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Introduction to Minerals
• Introduction and Definitions
• Chemical Classification
• Diagnostic Properties
• Some Common Minerals
1
The word mineral is used in a variety of ways.
§ any valuable material extracted from the Earth like coal, gravel,
and even groundwater.
§ by nutritionists for elements metabolized by the body
§ as anything that isn’t animal or plant
Over 4,000 minerals have been identified in the scientific literature -
Approximately 40 - 50 new ones are discovered every year!
Luckily, there are relatively few (10-15) common rock-forming
minerals.
DEFINITIONS
A rock is any solid mass of mineral (or mineral-like) matter that occurs
naturally. A few rocks may be composed of only one mineral, but
most are an aggregate of several minerals.
A mineral is any naturally occurring inorganic solid that possesses an
orderly internal structure and a definite chemical composition.
1. naturally occurring (concrete, synthetic diamonds, etc. are
excluded).
2. inorganic (teeth, seashells, trees, etc. are excluded)
3. solid (gases and liquids are excluded)
4. orderly internal structure (amorphous solids like glass are
excluded)
5. definite chemical composition
examples: C Diamond
NaCl Halite
(Na,Ca)Al(Si,Al)Si2O8 Plagioclase
One way that rocks are characterized is by their mineral content.
For example, the rock granite commonly contains the three minerals:
•quartz
•feldspar
•biotite
quartz feldspar biotite
Luckily, most rocks are
composed of a few
common rock-forming
minerals.
5
Wikipedia
contributor:
Benjah-bmm27
Part of the definition of a mineral is that it has
an orderly internal structure, i.e. crystal
structure.
The top image shows the crystal structure of
halite (common table salt) NaCl (Na = purple,
Cl = green).
The bottom image shows a halite crystal.
It is clear that the crystal structure of a
mineral may control important mineral
properties such as its form (crystal shape) and
cleavage.
Some materials are mineral-like but lack
crystal structure and are known as
mineraloids (ex. amber, obsidian, etc.)
Rob
Lavinsky,
iRocks.com
–
CC-BY-SA-3.0
6
Part of the definition of a mineral is that minerals have a definite
chemical composition.
The composition or chemistry of a mineral is an important property
that may control geologic process such as weathering, melting,
metamorphism, etc.
Some minerals have a simple chemical formula
examples: diamond C
halite NaCl
quartz SiO2
Other minerals have chemical formulas that vary between very specific
limits. This is because some elements are similar and may substitute
for others within the crystal structure.
examples: plagioclase (Na,Ca)Al(Si,Al)Si2O8
olivine (Mg,Fe)2SiO4
7
Question
Graphite and diamond are pure carbon have
the same chemical formula:
C (pure carbon)
But,
diamond is the hardest substance know
and,
graphite is one of the softest minerals.
If they have the same chemical formula,
why are they different minerals?
Rob
Lavinsky,
iRocks.com
–
CC-BY-SA-3.0
Wikimedia:
Mario
Sarto
8
Chemical Classification of Minerals
Minerals are classified based on their (anion) chemistry:
•minerals that contain silica (SiO2) are silicates ex. quartz SiO2
•minerals that contain carbonate (CO3
2-) are carbonate ex. calcite CaCO3
•minerals that contain sulfur (S) are sulfides ex. pyrite FeS2
•minerals that contain oxygen (O) are oxides ex. magnetite Fe3O4
Silicates are the most common minerals and the properties of silicate
minerals significantly control geologic processes. For example,
•silica-rich magma and lava is more explosive or violent when it
erupts. The amount of silica affects the mode of eruption.
•silica-rich minerals tend to be more resistant to chemical weathering
than silica-poor minerals
Diagnostic Properties of Minerals
Minerals may be identified by different physical and chemical
properties. It is important to understand that a minerals is usually
identified by a variety of properties. No single property is diagnostic
for all minerals. Common diagnostic properties include:
•Color
•Streak
•Luster
•Hardness
Other properties that may be diagnostic for a mineral may include:
•Crystal form
•Cleavage/fracture
•Magnetism
•Reaction to acid
•Density
•Smell/Taste and many more.
Color
Color seems like an easy property but it is risky to identify a mineral
by its color alone.
Most minerals can have a wide range of colors due to small amounts of
impurities in them such as these examples of quartz.
Another example, rubies and sapphires are the
same mineral, corundum, and have a wide
range of colors! So color alone is not very
diagnostic.
Smokey Quartz Amethyst Quartz Citrine Quartz Rose Quartz
Corundum
Streak
A mineral’s streak is the color
of a powdered mineral on a
streak plate (unglazed
porcelain tile).
This property can be
diagnostic for a small number
of minerals (usually those
with a metallic luster).
Although the color of a
mineral may vary, the color of
the streak remains
surprisingly constant.
harmonscieince6
Luster
Luster describes the way that the
surface of the mineral reflects
light. There are many types of
lusters but the common ones are:
•Metallic
•Nonmetallic
•glassy
•brilliant
•dull
Wikimedia:
CarlesMillan
Wulfex India
Hardness
Hardness is a mineral’s ability to
resist being scratched.
The Mohs hardness scale is a
unitless 10-point scale with each
hardness value represented by a
common mineral. The Mohs’
hardness scale is not linear!
Hardness can be directly related to
bond strength – hardness is an
expression of the weakest bond.
Compare the hardness of graphite
(H=1) and diamond (H=10); they
have the same chemical
composition but different
bonds/structures.
14
Crystal Form
Some minerals that grow without being impeded by their environment
develop characteristic crystal shapes or crystal form that represents the
symmetry of the crystal structure. Crystal form can be a diagnostic
property for some minerals.
Quartz has an internal structure
that has a 6-sided (hexagonal)
symmetry. As a result, quartz
crystals commonly are 6-sided.
Halite has an internal structure that
has a cubic (4-sided) symmetry. As
a result, halite crystals commonly
are cube shaped.
Wikimedia:
Piotr
Sosnowski
Cleavage
Cleavage is the tendency of
minerals to break parallel to
crystallographic planes along
which chemical bonds are weaker
than others.
Cleavage surfaces are not
necessarily parallel to crystal
faces.
It may be difficult to distinguish
between cleavage planes and
crystal faces.
University
of
Georgia
Mica has one direction of cleavage and breaks into flat sheets.
Halite has three directions of cleavage breaks to form cubes.
MacMaster
Virtual
Geology
Museum:
Lisa
Leoni
Fracture
Fracture is the way a mineral breaks in the absence of a cleavage
plane. In some crystals, the strength of bonds is approximately equal
in all crystallographic directions. Several types of fracture can be
described:
conchoidal – smooth curved surfaces resembling shells
fibrous – common with asbestos
hackly – jagged fractures with sharp edges
irregular or uneven – rough or irregular surfaces
Conchoidal fracture in
obsidian.
Fibrous fracture in
chrysotile.
Hackly fracture in native
copper.
Siim Sepp USGS Wikimedia: John Mortimore
Magnetism
Magnetism in minerals results from atomic
properties of certain metal atoms in
minerals.
This property is diagnostic for a few
minerals such as magnetite.
Reaction to Acid
Minerals that contain the chemical
component carbonate (CO3
2-) react to
acid by effervescing.
The mineral calcite effervesces by the
reaction:
Herschel Friedman
CaCO3 + 2HCl —> CO2 + Ca2+ + 2Cl- + H2O
Guillermo Rocha/Brooklyn College
Other Properties
There are many other physical properties
that may be diagnostic for some minerals.
•Play of color
•Smell/Taste
•Luminescence
It is important to understand that not all
properties are diagnostic for all minerals.
Wikimedia User: Mitchell Gore
Nature’s Rainbows
Let’s look at
some minerals.
It is usually white or colorless but has a wide range
of colors; some of its colored varieties are semi-
precious gems such as amethyst and citrine.
Quartz is used to make glass and computer chips.
Quartz commonly forms nicely shaped 6-sided
crystals that are widely available.
Quartz is common in igneous and metamorphic
rocks. It is resistant to chemical weathering and is a
common constituent of sediments such as sand and
sedimentary rocks because it is resistant to
weathering.
Quartz SiO2
Quartz is a silicate mineral and is the second most
common mineral in the Earth’s crust.
Feldspar NaAlSi3O8 - CaAl2Si2O8 - KAlSi3O8
Feldspar is a large, complex family of silicate minerals
and is the most common mineral in the Earth’s crust.
Since it has a wide range of chemical compositions, its
appearance may also vary widely.
Feldspar is commonly white to dark gray in color.
Some common varieties are pink.
Feldspars are used in the
manufacturing of specialized glasses
and ceramics. It is commonly used in
aggregate and, because it is so
common, is commonly used in
construction (building facing, etc.).
Univ. of Pittsburgh
Wikimedia:
Rob
Lavinsky
Pyrite FeS2
Pyrite is a sulfide mineral and is one of the most
common of the minerals with metallic luster. It is
also known as “fool’s gold.”
Although it usually forms massive groups of
indistinct crystals, it may also form beautifully
formed cubic and soccer ball-shaped crystals.
It also commonly replaces organic material and
forms fossils.
It has little economic importance now, but in the
past, it was an important source of iron and sulfur.
Magnetite Fe3O4
Magnetite is an oxide mineral and is a
common iron ore mineral.
It is usually black in color and has a
black streak. Its luster is commonly
metallic but may appear submetallic.
Magnetite forms massive groups of
small indistinct crystals, but may
rarely form octahedral crystals.
The most distinguishing property of
magnetite is that it is magnetic.
Herschel Friedman
Wikimedia: Rob Lavinsky
Talc Mg2Si4O10(OH)2
Talc is a silicate mineral and is commonly
found in metamorphic rocks.
Although it is not a very common mineral,
it is a good one to show to students because
of its very low hardness. The extreme
softness of the mineral gives it a slippery
feel.
It is usually white to light green in color
and may exhibit one-direction of cleavage.
Its nonmetallic luster may appear glassy to
pearly in appearance.
Talc is used as an industrial lubricant, as a
filler in paints and plastic and commonly as
a major ingredient in talcum powder and
cosmetics.
USGS
Wikimedia: Mattman723
Mica
Muscovite KAl2(Si3O10)(OH,F,Cl)2
Biotite K(Fe,Mg)3AlSi3O10(OH)2
Muscovite and biotite are silicates and are
two of the most common types of mica.
The micas are a complex group of
minerals that are characterized by
excellent cleavage in one direction - thus,
it can be split into thin flexible sheets.
Muscovite and biotite can be distinguished
from one another by color: muscovite is
clear to tan-brown and biotite is dark
brown to black.
The hardness of the micas ranges 2-3.
University
of
Georgia
Wikimedia:
Rob
Lavinsky
Hornblende Ca2(Mg,Fe)4Al(Si7Al)O22(OH,F)2
Hornblende is a silicate and is the most
common member of a complex family of
minerals known as the amphiboles.
Hornblende is common in igneous and
metamorphic rocks. It is uncommon in
sedimentary rocks because it quickly
alters to other minerals at the Earth’s
surface.
Hornblende has a Moh’s hardness of 5-6 so that its hardness is
approximately that of glass.
Hornblende has 2 directions of cleavage - thus it can be easily
distinguished from biotite mica.
USGS
Fluorite CaF2
Fluorite is a distinctive but relatively
uncommon halide mineral mineral. It is
most commonly associated with
hydrothermal deposits.
It comes in a wide range of colors - clear,
yellow, purple and green are common.
It has a Moh’s hardness of 4 and has
excellent cleavage in 4 directions.
Fluorite is our primary source for fluorine.
Calcite CaCO3
Calcite is a common carbonate mineral, especially in
sedimentary rocks. It is also associated with biological
activity in the production of shells.
Calcite is usually colorless to white in color but
may show a range of pale colors including
yellow, pink and green.
It has 3 directions of cleavage - forming
rhombohedra (“smooshed” cubes).
Calcite is most distinguished by its vigorous
reaction to acid.
Calcite is used to manufacture cement and as a
calcium dietary supplement.

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INTRODUCCIÓN A LOS ESTUDIOS DE MINERALES.pdf

  • 1. Introduction to Minerals • Introduction and Definitions • Chemical Classification • Diagnostic Properties • Some Common Minerals 1
  • 2. The word mineral is used in a variety of ways. § any valuable material extracted from the Earth like coal, gravel, and even groundwater. § by nutritionists for elements metabolized by the body § as anything that isn’t animal or plant Over 4,000 minerals have been identified in the scientific literature - Approximately 40 - 50 new ones are discovered every year! Luckily, there are relatively few (10-15) common rock-forming minerals.
  • 3. DEFINITIONS A rock is any solid mass of mineral (or mineral-like) matter that occurs naturally. A few rocks may be composed of only one mineral, but most are an aggregate of several minerals. A mineral is any naturally occurring inorganic solid that possesses an orderly internal structure and a definite chemical composition. 1. naturally occurring (concrete, synthetic diamonds, etc. are excluded). 2. inorganic (teeth, seashells, trees, etc. are excluded) 3. solid (gases and liquids are excluded) 4. orderly internal structure (amorphous solids like glass are excluded) 5. definite chemical composition examples: C Diamond NaCl Halite (Na,Ca)Al(Si,Al)Si2O8 Plagioclase
  • 4. One way that rocks are characterized is by their mineral content. For example, the rock granite commonly contains the three minerals: •quartz •feldspar •biotite quartz feldspar biotite Luckily, most rocks are composed of a few common rock-forming minerals.
  • 5. 5 Wikipedia contributor: Benjah-bmm27 Part of the definition of a mineral is that it has an orderly internal structure, i.e. crystal structure. The top image shows the crystal structure of halite (common table salt) NaCl (Na = purple, Cl = green). The bottom image shows a halite crystal. It is clear that the crystal structure of a mineral may control important mineral properties such as its form (crystal shape) and cleavage. Some materials are mineral-like but lack crystal structure and are known as mineraloids (ex. amber, obsidian, etc.) Rob Lavinsky, iRocks.com – CC-BY-SA-3.0
  • 6. 6 Part of the definition of a mineral is that minerals have a definite chemical composition. The composition or chemistry of a mineral is an important property that may control geologic process such as weathering, melting, metamorphism, etc. Some minerals have a simple chemical formula examples: diamond C halite NaCl quartz SiO2 Other minerals have chemical formulas that vary between very specific limits. This is because some elements are similar and may substitute for others within the crystal structure. examples: plagioclase (Na,Ca)Al(Si,Al)Si2O8 olivine (Mg,Fe)2SiO4
  • 7. 7 Question Graphite and diamond are pure carbon have the same chemical formula: C (pure carbon) But, diamond is the hardest substance know and, graphite is one of the softest minerals. If they have the same chemical formula, why are they different minerals? Rob Lavinsky, iRocks.com – CC-BY-SA-3.0 Wikimedia: Mario Sarto
  • 8. 8 Chemical Classification of Minerals Minerals are classified based on their (anion) chemistry: •minerals that contain silica (SiO2) are silicates ex. quartz SiO2 •minerals that contain carbonate (CO3 2-) are carbonate ex. calcite CaCO3 •minerals that contain sulfur (S) are sulfides ex. pyrite FeS2 •minerals that contain oxygen (O) are oxides ex. magnetite Fe3O4 Silicates are the most common minerals and the properties of silicate minerals significantly control geologic processes. For example, •silica-rich magma and lava is more explosive or violent when it erupts. The amount of silica affects the mode of eruption. •silica-rich minerals tend to be more resistant to chemical weathering than silica-poor minerals
  • 9. Diagnostic Properties of Minerals Minerals may be identified by different physical and chemical properties. It is important to understand that a minerals is usually identified by a variety of properties. No single property is diagnostic for all minerals. Common diagnostic properties include: •Color •Streak •Luster •Hardness Other properties that may be diagnostic for a mineral may include: •Crystal form •Cleavage/fracture •Magnetism •Reaction to acid •Density •Smell/Taste and many more.
  • 10. Color Color seems like an easy property but it is risky to identify a mineral by its color alone. Most minerals can have a wide range of colors due to small amounts of impurities in them such as these examples of quartz. Another example, rubies and sapphires are the same mineral, corundum, and have a wide range of colors! So color alone is not very diagnostic. Smokey Quartz Amethyst Quartz Citrine Quartz Rose Quartz Corundum
  • 11. Streak A mineral’s streak is the color of a powdered mineral on a streak plate (unglazed porcelain tile). This property can be diagnostic for a small number of minerals (usually those with a metallic luster). Although the color of a mineral may vary, the color of the streak remains surprisingly constant. harmonscieince6
  • 12. Luster Luster describes the way that the surface of the mineral reflects light. There are many types of lusters but the common ones are: •Metallic •Nonmetallic •glassy •brilliant •dull Wikimedia: CarlesMillan Wulfex India
  • 13. Hardness Hardness is a mineral’s ability to resist being scratched. The Mohs hardness scale is a unitless 10-point scale with each hardness value represented by a common mineral. The Mohs’ hardness scale is not linear! Hardness can be directly related to bond strength – hardness is an expression of the weakest bond. Compare the hardness of graphite (H=1) and diamond (H=10); they have the same chemical composition but different bonds/structures.
  • 14. 14 Crystal Form Some minerals that grow without being impeded by their environment develop characteristic crystal shapes or crystal form that represents the symmetry of the crystal structure. Crystal form can be a diagnostic property for some minerals. Quartz has an internal structure that has a 6-sided (hexagonal) symmetry. As a result, quartz crystals commonly are 6-sided. Halite has an internal structure that has a cubic (4-sided) symmetry. As a result, halite crystals commonly are cube shaped. Wikimedia: Piotr Sosnowski
  • 15. Cleavage Cleavage is the tendency of minerals to break parallel to crystallographic planes along which chemical bonds are weaker than others. Cleavage surfaces are not necessarily parallel to crystal faces. It may be difficult to distinguish between cleavage planes and crystal faces. University of Georgia Mica has one direction of cleavage and breaks into flat sheets. Halite has three directions of cleavage breaks to form cubes. MacMaster Virtual Geology Museum: Lisa Leoni
  • 16. Fracture Fracture is the way a mineral breaks in the absence of a cleavage plane. In some crystals, the strength of bonds is approximately equal in all crystallographic directions. Several types of fracture can be described: conchoidal – smooth curved surfaces resembling shells fibrous – common with asbestos hackly – jagged fractures with sharp edges irregular or uneven – rough or irregular surfaces Conchoidal fracture in obsidian. Fibrous fracture in chrysotile. Hackly fracture in native copper. Siim Sepp USGS Wikimedia: John Mortimore
  • 17. Magnetism Magnetism in minerals results from atomic properties of certain metal atoms in minerals. This property is diagnostic for a few minerals such as magnetite. Reaction to Acid Minerals that contain the chemical component carbonate (CO3 2-) react to acid by effervescing. The mineral calcite effervesces by the reaction: Herschel Friedman CaCO3 + 2HCl —> CO2 + Ca2+ + 2Cl- + H2O Guillermo Rocha/Brooklyn College
  • 18. Other Properties There are many other physical properties that may be diagnostic for some minerals. •Play of color •Smell/Taste •Luminescence It is important to understand that not all properties are diagnostic for all minerals. Wikimedia User: Mitchell Gore Nature’s Rainbows
  • 19. Let’s look at some minerals.
  • 20. It is usually white or colorless but has a wide range of colors; some of its colored varieties are semi- precious gems such as amethyst and citrine. Quartz is used to make glass and computer chips. Quartz commonly forms nicely shaped 6-sided crystals that are widely available. Quartz is common in igneous and metamorphic rocks. It is resistant to chemical weathering and is a common constituent of sediments such as sand and sedimentary rocks because it is resistant to weathering. Quartz SiO2 Quartz is a silicate mineral and is the second most common mineral in the Earth’s crust.
  • 21. Feldspar NaAlSi3O8 - CaAl2Si2O8 - KAlSi3O8 Feldspar is a large, complex family of silicate minerals and is the most common mineral in the Earth’s crust. Since it has a wide range of chemical compositions, its appearance may also vary widely. Feldspar is commonly white to dark gray in color. Some common varieties are pink. Feldspars are used in the manufacturing of specialized glasses and ceramics. It is commonly used in aggregate and, because it is so common, is commonly used in construction (building facing, etc.). Univ. of Pittsburgh Wikimedia: Rob Lavinsky
  • 22. Pyrite FeS2 Pyrite is a sulfide mineral and is one of the most common of the minerals with metallic luster. It is also known as “fool’s gold.” Although it usually forms massive groups of indistinct crystals, it may also form beautifully formed cubic and soccer ball-shaped crystals. It also commonly replaces organic material and forms fossils. It has little economic importance now, but in the past, it was an important source of iron and sulfur.
  • 23. Magnetite Fe3O4 Magnetite is an oxide mineral and is a common iron ore mineral. It is usually black in color and has a black streak. Its luster is commonly metallic but may appear submetallic. Magnetite forms massive groups of small indistinct crystals, but may rarely form octahedral crystals. The most distinguishing property of magnetite is that it is magnetic. Herschel Friedman Wikimedia: Rob Lavinsky
  • 24. Talc Mg2Si4O10(OH)2 Talc is a silicate mineral and is commonly found in metamorphic rocks. Although it is not a very common mineral, it is a good one to show to students because of its very low hardness. The extreme softness of the mineral gives it a slippery feel. It is usually white to light green in color and may exhibit one-direction of cleavage. Its nonmetallic luster may appear glassy to pearly in appearance. Talc is used as an industrial lubricant, as a filler in paints and plastic and commonly as a major ingredient in talcum powder and cosmetics. USGS Wikimedia: Mattman723
  • 25. Mica Muscovite KAl2(Si3O10)(OH,F,Cl)2 Biotite K(Fe,Mg)3AlSi3O10(OH)2 Muscovite and biotite are silicates and are two of the most common types of mica. The micas are a complex group of minerals that are characterized by excellent cleavage in one direction - thus, it can be split into thin flexible sheets. Muscovite and biotite can be distinguished from one another by color: muscovite is clear to tan-brown and biotite is dark brown to black. The hardness of the micas ranges 2-3. University of Georgia Wikimedia: Rob Lavinsky
  • 26. Hornblende Ca2(Mg,Fe)4Al(Si7Al)O22(OH,F)2 Hornblende is a silicate and is the most common member of a complex family of minerals known as the amphiboles. Hornblende is common in igneous and metamorphic rocks. It is uncommon in sedimentary rocks because it quickly alters to other minerals at the Earth’s surface. Hornblende has a Moh’s hardness of 5-6 so that its hardness is approximately that of glass. Hornblende has 2 directions of cleavage - thus it can be easily distinguished from biotite mica. USGS
  • 27. Fluorite CaF2 Fluorite is a distinctive but relatively uncommon halide mineral mineral. It is most commonly associated with hydrothermal deposits. It comes in a wide range of colors - clear, yellow, purple and green are common. It has a Moh’s hardness of 4 and has excellent cleavage in 4 directions. Fluorite is our primary source for fluorine.
  • 28. Calcite CaCO3 Calcite is a common carbonate mineral, especially in sedimentary rocks. It is also associated with biological activity in the production of shells. Calcite is usually colorless to white in color but may show a range of pale colors including yellow, pink and green. It has 3 directions of cleavage - forming rhombohedra (“smooshed” cubes). Calcite is most distinguished by its vigorous reaction to acid. Calcite is used to manufacture cement and as a calcium dietary supplement.