1. Course: Basic Electronics
1
7 November 2023
Topic – P-N Junction Diode
Dr. Sharad T. Jadhav
Associate Professor
ECE Department
SITCOE, Yadrav
2. Syllabus
UNIT – I : DIODES AND CIRCUITS
PN junction diode,
V-I characteristics,
Diode as a rectifier,
Specification of rectifier diodes,
HW, FW, Bridge rectifiers,
Equation for Idc, Vdc, Vrms, Irms, efficiency and
ripple factor for each configuration,
Capacitor filter, ripple factor,
Zener diode characteristics, specification, zener
voltage regulator,
LED characteristics, configurations – discrete,
seven
segment, Bar graph, matrix, concept of multiple
display.
7 November 2023 UNIT - I Diodes and Circuits 2
3. Atomic Structure
All matters is made up of atoms; and all atoms
consist of electrons, protons, and neutrons.
In this section we will learn about the structure of
the atom, electron orbits and shells, valence
electrons, ions, and semiconductor materials –
Silicon and Germanium
7 November 2023 UNIT - I Diodes and Circuits 3
4. Atomic Structure
After completing this section, you should be able to:
Discuss the basic structure of atom.
Define nucleus, protons, neutrons, and electron
Describe an element’s atomic number
Explain electron shells
Explain what a valence electron is
Describe ionization
Explain what a free electron is
7 November 2023 UNIT - I Diodes and Circuits 4
5. Any substance, solid, liquid or gaseous is made
up of molecules and molecules are made up of
atoms.
Atoms contains tiny particles called protons,
electrons and neutrons. Which are called as
fundamental particles.
Protons are positively charged, electrons are
negatively charged and the neutrons are
electrically neutral
The structure of an Atom
7 November 2023 UNIT - I Diodes and Circuits 5
6. The structure of an Atom
FIGURE 1-1 The Bohr model of an atom showing electrons in orbits and around
the nucleus, which consists of protons and neutrons. The “tails” on the electrons
indicate motion.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 6
7. The structure of an Atom
FIGURE 1-2 The two simplest atoms, hydrogen and helium.
7 November 2023 UNIT - I Diodes and Circuits 7
9. 1. The Nucleus: The nucleus of an atom consists
of two types particles – protons and neutrons.
For a given atom, the number of protons in the
nucleus is normally equals to the number of
orbiting electrons
+
-
-
-
-
-
-
Nucleus
The structure of an Atom
7 November 2023 UNIT - I Diodes and Circuits 9
10. 2. Atoms are electrically neutral: Since the protons and
orbital electrons are equal in number, their equal and
opposite charge will neutralize each other electrically.
Therefore atoms are normally electrically neutral.
An electron has a negative charge equal to 1.6 X 10 -19
coulomb and a neutron has no charge at all.
The mass of an electron is 9.1 X 10-31 Kg
+
-
-
-
-
-
-
Nucleus
The structure of an Atom
7 November 2023 UNIT - I Diodes and Circuits 10
11. +
-
-
-
-
-
-
Nucleus
The structure of an Atom
3. Atoms can be converted into ions:
If an atom losses an electron then the number of
protons becomes higher than the number of
electrons. Therefore the atom becomes
positively charged and it is referred to as a
positive ion.
7 November 2023 UNIT - I Diodes and Circuits 11
12. +
-
-
-
-
-
-
Nucleus
The structure of an Atom
3. Atoms can be converted into ions:
Similarly if an atom gains an additional electron
then it becomes negatively charged and called
as negative ion.
7 November 2023 UNIT - I Diodes and Circuits 12
13. The structure of an Atom
4. Electron orbits or shell:
Electrons can occupy only certain orbital rings or shells which are
at a fixed distance from the nucleus.
Each shell can contain only a particular number of electrons.
In general a shell can contain at the most 2n2 number of
electrons where “n” is the shell number.
The exception for this rule is that the outermost shell cannot
contain more than eight electrons.
+
-
-
-
-
-
-
- -
-
-
- -
-
-
Nucleus
Electrons
Outermost orbit
Valence electrons
7 November 2023 UNIT - I Diodes and Circuits 13
14. The structure of an Atom
5. Valence shell and valence electrons:
The outermost shell is known as the valence shell and the
electrons in it are called as valence electrons.
These valence electrons determine the electrical characteristics
of each particular atom.
The valence shell may be completely filled or partially filled of
valence electrons.
+
-
-
-
-
-
-
- -
-
-
- -
-
-
Nucleus
Electrons
Outermost orbit
Valence electrons
7 November 2023 UNIT - I Diodes and Circuits 14
15. Introduction to semiconductor
The materials such as copper, aluminium etc. are good
conductors of electricity.
While the materials such as wood , glass, mica etc. are
bad conductors of electricity and are called insulators.
There is another class of materials, whose conductivity
i.e. ability to carry electricity, lies between that of
conductors and insulators. Such materials are called
semiconductors.
Germanium (Ge) and Silicon (Si) are two well known
semiconductor.
7 November 2023 UNIT - I Diodes and Circuits 15
16. The structure of Silicon (Si) Atom
Silicon Atom
A silicon atom consists of 14 protons and 14 neutrons inside the
nucleus and 14 revolving electrons.
These 14 electrons are distributed among different shell.
+14
-
-
-
-
-
-
- -
-
-
- -
-
-
Nucleus
Electrons
Outermost orbit
Valence electrons
7 November 2023 UNIT - I Diodes and Circuits 16
17. The structure of Silicon (Si) Atom
Silicon Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
+14
-
-
2
7 November 2023 UNIT - I Diodes and Circuits 17
18. The structure of Silicon (Si) Atom
Silicon Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
+14
-
-
-
-
-
-
- -
-
- 2
8
7 November 2023 UNIT - I Diodes and Circuits 18
19. The structure of Silicon (Si) Atom
Silicon Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
While third shell which is called as valence shell contains 4 electrons
+14
-
-
-
-
-
-
- -
-
-
- -
-
-
Nucleus
Electrons
Outermost orbit
Valence electrons
2
8
4
7 November 2023 UNIT - I Diodes and Circuits 19
20. The structure of Germanium (Ge) Atom
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
+32
-
- Nucleus
2
7 November 2023 UNIT - I Diodes and Circuits 20
21. The structure of Germanium (Ge) Atom
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
-
Nucleus
2
+32
-
-
-
-
-
- -
-
-
8
7 November 2023 UNIT - I Diodes and Circuits 21
22. The structure of Germanium (Ge) Atom
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
The third shell contains 18 electrons ( 2n2 = 18 since n=3 third shell)
+32
-
-
-
-
-
-
- -
-
-
-
-
-
-
Nucleus
Electrons
-
-
-
-
-
-
-
-
-
-
-
-
-
-
2
8
18
7 November 2023 UNIT - I Diodes and Circuits 22
23. The structure of Germanium (Ge) Atom
Germanium Atom
The first shell contains 2 electrons ( 2n2 = 2 since n=1 first shell)
The second shell contains 8 electrons ( 2n2 = 8 since n=2 second shell)
The third shell contains 18 electrons ( 2n2 = 18 since n=3 third shell)
And the outermost shell contains 4 valence electrons.
+32
-
-
-
-
-
-
- -
-
-
-
-
-
-
Nucleus
Electrons
Outermost orbit
Valence electrons
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
2
8
18
4
7 November 2023 UNIT - I Diodes and Circuits 23
24. Silicon as well as Germanium atoms contains 4 electrons in the valence
shell.
If there are 4 electrons in the outermost orbit the semiconductor material is
called as Tetravalent semiconductor or pure or Intrinsic semiconductor
7 November 2023 UNIT - I Diodes and Circuits 24
26. Ionization
When in equilibrium, an atom is electrically neutral, as
the number of protons is exactly equal to the number of
electrons.
7 November 2023 UNIT - I Diodes and Circuits 26
27. Ionization
When in equilibrium, an atom is electrically neutral, as
the number of protons is exactly equal to the number of
electrons.
But if the electrons from the outermost orbit (valence
electron) is extracted, then the atom does not remain
electrically neutral.
7 November 2023 UNIT - I Diodes and Circuits 27
28. Ionization
When in equilibrium, an atom is electrically neutral, as
the number of protons is exactly equal to the number of
electrons.
But if the electrons from the outermost orbit (valence
electron) is extracted, then the atom does not remain
electrically neutral.
Since it has lost one electron, it has lost some negative
charge. So the atom becomes positively charged and
called as positive ion.
7 November 2023 UNIT - I Diodes and Circuits 28
29. Ionization
When in equilibrium, an atom is electrically neutral, as
the number of protons is exactly equal to the number of
electrons.
But if the electrons from the outermost orbit (valence
electron) is extracted, then the atom does not remain
electrically neutral.
Since it has lost one electron, it has lost some negative
charge. So the atom becomes positively charged and
called as positive ion.
On the other hand, addition of an electron to an atom will
convert it into negative ion.
7 November 2023 UNIT - I Diodes and Circuits 29
30. Ionization
When in equilibrium, an atom is electrically neutral, as
the number of protons is exactly equal to the number of
electrons.
But if the electrons from the outermost orbit (valence
electron) is extracted, then the atom does not remain
electrically neutral.
Since it has lost one electron, it has lost some negative
charge. So the atom becomes positively charged and
called as positive ion.
On the other hand, addition of an electron to an atom will
convert it into negative ion.
The process of conversion from an electrically neutral to
an ion is called as Ionization.
7 November 2023 UNIT - I Diodes and Circuits 30
31. Concept of energy levels
Each electronic orbit has an energy level associate with it.
The electrons in the inner orbits are more closely bound to the
nucleus and posses less energy.
As we move towards the valence shell, the binding force between
nucleus and electrons reduces and the electrons posses higher
energy.
+
- - -
-
-
-
-
-
-
-
- -
-
-
Energy levels increases as
we away from the nucleus
Valence orbit shell
has highest energy level
Shell 1
Lowest energy
nucleus
7 November 2023 UNIT - I Diodes and Circuits 31
32. Free electrons
The valence electrons are very loosely bound with the nucleus .
If an external energy is given to them, they can easily break away
from the nucleus and become free.
Such electron which are free from the force of attraction of nucleus
are called as free electrons
+
- - -
-
-
-
-
-
-
- -
-
-
Energy levels increases as
we away from the nucleus
Valence orbit shell
has highest energy level
Shell 1
Lowest energy
nucleus - Free electron
7 November 2023 UNIT - I Diodes and Circuits 32
33. Free electrons
These free electrons posses an energy which is higher than that of
valence electrons.
The electric current flows due to these free electrons and they are
said to be in the conduction band.
The energy level of conduction band is higher than that of valence
shell
+
- - -
-
-
-
-
-
-
- -
-
-
Energy levels increases as
we away from the nucleus
Valence orbit shell
has highest energy level
Shell 1
Lowest energy
nucleus - Free electron
7 November 2023 UNIT - I Diodes and Circuits 33
34. Energy Bands
+
- - -
-
-
-
-
-
-
- -
-
-
Energy levels increases as
we away from the nucleus
Valence orbit shell
has highest energy level
1st Band
nucleus - Free electron
1st Band
2nd Band
Valence band
Conduction band
2nd Band
Valence band
Edge of the nucleus
1st Band
2nd Band
Valence Band
conduction
Band
Energy
Forbidden energy gap
EG
7 November 2023 UNIT - I Diodes and Circuits 34
35. Energy Bands
1st Band
2nd Band
Valence band
Conduction band
Edge of the nucleus
1st Band
2nd Band
Valence Band
conduction
Band
Energy
•The electrons in the first shell will require the highest amount of energy
for their extraction. Therefore the first shell is said to have lowest
amount of energy associate with it
On the other hand, the valence electrons require the lowest amount of
energy for their extraction. Hence valence shells are said to have the
highest amount of energy.
7 November 2023 UNIT - I Diodes and Circuits 35
36. Energy Bands
1st Band
2nd Band
Valence band
Conduction band
Edge of the nucleus
1st Band
2nd Band
Valence Band
conduction
Band
Energy
Forbidden energy gap
EG
•Valence Band :
the valence band corresponds to the valence electrons present
in the different atoms of the materials.
Energy associates with the valence band is the second highest
as shown in figure
7 November 2023 UNIT - I Diodes and Circuits 36
37. Energy Bands
1st Band
2nd Band
Valence band
Conduction band
Edge of the nucleus
1st Band
2nd Band
Valence Band
conduction
Band
Energy
Forbidden energy gap
EG
•Conduction Band :
Conduction band has the highest energy associated with it
The electrons in the conduction band are the free electrons i.e. the
electrons which are disconnected from their respective atoms.
Conduction band electrons are actually responsible for the flow of
current . More number of electrons in the conduction band more
will be the current
7 November 2023 UNIT - I Diodes and Circuits 37
38. Energy Bands
1st Band
2nd Band
Valence band
Conduction band
Edge of the nucleus
1st Band
2nd Band
Valence Band
conduction
Band
Energy
Forbidden energy gap
EG
• Forbidden Gap :
As shown in figure the forbidden gap is the energy gap that
separates the conduction and valence band.
No electrons can normally exist in the forbidden gap. For any given
type of material the forbidden gap may be large, small or even
nonexistent.
The materials are classified as conductors, insulators and
semiconductors based on the relative width of the forbidden gap.
7 November 2023 UNIT - I Diodes and Circuits 38
39. Jump from valence band to conduction band
If the valence band electrons can jump across the
forbidden gap and enter into the conduction band then
they will become free electrons and be available for
conduction.
The valence electrons can jump if we provide additional
energy to them . This additional energy can be supplied
by increasing the temperature or focusing light on the
material etc.
This is the reason why conductivity of certain materials
increase with increase in temperature.
7 November 2023 UNIT - I Diodes and Circuits 39
40. Let us understand conductor, insulators and
semiconductors based on their energy band diagram
Conductors
Conductors are materials which allows the current to flow very
easily. This is due to the large number of free electrons present in
the conductors.
From the energy band diagram of conductors shown in figure, for
metals like copper, aluminium etc. there is no “forbidden gap”
present between the valence and conduction band.
Therefore even at room temperature, a large number of free
electrons are present and available for conduction.
Conduction
Band
Valence
Band
Bands
overlap
Conduction band
Valence band
7 November 2023 UNIT - I Diodes and Circuits 40
41. Let us understand conductor, insulators and
semiconductors based on their energy band diagram
Insulators
The energy band diagram of an insulator is shown in figure
The forbidden gap between the conduction band valence band is
extremely wide.
Normally the valence electrons cannot jump that far and enter into
the conduction band. Therefore conduction those not takes place
and these materials are known as insulators
Conduction
Band
Valence
Band
Large
forbidden
gap
Conduction band
Valence band
EG = 6 eV
7 November 2023 UNIT - I Diodes and Circuits 41
42. Let us understand conductor, insulators and
semiconductors based on their energy band diagram
Semiconductors
Semiconductor have the conduction properties which are in between
those of conductors and insulators.
We can say that semiconductors are neither conductors nor
insulators. Forbidden gap is very narrow as compared to that of the
insulator.
The forbidden gap for Silicon EG = 1.1 eV
For Germanium EG = 0.72 eV
Conduction
Band
Valence
Band
small
forbidden
gap
Conduction band
Valence band
EG = 1 eV
7 November 2023 UNIT - I Diodes and Circuits 42
43. Let us understand conductor, insulators and
semiconductors based on their energy band diagram
Conduction
Band
Valence
Band
small
forbidden
gap
EG = 1 eV
Conduction
Band
Valence
Band
Large
forbidden
gap
Conduction
Band
Valence
Band
Bands
overlap
Conductor Insulator Semiconductor
7 November 2023 UNIT - I Diodes and Circuits 43
44. Why silicon is more widely used semiconductor material
The valence electrons in germanium are in the fourth shell
while those in silicon are in the third shell, i.e. closer to the
nucleus.
This means that the germanium valence electrons are at
higher energy levels than those in Silicon.
Hence germanium valence electrons will need smaller amount
of additional energy to escape from the atom.
Due to this, the germanium produces more number electron
hole pairs than silicon.
Hence the leakage current is more in germanium than that of
silicon.
This property make germanium more unstable at high
temperatures, therefore silicon is more widely used material
than germanium.
7 November 2023 UNIT - I Diodes and Circuits 44
45. Types of Semiconductors
The semiconductors are classified into two categories as:
Intrinsic semiconductors and
Extrinsic semiconductors.
7 November 2023 UNIT - I Diodes and Circuits 45
46. Intrinsic Semiconductors
Intrinsic means pure, so intrinsic semiconductors are the
semiconductors in their purest possible form.
The presence of impurity (i.e. atoms of other material) is as
low as 1 part in 100 million parts of the semiconductor atoms.
The intrinsic semiconductors are insulators or very very poor
conductors, at room temperature.
Silicon and germanium are intrinsic semiconductor
7 November 2023 UNIT - I Diodes and Circuits 46
47. Extrinsic Semiconductors
Extrinsic means impure, so we can obtain the extrinsic
semiconductors from intrinsic ones by adding impurities to
them.
Impurity is nothing but some other material. The process of
adding impurities is called as “ doping”
Due to doping, the conductivity of the semiconductor
increases.
Extrinsic semiconductor are of two types:
n- type semiconductor
p- type semiconductor
The type of extrinsic semiconductor (n or p) depends on the
type of impurity ( or dopant ) being used
7 November 2023 UNIT - I Diodes and Circuits 47
48. Intrinsic Semiconductors
two dimensional representation
We know that in a silicon or germanium atom there are four
valence electrons
Si
7 November 2023 UNIT - I Diodes and Circuits 48
49. Intrinsic Semiconductors
two dimensional representation
Si
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 49
50. Intrinsic Semiconductors
two dimensional representation
We know that in a silicon or germanium atom there are four
valence electrons
In an intrinsic Si or Ge crystal these four valence electrons are
bound to four adjacent atoms
Si
Si Si
Si
Si
Si
Si
Si
Si
Covalent Bond
7 November 2023 UNIT - I Diodes and Circuits 50
51. Intrinsic Semiconductors
two dimensional representation
Each one of the four valence electrons in each atoms forms a
bond with a valence electrons from the adjoining atom as
shown. This bond is nothing but sharing of electrons. These
bonds are Known as covalent bond
Si
Si Si
Si
Si
Si
Si
Si
Si
Covalent Bond
7 November 2023 UNIT - I Diodes and Circuits 51
52. Intrinsic Semiconductors
two dimensional representation
Si Si
Si
Si
Si
Si
Covalent Bond
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 52
53. Conduction in intrinsic semiconductor
The intrinsic semiconductor behaves like perfect
insulator at the absolute zero temperature.
But the behavior changes with increase in
temperature. At around the room temperature,
electrons becomes available for conduction and
current can flow.
7 November 2023 UNIT - I Diodes and Circuits 53
54. Conduction in intrinsic semiconductor
The intrinsic semiconductor behaves like perfect
insulator at the absolute zero temperature.
But the behavior changes with increase in
temperature. At around the room temperature,
electrons becomes available for conduction and
current can flow.
FIGURE Creation of electron-hole pairs in a silicon crystal. Electrons in the conduction band
are free.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 54
55. FIGURE Electron-hole pairs in a silicon crystal. Free electrons are being generated
continuously while some recombine with holes.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 55
56. Generation of electron-hole pairs at
increased temperature
At increase in temperature many valence electrons will absorb
the thermal energy, breaks the covalent bonds and go into the
conduction band
Thus they becomes free for conduction. When an electron
break a covalent bond and becomes free, a vacancy is
created in the broken covalent bond.
Si Si
Si Si
Free electron
hole
7 November 2023 UNIT - I Diodes and Circuits 56
57. Generation of electron-hole pairs at
increased temperature
This vacancy is called as “hole”. Thus corresponding to every
free electron, hole is created.
Therefore the number of free electrons are generated due to
increased in temperature is exactly equal to the number of
holes.
As the free electrons and holes are generated in pairs they
are called as thermally generated electron hole pair.
Si Si
Si Si
Free electron
hole
7 November 2023 UNIT - I Diodes and Circuits 57
58. Generation of electron-hole pairs at
increased temperature
The electrons and holes both can operate as charge carriers.
The holes is said to have a positive charge as it is nothing but
absence of an electron.
Thus the conductivity of an intrinsic semiconductor thus
increases due to the increase in temperature.
Si Si
Si Si
Free electron
hole
7 November 2023 UNIT - I Diodes and Circuits 58
59. Recombination
The free electrons in the conduction band, when come across
the hole will jump into the hole.
This process is called as the recombination process
Si Si
Si Si
Free electron
hole
7 November 2023 UNIT - I Diodes and Circuits 59
60. Recombination
When a conduction band electron return back to valence
band, and recombines with a hole, it release energy equal to
the energy gap between conduction and valence bands.
This principle is used in the light emitting diode (LED)
Si Si
Si Si
Free electron
hole
7 November 2023 UNIT - I Diodes and Circuits 60
61. FIGURE Hole current in intrinsic silicon.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 61
62. Electron and hole current
Electron Current
As we apply voltage across a piece of intrinsic semiconductor
material, the thermally generated free electrons in the
conduction band are attracted towards the positive end
The current is constitute due to the movement of free
electrons is called as electron current as shown in figure
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 62
63. Electron and hole current
Hole Current
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 63
64. Electron and hole current
Hole Current
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 64
65. Electron and hole current
Hole Current
Si Si
Si
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 65
66. Electron and hole current
Hole Current
Si Si
Si
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 66
67. Electron and hole current
Hole Current
Si Si
Si
Si Si
Si
Hole movement electron movement
7 November 2023 UNIT - I Diodes and Circuits 67
68. Electron and hole current
Total current
The flow of an electric current is due to the movement of
electrons in the conduction band and movement of holes in
the valence band.
Total current = electron current + hole current
Si Si
Si
7 November 2023 UNIT - I Diodes and Circuits 68
69. FIGURE Electron current in intrinsic silicon is produced by the movement of thermally
generated free electrons.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 69
70. Semiconductors have a negative
temperature coefficient of resistivity
As the temperature rises, more number of electrons will
absorb the thermal energy to break the covalent bonds and
contributes to the number of free carriers.
The increase in the number of electrons and holes will
increase the conductivity of the semiconductor and results in
the lower resistance level.
Thus the resistance of the semiconductor decreases with
increase in temperature. Therefore they are said to have a
“ negative temperature coefficient” of resistivity.
7 November 2023 UNIT - I Diodes and Circuits 70
71. Conventional current
The current flow from positive to negative is referred to as
conventional current.
Under the influence of the external dc source or battery the free
electrons in the semiconductor slab which are negatively charged
will attracted towards the positive terminal and holes being
positively charged will be attracted towards the negative terminal of
the external battery.
-
-
-
h
h
h
e
e
e
Conventional current
Electron flow
External DC source
Semiconductor slab
7 November 2023 UNIT - I Diodes and Circuits 71
72. Extrinsic Semiconductors
Doping Process
In the process of doping, impurities are added to the
pure Silicon or Germanium.
The impurities are the material used to dope the intrinsic
semiconductor materials. These materials can be of two
types:
1. Donor impurity 2. Acceptor impurity
7 November 2023 UNIT - I Diodes and Circuits 72
73. Donor impurity
The material which is being used as impurity in the
process of doping is called as “dopant”.
When the dopant is Pentavalent atom i.e. the atom
containing five valence electrons then it is called as the
“ donor impurity” and the doping is called as “ donor
doping”
Donor doping is used to manufacture n-type extrinsic
semiconductor.
7 November 2023 UNIT - I Diodes and Circuits 73
74. Acceptor impurity
When the dopant is trivalent atom i.e. the atom
consisting of only three valence electrons, then it is
called as the “ acceptor impurity” and the doping is called
“acceptor doping”.
Acceptor doping is used to manufacture p-type extrinsic
semiconductor.
7 November 2023 UNIT - I Diodes and Circuits 74
75. n-type semiconductor
The n–type semiconductor is formed by adding small
amount of Pentavalent impurity to the pure Si or Ge
material which act as base material.
The Pentavalent atom is the one which has five valence
electrons.
The examples of Pentavalent materials are :
Antimony (Sb)(51),
Arsenic (As) (33) and
Phosphorous (P)(15).
7 November 2023 UNIT - I Diodes and Circuits 75
76. n-type semiconductor
formation of covalent bond
As
Si Si
Si
Si
Si
Si
Si
Si
Covalent Bond
Fifth valence electron
Of Arsenic
(Extra Free electron)
When a pentavalent impurity such as Arsenic is added to the
intrinsic semiconductor, four valence electrons of Arsenic
atom form four covalent bonds with four valence electrons of
the neighboring silicon atom
7 November 2023 UNIT - I Diodes and Circuits 76
77. FIGURE Pentavalent impurity atom in a silicon crystal structure. An antimony (Sb) impurity
atom is shown in the center. The extra electron from the Sb atom becomes a free electron.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 77
78. majority and minority carriers in the n-type semiconductor
A large number of free electrons are present along with a small number of
thermally generated holes in an n-type semiconductor.
So the conduction largely takes place due to the free electrons. Therefore
the free electrons are called “ majority carrier” and holes are known as
“ minority carrier”.
When an external DC voltage is applied to the n-type semiconductor
material, the free electrons move towards the positive terminal of the
source and hole move towards the negative end
-
-
h
h
e
e
Conventional current
Electron flow
N-type material
-
-
-
e
e
e
-
-
e
e
-
e -
e
- e
-
e
-
e
- e
7 November 2023 UNIT - I Diodes and Circuits 78
79. P-type semiconductor
The P–type semiconductor is formed by adding small
amount of trivalent impurity to the pure Si or Ge material
which act as base material.
The trivalent atom is the one which has three valence
electrons.
The examples of trivalent materials are :
Boron(B)(5),
Gallium(Ga)(31) and
Indium(In)(49).
7 November 2023 UNIT - I Diodes and Circuits 79
80. p-type semiconductor
formation of covalent bond
Ga
Si Si
Si
Si
Si
Si
Si
Si
Broken Covalent Bond
Hole created due to
Incomplete bond
When a trivalent impurity such as Gallium is added to the
intrinsic semiconductor, three valence electrons of gallium
atom form three covalent bonds with three valence electrons
of the neighboring silicon atom
Covalent Bond
7 November 2023 UNIT - I Diodes and Circuits 80
81. FIGURE 1-16 Trivalent impurity atom in a silicon crystal structure. A boron (B) impurity atom
is shown in the center.
Thomas L. Floyd
Electronic Devices, 6e and Electronic
Devices: Electron Flow Version, 4e
7 November 2023 UNIT - I Diodes and Circuits 81
82. majority and minority carriers in the p-type semiconductor
+
+
h
h
Conventional current
Electron flow
P-type material
-
-
e
e
+
+
+ +
+
+
+
+ +
7 November 2023 UNIT - I Diodes and Circuits 82
83. p-n junction
P-type semiconductor and an n-type semiconductor are
joined together with the help of special fabrication
technique to form a p-n junction
+
+
+ +
+
+ +
+
-
-
-
-
-
-
-
-
p-type
semiconductor
n-type
semiconductor
7 November 2023 UNIT - I Diodes and Circuits 83
84. p-n junction
P-type semiconductor and an n-type semiconductor are
joined together with the help of special fabrication
technique to form a p-n junction
+
+
+ +
+
+ +
+
-
-
-
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
7 November 2023 UNIT - I Diodes and Circuits 84
85. p-n junction
Terminals are brought out for the external connection
with p-type semiconductor. The p-side is called as anode
and the n-side is called as cathode.
Anode Cathode
+
+
+ +
+
+ +
+
-
-
-
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
7 November 2023 UNIT - I Diodes and Circuits 85
86. p-n junction
Terminals are brought out for the external connection with p-
type semiconductor. The p-side is called as anode and the
n-side is called as cathode.
The p-n junction forms the basic semiconductor device called
diode
Anode cathode
+
+
+ +
+
+ +
+
-
-
-
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
7 November 2023 UNIT - I Diodes and Circuits 86
87. Diffusion
At the junction, one side has a high concentration of
holes and other side has high concentration of electrons.
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
7 November 2023 UNIT - I Diodes and Circuits 87
88. Diffusion
At the junction, one side has a high concentration of
holes and other side has high concentration of electrons.
Due to this a concentration gradient is created across
the junction, and a process of charge carrier as shown in
figure.
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
7 November 2023 UNIT - I Diodes and Circuits 88
89. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
7 November 2023 UNIT - I Diodes and Circuits 89
90. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
7 November 2023 UNIT - I Diodes and Circuits 90
91. formation of the depletion region
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
7 November 2023 UNIT - I Diodes and Circuits 91
92. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
+
-
n-type
semiconductor
junction
Anode cathode
7 November 2023 UNIT - I Diodes and Circuits 92
93. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
7 November 2023 UNIT - I Diodes and Circuits 93
94. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
7 November 2023 UNIT - I Diodes and Circuits 94
95. formation of the depletion region
Note that no external voltage is applied between the
terminals of the p-n junction, hence the p-n junction is
said to be unbiased.
The free electrons from “n” side will diffuse into the p
side and recombine with the holes present there.
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
7 November 2023 UNIT - I Diodes and Circuits 95
96. formation of the depletion region
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
7 November 2023 UNIT - I Diodes and Circuits 96
97. formation of the depletion region
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
7 November 2023 UNIT - I Diodes and Circuits 97
98. formation of the depletion region
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
7 November 2023 UNIT - I Diodes and Circuits 98
99. formation of the depletion region
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
7 November 2023 UNIT - I Diodes and Circuits 99
100. formation of the depletion region
+
+
+ +
+
-
-
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
+
-
+
+
+
-
-
-
Negative immobile ions Positive immobile ions
Each electron diffusing into the “p” side will leave behind
a positive immobile ion on the n-side.
When electron combine with a hole on the p-side, an
atom which accepts this electron, losses its electrically
neutral status and become a negative immobile ion as
shown in figure
7 November 2023 UNIT - I Diodes and Circuits 100
101. formation of the depletion region
Due to this recombination process, a large number of
positive ions accumulate near the junction on the n-side
and a large number of negative immobile ions will
accumulate on the p-side near the junction
+
+
+
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
-
-
-
+
+
+
Depletion
region
Negative immobile ions Positive immobile ions
7 November 2023 UNIT - I Diodes and Circuits 101
102. formation of the depletion region
The negatively charged ions on the p-side will start
repelling the electrons which attempts to diffuse into the
p-side and after some time the diffusion will stop
completely.
At this point the junction is said to have attained an
equilibrium.
+
+
+
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
-
-
-
+
+
+
Depletion
region
Negative immobile ions Positive immobile ions
7 November 2023 UNIT - I Diodes and Circuits 102
103. width of the depletion region
Practically the width of depletion region is very small of
the order of 0.5 to 1 micron where 1 micron is equal to
1X10-6 meter.
Thus the depletion region is very thin as compared to the
width of p and n region.
+
+
+
-
-
-
P-type
semiconductor
n-type
semiconductor
junction
Anode cathode
-
-
-
+
+
+
Depletion
region
Negative immobile ions Positive immobile ions
7 November 2023 UNIT - I Diodes and Circuits 103
104. Barrier potential or junction potential
Due to the presence of immobile positive and negative ions on
opposite sides of the junction, an electric field is created across
the junction. This electric field is known as the “barrier
potential”.
The polarities of barrier potential are decided by the type of
immobile ions present on the two sides of the junction.
+
+
+
-
-
-
P-type
semiconductor
n-type
semiconductor
Anode cathode
-
-
-
+
+
+
Depletion
region
- + Barrier potential or
Junction potential
7 November 2023 UNIT - I Diodes and Circuits 104
105. Barrier potential or junction potential
Barrier potential is measured in volts. The barrier potential for
silicon is about 0.6 Volt whereas its value for the Germanium
is 0.2 Volt.
+
+
+
-
-
-
P-type
semiconductor
n-type
semiconductor
Anode cathode
-
-
-
+
+
+
Depletion
region
- + Barrier potential or
Junction potential
7 November 2023 UNIT - I Diodes and Circuits 105
106. penetration of depletion region
The penetration of the depletion region into p or n-side
depends on the doping levels of those sides
If both these sides are equally doped then the depletion
region penetrates equally on both the sides as shown in
figure:
P N
J
Equal penetration
On both side
Both sides are equally doped
7 November 2023 UNIT - I Diodes and Circuits 106
107. penetration of depletion region
The penetration of the depletion region into p or n-side
depends on the doping levels of those sides
But if p-region is lightly doped as compared to the n-
region the penetration of depletion region is more on the
p-side as shown in figure
P N
J
More penetration
On p-side
P-side is lightly doped
7 November 2023 UNIT - I Diodes and Circuits 107
108. penetration of depletion region
The penetration of the depletion region into p or n-side
depends on the doping levels of those sides
Similarly if n-side is lightly doped as compared to p-side
then the depletion extend more into the n-side as sown
P N
J
More penetration
On n-side
n-side is lightly doped
7 November 2023 UNIT - I Diodes and Circuits 108
109. penetration of depletion region
P N
J
Equal penetration
On both side
Both sides are equally doped
More penetration
On p-side
P-side is lightly doped
P N
J
P N
J
More penetration
On n-side
n-side is lightly doped
Thus the depletion region always penetrates more on the side which is lightly doped
as compared to the other
7 November 2023 UNIT - I Diodes and Circuits 109