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International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
A Study on Refrigeration
Poonam Dhankhar
M. Tech, G.J.U.S & T Hissar, Haryana, India
Abstract: Refrigeration is a basic method of food preservation. All the refrigeration methods for food preservation are based on
Reverse Carnot cycle, which explains Adiabatic and Isothermal Expansion and Compression. Basic components used in these cycles are
Evaporator, Compressor, Condenser and Expansion Valve. Generally used cycle is Vapor Compression Cycle. Other cycles are Vapor
Absorption Cycle, Gas Cycle. Other new methods of Refrigeration are Thermoelectric and Magnetic Refrigeration. Various types of
refrigerants are used in these cycles based upon their properties. Commercially Refrigeration is used as preservation method in various
food industries like Dairy and Meat Processing industry.
Keywords: Food preservation, reverse carnot cycle, evaporator, compressor, condenser, vapor compression cycle, Thermoelectric and
Magnetic Refrigeration
1. Introduction [1] [4]
Refrigeration is a process in which work is done to remove
heat from one location to another. Refrigeration has many
applications including but not limited to household
refrigerators, industrial freezers, cryogenics, air
conditioning, and heat pumps. In order to satisfy the Second
Law of Thermodynamics, some form of work must be
performed to accomplish this. The work is traditionally done
by mechanical work but can also be done by magnetism,
laser or other means. Since the turn of the century, there has
been steady growth of application of refrigeration in
preservation of perishable food products, agriculture and
fishery.
The purpose of refrigeration for food is to retard
deterioration by micro-organisms, chemical and physical
processes. By cooling at temperatures just above freezing it
is possible to achieve a limited extension of storage time
which is often sufficient for safe distribution and marketing.
By freezing to temperature as low as -30ᴼC, deterioration
can be slowed down further and this increases the storage
time. Refrigeration has applications in diverse industries,
such as manufacturing chemicals, petroleum, refineries,
paper and pulp industries also.
2. Review of Literature [6]
Ice harvesting:‐ The use of ice to refrigerate and thus
preserve food goes back to prehistoric times. Through the
ages, the seasonal harvesting of snow and ice was a regular
practice of most of the ancient cultures: Chinese, Hebrews,
Greeks, Romans, Persians. Ice and snow were stored in
caves or dugouts lined with straw or other insulating
materials. The Persians stored ice in pits called yakhchals.
Rationing of the ice allowed the preservation of foods over
the warm periods. This practice worked well down through
the centuries, with ice houses remaining in use into the
twentieth century. In the 16th century, the discovery of
chemical refrigeration was one of the first steps toward
artificial means of refrigeration. Sodium nitrate or
potassium nitrate, when added to water, lowered the water
temperature and created a sort of refrigeration bath for
cooling substances. During the first half of the 19th century,
ice harvesting became big business in America. New
Englander Frederic Tudor, who became known as the
"Ice King", worked on developing better insulation
products for the long distance shipment of ice, especially to
the tropics.
First refrigeration systems:- The first known method of
artificial refrigeration was demonstrated by William Cullen
at the University of Glasgow in Scotland in 1756. Cullen
used a pump to create a partial vacuum over a container of
diethyl ether, which then boiled, absorbing heat from the
surrounding air. The experiment even created a small
amount of ice, but had no practical application at that time.
In 1758, Benjamin Franklin and John Hadley, professor of
chemistry at Cambridge University, conducted an
experiment to explore the principle of evaporation as a
means to rapidly cool an object. Franklin and Hadley
confirmed that evaporation of highly volatile liquids such as
alcohol and ether could be used to drive down the
temperature of an object past the freezing point of water.
They conducted their experiment with the bulb of a mercury
thermometer. They lowered the temperature of the
thermometer bulb down to 7 °F (−14 °C) while the ambient
temperature was 65 °F (18 °C). Franklin noted that soon
after they passed the freezing point of water (32 °F) a thin
film of ice formed on the surface of the thermometer's bulb
and that the ice mass was about a quarter inch thick when
they stopped the experiment upon reaching 7 °F (−14 °C).
In 1820, the British scientist Michael Faraday liquefied
ammonia and other gases by using high pressures and low
temperatures.
An American living in Great Britain, Jacob Perkins,
obtained the first patent for a vapor-compression
refrigeration system in 1834. In 1842, an American
physician, John Gorrie, designed the first system for
refrigerating water to produce ice. His system compressed
air, then partially cooled the hot compressed air with water
before allowing it to expand while doing part of the work
required to drive the air compressor. That isentropic (the
process takes place from initiation to completion without an
increase or decrease in the entropy of the system, i.e., the
entropy of the system remains constant) expansion cooled
the air to a temperature low enough to freeze water and
produce ice, or to flow "through a pipe for effecting
Paper ID: 020132041 1212
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
refrigeration otherwise" as stated in his patent granted by the
U.S. Patent Office in 1851.Gorrie built a working prototype
(A prototype is an early sample or model built to test a
concept or process or to act as a thing to be replicated or
learned from), but his system was a commercial failure.
Alexander Twining began experimenting with vapor-
compression refrigeration in 1848 and obtained patents in
1850 and 1853. He is credited with having initiated
commercial refrigeration in the United States by 1856.
The first gas absorption refrigeration system using gaseous
ammonia dissolved in water (referred to as "aqua ammonia")
was developed by Ferdinand Carré of France in 1859 and
patented in 1860. Due to the toxicity of ammonia, such
systems were not developed for use in homes, but were used
to manufacture ice for sale.
Thaddeus Lowe, an American balloonist from the Civil
War, had experimented over the years with the properties of
gases. One of his mainstay enterprises was the high-volume
production of hydrogen gas. He also held several patents on
ice making machines. His "Compression Ice Machine"
would revolutionize the cold storage industry. In 1869 he
and other investors purchased an old steamship onto which
they loaded one of Lowe’s refrigeration units and began
shipping fresh fruit from New York to the Gulf Coast area,
and fresh meat from Galveston, Texas back to New York.
Because of Lowe’s lack of knowledge about shipping, the
business was a costly failure, and it was difficult for the
public to get used to the idea of being able to consume meat
that had been so long out of the packing house.
Domestic mechanical refrigerators became available in the
United States around 1911.
a) Widespread commercial use
By the 1870s breweries had become the largest users of
commercial refrigeration units, though some still relied on
harvested ice. Though the ice-harvesting industry had grown
immensely by the turn of the 20th century, pollution and
sewage had begun to creep into natural ice making it a
problem in the metropolitan suburbs. Eventually breweries
began to complain of tainted ice. This raised demand for
more modern and consumer-ready refrigeration and ice-
making machines. In 1895, German engineer Carl von
Linde set up a large-scale process for the production of
liquid air and eventually liquid oxygen for use in safe
household refrigerators.
Refrigerated railroad cars were introduced in the US in the
1840s for the short-run transportation of dairy products.
By 1900, the meat packing houses of Chicago had adopted
ammonia-cycle commercial refrigeration. By 1914, almost
every location used artificial refrigeration. The big meat
packers, Armour, Swift, and Wilson, had purchased the
most expensive units which they installed on train cars and
in branch houses and storage facilities in the more remote
distribution areas.It was not until the middle of the 20th
century that refrigeration units were designed for installation
on tractor-trailer rigs (trucks or Lorries). Refrigerated
vehicles are used to transport perishable goods, such as
frozen foods, fruit and vegetables, and temperature-sensitive
chemicals. Most modern refrigerators keep the temperature
between -40 and 20 °C and have a maximum payload of
around 24,000 kg gross weight (in Europe).
b) Home and consumer use
With the invention of synthetic refrigerants based mostly on
a chlorofluorocarbon (CFC) chemical, safer refrigerators
were possible for home and consumer use. Freon is a
trademark of the DuPont Corporation and refers to these
CFC, and later hydro chlorofluorocarbon (HCFC) and hydro
fluorocarbon (HFC), refrigerants developed in the late
1920s. These refrigerants were considered at the time to be
less harmful than the commonly used refrigerants of the
time, including methyl formate, ammonia, methyl chloride,
and sulfur dioxide. The intent was to provide refrigeration
equipment for home use without danger: these CFC
refrigerants answered that need. However, in the 1970s the
compounds were found to be reacting with atmospheric
ozone, an important protection against solar ultraviolet
radiation, and their use as a refrigerant worldwide was
curtailed in the Montreal Protocol of 1987.
3. Basic Refrigeration Principle [4] [5]
If you were to place a hot cup of coffee on a table and leave
it for a while, the heat in the coffee would be transferred to
the materials in contact with the coffee, i.e. the cup, the table
and the surrounding air. As the heat is transferred, the coffee
in time cools. Using the same principle, refrigeration works
by removing heat from a product and transferring that heat
to the outside air.
Refrigeration is used to cool products. The refrigeration
system (R) transfers heat from a cooler low-energy reservoir
to a warmer high-energy reservoir
Figure 1: Schematic representation of refrigeration
system
4. Refrigeration System Components [5]
There are five basic components of a refrigeration system,
these are: Evaporator, Compressor, Condenser, Expansion
Valve and Refrigerant- to conduct the heat from the product.
In order for the refrigeration cycle to operate successfully
each component must be present within the refrigeration
system.
Paper ID: 020132041 1213
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
4.1 The Evaporator
The purpose of the evaporator is to remove unwanted heat
from the product, via the liquid refrigerant. The liquid
refrigerant contained within the evaporator is boiling at a
low-pressure. The level of this pressure is determined by two
factors:
 The rate at which the heat is absorbed from the product to
the liquid refrigerant in the evaporator
 The rate at which the low-pressure vapour is removed
from the evaporator by the compressor
 To enable the transfer of heat, the temperature of the
liquid refrigerant must be lower than the temperature of
the product being cooled. Once transferred, the liquid
refrigerant is drawn from the evaporator by the
compressor via the suction line. When leaving the
evaporator coil the liquid refrigerant is in vapor form.
4.2 The Compressor
The purpose of the compressor is to draw the low-
temperature, low-pressure vapour from the evaporator via
the suction line. When vapour is compressed it rises in
temperature. Therefore, the compressor transforms the
vapour from a low-temperature vapor to a high-temperature
vapour, in turn increasing the pressure. The vapor is then
released from the compressor in to the discharge line.
4.3 The Condenser
The purpose of the condenser is to extract heat from the
refrigerant to the outside air. Fans mounted above the
condenser unit are used to draw air through the condenser
coils. The temperature of the high-pressure vapour
determines the temperature at which the condensation
begins. As heat has to flow from the condenser to the air, the
condensation temperature must be higher than that of the air;
usually between - 12°C and -1°C. The high-pressure vapour
within the condenser is then cooled to the point where it
becomes a liquid refrigerant once more, whilst retaining
some heat. The liquid refrigerant then flows from the
condenser in to the liquid line.
4.4 The Expansion Valve
Within the refrigeration system, the expansion valve is
located at the end of the liquid line, before the evaporator.
The high-pressure liquid reaches the expansion valve,
having come from the condenser. The valve then reduces the
pressure of the refrigerant as it passes through the orifice,
which is located inside the valve. On reducing the pressure,
the temperature of the refrigerant also decreases to a level
below the surrounding air. This low-pressure, low
temperature liquid is then pumped in to the evaporator.
5. Methods of Refrigeration [4] [6]
Methods of refrigeration can be classified as;
 Non-Cyclic
 Cyclic
 Thermoelectric
 Magnetic Refrigeration
 Other Methods
5.1 Non-cyclic refrigeration
In non-cyclic refrigeration, cooling is accomplished by
melting ice or by subliming dry ice (frozen carbon dioxide).
These methods are used for small-scale refrigeration such as
in laboratories and workshops, or in portable coolers. Ice
owes its effectiveness as a cooling agent to its constant
melting point of 0 °C (32 °F). In order to melt, ice must
absorb 333.55 kJ/kg (approx. 144 Btu/lb) of heat. Foodstuffs
maintained at this temperature or slightly above have an
increased storage life. Solid carbon dioxide has no liquid
phase at normal atmospheric pressure, so sublimes directly
from the solid to vapor phase at a temperature of -78.5 °C (-
109.3 °F), and is therefore effective for maintaining products
at low temperatures during the period of sublimation
(Sublimation refers to the process of transition of a
substance from the solid phase to the gas phase without
passing through an intermediate liquid phase). Systems such
as this where the refrigerant evaporates and is vented into
the atmosphere are known as "total loss refrigeration".
5.1.1 Ice Refrigeration
In this method the ordinary ice is used for keeping the space
at temperature below the surrounding temperature. The
temperature of ice is considered to be 0 degree Celsius hence
it can be used to maintain the temperatures of about 5 to 10
degree Celsius. To use the ice for refrigerating effect a
closed and insulated chamber is required. On one side of the
chamber ice is kept while on the other side there is a space
which is to be cooled where some material to be cooled can
be placed. If the temperature below 0 degree Celsius is
required, then the mixture of ice and salt is used. This
method of cooling is still being used for cooling the cold
drinks, keeping the water chilled in thermos, etc.
5.1.2 Dry ice refrigeration
Dry ice is the solid carbon dioxide having the temperature of
-78 degree Celsius. Dry ice converts directly from solid state
to gaseous; this process is called as sublimation. Dry ice can
be pressed into various sizes and shapes as blocks or slabs.
Dry ice is usually packed in the frozen food cartons along
with the food that has to be kept frozen for long intervals of
time. When the dry ice gets converted into vapor state it
keeps the food frozen. The process of dry ice refrigeration is
now-a-days being used for freezing the food in aircraft
transportation. The non-cyclic methods of refrigeration can
be used only in places where small amount of refrigeration is
required in places like laboratories, workshops, water
coolers, small old drink shops, small hotels etc.
5.2 Cyclic Refrigeration [2]
This consists of a refrigeration cycle, where heat is removed
from a low-temperature space or source and rejected to a
high-temperature sink with the help of external work, and its
inverse, the thermodynamic power cycle. In the power cycle,
heat is supplied from a high-temperature source to the
engine, part of the heat being used to produce work and the
rest being rejected to a low-temperature sink. This satisfies
the second law of thermodynamics.
Paper ID: 020132041 1214
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Paper ID: 020132041 1216
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
The gas cycle is less efficient than the vapor compression
cycle. As such the working fluid does not receive and reject
heat at constant temperature. In the gas cycle, the
refrigeration effect is equal to the product of the specific
heat of the gas and the rise in temperature of the gas in the
low temperature side. Therefore, for the same cooling load, a
gas refrigeration cycle will require a large mass flow rate
and would be bulky.
Because of their lower efficiency and larger bulk, air cycle
coolers are not often used nowadays in terrestrial cooling
devices. The air cycle machine is very common, however,
on gas turbine-powered jet aircraft because compressed air is
readily available from the engines' compressor sections.
These jet aircraft's cooling and ventilation units also serve
the purpose of pressurizing the aircraft.
5.3 Thermoelectric refrigeration [1] [6]
Thermoelectric cooling uses the Peltier effect to create a heat
flux between the junctions of two different types of
materials. This effect is commonly used in camping and
portable coolers and for cooling electronic components and
small instruments.
5.4 Magnetic refrigeration [1] [6]
Magnetic refrigeration, or adiabatic demagnetization, is a
cooling technology based on the magnetocaloric effect, an
intrinsic property of magnetic solids. The refrigerant is often
a paramagnetic salt, such as cerium magnesium nitrate. The
active magnetic dipoles in this case are those of the electron
shells of the paramagnetic atoms.
A strong magnetic field is applied to the refrigerant, forcing
its various magnetic dipoles to align and putting these
degrees of freedom of the refrigerant into a state of lowered
entropy. A heat sink then absorbs the heat released by the
refrigerant due to its loss of entropy. Thermal contact with
the heat sink is then broken so that the system is insulated,
and the magnetic field is switched off. This increases the
heat capacity of the refrigerant, thus decreasing its
temperature below the temperature of the heat sink. Because
few materials exhibit the required properties at room
temperature, applications have so far been limited to
cryogenics and research.
5.5 Other Methods [1] [6]
Other methods of refrigeration include the:-
5.5.1)Air cycle machine: - An air cycle machine (ACM) is
the refrigeration unit of the environmental control system
(ECS) used in pressurized gas turbine-powered aircrafts. The
Air Cycle cooling process uses air instead of Freon in a gas
cycle
Paper ID: 020132041 1217
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
5.5.2) The vortex tube: - It is a mechanical device that
separates a compressed gas into hot and cold streams. It has
no parts. It is used for spot cooling, when compressed air is
available; and
5.5.3) Thermo acoustic refrigeration: - Thermo acoustic
engines are thermo acoustic devices which use high-
amplitude sound waves to pump heat from one place to
another. It is using sound waves in a pressurized gas to drive
heat transfer and heat exchange.
5.5.4)Steam jet cooling: - Steam jet cooling uses a high-
pressure jet of steam to cool water or other fluid media. Its
principle is, steam is passed through a vacuum ejector of
high efficiency to exhaust a separate, closed vessel which
forms part of a cooling water circuit. The partial vacuum in
the vessel causes some of the water to evaporate, thus giving
up heat through evaporative cooling. The chilled water is
pumped through the circuit to air coolers, while the
evaporated water from the ejector is recovered in separate
condensers and returned to the cooling circuit. Steam jet
cooling experienced a wave of popularity during the early
1930s for air conditioning large buildings. Steam ejector
refrigeration cycles were later supplanted by systems using
mechanical compressors.
6. Unit of refrigeration [6]
The units of refrigeration are always a unit of power.
Domestic and commercial refrigerators may be rated in kJ/s,
or Btu/h of cooling. For commercial and industrial
refrigeration systems most of the world uses the kilowatt
(kW) as the basic unit refrigeration. Typically, commercial
and industrial refrigeration systems North America are rated
in Tons of Refrigeration (TR). Historically, one Ton of
Refrigeration was defined as the energy removal rate that
will freeze one short ton of water at 0 °C (32 °F) in one day.
This was very important because many early refrigeration
systems were in ice houses. The simple unit allowed owners
of this refrigeration systems measure a days output of ice
against energy consumption and compare their plant to one
down the street. While ice houses make up a much smaller
part of the refrigeration industry than they once did the unit
of Tons of Refrigeration has remained in North America.
The unit's value as historically defined is approximately
11,958 BTU/hr (3.505 kW) has been redefined to be exactly
12,000 BTU/hr (3.517 kW).
While not truly a unit, a refrigeration system's Coefficient of
Performance (CoP) is very important in determining a
system's overall efficiency. It is defined as refrigeration
capacity in kW divided by the energy input in kW. While
CoP is a very simple measure, like the kW, it is typically not
used for industrial refrigeration in North America. Owners
and manufacturers of these systems typically use
Performance Factor. A system's Performance Factor is
defined as a system's energy input in horsepower divided by
its refrigeration capacity in Tons of Refrigeration. Both
Coefficient of Performance and Performance Factor can be
applied to either the entire system or to system components.
For example an individual compressor can be rated by
looking at the energy required to run the compressor versus
the expected refrigeration capacity based on inlet volume
flow rate. It is important to note that both Coefficient of
Performance and Performance Factor for a refrigeration
system are only defined at specific operating conditions.
Moving away from those operating conditions can
dramatically change a system's performance.
7. Assessment of Refrigeration [4]
7.1 TR
TR is the cooling effect produced is quantified as tons of
refrigeration, also referred to as “chiller tonnage.
§ TR = Q x Cp x (Ti – To) / 3024
Where Q is mass flow rate of coolant in kg/hr, Cp is coolant
specific heat in kCal /kg deg C, Ti is inlet temperature of
coolant to evaporator (chiller) in 0C, To is outlet
temperature of coolant from evaporator (chiller) in 0C.
1 TR of refrigeration = 3024 kCal/hr heat rejected
7.2 Specific Power Consumption
The specific power consumption kW/TR is a useful indicator
of the performance of a refrigeration system. By measuring
the refrigeration duty performed in TR and the kW inputs,
kW/TR is used as an energy performance indicator.
7.3 Coefficient of Performance
The theoretical Coefficient of Performance (Carnot), {COP
(Carnot), a standard measure of refrigeration efficiency of an
ideal refrigeration system} depends on two key system
temperatures:
Evaporator temperature (Te) and Condenser temperature
(Tc)
COP is given as: COP (Carnot) = Te / (Tc - Te)
This expression also indicates that higher COP (Carnot) is
achieved with higher evaporator temperatures and lower
condenser temperatures. But COP (Carnot) is only a ratio of
temperatures, and does not take into account the type of
compressor.
Hence the COP normally used in industry is calculated as
follows:
where the cooling effect is the difference in enthalpy across
the evaporator and expressed as kW.
Paper ID: 020132041 1218
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
8. Common Refrigerants [7]
There are several fluorocarbon refrigerants that have been
developed for use in VCRC.
Dichlorofluoromethane CCl2F2 R12
- used for refrigeration systems at higher
temperature levels typically, water chillers
and air conditioning.
has less chlorine, a little better for the
environment than R12 and used for lower
temperature applications
CHClF2 R22
tetrafluorethane - no chlorine ,it went into
production in 1991 and acted as replacement
for R12
CFH2CF3 R134a
Dichlorofluoroethane C2H3FCl2 R141b
corrosive and toxic, used in absorption
systems
NH3 Ammonia
behaves in the supercritical region, low
efficiency
CO2 R744
Combustible propane R290
9. How to Choose a Refrigerant [7]
Factors needed to be considered are Ozone Depletion
Potential, Global Warming Potential, Combustibility,
Thermal Factors.
 Ozone Depletion Potential: these are chlorinated and
brominated refrigerants, acts as a catalyst to destroy ozone
molecules and reduces the natural shielding effect from
incoming ultra violet B radiation.
 Global Warming Potential: Gases that absorb infrared
energy, with a high number of carbon-fluorine bonds and
generally have a long atmospheric lifetime.
 Combustibility: All hydro-carbon fuels, such as propane
 Thermal Factors:-The heat of vaporization of the
refrigerant should be high. The higher h(fg), the greater
the refrigerating effect per kg of fluid circulated. The
specific heat of the refrigerant should be low. The lower
the specific heat, the less heat it will pick up for a given
change in temperature during the throttling or in flow
through the piping and consequently the greater the
refrigerating effect per kg of refrigerant. The specific
volume of the refrigerant should be low to minimize the
work required per kg of refrigerant circulated. Since
evaporation and condenser temperatures are fixed by the
temperatures of the surroundings. Selection is based on
the suitability of the pressure-temperature relationship of
the refrigerant
 Other factors include:‐ Chemical Stability, Toxicity,
Cost, Environmental Friendliness, Does not result in very
low pressures in the evaporator (air leakage), Does not
result in very high pressures in the condenser (refrigerant
leakage)
The vapor compression cycle is most commonly used for
refrigeration.
Comparison of vapor compression and gas compression
refrigerating cycles based on following parameters: [4]
1)Type of refrigerant used: In vapor compression cycle
liquids like Freon and ammonia are used as the refrigerant.
In the gas cycle the gas like air is used as the refrigerant.
2)Heat exchangers: In the vapor compression refrigeration
cycle condenser and evaporator are the two heat
exchangers where the refrigerant gives up and absorbs
heat respectively. The refrigerant undergoes change in
phase in both the heat exchangers. In the gas cycle the
refrigerant exchanges heat in the heat exchangers, but
there is no phase change of the gas.
3)Efficiency of the cycle: The efficiency of the vapor
compression cycle is more than that of the gas cycle. For
producing the same amount of refrigerating effect in the
gas cycle, large volume of gas is required; hence the
systems tend to become very large, bulky and expensive,
which are not affordable for the domestic applications.
4)Applications: The vapor compression cycle is most
widely used for the refrigeration purposes. It is used in
household refrigerators, air-conditioners, water cooler, ice
and ice cream makers, deep freezers, large industrial
refrigeration and air-conditioning systems, etc. Since the
size of the gas compression systems is very large, they are
not used for the domestic and industrial purposes. They
are used widely in the aircraft air-conditioning systems
since in aircrafts air at very high pressures is available
readily and there won’t be the need of air compressors.
This makes the air-conditioning system in the aircraft light
weight and less power consuming. The use of air as the
refrigerant in aircraft prevents the dangers of fire of from
the flammable refrigerants.
Differences between an absorption refrigeration system and
a VCRC [4]
Absorption RS VCRC
 The refrigerant is absorbed by an
absorbent material to form a
liquid solution.
 Vapour is compressed
between the evaporator
and the condenser.
 Heat is added to the process to
retrieve the refrigerant vapour
from the liquid solution.
 Process is driven by work
 Process is driven by heat
10. Current Applications of Refrigeration [6]
Probably the most widely used current applications of
refrigeration are for the refrigeration of foodstuffs in homes,
restaurants and large storage warehouses. The use of
refrigerators in kitchens for the storage of fruits and
vegetables has permitted the addition of fresh salads to the
modern diet year round, and to store fish and meats safely
for long periods.
In commerce and manufacturing, there are many uses for
refrigeration. Refrigeration is used to liquefy gases like
oxygen, nitrogen, propane and methane for example. In
compressed air purification, it is used to condense water
vapor from compressed air to reduce its moisture content. In
oil refineries, chemical plants, and petrochemical plants,
refrigeration is used to maintain certain processes at their
required low temperatures (for example, in the alkylation of
butenes and butane to produce a high octane gasoline
component). Metal workers use refrigeration to temper steel
and cutlery. In transporting temperature-sensitive foodstuffs
Paper ID: 020132041 1219
International Journal of Science and Research (IJSR)
ISSN (Online): 2319-7064
Impact Factor (2012): 3.358
Volume 3 Issue 5, May 2014
www.ijsr.net
Licensed Under Creative Commons Attribution CC BY
and other materials by trucks, trains, airplanes and sea-going
vessels, refrigeration is a necessity.
Dairy products are constantly in need of refrigeration, and it
was only discovered in the past few decades that eggs
needed to be refrigerated during shipment rather than
waiting to be refrigerated after arrival at the grocery store.
Meats, poultry and fish all must be kept in climate-
controlled environments before being sold. Refrigeration
also helps keep fruits and vegetables edible longer. One of
the most influential uses of refrigeration was in the
development of the sushi/sashimi industry in Japan. Prior to
the discovery of refrigeration, many sushi connoisseurs
suffered great morbidity and mortality from diseases such as
hepatitis A However the dangers of unrefrigerated sashimi
was not brought to light for decades due to the lack of
research and healthcare distribution across rural Japan.
Around mid-century, the Zojirushi Corporation based in
Kyoto made breakthroughs in refrigerator designs making
refrigerators cheaper and more accessible for restaurant
proprietors and the general public.
References
[1] Ameen Ahmadul Refrigeration and Air Conditioning
Prentice Hall of India Pvt. Ltd. Publishing company,
New Delhi
[2] Arora, C.P. Refrigeration and Air Conditioning. Second
edition. Tata McGraw-Hill
[3] Publishing Company Ltd. 2000.
[4] Arora, Ramesh Chandra. "Mechanical vapour
compression refrigeration". Refrigeration and Air
Conditioning. New Delhi, India: PHI Learning
[5] Energy Efficiency Guide for Industry in Asia –
www.energyefficiencyasia.org Copyright © United
Nations Environment Programme (year 2006),
Refrigeration & Air conditioning system
[6] www.honeywell.com/refrigeration, An introduction to
Refrigeration.
[7] http://en.wikipedia.org/wiki/Refrigeration
[8] http://educypedia.karadimov.info/library/c6.pdf
Paper ID: 020132041 1220

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A Study On Refrigeration

  • 1. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY A Study on Refrigeration Poonam Dhankhar M. Tech, G.J.U.S & T Hissar, Haryana, India Abstract: Refrigeration is a basic method of food preservation. All the refrigeration methods for food preservation are based on Reverse Carnot cycle, which explains Adiabatic and Isothermal Expansion and Compression. Basic components used in these cycles are Evaporator, Compressor, Condenser and Expansion Valve. Generally used cycle is Vapor Compression Cycle. Other cycles are Vapor Absorption Cycle, Gas Cycle. Other new methods of Refrigeration are Thermoelectric and Magnetic Refrigeration. Various types of refrigerants are used in these cycles based upon their properties. Commercially Refrigeration is used as preservation method in various food industries like Dairy and Meat Processing industry. Keywords: Food preservation, reverse carnot cycle, evaporator, compressor, condenser, vapor compression cycle, Thermoelectric and Magnetic Refrigeration 1. Introduction [1] [4] Refrigeration is a process in which work is done to remove heat from one location to another. Refrigeration has many applications including but not limited to household refrigerators, industrial freezers, cryogenics, air conditioning, and heat pumps. In order to satisfy the Second Law of Thermodynamics, some form of work must be performed to accomplish this. The work is traditionally done by mechanical work but can also be done by magnetism, laser or other means. Since the turn of the century, there has been steady growth of application of refrigeration in preservation of perishable food products, agriculture and fishery. The purpose of refrigeration for food is to retard deterioration by micro-organisms, chemical and physical processes. By cooling at temperatures just above freezing it is possible to achieve a limited extension of storage time which is often sufficient for safe distribution and marketing. By freezing to temperature as low as -30ᴼC, deterioration can be slowed down further and this increases the storage time. Refrigeration has applications in diverse industries, such as manufacturing chemicals, petroleum, refineries, paper and pulp industries also. 2. Review of Literature [6] Ice harvesting:‐ The use of ice to refrigerate and thus preserve food goes back to prehistoric times. Through the ages, the seasonal harvesting of snow and ice was a regular practice of most of the ancient cultures: Chinese, Hebrews, Greeks, Romans, Persians. Ice and snow were stored in caves or dugouts lined with straw or other insulating materials. The Persians stored ice in pits called yakhchals. Rationing of the ice allowed the preservation of foods over the warm periods. This practice worked well down through the centuries, with ice houses remaining in use into the twentieth century. In the 16th century, the discovery of chemical refrigeration was one of the first steps toward artificial means of refrigeration. Sodium nitrate or potassium nitrate, when added to water, lowered the water temperature and created a sort of refrigeration bath for cooling substances. During the first half of the 19th century, ice harvesting became big business in America. New Englander Frederic Tudor, who became known as the "Ice King", worked on developing better insulation products for the long distance shipment of ice, especially to the tropics. First refrigeration systems:- The first known method of artificial refrigeration was demonstrated by William Cullen at the University of Glasgow in Scotland in 1756. Cullen used a pump to create a partial vacuum over a container of diethyl ether, which then boiled, absorbing heat from the surrounding air. The experiment even created a small amount of ice, but had no practical application at that time. In 1758, Benjamin Franklin and John Hadley, professor of chemistry at Cambridge University, conducted an experiment to explore the principle of evaporation as a means to rapidly cool an object. Franklin and Hadley confirmed that evaporation of highly volatile liquids such as alcohol and ether could be used to drive down the temperature of an object past the freezing point of water. They conducted their experiment with the bulb of a mercury thermometer. They lowered the temperature of the thermometer bulb down to 7 °F (−14 °C) while the ambient temperature was 65 °F (18 °C). Franklin noted that soon after they passed the freezing point of water (32 °F) a thin film of ice formed on the surface of the thermometer's bulb and that the ice mass was about a quarter inch thick when they stopped the experiment upon reaching 7 °F (−14 °C). In 1820, the British scientist Michael Faraday liquefied ammonia and other gases by using high pressures and low temperatures. An American living in Great Britain, Jacob Perkins, obtained the first patent for a vapor-compression refrigeration system in 1834. In 1842, an American physician, John Gorrie, designed the first system for refrigerating water to produce ice. His system compressed air, then partially cooled the hot compressed air with water before allowing it to expand while doing part of the work required to drive the air compressor. That isentropic (the process takes place from initiation to completion without an increase or decrease in the entropy of the system, i.e., the entropy of the system remains constant) expansion cooled the air to a temperature low enough to freeze water and produce ice, or to flow "through a pipe for effecting Paper ID: 020132041 1212
  • 2. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY refrigeration otherwise" as stated in his patent granted by the U.S. Patent Office in 1851.Gorrie built a working prototype (A prototype is an early sample or model built to test a concept or process or to act as a thing to be replicated or learned from), but his system was a commercial failure. Alexander Twining began experimenting with vapor- compression refrigeration in 1848 and obtained patents in 1850 and 1853. He is credited with having initiated commercial refrigeration in the United States by 1856. The first gas absorption refrigeration system using gaseous ammonia dissolved in water (referred to as "aqua ammonia") was developed by Ferdinand Carré of France in 1859 and patented in 1860. Due to the toxicity of ammonia, such systems were not developed for use in homes, but were used to manufacture ice for sale. Thaddeus Lowe, an American balloonist from the Civil War, had experimented over the years with the properties of gases. One of his mainstay enterprises was the high-volume production of hydrogen gas. He also held several patents on ice making machines. His "Compression Ice Machine" would revolutionize the cold storage industry. In 1869 he and other investors purchased an old steamship onto which they loaded one of Lowe’s refrigeration units and began shipping fresh fruit from New York to the Gulf Coast area, and fresh meat from Galveston, Texas back to New York. Because of Lowe’s lack of knowledge about shipping, the business was a costly failure, and it was difficult for the public to get used to the idea of being able to consume meat that had been so long out of the packing house. Domestic mechanical refrigerators became available in the United States around 1911. a) Widespread commercial use By the 1870s breweries had become the largest users of commercial refrigeration units, though some still relied on harvested ice. Though the ice-harvesting industry had grown immensely by the turn of the 20th century, pollution and sewage had begun to creep into natural ice making it a problem in the metropolitan suburbs. Eventually breweries began to complain of tainted ice. This raised demand for more modern and consumer-ready refrigeration and ice- making machines. In 1895, German engineer Carl von Linde set up a large-scale process for the production of liquid air and eventually liquid oxygen for use in safe household refrigerators. Refrigerated railroad cars were introduced in the US in the 1840s for the short-run transportation of dairy products. By 1900, the meat packing houses of Chicago had adopted ammonia-cycle commercial refrigeration. By 1914, almost every location used artificial refrigeration. The big meat packers, Armour, Swift, and Wilson, had purchased the most expensive units which they installed on train cars and in branch houses and storage facilities in the more remote distribution areas.It was not until the middle of the 20th century that refrigeration units were designed for installation on tractor-trailer rigs (trucks or Lorries). Refrigerated vehicles are used to transport perishable goods, such as frozen foods, fruit and vegetables, and temperature-sensitive chemicals. Most modern refrigerators keep the temperature between -40 and 20 °C and have a maximum payload of around 24,000 kg gross weight (in Europe). b) Home and consumer use With the invention of synthetic refrigerants based mostly on a chlorofluorocarbon (CFC) chemical, safer refrigerators were possible for home and consumer use. Freon is a trademark of the DuPont Corporation and refers to these CFC, and later hydro chlorofluorocarbon (HCFC) and hydro fluorocarbon (HFC), refrigerants developed in the late 1920s. These refrigerants were considered at the time to be less harmful than the commonly used refrigerants of the time, including methyl formate, ammonia, methyl chloride, and sulfur dioxide. The intent was to provide refrigeration equipment for home use without danger: these CFC refrigerants answered that need. However, in the 1970s the compounds were found to be reacting with atmospheric ozone, an important protection against solar ultraviolet radiation, and their use as a refrigerant worldwide was curtailed in the Montreal Protocol of 1987. 3. Basic Refrigeration Principle [4] [5] If you were to place a hot cup of coffee on a table and leave it for a while, the heat in the coffee would be transferred to the materials in contact with the coffee, i.e. the cup, the table and the surrounding air. As the heat is transferred, the coffee in time cools. Using the same principle, refrigeration works by removing heat from a product and transferring that heat to the outside air. Refrigeration is used to cool products. The refrigeration system (R) transfers heat from a cooler low-energy reservoir to a warmer high-energy reservoir Figure 1: Schematic representation of refrigeration system 4. Refrigeration System Components [5] There are five basic components of a refrigeration system, these are: Evaporator, Compressor, Condenser, Expansion Valve and Refrigerant- to conduct the heat from the product. In order for the refrigeration cycle to operate successfully each component must be present within the refrigeration system. Paper ID: 020132041 1213
  • 3. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY 4.1 The Evaporator The purpose of the evaporator is to remove unwanted heat from the product, via the liquid refrigerant. The liquid refrigerant contained within the evaporator is boiling at a low-pressure. The level of this pressure is determined by two factors:  The rate at which the heat is absorbed from the product to the liquid refrigerant in the evaporator  The rate at which the low-pressure vapour is removed from the evaporator by the compressor  To enable the transfer of heat, the temperature of the liquid refrigerant must be lower than the temperature of the product being cooled. Once transferred, the liquid refrigerant is drawn from the evaporator by the compressor via the suction line. When leaving the evaporator coil the liquid refrigerant is in vapor form. 4.2 The Compressor The purpose of the compressor is to draw the low- temperature, low-pressure vapour from the evaporator via the suction line. When vapour is compressed it rises in temperature. Therefore, the compressor transforms the vapour from a low-temperature vapor to a high-temperature vapour, in turn increasing the pressure. The vapor is then released from the compressor in to the discharge line. 4.3 The Condenser The purpose of the condenser is to extract heat from the refrigerant to the outside air. Fans mounted above the condenser unit are used to draw air through the condenser coils. The temperature of the high-pressure vapour determines the temperature at which the condensation begins. As heat has to flow from the condenser to the air, the condensation temperature must be higher than that of the air; usually between - 12°C and -1°C. The high-pressure vapour within the condenser is then cooled to the point where it becomes a liquid refrigerant once more, whilst retaining some heat. The liquid refrigerant then flows from the condenser in to the liquid line. 4.4 The Expansion Valve Within the refrigeration system, the expansion valve is located at the end of the liquid line, before the evaporator. The high-pressure liquid reaches the expansion valve, having come from the condenser. The valve then reduces the pressure of the refrigerant as it passes through the orifice, which is located inside the valve. On reducing the pressure, the temperature of the refrigerant also decreases to a level below the surrounding air. This low-pressure, low temperature liquid is then pumped in to the evaporator. 5. Methods of Refrigeration [4] [6] Methods of refrigeration can be classified as;  Non-Cyclic  Cyclic  Thermoelectric  Magnetic Refrigeration  Other Methods 5.1 Non-cyclic refrigeration In non-cyclic refrigeration, cooling is accomplished by melting ice or by subliming dry ice (frozen carbon dioxide). These methods are used for small-scale refrigeration such as in laboratories and workshops, or in portable coolers. Ice owes its effectiveness as a cooling agent to its constant melting point of 0 °C (32 °F). In order to melt, ice must absorb 333.55 kJ/kg (approx. 144 Btu/lb) of heat. Foodstuffs maintained at this temperature or slightly above have an increased storage life. Solid carbon dioxide has no liquid phase at normal atmospheric pressure, so sublimes directly from the solid to vapor phase at a temperature of -78.5 °C (- 109.3 °F), and is therefore effective for maintaining products at low temperatures during the period of sublimation (Sublimation refers to the process of transition of a substance from the solid phase to the gas phase without passing through an intermediate liquid phase). Systems such as this where the refrigerant evaporates and is vented into the atmosphere are known as "total loss refrigeration". 5.1.1 Ice Refrigeration In this method the ordinary ice is used for keeping the space at temperature below the surrounding temperature. The temperature of ice is considered to be 0 degree Celsius hence it can be used to maintain the temperatures of about 5 to 10 degree Celsius. To use the ice for refrigerating effect a closed and insulated chamber is required. On one side of the chamber ice is kept while on the other side there is a space which is to be cooled where some material to be cooled can be placed. If the temperature below 0 degree Celsius is required, then the mixture of ice and salt is used. This method of cooling is still being used for cooling the cold drinks, keeping the water chilled in thermos, etc. 5.1.2 Dry ice refrigeration Dry ice is the solid carbon dioxide having the temperature of -78 degree Celsius. Dry ice converts directly from solid state to gaseous; this process is called as sublimation. Dry ice can be pressed into various sizes and shapes as blocks or slabs. Dry ice is usually packed in the frozen food cartons along with the food that has to be kept frozen for long intervals of time. When the dry ice gets converted into vapor state it keeps the food frozen. The process of dry ice refrigeration is now-a-days being used for freezing the food in aircraft transportation. The non-cyclic methods of refrigeration can be used only in places where small amount of refrigeration is required in places like laboratories, workshops, water coolers, small old drink shops, small hotels etc. 5.2 Cyclic Refrigeration [2] This consists of a refrigeration cycle, where heat is removed from a low-temperature space or source and rejected to a high-temperature sink with the help of external work, and its inverse, the thermodynamic power cycle. In the power cycle, heat is supplied from a high-temperature source to the engine, part of the heat being used to produce work and the rest being rejected to a low-temperature sink. This satisfies the second law of thermodynamics. Paper ID: 020132041 1214
  • 4. A th ci H & au th w fr st he (T va co th lo pr m m R C 1 2 V 1 2 5 T re in sc co T di re F en te te va A refrigeration he refrigerant irculates thro HVACR (HVA & Refrigerati utomotive env he "process" o whether it is a p rom hot to co torage volume eat source int Thermal insul arious process ontact or in ra he work and ower tempera rinciple of mathematically most common Rankin vapor-c Cyclic refrigera . Vapor cycle . Gas cycle Vapor cycle re . Vapor-comp . Vapor-abso .2.1 Vapor-co The vapor-com efrigerators a ndustrial refr chematic diag ompression re Figur The thermodyn iagram as sho efrigerant such rom point 1 to ntropy and e emperature, b emperature. F apor travels t n cycle describ as it alternate ough a refrig ACR (Heating ion) refers vironmental c of refrigerant packaged or s old. Work is a e by pumping to a higher te lation is the ses of heat tra ange of radiat energy requi ature in the the refrige y by Sadi Carn types of refrig compression r ation can be c e, and frigeration can pression refrig orption refrige ompression C mpression cyc as well as in rigeration sy gram of the c efrigeration sy re 1: Vapor co namics of th own in Figur h as Freon en o point 2, the xits the com but still belo rom point 2 t through the co Internatio Licens bes the change ely absorbs an gerator. It i g, Ventilating to technolog comfort) work flow through split system. H applied to coo g heat from a emperature he reduction of ansfer between tive influence ired to achiev cooled spac eration cycle not in 1824 as geration syste refrigeration c classified as: n further be cl geration ration Cycle cle is used i n many large ystems. Figu components o ystem. ompression ref he cycle can re 2. In this c nters the com vapor is com mpressor as a ow the vapor to point 3 and ondenser whi onal Journa ISSN Impac Volume sed Under Cre es that take pl nd rejects hea s also appli g, Air Conditi gy of indoo k, when desc h an HVACR Heat naturally ol a living spa a lower tempe eat sink. Insu f the effects o n objects in th e) is used to r ve and maint ce. The ope e was desc s a heat engine ems use the rev cycle. lassified as: in most hous e commercia re 1 provid of a typical v frigeration be analyzed cycle, a circu mpressor as a v mpressed at co vapor at a h r pressure a d on to point ich cools the al of Scienc N (Online): 23 ct Factor (201 e 3 Issue 5, www.ijsr.n eative Commo lace in at as it ed to ioning or or cribing R unit, flows ace or erature ulation of the hermal reduce tain a erating cribed e. The verse- sehold al and des a vapor- on a ulating vapor. nstant higher t that 4, the vapor unt a li tem goe val eva hal Tha tem liqu or air acr vap the The com acc sys com beh Her (ref 1) 2) 3) ce and Rese 19-7064 12): 3.358 May 2014 net ons Attribution til it starts con iquid by remo mperature. Bet es through th ve) where its aporation and f of the liquid at results in mperature and uid-vapor mix tubes and is (from the spa ross the evapo por returns to thermodynam e above dis mpression ref count real-wor stem, slight mpression of havior (if any) Figure re are the var fer the figure) Compression compressor a temperature. refrigerant id superheated s Condensatio the condense due to whic remains cons Expansion: expansion v expansion of temperature leaves expan partially in ga earch (IJSR n CC BY ndensing, and oving addition tween points he expansion s pressure abr d auto-refriger d. a mixture of d pressure as xture then trav completely v ace being refr orator coil or t the compress mic cycle. scussion is frigeration cy rld effects like thermodynam f the refriger ). e 2: Temperat rious processe ): n: The vapo and get compr During this deally remain state. on: The super er where it is ch its tempe tant and it get The liquid valve or thr f the refriger and pressure nsion valve aseous state. R) d then condens al heat at con 4 and 5, the valve (also ruptly decreas ration of, typ f liquid and v shown at p vels through th aporized by c rigerated) bein tubes. The res sor inlet at po based on th ycle, and do e frictional pr mic irreversib rant vapor, o ture–Entropy d es of vapor c ors of refrig essed to high process the ns constant rheated refrig cooled eithe erature reduc ts converted in refrigerant rottling valve rant occurs, d e falls down. in partially ses the vapor stant pressure liquid refrige called a thr ses, causing f pically, less vapor at a lo oint 5. The he evaporator cooling the w ng blown by a sulting refrige oint 1 to comp he ideal va es not take essure drop in bility during or non-ideal diagram compression c gerant enter pressure and h e entropy of and it leave gerant then en er by air or w ces, but pres nto liquid stat then enters e where sud due to which . The refrige liquid state into e and erant ottle flash than ower cold coil warm a fan erant plete apor- into n the the gas cycle the high the s in nters water ssure e. the dden h its erant and Paper ID: 020132041 1215
  • 5. 4) T co cy cy co re cy 5 In ab an co it (a T fo re in ov T ex re is a ) Evaporatio partially ga enters the e kept. It is h The refriger cooled and This low pre ompressor wh ycle of refrige yclic process ommercial efrigerator is ycle. .2.2 Vapor ab n the early bsorption cyc nd widely u ompression cy ts importance about one fift Today, the vap or heating is ecreational ve ndustrial env vercomes its i The absorption xcept for th efrigerant vap s replaced by suitable liqui on or coolin aseous refrig evaporator wh here where the rant absorbs t gets converte ssure refrige here it is co eration repeat is used for ref applications. a good exam bsorption cyc years of the le using wate used. After t ycle, the vapo because of its fth of that of por absorption available bu ehicles that c vironments inefficiency. n cycle is sim he method o por. In the abs an absorber w d, a liquid pum Internatio Licens ng: The pa erant at very here the substa e refrigeration the heat from d into vapor s rant is then mpressed aga ts again. The frigeration in The ord mple of the cle e twentieth c er-ammonia sy the developm or absorption s low coeffici f the vapor c n cycle is used ut electricity carry LP gas. where plen milar to the c f raising the sorption syste which dissolve mp which rais onal Journa ISSN Impac Volume sed Under Cre artially liquid y low tempe ance to be coo n effect is prod the substance state. absorbed b ain and the w vapor compre domestic as w dinary hous application o century, the ystems was po ment of the cycle lost mu ient of perform ompression c d mainly wher is not, such It is also us tiful waste compression e pressure o em, the comp es the refriger ses the pressur al of Scienc N (Online): 23 ct Factor (201 e 3 Issue 5, www.ijsr.n eative Commo d and erature oled is duced. e to be y the whole ession well as sehold of this vapor opular vapor uch of mance cycle). re fuel as in sed in heat cycle, of the ressor rant in re and a g vap by is m com com com (ab [ab The sim me vap wh var 1) C abs the abs Thi hea am pre pro stea mu is l of h 2) tem wat 3) E in t of t 4) E wh in v by pro The bro sys bro 5.2 Wh exp call the cyc eva gas ce and Rese 19-7064 12): 3.358 May 2014 net ons Attribution enerator whic por from the h the liquid pum much smaller mpression cyc mbination of r mmon combin bsorbent), and bsorbent]. e various pro milar to the o thod of comp por absorption hich has very rious processe Compression sorption system re is absorber sorbent, in w is mixture of ated thus inc mmonia occur essure and h ovided to the am. The amo uch lesser than ots of saving heat in the for Condensati mperature then ter and its tem Expansion: T throttling valv the ammonia r Evaporation: here it produce vapor state an absorbent, w ocess repeats a ere are differe omide that can stems are ca omide absorpti .3 Gas cycle hen the work panded but do led a gas cyc re is no cond cle, compone aporator in a v s-to-gas heat e earch (IJSR n CC BY ch, on heat add high-pressure mp but, for a than needed b cle. In an abs refrigerant an nations are am d water (refr ocesses of th one in vapor pression of t n system amm high affinity es of vapor abs n or absorptio m there is no r. The absorb which the ref f water and a crease in tem s. Ammonia high temperat e pump and h ount of electr n that required of electricity, rm of steam ha ion: The r n enters cond mperature and Thereafter the ve due to whic refrigerant red : Finally the re es the cooling nd then enters water and co again and cycl ent types abs n be used wit alled water a ion system. [3] king fluid is oesn't change p cle. Air is mo densation and ents correspo vapor compres exchangers in R) dition, drives liquid. Some given quantity by the compre sorption refrig nd absorbent i mmonia (refrig rigerant) and he vapor abso compression the refrigeran monia is used to dissolve in sorption cycle on of the refr traditional co ber consists o frigerant, amm ammonia is t mperature and leaves the ture. Some w heating is ca ricity required d by the compr however, the as to be provid refrigerant a denser where pressure redu expansion of ch the tempera duces drastica efrigerant ente effect. It leav absorber, wh mpressed by le continues. orbents like w th refrigerant absorption sy a gas that is phase, the refr st often this w evaporation nding to the ssion cycle ar gas cycles. off the refrige e work is requ y of refrigeran essor in the v gerator, a suit is used. The m gerant) and w lithium brom orption cycle n cycle, only nt is different as the refriger n water. Here e: rigerant: In v ompressor, ins f water, calle monia, dissol then pumped d pressure of absorber at h work has to arried out by d by the pum ressor hence t additional so ded. at pressure e it is cooled uces. refrigerant oc ature and pres ally and sudde ers the evapor ves the evapor here it is absor the pump. water and lith ammonia. Th ystem or lith compressed frigeration cyc working fluid intended in a e condenser e the hot and erant uired nt, it apor table most water mide are the t. In rant, e are apor stead ed as lves. and f the high o be y the mp is there urce and d by ccurs ssure enly. rator rator rbed This hium hese hium and cle is d. As a gas and cold Paper ID: 020132041 1216
  • 6. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY The gas cycle is less efficient than the vapor compression cycle. As such the working fluid does not receive and reject heat at constant temperature. In the gas cycle, the refrigeration effect is equal to the product of the specific heat of the gas and the rise in temperature of the gas in the low temperature side. Therefore, for the same cooling load, a gas refrigeration cycle will require a large mass flow rate and would be bulky. Because of their lower efficiency and larger bulk, air cycle coolers are not often used nowadays in terrestrial cooling devices. The air cycle machine is very common, however, on gas turbine-powered jet aircraft because compressed air is readily available from the engines' compressor sections. These jet aircraft's cooling and ventilation units also serve the purpose of pressurizing the aircraft. 5.3 Thermoelectric refrigeration [1] [6] Thermoelectric cooling uses the Peltier effect to create a heat flux between the junctions of two different types of materials. This effect is commonly used in camping and portable coolers and for cooling electronic components and small instruments. 5.4 Magnetic refrigeration [1] [6] Magnetic refrigeration, or adiabatic demagnetization, is a cooling technology based on the magnetocaloric effect, an intrinsic property of magnetic solids. The refrigerant is often a paramagnetic salt, such as cerium magnesium nitrate. The active magnetic dipoles in this case are those of the electron shells of the paramagnetic atoms. A strong magnetic field is applied to the refrigerant, forcing its various magnetic dipoles to align and putting these degrees of freedom of the refrigerant into a state of lowered entropy. A heat sink then absorbs the heat released by the refrigerant due to its loss of entropy. Thermal contact with the heat sink is then broken so that the system is insulated, and the magnetic field is switched off. This increases the heat capacity of the refrigerant, thus decreasing its temperature below the temperature of the heat sink. Because few materials exhibit the required properties at room temperature, applications have so far been limited to cryogenics and research. 5.5 Other Methods [1] [6] Other methods of refrigeration include the:- 5.5.1)Air cycle machine: - An air cycle machine (ACM) is the refrigeration unit of the environmental control system (ECS) used in pressurized gas turbine-powered aircrafts. The Air Cycle cooling process uses air instead of Freon in a gas cycle Paper ID: 020132041 1217
  • 7. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY 5.5.2) The vortex tube: - It is a mechanical device that separates a compressed gas into hot and cold streams. It has no parts. It is used for spot cooling, when compressed air is available; and 5.5.3) Thermo acoustic refrigeration: - Thermo acoustic engines are thermo acoustic devices which use high- amplitude sound waves to pump heat from one place to another. It is using sound waves in a pressurized gas to drive heat transfer and heat exchange. 5.5.4)Steam jet cooling: - Steam jet cooling uses a high- pressure jet of steam to cool water or other fluid media. Its principle is, steam is passed through a vacuum ejector of high efficiency to exhaust a separate, closed vessel which forms part of a cooling water circuit. The partial vacuum in the vessel causes some of the water to evaporate, thus giving up heat through evaporative cooling. The chilled water is pumped through the circuit to air coolers, while the evaporated water from the ejector is recovered in separate condensers and returned to the cooling circuit. Steam jet cooling experienced a wave of popularity during the early 1930s for air conditioning large buildings. Steam ejector refrigeration cycles were later supplanted by systems using mechanical compressors. 6. Unit of refrigeration [6] The units of refrigeration are always a unit of power. Domestic and commercial refrigerators may be rated in kJ/s, or Btu/h of cooling. For commercial and industrial refrigeration systems most of the world uses the kilowatt (kW) as the basic unit refrigeration. Typically, commercial and industrial refrigeration systems North America are rated in Tons of Refrigeration (TR). Historically, one Ton of Refrigeration was defined as the energy removal rate that will freeze one short ton of water at 0 °C (32 °F) in one day. This was very important because many early refrigeration systems were in ice houses. The simple unit allowed owners of this refrigeration systems measure a days output of ice against energy consumption and compare their plant to one down the street. While ice houses make up a much smaller part of the refrigeration industry than they once did the unit of Tons of Refrigeration has remained in North America. The unit's value as historically defined is approximately 11,958 BTU/hr (3.505 kW) has been redefined to be exactly 12,000 BTU/hr (3.517 kW). While not truly a unit, a refrigeration system's Coefficient of Performance (CoP) is very important in determining a system's overall efficiency. It is defined as refrigeration capacity in kW divided by the energy input in kW. While CoP is a very simple measure, like the kW, it is typically not used for industrial refrigeration in North America. Owners and manufacturers of these systems typically use Performance Factor. A system's Performance Factor is defined as a system's energy input in horsepower divided by its refrigeration capacity in Tons of Refrigeration. Both Coefficient of Performance and Performance Factor can be applied to either the entire system or to system components. For example an individual compressor can be rated by looking at the energy required to run the compressor versus the expected refrigeration capacity based on inlet volume flow rate. It is important to note that both Coefficient of Performance and Performance Factor for a refrigeration system are only defined at specific operating conditions. Moving away from those operating conditions can dramatically change a system's performance. 7. Assessment of Refrigeration [4] 7.1 TR TR is the cooling effect produced is quantified as tons of refrigeration, also referred to as “chiller tonnage. § TR = Q x Cp x (Ti – To) / 3024 Where Q is mass flow rate of coolant in kg/hr, Cp is coolant specific heat in kCal /kg deg C, Ti is inlet temperature of coolant to evaporator (chiller) in 0C, To is outlet temperature of coolant from evaporator (chiller) in 0C. 1 TR of refrigeration = 3024 kCal/hr heat rejected 7.2 Specific Power Consumption The specific power consumption kW/TR is a useful indicator of the performance of a refrigeration system. By measuring the refrigeration duty performed in TR and the kW inputs, kW/TR is used as an energy performance indicator. 7.3 Coefficient of Performance The theoretical Coefficient of Performance (Carnot), {COP (Carnot), a standard measure of refrigeration efficiency of an ideal refrigeration system} depends on two key system temperatures: Evaporator temperature (Te) and Condenser temperature (Tc) COP is given as: COP (Carnot) = Te / (Tc - Te) This expression also indicates that higher COP (Carnot) is achieved with higher evaporator temperatures and lower condenser temperatures. But COP (Carnot) is only a ratio of temperatures, and does not take into account the type of compressor. Hence the COP normally used in industry is calculated as follows: where the cooling effect is the difference in enthalpy across the evaporator and expressed as kW. Paper ID: 020132041 1218
  • 8. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY 8. Common Refrigerants [7] There are several fluorocarbon refrigerants that have been developed for use in VCRC. Dichlorofluoromethane CCl2F2 R12 - used for refrigeration systems at higher temperature levels typically, water chillers and air conditioning. has less chlorine, a little better for the environment than R12 and used for lower temperature applications CHClF2 R22 tetrafluorethane - no chlorine ,it went into production in 1991 and acted as replacement for R12 CFH2CF3 R134a Dichlorofluoroethane C2H3FCl2 R141b corrosive and toxic, used in absorption systems NH3 Ammonia behaves in the supercritical region, low efficiency CO2 R744 Combustible propane R290 9. How to Choose a Refrigerant [7] Factors needed to be considered are Ozone Depletion Potential, Global Warming Potential, Combustibility, Thermal Factors.  Ozone Depletion Potential: these are chlorinated and brominated refrigerants, acts as a catalyst to destroy ozone molecules and reduces the natural shielding effect from incoming ultra violet B radiation.  Global Warming Potential: Gases that absorb infrared energy, with a high number of carbon-fluorine bonds and generally have a long atmospheric lifetime.  Combustibility: All hydro-carbon fuels, such as propane  Thermal Factors:-The heat of vaporization of the refrigerant should be high. The higher h(fg), the greater the refrigerating effect per kg of fluid circulated. The specific heat of the refrigerant should be low. The lower the specific heat, the less heat it will pick up for a given change in temperature during the throttling or in flow through the piping and consequently the greater the refrigerating effect per kg of refrigerant. The specific volume of the refrigerant should be low to minimize the work required per kg of refrigerant circulated. Since evaporation and condenser temperatures are fixed by the temperatures of the surroundings. Selection is based on the suitability of the pressure-temperature relationship of the refrigerant  Other factors include:‐ Chemical Stability, Toxicity, Cost, Environmental Friendliness, Does not result in very low pressures in the evaporator (air leakage), Does not result in very high pressures in the condenser (refrigerant leakage) The vapor compression cycle is most commonly used for refrigeration. Comparison of vapor compression and gas compression refrigerating cycles based on following parameters: [4] 1)Type of refrigerant used: In vapor compression cycle liquids like Freon and ammonia are used as the refrigerant. In the gas cycle the gas like air is used as the refrigerant. 2)Heat exchangers: In the vapor compression refrigeration cycle condenser and evaporator are the two heat exchangers where the refrigerant gives up and absorbs heat respectively. The refrigerant undergoes change in phase in both the heat exchangers. In the gas cycle the refrigerant exchanges heat in the heat exchangers, but there is no phase change of the gas. 3)Efficiency of the cycle: The efficiency of the vapor compression cycle is more than that of the gas cycle. For producing the same amount of refrigerating effect in the gas cycle, large volume of gas is required; hence the systems tend to become very large, bulky and expensive, which are not affordable for the domestic applications. 4)Applications: The vapor compression cycle is most widely used for the refrigeration purposes. It is used in household refrigerators, air-conditioners, water cooler, ice and ice cream makers, deep freezers, large industrial refrigeration and air-conditioning systems, etc. Since the size of the gas compression systems is very large, they are not used for the domestic and industrial purposes. They are used widely in the aircraft air-conditioning systems since in aircrafts air at very high pressures is available readily and there won’t be the need of air compressors. This makes the air-conditioning system in the aircraft light weight and less power consuming. The use of air as the refrigerant in aircraft prevents the dangers of fire of from the flammable refrigerants. Differences between an absorption refrigeration system and a VCRC [4] Absorption RS VCRC  The refrigerant is absorbed by an absorbent material to form a liquid solution.  Vapour is compressed between the evaporator and the condenser.  Heat is added to the process to retrieve the refrigerant vapour from the liquid solution.  Process is driven by work  Process is driven by heat 10. Current Applications of Refrigeration [6] Probably the most widely used current applications of refrigeration are for the refrigeration of foodstuffs in homes, restaurants and large storage warehouses. The use of refrigerators in kitchens for the storage of fruits and vegetables has permitted the addition of fresh salads to the modern diet year round, and to store fish and meats safely for long periods. In commerce and manufacturing, there are many uses for refrigeration. Refrigeration is used to liquefy gases like oxygen, nitrogen, propane and methane for example. In compressed air purification, it is used to condense water vapor from compressed air to reduce its moisture content. In oil refineries, chemical plants, and petrochemical plants, refrigeration is used to maintain certain processes at their required low temperatures (for example, in the alkylation of butenes and butane to produce a high octane gasoline component). Metal workers use refrigeration to temper steel and cutlery. In transporting temperature-sensitive foodstuffs Paper ID: 020132041 1219
  • 9. International Journal of Science and Research (IJSR) ISSN (Online): 2319-7064 Impact Factor (2012): 3.358 Volume 3 Issue 5, May 2014 www.ijsr.net Licensed Under Creative Commons Attribution CC BY and other materials by trucks, trains, airplanes and sea-going vessels, refrigeration is a necessity. Dairy products are constantly in need of refrigeration, and it was only discovered in the past few decades that eggs needed to be refrigerated during shipment rather than waiting to be refrigerated after arrival at the grocery store. Meats, poultry and fish all must be kept in climate- controlled environments before being sold. Refrigeration also helps keep fruits and vegetables edible longer. One of the most influential uses of refrigeration was in the development of the sushi/sashimi industry in Japan. Prior to the discovery of refrigeration, many sushi connoisseurs suffered great morbidity and mortality from diseases such as hepatitis A However the dangers of unrefrigerated sashimi was not brought to light for decades due to the lack of research and healthcare distribution across rural Japan. Around mid-century, the Zojirushi Corporation based in Kyoto made breakthroughs in refrigerator designs making refrigerators cheaper and more accessible for restaurant proprietors and the general public. References [1] Ameen Ahmadul Refrigeration and Air Conditioning Prentice Hall of India Pvt. Ltd. Publishing company, New Delhi [2] Arora, C.P. Refrigeration and Air Conditioning. Second edition. Tata McGraw-Hill [3] Publishing Company Ltd. 2000. [4] Arora, Ramesh Chandra. "Mechanical vapour compression refrigeration". Refrigeration and Air Conditioning. New Delhi, India: PHI Learning [5] Energy Efficiency Guide for Industry in Asia – www.energyefficiencyasia.org Copyright © United Nations Environment Programme (year 2006), Refrigeration & Air conditioning system [6] www.honeywell.com/refrigeration, An introduction to Refrigeration. [7] http://en.wikipedia.org/wiki/Refrigeration [8] http://educypedia.karadimov.info/library/c6.pdf Paper ID: 020132041 1220