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STUDY OF MINERALS
Dr.R.K.Kaleeswari
Professor (SS&AC)
Department of Soil Science & Agrl. Chemistry
TNAU, Coimbatore, India
DEFINITION
A mineral is a naturally occurring solid with
a highly ordered atomic arrangement and a
definite chemical composition.
 It is usually formed by inorganic processes
MINERALOGY
The study of the chemistry, atomic structure,
physical properties, and genesis of minerals
THE PHYSICAL PROPERTIES OF
MINERALS
Color
Streak
Luster
Hardness
External Crystal Form
Cleavage
THE PHYSICAL PROPERTIES OF
MINERALS (CONT.)
Fracture
Specific Gravity
Special Properties
Other Properties
Chemical Tests
IMPORTANT PHYSICAL
PROPERTIES I
Luster - This property describes the
appearance of reflected light from the mineral's
surface.
Nonmetallic minerals are described using the
following terms: vitreous, pearly, silky, resinous,
and earthy.
IMPORTANT PHYSICAL
PROPERTIES II
 Color - Although an obvious feature, it is often
unreliable to use to determine the type of mineral.
For example, quartz is found in a variety of colors.
Color of a mineral may be quite diagnostic for the trace
element and coordination number of its bonding
environment.
IMPORTANT PHYSICAL
PROPERTIES III
 Streak - The color of a mineral in its powdered form;
obtained by rubbing the mineral against an unglazed
porcelain plate.
 Streak is usually less variable than color.
 Useful for distinguishing between minerals with
metallic luster.
DENSITY AND SPECIFIC GRAVITY
 Density - Defined as the mass divided by the volume
 SI units: kg m-3
 Specific Gravity - Ratio of the mass of a substance to
the mass of an equal volume of water.
 S.G. is unitless.
 Examples - quartz (SiO2) has a S.G. of 2.65 while
galena (PbS) has a S.G. of 7.5 and gold (Au) has a S.G.
of 19.3.
COLOR AND DENSITY
 Two broad categories are ferromagnesian and
nonferromagnesian silicates, which simply means
iron and magnesian bearing or not. The presence or
absence of Fe and Mg strongly affects the external
appearance (color) and density of the minerals.
COLOR AND DENSITY
 Ferromagnesian silicates - dark color, density
range from 3.2 - 3.6 g/cc
 Olivine
 Pyroxenes
 Amphiboles
 Mica
 Garnet
 Nonferromagnesian silicates - light color,
density close to 2.7 g/cc
 Mica
 Feldspars
 Quartz
 Clay
IMPORTANT PHYSICAL
PROPERTIES IV
 Crystal form
The external morphology of crystals generally reflect
the internal arrangement of their constituent atoms.
IMPORTANT PHYSICAL
PROPERTIES V
 Hardness
 This is the resistance of the mineral to abrasion or
scratching.
 This property doesn't vary greatly from sample to
sample of the same mineral, and thus is highly
diagnostic.
HARDNESS
 It also is a direct reflection of the bonding type and internal
atomic arrangement.
 A value is obtained by comparing the mineral to a standard
scale devised by Moh, which is comprised of 10 minerals
ranging in hardness from talc (softest) to diamond
(hardest).
MOHS’ HARDNESS
SCALE
POLYMORPHISM AND
POLYMORPHS
 Substances having the same chemical composition but
different crystal structures.
 e.g. diamond and graphite
 Both minerals are composed of pure carbon, but diamond
is the high pressure polymorph of graphite.
 This gives rise to extremely different physical properties.
DIAMOND VS. GRAPHITE CRYSTAL
STRUCTURES
Hardness: 10 Hardness: 1-2
FINGERNAIL HARDNESS (2.5) SCRATCHES
GYPSUM (2)
IMPORTANT PHYSICAL
PROPERTIES VI
 Cleavage - Orientation and number of
planes of weakness within a mineral. Directly
reflects the orientation of weak bonds within
the crystal structure. This feature is also
highly diagnostic.
 Fracture - This describes how a mineral
breaks if it is not along well defined planes. In
minerals with low symmetry and highly
interconnected atomic networks, irregular
fracture is common.
SPECIAL AND OTHER
PROPERTIES
 Striations - Commonly found on plagioclase
feldspar. Straight, parallel lines on one or
more of the cleavage planes caused by mineral
twinning.
 Magnetism - Property of a substance such
that it will spontaneous orient itself within a
magnetic field. Magnetite (Fe3O4) has this
property and it can be used to distinguish it
from other non-magnetite iron oxides, such as
hematite (Fe2O3).
 Double Refraction - Seen in calcite crystals.
Light is split or refracted into two components
giving rise to two distinct images.
 Silicates and Non silicates
 Silicates – made of silicon and oxygen and make up 92 % of Earth’s crust.
 Ferromagnesian Silicates
 made of iron, magnesium, and silicates
 Form a basic tetrahederal structure.
 Higher density and darker color than other silicates due to the presence
of iron and magnesium
 Non ferromagnesiam Silicates
 silicates that do not contain either iron or magnesium.
 Lower density and lighter color than the ferromagnesian silicates.
Structure of silicates
Isolated tetrahedrons
Chain silicates
Sheet silicates
Framework silicates
 Nonsilicates – make up 8% of Earth’s crust
 Carbonates
 Sulfates
 Oxides
 Sulfides
 Halides
 Phosphates
 Hydroxides
 Native elements
Non silicates

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Minerals.pptx

  • 1. STUDY OF MINERALS Dr.R.K.Kaleeswari Professor (SS&AC) Department of Soil Science & Agrl. Chemistry TNAU, Coimbatore, India
  • 2. DEFINITION A mineral is a naturally occurring solid with a highly ordered atomic arrangement and a definite chemical composition.  It is usually formed by inorganic processes
  • 3. MINERALOGY The study of the chemistry, atomic structure, physical properties, and genesis of minerals
  • 4. THE PHYSICAL PROPERTIES OF MINERALS Color Streak Luster Hardness External Crystal Form Cleavage
  • 5. THE PHYSICAL PROPERTIES OF MINERALS (CONT.) Fracture Specific Gravity Special Properties Other Properties Chemical Tests
  • 6. IMPORTANT PHYSICAL PROPERTIES I Luster - This property describes the appearance of reflected light from the mineral's surface. Nonmetallic minerals are described using the following terms: vitreous, pearly, silky, resinous, and earthy.
  • 7. IMPORTANT PHYSICAL PROPERTIES II  Color - Although an obvious feature, it is often unreliable to use to determine the type of mineral. For example, quartz is found in a variety of colors. Color of a mineral may be quite diagnostic for the trace element and coordination number of its bonding environment.
  • 8. IMPORTANT PHYSICAL PROPERTIES III  Streak - The color of a mineral in its powdered form; obtained by rubbing the mineral against an unglazed porcelain plate.  Streak is usually less variable than color.  Useful for distinguishing between minerals with metallic luster.
  • 9. DENSITY AND SPECIFIC GRAVITY  Density - Defined as the mass divided by the volume  SI units: kg m-3  Specific Gravity - Ratio of the mass of a substance to the mass of an equal volume of water.  S.G. is unitless.  Examples - quartz (SiO2) has a S.G. of 2.65 while galena (PbS) has a S.G. of 7.5 and gold (Au) has a S.G. of 19.3.
  • 10. COLOR AND DENSITY  Two broad categories are ferromagnesian and nonferromagnesian silicates, which simply means iron and magnesian bearing or not. The presence or absence of Fe and Mg strongly affects the external appearance (color) and density of the minerals.
  • 11. COLOR AND DENSITY  Ferromagnesian silicates - dark color, density range from 3.2 - 3.6 g/cc  Olivine  Pyroxenes  Amphiboles  Mica  Garnet  Nonferromagnesian silicates - light color, density close to 2.7 g/cc  Mica  Feldspars  Quartz  Clay
  • 12. IMPORTANT PHYSICAL PROPERTIES IV  Crystal form The external morphology of crystals generally reflect the internal arrangement of their constituent atoms.
  • 13. IMPORTANT PHYSICAL PROPERTIES V  Hardness  This is the resistance of the mineral to abrasion or scratching.  This property doesn't vary greatly from sample to sample of the same mineral, and thus is highly diagnostic.
  • 14. HARDNESS  It also is a direct reflection of the bonding type and internal atomic arrangement.  A value is obtained by comparing the mineral to a standard scale devised by Moh, which is comprised of 10 minerals ranging in hardness from talc (softest) to diamond (hardest).
  • 16. POLYMORPHISM AND POLYMORPHS  Substances having the same chemical composition but different crystal structures.  e.g. diamond and graphite  Both minerals are composed of pure carbon, but diamond is the high pressure polymorph of graphite.  This gives rise to extremely different physical properties.
  • 17. DIAMOND VS. GRAPHITE CRYSTAL STRUCTURES Hardness: 10 Hardness: 1-2
  • 18. FINGERNAIL HARDNESS (2.5) SCRATCHES GYPSUM (2)
  • 19. IMPORTANT PHYSICAL PROPERTIES VI  Cleavage - Orientation and number of planes of weakness within a mineral. Directly reflects the orientation of weak bonds within the crystal structure. This feature is also highly diagnostic.  Fracture - This describes how a mineral breaks if it is not along well defined planes. In minerals with low symmetry and highly interconnected atomic networks, irregular fracture is common.
  • 20. SPECIAL AND OTHER PROPERTIES  Striations - Commonly found on plagioclase feldspar. Straight, parallel lines on one or more of the cleavage planes caused by mineral twinning.  Magnetism - Property of a substance such that it will spontaneous orient itself within a magnetic field. Magnetite (Fe3O4) has this property and it can be used to distinguish it from other non-magnetite iron oxides, such as hematite (Fe2O3).  Double Refraction - Seen in calcite crystals. Light is split or refracted into two components giving rise to two distinct images.
  • 21.  Silicates and Non silicates  Silicates – made of silicon and oxygen and make up 92 % of Earth’s crust.  Ferromagnesian Silicates  made of iron, magnesium, and silicates  Form a basic tetrahederal structure.  Higher density and darker color than other silicates due to the presence of iron and magnesium  Non ferromagnesiam Silicates  silicates that do not contain either iron or magnesium.  Lower density and lighter color than the ferromagnesian silicates.
  • 22. Structure of silicates Isolated tetrahedrons Chain silicates Sheet silicates Framework silicates
  • 23.  Nonsilicates – make up 8% of Earth’s crust  Carbonates  Sulfates  Oxides  Sulfides  Halides  Phosphates  Hydroxides  Native elements Non silicates