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Air Quality Management
Thought of the Day




     Air Quality Management   2
Global Leader in Energy Use




          Air Quality Management   3
Air Quality Management   4
Emissions & Effects




      Air Quality Management   5
Emission Events Included in a Fuel
        Cycle Assessment




             Air Quality Management   6
Total Vehicle Well-to-Wheel Energy Cycle




                Air Quality Management   7
National Average Emission Categories for
 CO, SOx, NOx, VOC & PM-US EPA 2003




                Air Quality Management     8
Electricity generation by fuel in billion
      kilowatt hours, 1949-2020




                Air Quality Management      9
US Electricity Generation by Source




              Air Quality Management   10
Air Quality Management   11
High Cancer Risk Counties for Urban
        Air Toxics in 1996




             Air Quality Management   12
Potential Violations of PM2.5 and O3
        Source: US-EPA 2002




              Air Quality Management   13
World Vehicles per Capita
• According to the 2007-
  2008 World Motor
  Vehicle Market Report,
  the     world's   motor
  vehicle       population
  reached 789.8 million
  units in 2005




                      Air Quality Management   14
Trends in Nationwide SO2 and NO2
            Emissions




            Air Quality Management   15
Personal Exposure Meter to measure exposure
    to PM and Gases during daily activities

 Exposure: Whether and
 how a human or other
 organism comes into
 contact         with        a
 chemical,      usually     by
 eating      or       drinking
 it, inhaling it, or touching
 it and having it penetrate
 the skin

                         Air Quality Management   16
Four Chamber Greenhouse-based exposure system
     to study effects of elevated CO2 on plants




                  Air Quality Management    17
Air Quality Management   18
Free Air CO2 Enrichment (FACE)




           Air Quality Management   19
Emission-Inventory
Development, Evaluation and
       Improvement




          Air Quality Management   20
SO2 emissions from electric utilities in
   United States from 1980-2001




                Air Quality Management   21
Regional SO2 Emissions from Electric
              Utilities




              Air Quality Management   22
Location of Surface O3 Monitoring Sites




                Air Quality Management   23
Photochemical Assessment Monitoring
         Stations (PAMS)
Site #1 - Upwind and background
characterization site.
Site #2 - Maximum ozone precursor
emissions impact site.
Site #3 - Maximum ozone concentration
site. These sites are intended to monitor
maximum         ozone       concentrations
occurring downwind from the area of
maximum precursor emissions.
Site #4 - Extreme downwind monitoring
site. These sites are established to
characterize the extreme downwind
transported ozone and its precursor
concentrations exiting the area and will
identify those areas which are potentially
contributing to overwhelming ozone
transport into other areas.        Air Quality Management   24
Air Quality Models
•   Air quality models use mathematical
    and numerical techniques to simulate
    the physical and chemical processes
    that affect air pollutants as they
    disperse     and    react   in    the
    atmosphere.
•   inputs of meteorological data
•   source information
•   emission rates
•   stack height
•   models are designed to characterize
    primary pollutants
•   secondary pollutants that are formed
    as a result of complex chemical
    reactions within the atmosphere

                                  Air Quality Management   25
Surface Data
•   Surface data are meteorological data
    that are measured at the earth’s
    surface (technically, somewhere
    between the ground level and 10m).
•   data contains physical parameters
•   Temperature
•   dew point
•   wind direction
•   wind speed
•   cloud cover
•   cloud layer(s)
•   Visibility
•   current weather
•   precipitation amount
•   Surface data are reported by the
    National Weather Service for each
    hour

                                 Air Quality Management   26
World Car Sales by Manufacturers
           1998-2005




            Air Quality Management   27
Well to Wheel Emissions




        Air Quality Management   28
Fuel Cycle Emissions
Full fuel cycle emissions:
1. Biodiesel
2. Conventional (Petroleum) Fuels (Gasoline and Diesel)
3. Electricity
4. Ethanol (E-10 and E-85)
5. Hydrogen
6. Natural Gas (compressed natural gas [CNG], and liquefied
natural gas [LNG])
7. Propane
8. Renewable Diesel
9. Synthetic Fuels (Dimethyl Ether and Methanol)
10. XTLs (Biomass-to-Liquid, Coal-to-Liquid, Gas-to-Liquid)
                         Air Quality Management               29
Air Quality Management   30
Fuel Pathways




   Air Quality Management   31
Study in Taiwan




    Air Quality Management   32
Global Warming




    Air Quality Management   33
Health Effects Institute
                                      Asian Risk Estimates Similar to West
                            Percent Increase in Mortality per 10 µg increase in PM10



                            0.8
                                                                        0.62
         Percent Increase




                                                0.46
                            0.6
                                                                                        0.49
                            0.4

                             0.2

                                  0

                                      US (90 Cities)
                                                       Europe (21 Cities)
                                                                                Asia (4 Cities)


Health Effects Institute, 2008                         Air Quality Management                     34
Implement a Project-II
                          Due Date: Friday, 17th May, 2013

A PENNY SAVED IS A PENNY EARNED…
… have to save money or earn money…
… up to Rs 10,000 within one month…

•    Solid Waste Management
•    Air Quality Management
•    Energy Audit
•    Material Recovery from Solid Waste
•    Biofuels
•    Energy Conservation
•    Selling Drinking Water
Or
•    Any smart idea related to Public Health
     Engineering

Note: Provide complete data related to the activities
in terms of Rupees
                                    Air Quality Management   35
Air Quality Management
            in
        Pakistan
The World Bank Assessment Report (Pakistan)
• Mean annual cost of Environmental
  and Natural Resource Damage is
                                                Environmental and Natural
  about Rs. 365 billion or 6% of GDP
                                                    Resource Damage
• Air pollution contributes 1/3 to the                (Rs. 365 billion)       Indoor
  total damage                                                                  air
                                                                             pollution
• Rs. 67 billion for Indoor air                                                19%
  pollution
                                                 Others
• Rs. 65 billion for Urban air                   (Water,
  pollution                                       Waste
                                                  water,
• Annually urban air pollution causes             Solid
                                                 waste )
   – 22,000 deaths among adults                                             Urban air
                                                   63%                      pollution
   – 700 deaths among young                                                   18%
      children
                               Air Quality Management                          37
Annual Cost of Urban Air Pollution
   Health Impacts (Billion Rs)




             Air Quality Management   38
National Environmental Quality Standards NEQS for Ambient Air
                                                           Concentration in Ambient Air
          Pollutants            Time-weighted average       Effective from 1st January,
                                                                        2009
                                   Annual Average                    80 µg/m3
        Sulfur Dioxide
                                        24 hour                     120 µg/m3
                                   Annual Average                    40 µg/m3
   Oxides of Nitrogen as NO
                                        24 hour                      40 µg/m3
                                   Annual Average                    40 µg/m3
   Oxides of Nitrogen as NO2
                                        24 hour                      80 µg/m3
           Ozone                         1 hour                     180 µg/m3
 Suspended Particulate Matter      Annual Average                   400 µg/m3
            SPM                         24 hour                     550 µg/m3
                                   Annual Average                   200 µg/m3
   Particulate Matter PM10
                                        24 hour                     250 µg/m3
                                   Annual Average                    25 µg/m3
   Particulate Matter PM2.5             24 hour                      40 µg/m3
                                         1 hour                      25 µg/m3
                                   Annual Average                   1.5 µg/m3
          Lead (Pb)
                                        24 hour                     2.0 µg/m3
                                         8 hour                      5 mg/m3
    Carbon Monoxide (CO)          Air Quality Management                                39
                                         1 hour                     10 mg/m3
Number of Vehicles in Pakistan




           Air Quality Management   40
Power Shortfall in Pakistan
Overall power shortfall current and projected in
Pakistan as:
• 6577 MW in 2010
• 18320 MW in 2015
• 36462 MW by 2020



                               Primary Energy Supplies by source in Pakistan

                   Air Quality Management                              41
Ambient Air Quality Daily Mean Value




              Air Quality Management   42
Summary of Equipment




       Air Quality Management   43
Mobile Automatic Air Quality
    Monitoring Station




          Air Quality Management   44
SOx & NOx




 Air Quality Management   45
CO, CH4 & O3




  Air Quality Management   46
Low Volume Air Sampler




       Air Quality Management   47
Particulate Matter Sampling
                               Filter Preparation

                            Drying and Conditioning
      Numbering                                              Weighing
                            (200C, 50%R.H), 24 hrs



                                   Sampling

Filter setting to sampler    Sampling (12+12 hrs)     Collecting sampled filter




                            Sample Measurement
Drying and Conditioning                               Calculate concentration/
                                   Weighing              Preserve sample
(200C, 50%R.H), 48 hrs
Calculation of Suspended Particulate Matter

The concentration of Total Suspended Particulate was calculated using the
following formula (40 CFR Appendix B, Part 50, USEPA)
                                             6
                       Wf      Wi       10             (µg/m3)
          TSP =
                               V
   where,
       TSP is mass concentration of total suspended particulate matter (µg/m3)
       Wi is initial weight of clean filter (g)
       Wf is final weight of exposed filter (g)
       V is the sampled air volume (m3)
       106 is for conversion of g to µg
High Volume Air Sampler
    Measuring PM10




        Air Quality Management   50
Weighing after 24 Hours




        Air Quality Management   51
Sample Preparation For AAS
Sample Cutting

  Sample ½ piece

     Beaker (100 mL)
     HCl (1+1) 30mL, H2O2 (30%) 5mL


         Heat on Hot Plate                     1200C, 1Hr



              Filtration     Filter Paper/Funnel
Sample Preparation For AAS

Filtered Solution

   Conc. on Hot Plate Add HNO (2+98)
                                  3
             soon before dry-up


      Constant Vol (25mL) HNO (2+98)  3




         Sample Transfer Polyethylene Bottle

             AAS Analysis
Glassware




 Air Quality Management   54
Cutting Exposed Filter Paper




          Air Quality Management   55
Acid Extraction




    Air Quality Management   56
Atomic Absorption Spectroscopy (AAS)




              Air Quality Management   57
Proton Induced X-ray Emissions (PIXE)




              Air Quality Management   58
Stack Gas Emission Monitoring




           Air Quality Management   59
Stack Gas Emission Monitoring




           Air Quality Management   60
Stack Gas Emission Monitoring




           Air Quality Management   61
Transboundary Effects
      Fires in Northwest India (MODIS)
Moderate Resolution Imaging Spectroradiometer




                  Air Quality Management   62
US-AID Project
Energy Auditing Serena




       Air Quality Management   63
UN-Habitat Project
  Green Roofs




     Air Quality Management   64
UN-Habitat Project
  Green Roofs




     Air Quality Management   65
Crescent Mills, Faisalabad




         Air Quality Management   66
CNG Driven Vehicles in Pakistan




                            Traffic Police Officials penalizing smoke
                            emitting vehicle operators

            Air Quality Management                                 67
Thank You




 Air Quality Management   68

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Air Quality Management

  • 2. Thought of the Day Air Quality Management 2
  • 3. Global Leader in Energy Use Air Quality Management 3
  • 5. Emissions & Effects Air Quality Management 5
  • 6. Emission Events Included in a Fuel Cycle Assessment Air Quality Management 6
  • 7. Total Vehicle Well-to-Wheel Energy Cycle Air Quality Management 7
  • 8. National Average Emission Categories for CO, SOx, NOx, VOC & PM-US EPA 2003 Air Quality Management 8
  • 9. Electricity generation by fuel in billion kilowatt hours, 1949-2020 Air Quality Management 9
  • 10. US Electricity Generation by Source Air Quality Management 10
  • 12. High Cancer Risk Counties for Urban Air Toxics in 1996 Air Quality Management 12
  • 13. Potential Violations of PM2.5 and O3 Source: US-EPA 2002 Air Quality Management 13
  • 14. World Vehicles per Capita • According to the 2007- 2008 World Motor Vehicle Market Report, the world's motor vehicle population reached 789.8 million units in 2005 Air Quality Management 14
  • 15. Trends in Nationwide SO2 and NO2 Emissions Air Quality Management 15
  • 16. Personal Exposure Meter to measure exposure to PM and Gases during daily activities Exposure: Whether and how a human or other organism comes into contact with a chemical, usually by eating or drinking it, inhaling it, or touching it and having it penetrate the skin Air Quality Management 16
  • 17. Four Chamber Greenhouse-based exposure system to study effects of elevated CO2 on plants Air Quality Management 17
  • 19. Free Air CO2 Enrichment (FACE) Air Quality Management 19
  • 20. Emission-Inventory Development, Evaluation and Improvement Air Quality Management 20
  • 21. SO2 emissions from electric utilities in United States from 1980-2001 Air Quality Management 21
  • 22. Regional SO2 Emissions from Electric Utilities Air Quality Management 22
  • 23. Location of Surface O3 Monitoring Sites Air Quality Management 23
  • 24. Photochemical Assessment Monitoring Stations (PAMS) Site #1 - Upwind and background characterization site. Site #2 - Maximum ozone precursor emissions impact site. Site #3 - Maximum ozone concentration site. These sites are intended to monitor maximum ozone concentrations occurring downwind from the area of maximum precursor emissions. Site #4 - Extreme downwind monitoring site. These sites are established to characterize the extreme downwind transported ozone and its precursor concentrations exiting the area and will identify those areas which are potentially contributing to overwhelming ozone transport into other areas. Air Quality Management 24
  • 25. Air Quality Models • Air quality models use mathematical and numerical techniques to simulate the physical and chemical processes that affect air pollutants as they disperse and react in the atmosphere. • inputs of meteorological data • source information • emission rates • stack height • models are designed to characterize primary pollutants • secondary pollutants that are formed as a result of complex chemical reactions within the atmosphere Air Quality Management 25
  • 26. Surface Data • Surface data are meteorological data that are measured at the earth’s surface (technically, somewhere between the ground level and 10m). • data contains physical parameters • Temperature • dew point • wind direction • wind speed • cloud cover • cloud layer(s) • Visibility • current weather • precipitation amount • Surface data are reported by the National Weather Service for each hour Air Quality Management 26
  • 27. World Car Sales by Manufacturers 1998-2005 Air Quality Management 27
  • 28. Well to Wheel Emissions Air Quality Management 28
  • 29. Fuel Cycle Emissions Full fuel cycle emissions: 1. Biodiesel 2. Conventional (Petroleum) Fuels (Gasoline and Diesel) 3. Electricity 4. Ethanol (E-10 and E-85) 5. Hydrogen 6. Natural Gas (compressed natural gas [CNG], and liquefied natural gas [LNG]) 7. Propane 8. Renewable Diesel 9. Synthetic Fuels (Dimethyl Ether and Methanol) 10. XTLs (Biomass-to-Liquid, Coal-to-Liquid, Gas-to-Liquid) Air Quality Management 29
  • 31. Fuel Pathways Air Quality Management 31
  • 32. Study in Taiwan Air Quality Management 32
  • 33. Global Warming Air Quality Management 33
  • 34. Health Effects Institute Asian Risk Estimates Similar to West Percent Increase in Mortality per 10 µg increase in PM10 0.8 0.62 Percent Increase 0.46 0.6 0.49 0.4 0.2 0 US (90 Cities) Europe (21 Cities) Asia (4 Cities) Health Effects Institute, 2008 Air Quality Management 34
  • 35. Implement a Project-II Due Date: Friday, 17th May, 2013 A PENNY SAVED IS A PENNY EARNED… … have to save money or earn money… … up to Rs 10,000 within one month… • Solid Waste Management • Air Quality Management • Energy Audit • Material Recovery from Solid Waste • Biofuels • Energy Conservation • Selling Drinking Water Or • Any smart idea related to Public Health Engineering Note: Provide complete data related to the activities in terms of Rupees Air Quality Management 35
  • 36. Air Quality Management in Pakistan
  • 37. The World Bank Assessment Report (Pakistan) • Mean annual cost of Environmental and Natural Resource Damage is Environmental and Natural about Rs. 365 billion or 6% of GDP Resource Damage • Air pollution contributes 1/3 to the (Rs. 365 billion) Indoor total damage air pollution • Rs. 67 billion for Indoor air 19% pollution Others • Rs. 65 billion for Urban air (Water, pollution Waste water, • Annually urban air pollution causes Solid waste ) – 22,000 deaths among adults Urban air 63% pollution – 700 deaths among young 18% children Air Quality Management 37
  • 38. Annual Cost of Urban Air Pollution Health Impacts (Billion Rs) Air Quality Management 38
  • 39. National Environmental Quality Standards NEQS for Ambient Air Concentration in Ambient Air Pollutants Time-weighted average Effective from 1st January, 2009 Annual Average 80 µg/m3 Sulfur Dioxide 24 hour 120 µg/m3 Annual Average 40 µg/m3 Oxides of Nitrogen as NO 24 hour 40 µg/m3 Annual Average 40 µg/m3 Oxides of Nitrogen as NO2 24 hour 80 µg/m3 Ozone 1 hour 180 µg/m3 Suspended Particulate Matter Annual Average 400 µg/m3 SPM 24 hour 550 µg/m3 Annual Average 200 µg/m3 Particulate Matter PM10 24 hour 250 µg/m3 Annual Average 25 µg/m3 Particulate Matter PM2.5 24 hour 40 µg/m3 1 hour 25 µg/m3 Annual Average 1.5 µg/m3 Lead (Pb) 24 hour 2.0 µg/m3 8 hour 5 mg/m3 Carbon Monoxide (CO) Air Quality Management 39 1 hour 10 mg/m3
  • 40. Number of Vehicles in Pakistan Air Quality Management 40
  • 41. Power Shortfall in Pakistan Overall power shortfall current and projected in Pakistan as: • 6577 MW in 2010 • 18320 MW in 2015 • 36462 MW by 2020 Primary Energy Supplies by source in Pakistan Air Quality Management 41
  • 42. Ambient Air Quality Daily Mean Value Air Quality Management 42
  • 43. Summary of Equipment Air Quality Management 43
  • 44. Mobile Automatic Air Quality Monitoring Station Air Quality Management 44
  • 45. SOx & NOx Air Quality Management 45
  • 46. CO, CH4 & O3 Air Quality Management 46
  • 47. Low Volume Air Sampler Air Quality Management 47
  • 48. Particulate Matter Sampling Filter Preparation Drying and Conditioning Numbering Weighing (200C, 50%R.H), 24 hrs Sampling Filter setting to sampler Sampling (12+12 hrs) Collecting sampled filter Sample Measurement Drying and Conditioning Calculate concentration/ Weighing Preserve sample (200C, 50%R.H), 48 hrs
  • 49. Calculation of Suspended Particulate Matter The concentration of Total Suspended Particulate was calculated using the following formula (40 CFR Appendix B, Part 50, USEPA) 6 Wf Wi 10 (µg/m3) TSP = V where, TSP is mass concentration of total suspended particulate matter (µg/m3) Wi is initial weight of clean filter (g) Wf is final weight of exposed filter (g) V is the sampled air volume (m3) 106 is for conversion of g to µg
  • 50. High Volume Air Sampler Measuring PM10 Air Quality Management 50
  • 51. Weighing after 24 Hours Air Quality Management 51
  • 52. Sample Preparation For AAS Sample Cutting Sample ½ piece Beaker (100 mL) HCl (1+1) 30mL, H2O2 (30%) 5mL Heat on Hot Plate 1200C, 1Hr Filtration Filter Paper/Funnel
  • 53. Sample Preparation For AAS Filtered Solution Conc. on Hot Plate Add HNO (2+98) 3 soon before dry-up Constant Vol (25mL) HNO (2+98) 3 Sample Transfer Polyethylene Bottle AAS Analysis
  • 54. Glassware Air Quality Management 54
  • 55. Cutting Exposed Filter Paper Air Quality Management 55
  • 56. Acid Extraction Air Quality Management 56
  • 57. Atomic Absorption Spectroscopy (AAS) Air Quality Management 57
  • 58. Proton Induced X-ray Emissions (PIXE) Air Quality Management 58
  • 59. Stack Gas Emission Monitoring Air Quality Management 59
  • 60. Stack Gas Emission Monitoring Air Quality Management 60
  • 61. Stack Gas Emission Monitoring Air Quality Management 61
  • 62. Transboundary Effects Fires in Northwest India (MODIS) Moderate Resolution Imaging Spectroradiometer Air Quality Management 62
  • 63. US-AID Project Energy Auditing Serena Air Quality Management 63
  • 64. UN-Habitat Project Green Roofs Air Quality Management 64
  • 65. UN-Habitat Project Green Roofs Air Quality Management 65
  • 66. Crescent Mills, Faisalabad Air Quality Management 66
  • 67. CNG Driven Vehicles in Pakistan Traffic Police Officials penalizing smoke emitting vehicle operators Air Quality Management 67
  • 68. Thank You Air Quality Management 68