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DESIGNING WITH
POLYMERS:
TOOLS AND PROCESS
BY KARTIK SRINIVAS
ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM
Non-linear materials like polymers present a
challenge to successfully obtain the required input
data for FEA. In this paper we review the techniques
and technology available to obtain the relevant data
using existing methodologies for elastomeric
materials and present information on how this can
be improved for reliable simulations for rapid
prototyping.
APPLICATIONOF CAE TOOLS:
Predicting Stiffness: Establishing the correct
stiffness for a component is an important
specification requirement for the automotive and
aerospace industry. It is preferred to “fine-tune” the
stiffness of a part in all the three axes with the
selected material before making the prototype.
Deformed Shapes: FEA and CFD can provide a
deformed shape of the part with actual service
conditions imposed on the part.
Durability Analysis: Based on the deformation and
stress-strain distribution, relative durability analysis
can be performed.
Life Prediction: With stress-strain information of a
part from thermal aging, fatigue aging and unaged
test data, one can develop an empirical estimate of
service life of the part.
Identifying the “Hot Spots” of the Part:
Computational mechanics tools provide stress
distribution of the part at various points. This
information is helpful for identifying the stress “hot
spots” in a particular design. This stress “hot spot”
may be crack initiation point.
Mold Design: CFD and FEA can be used to design
extruders, mixers, and other production equipment.
Only low strain FEA is needed to optimize the mold
design under the influence of a clamping force and
internal pressures. By establishing the stress
distribution throughout the mold, optimum design
can be calculated for various zones in the mold.
Finite element analysis (FEA) is a major CAE
tool used for virtual product development in
polymer engineering. The quality of the CAE
carried out is directly related to the input
material property and simulation
technology.
PAGE 1 WHITE PAPERENGINEERING WITH
POLYMERS
ENGINEERING WITH
POLYMERS
WHITE PAPERPAGE 2
ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM
CureSimulation: CFD and FEA can be used to
determine the temperatures in a molding process as
a function to time. This transient thermal diffusion
analysis needs input data such as thermal
conductivity and thermal capacitance of the rubber
as a function of temperature. Repeated FEA
iterations can establish the optimum cure as a
function of mold temperature and time.
InjectionMolding: Similar to cure simulation,
injection molding simulation by CFD and FEA is a
transient process. The main purpose in examining
injection molding is the characterization of apparent
viscosity of the material with respect to shear rate
and temperature. This type of analyses can check
the positions of joint lines and accordingly adjust the
position of the gates. CFD and FEA will allow the
investigator to study the rates, temperatures, and
compound formulations to avoid scorch and
optimize the time for the injection cycle.
The application of computational mechanics
analysis techniques to elastomers presents unique
challenges in modeling the following characteristics:
1. The load-deflection behavior of an elastomer is
markedly non-linear.
2. The recoverable strains can be as high 400 %
making it imperative to use the large deflection
theory.
3. The stress-strain characteristics are highly
dependent on temperature and rate effects.
4. Elastomers are nearly incompressible.
5. Viscoelastic effects are significant.
FEA SUPPORT TESTING:
Most commercial FEA software packages use a
curve-fitting procedure to generate the
material constants for the selected material model.
The input to the curve-fitting procedure is the stress-
strain or stress-stretch data from the following
physical tests:
1. Uniaxial tension test
2. Uniaxial compression test
3. Planar shear test
4. Equibiaxial tension test
5. Volumetric compression test
A minimum of one test data is necessary, however
the greater the amount of test data, the
better the quality of the material constants and the
resulting simulation.
Figure 1: Uniaxial Tension Test
Testing should be carried out for the deformation
modes the elastomer part may experience during its
service life. The testing is carried out under a quasi-
static process by carefully selecting the test
parameters. The material can also be aged in a liquid
or at elevated temperatures before testing and thus
service conditions can be incorporated to generate
the material constants and subsequent FE analysis.
For applications involving very high strain rates a
Hopkinson’s bar can be used to test the materials
and obtain the relevant stress-strain data.
PAGE 3 WHITE PAPERENGINEERING WITH
POLYMERS
A material model describing the elastomer as
isotropic and hyperelastic is generally used and a
strain energy density function (W) is used to describe
the material behavior. The strain energy density
functions are mainly derived using statistical
mechanics, and continuum mechanics involving
invariant and stretch based approaches.
Statistical Mechanics Approach:
The statistical mechanics approach is based on the
assumption that the elastomeric material is made up
of randomly oriented molecular chains.
Figure2: MaterialTestingandFEAExamples
InvariantBasedContinuumMechanicsApproach:
The Invariant based continuum mechanics approach
is based on the assumption that for a isotropic,
hyperelastic material the strain energy density
function can be defined in terms of the Invariants.
StretchBasedContinuumMechanicsApproach:
The Stretch based continuum mechanics approach
is based on the assumption that the strain energy
potential can be expressed as a function of the
principal stretches rather than the invariants.
The choice of the material model depends heavily on
the material and the stretch ratios (strains) to which
it will be subjected during its service life. As a rule-of-
thumb for small strains of approximately 100 %,
simple models such as Mooney-Rivlin are sufficient.
For higher strains a higher order material model as
the Ogden model may be required to successfully
simulate the ”upturn” or strengthening that can
occur in some materials at higher strains.
THEORY OF VISCOMETRY:
The rheological analysis of samples is a fundamental
part of developing rubber products. Whilst they still
have their place, the use melt flow indexers’ is being
found to often give insufficient results. These simple
devices do not match the versatility of modern
rheometers, nor can they ensure that a new product
will be suitable for use. A rheometer can actually
measure sample properties at extremely low shear
rates indicating the molecular weight, or the high
shear rates seen in mixing, extrusion and molding.
The rheometer can measure the viscosity of product
at pre-programmed temperatures. This can also be
used to evaluate the processability and degradation
of materials at these temperatures.
Viscometry is probably the most common
rheological technique and essentially defines the
resistance of a fluid to flow. The equation for the
coefficient of viscosity is:
co-eff of viscosity = shear stress / shear rate
The flow properties can be classified into two
groups :
- Newtonian
- Non - Newtonian
Non-Newtonian materials such as non-drip paints
have changing viscosities with different shear rates
and should be characterized using controlled shear
stress or controlled shear rate rheometers.
There are many types of non-Newtonian behavior
but in broad terms they can be classified into one of
the three following groups:
- Shear Thinning or Pseudoplastic
- Shear Thickening or Dilatant
- Plastic Shear Thinning (Yield Value)
ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM
Summary: A brief review of material
characterization testing methods for FEA and CFD
simulation has been shown, limitations of the
associated theory and instruments used in material
characterization testing have been discussed.
Studies have shown that •CAE systems are not stand
alone processes but require additional support
procedures. Material characterization procedures for
FEA and CFD have been presented and pitfalls
reviewed. Input material properties are of prime
importance for reliable CAE simulation. With better
understanding of the testing procedure and
associated theory, the quality of the simulation can
be improved.
References:
1. ABAQUS Inc., ABAQUS: Theory and Reference
Manuals, ABAQUS Inc., RI, 02
2. Attard, M.M., Finite Strain: Isotropic Hyperelasticity,
International Journal of Solids and Structures, 2003
3. Bathe, K. J., Finite Element Procedures Prentice-
Hall, NJ, 96
4. Bergstrom, J. S., and Boyce, M. C., Mechanical
Behavior of Particle Filled Elastomers,Rubber
Chemistry and Technology, Vol. 72, 2000
5. Bhowmick, A. K., Hall, M. M., and Benarey, H. A.,
Rubber Products Manufacturing Technology, Marcel
Dekker, NY, 1994
6. Holden, G., Understanding Thermoplastic
Elastomers, Hanser Gardner Publications, 1999
7. CD-Adapco, Star-CD Users Manual, CD-Adapco,
2004
8. Fluent, Fluent CFD users Manual, Fluent USA, 2004
9. Srinivas, K., Material And Rheological
Characterization For Rapid Prototyping Of
Elastomers Components, American Chemical
Society, Rubber Division, 170th Technical Meeting,
Cincinnati, October 2006
Similar to material models used in FEA there are
many mathematical models to describe the
characteristic flow of a material including that
described by the Bingham model;
Shear stress = Yield stress + K x Shear rate
where, K is a constant.
Flowchart in Figure 3 shows the typical processes
involved in a CFD simulation to model the extrusion
process. The two major types of testing carried out is
for testing the material viscosity vs. the shear rate
and for material viscosity vs. temperature. Just as
curve fitting of stress-strain data as a material model
the viscosity vs. shear rate data is fitted to a material
model and input into the software code.
Figure 3: FlowChart for Extrusion Simulation using
CFD
The use of a particular type of rheometer is dictated
by the type of test data needed for the simulation
and different associated parameters. To model
simulations at high extrusion speeds and
temperature testing data is needed in the range of
20,000-30,000 sec-1. Use of a capillary rheometer
becomes necessary for such type of material
characterization testing.
ENGINEERING WITH
POLYMERS
WHITE PAPERPAGE 4
ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM

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Design with polymers tools and process - White Paper

  • 1. DESIGNING WITH POLYMERS: TOOLS AND PROCESS BY KARTIK SRINIVAS ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM Non-linear materials like polymers present a challenge to successfully obtain the required input data for FEA. In this paper we review the techniques and technology available to obtain the relevant data using existing methodologies for elastomeric materials and present information on how this can be improved for reliable simulations for rapid prototyping. APPLICATIONOF CAE TOOLS: Predicting Stiffness: Establishing the correct stiffness for a component is an important specification requirement for the automotive and aerospace industry. It is preferred to “fine-tune” the stiffness of a part in all the three axes with the selected material before making the prototype. Deformed Shapes: FEA and CFD can provide a deformed shape of the part with actual service conditions imposed on the part. Durability Analysis: Based on the deformation and stress-strain distribution, relative durability analysis can be performed. Life Prediction: With stress-strain information of a part from thermal aging, fatigue aging and unaged test data, one can develop an empirical estimate of service life of the part. Identifying the “Hot Spots” of the Part: Computational mechanics tools provide stress distribution of the part at various points. This information is helpful for identifying the stress “hot spots” in a particular design. This stress “hot spot” may be crack initiation point. Mold Design: CFD and FEA can be used to design extruders, mixers, and other production equipment. Only low strain FEA is needed to optimize the mold design under the influence of a clamping force and internal pressures. By establishing the stress distribution throughout the mold, optimum design can be calculated for various zones in the mold. Finite element analysis (FEA) is a major CAE tool used for virtual product development in polymer engineering. The quality of the CAE carried out is directly related to the input material property and simulation technology. PAGE 1 WHITE PAPERENGINEERING WITH POLYMERS
  • 2. ENGINEERING WITH POLYMERS WHITE PAPERPAGE 2 ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM CureSimulation: CFD and FEA can be used to determine the temperatures in a molding process as a function to time. This transient thermal diffusion analysis needs input data such as thermal conductivity and thermal capacitance of the rubber as a function of temperature. Repeated FEA iterations can establish the optimum cure as a function of mold temperature and time. InjectionMolding: Similar to cure simulation, injection molding simulation by CFD and FEA is a transient process. The main purpose in examining injection molding is the characterization of apparent viscosity of the material with respect to shear rate and temperature. This type of analyses can check the positions of joint lines and accordingly adjust the position of the gates. CFD and FEA will allow the investigator to study the rates, temperatures, and compound formulations to avoid scorch and optimize the time for the injection cycle. The application of computational mechanics analysis techniques to elastomers presents unique challenges in modeling the following characteristics: 1. The load-deflection behavior of an elastomer is markedly non-linear. 2. The recoverable strains can be as high 400 % making it imperative to use the large deflection theory. 3. The stress-strain characteristics are highly dependent on temperature and rate effects. 4. Elastomers are nearly incompressible. 5. Viscoelastic effects are significant. FEA SUPPORT TESTING: Most commercial FEA software packages use a curve-fitting procedure to generate the material constants for the selected material model. The input to the curve-fitting procedure is the stress- strain or stress-stretch data from the following physical tests: 1. Uniaxial tension test 2. Uniaxial compression test 3. Planar shear test 4. Equibiaxial tension test 5. Volumetric compression test A minimum of one test data is necessary, however the greater the amount of test data, the better the quality of the material constants and the resulting simulation. Figure 1: Uniaxial Tension Test Testing should be carried out for the deformation modes the elastomer part may experience during its service life. The testing is carried out under a quasi- static process by carefully selecting the test parameters. The material can also be aged in a liquid or at elevated temperatures before testing and thus service conditions can be incorporated to generate the material constants and subsequent FE analysis. For applications involving very high strain rates a Hopkinson’s bar can be used to test the materials and obtain the relevant stress-strain data.
  • 3. PAGE 3 WHITE PAPERENGINEERING WITH POLYMERS A material model describing the elastomer as isotropic and hyperelastic is generally used and a strain energy density function (W) is used to describe the material behavior. The strain energy density functions are mainly derived using statistical mechanics, and continuum mechanics involving invariant and stretch based approaches. Statistical Mechanics Approach: The statistical mechanics approach is based on the assumption that the elastomeric material is made up of randomly oriented molecular chains. Figure2: MaterialTestingandFEAExamples InvariantBasedContinuumMechanicsApproach: The Invariant based continuum mechanics approach is based on the assumption that for a isotropic, hyperelastic material the strain energy density function can be defined in terms of the Invariants. StretchBasedContinuumMechanicsApproach: The Stretch based continuum mechanics approach is based on the assumption that the strain energy potential can be expressed as a function of the principal stretches rather than the invariants. The choice of the material model depends heavily on the material and the stretch ratios (strains) to which it will be subjected during its service life. As a rule-of- thumb for small strains of approximately 100 %, simple models such as Mooney-Rivlin are sufficient. For higher strains a higher order material model as the Ogden model may be required to successfully simulate the ”upturn” or strengthening that can occur in some materials at higher strains. THEORY OF VISCOMETRY: The rheological analysis of samples is a fundamental part of developing rubber products. Whilst they still have their place, the use melt flow indexers’ is being found to often give insufficient results. These simple devices do not match the versatility of modern rheometers, nor can they ensure that a new product will be suitable for use. A rheometer can actually measure sample properties at extremely low shear rates indicating the molecular weight, or the high shear rates seen in mixing, extrusion and molding. The rheometer can measure the viscosity of product at pre-programmed temperatures. This can also be used to evaluate the processability and degradation of materials at these temperatures. Viscometry is probably the most common rheological technique and essentially defines the resistance of a fluid to flow. The equation for the coefficient of viscosity is: co-eff of viscosity = shear stress / shear rate The flow properties can be classified into two groups : - Newtonian - Non - Newtonian Non-Newtonian materials such as non-drip paints have changing viscosities with different shear rates and should be characterized using controlled shear stress or controlled shear rate rheometers. There are many types of non-Newtonian behavior but in broad terms they can be classified into one of the three following groups: - Shear Thinning or Pseudoplastic - Shear Thickening or Dilatant - Plastic Shear Thinning (Yield Value) ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM
  • 4. Summary: A brief review of material characterization testing methods for FEA and CFD simulation has been shown, limitations of the associated theory and instruments used in material characterization testing have been discussed. Studies have shown that •CAE systems are not stand alone processes but require additional support procedures. Material characterization procedures for FEA and CFD have been presented and pitfalls reviewed. Input material properties are of prime importance for reliable CAE simulation. With better understanding of the testing procedure and associated theory, the quality of the simulation can be improved. References: 1. ABAQUS Inc., ABAQUS: Theory and Reference Manuals, ABAQUS Inc., RI, 02 2. Attard, M.M., Finite Strain: Isotropic Hyperelasticity, International Journal of Solids and Structures, 2003 3. Bathe, K. J., Finite Element Procedures Prentice- Hall, NJ, 96 4. Bergstrom, J. S., and Boyce, M. C., Mechanical Behavior of Particle Filled Elastomers,Rubber Chemistry and Technology, Vol. 72, 2000 5. Bhowmick, A. K., Hall, M. M., and Benarey, H. A., Rubber Products Manufacturing Technology, Marcel Dekker, NY, 1994 6. Holden, G., Understanding Thermoplastic Elastomers, Hanser Gardner Publications, 1999 7. CD-Adapco, Star-CD Users Manual, CD-Adapco, 2004 8. Fluent, Fluent CFD users Manual, Fluent USA, 2004 9. Srinivas, K., Material And Rheological Characterization For Rapid Prototyping Of Elastomers Components, American Chemical Society, Rubber Division, 170th Technical Meeting, Cincinnati, October 2006 Similar to material models used in FEA there are many mathematical models to describe the characteristic flow of a material including that described by the Bingham model; Shear stress = Yield stress + K x Shear rate where, K is a constant. Flowchart in Figure 3 shows the typical processes involved in a CFD simulation to model the extrusion process. The two major types of testing carried out is for testing the material viscosity vs. the shear rate and for material viscosity vs. temperature. Just as curve fitting of stress-strain data as a material model the viscosity vs. shear rate data is fitted to a material model and input into the software code. Figure 3: FlowChart for Extrusion Simulation using CFD The use of a particular type of rheometer is dictated by the type of test data needed for the simulation and different associated parameters. To model simulations at high extrusion speeds and temperature testing data is needed in the range of 20,000-30,000 sec-1. Use of a capillary rheometer becomes necessary for such type of material characterization testing. ENGINEERING WITH POLYMERS WHITE PAPERPAGE 4 ALL RIGHTS RESERVED @ KARTIK SRINIVAS; HTTP: / / WWW. ADVANSES. COM