Talk given in the National Astronomy Meeting 2019, Lancaster, UK. A large number of neutron star mergers will be detected by LIGO/Virgo in the coming years. GW170817 confirmed that neutron star mergers would actually produce relativistic outflows (e.g. relativistic jets and cocoon). The polarimetry by LT and NRT would enable us to study the properties of the outflow in details (i.e. magnetic field structure/strength, and its angular dependence). We discuss polarization signals in the outflow emission, and we show the expected signal distributions for an upcoming neutron star merger sample.