPERTIES OF POLYMER MELTS - EXTRUSION -INJECTION MOLDING -BLOW MOLDING
  • 2. SHAPING PROCESSES FOR PLASTICS  Properties of Polymer Melts  Extrusion  Production of Sheet, Film, and Filaments  Coating Processes  Injection Molding  Other Molding Processes  Thermoforming  Casting  Polymer Foam Processing and Forming  Product Design Considerations 2
  • 3. PLASTIC PRODUCTS • Plastics can be shaped into a wide variety of products: • Molded parts, Extruded sections, Films, Sheets, Insulation coatings on electrical wires, Fibers for textiles • In addition, plastics are often the principal ingredient in other materials, such as • Paints and varnishes, Adhesives, Various polymer matrix composites 3
  • 4. PLASTIC SHAPING PROCESSES ARE IMPORTANT  Almost unlimited variety of part geometries  Plastic molding is a net shape process • Further shaping is not needed  Less energy is required than for metals due to much lower processing temperatures • Handling of product is simplified during production because of lower temperatures  Painting or plating is usually not required 4
  • 5. POLYMER MELTS • To shape a thermoplastic polymer it must be heated so that it softens to the consistency of a liquid • In this form, it is called a polymer melt • Important properties of polymer melts: • Viscosity • Viscoelasticity 5
  • 6. VISCOSITY OF POLYMER MELTS • Fluid property that relates shear stress to shear rate during flow. • Shear stress=viscosity times shear rate • Due to its high molecular weight, a polymer melt is a thick fluid with high viscosity. • Most polymer shaping processes involve flow through small channels or die openings. • Flow rates are often large, leading to high shear rates and shear stresses, so significant pressures are required to accomplish the processes. 6    Ketchup, a highly viscoelastic fluid (like the polymer melt)
  • 7. NEWTONIAN AND NON-NEWTONIAN FLUIDS 7 • Newtonian Material: Viscosity changes by temperature (not by time or shear rate) Examples: Air, water, honey, glycerine, Kerosene. • Non-Newtonian Material: Viscosity changes by temperature, time and shear rate). Examples: Polymer melt, ketchup, custard, toothpaste, starch suspensions, paint, shampoo, cream, etc
  • 8. VISCOSITY AND TEMPERATURE • Viscosity decreases with temperature, thus the fluid becomes thinner at higher temperatures Figure 13.2 Viscosity as a function of temperature for selected polymers at a shear rate of 103 s-1. 8 Temperature Viscosity
  • 9. VISCOSITY AND SHEAR RATE Viscosity of a polymer melt “usually” decreases with shear rate, thus the fluid becomes thinner at higher shear rates. 9 Shear rate Viscosity Figure 13.1 Viscosity relationships for Newtonian fluid and typical polymer melt.
  • 10. VISCOELASTIC BEHAVIOR • Material property that determines the strain that the material experiences when subjected to combinations of stress and temperature over time  Combination of viscosity and elasticity 10
  • 11. VISCOELASTICITY • Combination of viscosity and elasticity. • Examples: Shampoo, hand cream, mayonnaise, toothpaste, yoghurt. • Temperature, time and shear rate are important and affect the properties of viscoelastic materials (here the polymer melts). • Example: die swell in extrusion, in which the hot plastic expands when exiting the die opening. 11
  • 12. VISCOELASTIC MATERIAL 12 Viscoelastic Material: Exhibits both viscous and elastic material properties. Deformation of the material is dependent on the strain rate. Examples: Paint, polymer melt, bread dough, soft tissue, shampoo, toothpaste, mayonnaise, etc. Polymer pellets
  • 14. EXTRUSION  Compression process in which material is forced to flow through a die orifice to provide long continuous product whose cross-sectional shape is determined by the shape of the orifice.  Widely used for thermoplastics and elastomers to mass produce items such as tubing, pipes, hose, structural shapes, sheet and film, continuous filaments, and coated electrical wire. 14 Extrudate
  • 15. EXTRUDER Figure 13.4 Components and features of a (single-screw) extruder for plastics and elastomers. 15 Feedstock is moved from hopper and preheated. Polymer is transformed into fluid, air mixed is extracted, and material is compressed. Melt is homogenized and sufficient pressure developed to pump it through die opening.
  • 16. RHEOLOGICAL EFFECTS  A problem in extrusion of polymers is die swell, in which the profile of extruded material grows in size, reflecting its tendency to return to its previously larger cross section in the extruder barrel immediately after being squeezed through the smaller die opening 16  Shape memory: Extruded polymer "remembers" its previous shape when in the larger cross section of the extruder, tries to return to it after leaving the die orifice.
  • 17. RHEOLOGICAL EFFECTS • Die swell can be most easily measured for a circular cross section by means of the swell ratio, defined as 𝑟𝑥 = 𝐷𝑥 𝐷𝑑
  • 18. EXTRUDER SCREW • Divided into sections to serve several functions: • • Feed section - feedstock is moved from hopper and preheated. • Compression section - polymer is transformed into fluid, air mixed with pellets is extracted from melt, and material is compressed. • Metering section - melt is homogenized and sufficient pressure developed to pump it through die opening. 18 Figure 13.5 Details of an extruder screw inside the barrel. Pressure is largely determined by dc.
  • 19. MAIN COMPONENTS OF AN EXTRUDER • Barrel • Screw 19 Die - not an extruder component Special tool that must be fabricated for particular profile to be produced.
  • 20. EXTRUSION OF SOLID PROFILES • Regular shapes such as • Rounds • Squares • Irregular cross sections such as • Structural shapes • Door and window moldings • Automobile trim • House siding 20
  • 21. EXTRUSION DIE FOR SOLID CROSS SECTION Figure 13.8 (a) Side view cross-section of an extrusion die for solid regular shapes, such as round stock; (b) front view of die, with profile of extrudate. Die swell is evident in both views. 21
  • 22. HOLLOW PROFILES  Examples: tubes, pipes, hoses, and other cross-sections containing holes  Hollow profiles require mandrel to form the shape  Mandrel held in place using a spider. Polymer melt flows around legs supporting the mandrel to reunite into a monolithic tube wall  Mandrel often includes an air channel through which air is blown to maintain hollow form of extrudate during hardening 22 FYI: Extrusion bridge die making a hollow section product. Note that in the picture the die has been split to show the material passing through it. In reality, the die and the ring fit together, with a gap for the extruded material to flow through.
  • 23. EXTRUSION DIE FOR HOLLOW SHAPES Figure 13.10 Side view cross-section of extrusion die for shaping hollow cross-sections such as tubes and pipes; Section A-A is a front view cross-section showing how the mandrel is held in place; Section B-B shows the tubular cross-section just prior to exiting the die; die swell causes an enlargement of the diameter. 23
  • 24. WIRE AND CABLE COATING • Polymer melt is applied to bare wire as it is pulled at high speed through a die • A slight vacuum is drawn between wire and polymer to promote adhesion of coating • Wire provides rigidity during cooling - usually aided by passing coated wire through a water trough • Product is wound onto large spools at speeds up to 50 m/s (10,000 ft/min) 24
  • 25. EXTRUSION DIE FOR COATING WIRE Figure 13.11 Side view cross-section of die for coating of electrical wire by extrusion. 25
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  • 30. INJECTION MOLDING  Polymer is heated to a highly plastic state and forced to flow under high pressure into a mold cavity where it solidifies and the molding is then removed from cavity.  Produces discrete components almost always to net shape.  Typical cycle time 10 to 30 sec, but cycles of one minute or more are not uncommon. Similar to hot-chamber die casting. • Pellets fed into heated chamber. • Melt forced into split die chamber. • 10,000 to 50,000 psi. • Mold is water cooled. • Part is ejected. 30
  • 31. INJECTION MOLDED PARTS  Complex and intricate shapes are possible  Shape limitations: • Capability to fabricate a mold whose cavity is the same geometry as part • Shape must allow for part removal from mold  Part size from  50 g (2 oz) up to  25 kg (more than 50 lb), e.g., automobile bumpers  Injection molding is economical only for large production quantities due to high cost of mold 31
  • 32. POLYMERS FOR INJECTION MOLDING  Injection molding is the most widely used molding process for thermoplastics.  Some thermosets and elastomers are injection molded • Modifications in equipment and operating parameters must be made to avoid premature cross-linking of these materials before injection. Parts manufactured by injection molding 32
  • 33. Injection Molding Machine Figure 13.21 Diagram of an injection molding machine, reciprocating screw type (some mechanical details are simplified). - Melts and delivers polymer melt - Operates much like an extruder Two principal components - Opens and closes mold each injection cycle 33
  • 35. INJECTION MOLDING MACHINES • Injection molding machines differ in both injection unit and clamping unit • Name of injection molding machine is based on the type of injection unit used • Reciprocating-screw injection molding machine • Plunger-type injection molding machine • Several clamping designs • Mechanical (toggle) • Hydraulic 35
  • 37. SHRINKAGE • Reduction in linear size during cooling from molding to room temperature. • Polymers have high thermal expansion coefficients, so significant shrinkage occurs during solidification and cooling in mold. 37
  • 38. SHRINKAGE FACTORS Fillers in the plastic tend to reduce shrinkage Injection pressure – higher pressures force more material into mold cavity to reduce shrinkage Compaction time - similar effect – longer time forces more material into cavity to reduce shrinkage Molding temperature - higher temperatures lower polymer melt viscosity, allowing more material to be packed into mold to reduce shrinkage Shrinkage decreases if the following quantities increase: 38
  • 39. REACTION INJECTION MOLDING (RIM) • A processing technique for the formation of polymer parts by direct polymerization in the mold through a mixing activated reaction. • Two highly reactive liquid ingredients are mixed and immediately injected into a mold cavity where chemical reactions leading to solidification occur 39
  • 40. REACTION INJECTION MOLDING (RIM) • RIM was developed with polyurethane to produce large automotive parts such as bumpers and fenders. • RIM polyurethane parts possess a foam internal structure surrounded by a dense outer skin. 40
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  • 42. COMPRESSION MOLDING • A widely used molding process for thermosetting plastics. • Also used for rubber tires and polymer matrix composite parts. • Molding compound available in several forms: powders or pellets, or liquid. 42
  • 43. BLOW MOLDING • Molding process in which air pressure is used to inflate soft plastic into a mold cavity • Important for making one-piece hollow plastic parts with thin walls, such as bottles • Because these items are used for consumer beverages in mass markets, production is typically organized for very high quantities 43
  • 45. MATERIALS AND PRODUCTS IN BLOW MOLDING • Blow molding is limited to thermoplastics • Materials: high density polyethylene, polypropylene (PP), polyvinylchloride (PVC), and polyethylene terephthalate (PET) Products: disposable containers for beverages and other liquid consumer goods, large shipping drums (55 gallon) for liquids and powders, large storage tanks (2000 gallon), gasoline tanks, toys, and hulls for sail boards and small boats 45
  • 46. BLOW MOLDING PROCESS • Accomplished in two steps: 1. Fabrication of a starting tube, called a parison 2. Inflation of the tube to desired final shape • Forming the parison is accomplished by either • Extrusion or • Injection molding parison Final product 46