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International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163
Volume 1 Issue 5 (June 2014) http://ijirae.com
__________________________________________________________________________________________________________
© 2014, IJIRAE- All Rights Reserved Page - 188
Simulation of Contamination of Groundwater Using
Environmental Quality Model
Pallavi A. Patil1
Prof. Pravin S. Chaudhari2
Civil and Environmental Engineering Department Civil and Environmental Engineering Department
Veermata Jijabai Technological Institute, Veermata Jijabai Technological Institute,
ABSTRACT-- Ground water is an important source of water supply for municipalities, agriculture, and industry. Ground water
contamination is the degradation of the natural quality of the ground water. While determining the degree of contamination,
both the presence of a substance and its concentration must be considered. The level at which a substance could be harmful is
different for each substance. Ground water contamination occurs, or can occur, when ground water in the zone of saturation is
recharged with contaminated water or other liquid contaminants, or when a contaminant is placed or buried in the saturated
zone. Contamination may result from wells, improperly sealed or abandoned and landfills that allow contaminated surface water
to reach an aquifer. Hence hydrological and environmental simulation modelling needs increasing attention from the hydrology
and environmental modelling communities. Present case study in a paper emphasises on groundwater contamination due to
septic tank effluent.
Keywords — Groundwater contamination, Septic tanks, MODFLOW, Simulation
I INTRODUCTION
Groundwater pollution may be defined as the artificially induced degradation of natural groundwater quality. Pollution can impair
the use of water and can create hazards to public health through toxicity or the spread of disease. Most pollution originates from the
disposal of waste water which is being used for variety of purposes.
Thus, the large number of sources and causes can modify groundwater quality, ranging from septic tanks to irrigated agriculture. In
contrast with surface water pollution, subsurface water pollution is difficult to detect and is even more difficult to control, and may
persist for decades. With the growing recognition of the importance of underground water resources, efforts are needed to increase
to prevent, reduce, and eliminate groundwater pollution.
II GROUNDWATER CONTAMINATION
The occurrence of groundwater contamination and quality of groundwater has become major issues since some decades.
Environmental contamination of groundwater due to extensive use of fertilizers, pesticides in agriculture and toxic chemicals in
industry and in manufactured products has magnified the toxicity for plants, animals and society. Contaminants that can dissolve in
groundwater will move along with the water, potentially to wells used for drinking water. A combination of moving groundwater
and a continuous source of contamination can, therefore, pollute very large volumes and areas of groundwater. This presence and
the transport of contaminants constitute a potential threat to human health and ecosystem. The quantity and the suitability of
groundwater for human consumption and for irrigation are determined by its physical, chemical and bacteriological properties.
A. GROUNDWATER MODELING
A groundwater model is a mathematical tool designed to represent a simplified version of the physical, chemical and biological
processes taking place in a real field site. It is generally, a computer-based approximation of observed groundwater behaviour.
Groundwater modelling requires the development of as good a simplification of the geometry, aquifer properties and source / sink
terms of the system as is achievable. The first parts of the modeling involve developing a groundwater model that adequately
simulates the groundwater flow observed in long term monitoring. The second phase of model development is to couple the
groundwater flow model with a pair of contaminant transport models.
B. MODELING OBJECTIVES
Ground water models are commonly used to,
 Identify data gaps during hydro geologic characterization.
 Aid in the design of a monitoring well network.
 Determine the potential impacts of contaminated ground water on nearby wells.
 Aid in selection and design of remedial actions to control, or remove and treat, contaminated ground water.
C. COMPUTER MODEL MODFLOW
Three-dimensional numerical model Processing MODFLOW was developed by USGS. MODFLOW numerically evaluates the
partial differential equations for groundwater flow. The interface of MODFLOW is divided into three modules, the Input Module,
the Run Module, and the Output Module. The input Module provides the ability to create a graphical three-dimensional
representation of the study area. The values can be directly assigned to the study area and the software creates the appropriate files.
International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163
Volume 1 Issue 5 (June 2014) http://ijirae.com
__________________________________________________________________________________________________________
© 2014, IJIRAE- All Rights Reserved Page - 189
The Run Module allows the user to alter the parameters and options that are run specifically, such as the solver package, recharge
and wetting applications and the tolerances for convergence. The Output Module provides the display of all the modeling and
calibration results.
III CASE STUDY
A Area of Study
Figure 1 Study Area (google earth)
Septic tank and soak pit considered in a case study is located near girl’s hostel of the V.J.T.I. college campus and an observation
well is located at a distance of 120m from the soak pit. All the wastewater from toilets, latrines and bathrooms of six hostel blocks
occupying 500 students is discharged into septic tank. Effluent from the septic tank is then transferred to soak pit. Normal annual
rainfall in the area is 1800mm to 2400mm.
B Development of Groundwater Flow Model
Aquifer type of the study area is confined aquifer consisting of alluvial sand layer of thickness 15m. The total area of 15625m2
is
dived in a smaller grids sizes 5m x 5m each with 25 rows and 25 columns. A groundwater flow model is developed using
MOFLOW package. Soil parameters, recharge rate and pump rate of the observation well were assigned and the model was run for
1800days.
Table 1 Soil characteristics (Todd & Mays, 2005)
Soil type Porosity Hydraulic
conductivity
Specific yield
(%) (m/day) (%)
Gravel 28 150-450 23-25
Sand 0.43 2.5-45 23-27
Silt 46 0.08 8
Clay 42 0.0002 3
C Solute Transport Modeling For Chloride Concentration With MT3DMS Package
The concentration of chlorides in septic tank effluent i.e. at source was determined by experimental analysis which is found to be
2500mg/lit. Daily domestic discharge in a septic tank is 5m3
/day during working days of college and 1.25m3
/day during vacation
period. The pump rate of observation well is 1.5m3
/day during its 12 hours operating period. Assigning all these parameters the
MODFLOW package was run for 1800 days and hydraulic head and groundwater flow pattern outputs were simulated.
Table 2 Details of the parameters used in MT3DMS package
Parameter Details
Chloride concentration at source 2500 mg/lit
Longitudinal dispersivity 12.5m
Freundlich equilibrium constant 1
Freundlich Exponent 0.5531
International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163
Volume 1 Issue 5 (June 2014) http://ijirae.com
__________________________________________________________________________________________________________
© 2014, IJIRAE- All Rights Reserved Page - 190
D Results
1 Model Calibration
The present study calibrates the model for groundwater flow. The observed hydraulic head in the observation well is 8.5m and
simulated hydraulic head obtained by MODFLOW is 8.3m. Observed hydraulic head is nearly matching with simulated head. Hence
software is working effectively.
Figure 2 MODFLOW window showing the groundwater flow pattern developed after simulation
2 MODFLOW Application
In the present study, concentration of chlorides in observation well for the months January, February, March and April were
calculated using experimental analysis. And the solute transport model was run for the same. Also from the simulated results it was
found that the chlorides concentration requires 690 days of period to reach up to the observation well.
Table 3 Details of observed and calculated chloride concentrations on monthly basis
Time
Observed concentration using
experimental analysis (mg/lit)
Simulated concentration
using MODFLOW (mg/lit)
15th Jan 2014 76 63.45433
15th Feb 2014 79.5 66.25002
15th March 2014 80 69.26227
15th April 2014 80.5 72.45611
International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163
Volume 1 Issue 5 (June 2014) http://ijirae.com
__________________________________________________________________________________________________________
© 2014, IJIRAE- All Rights Reserved Page - 191
Figure 3 graph showing observed and simulated chloride concentrations in observation well
Fom the graph it can be observed that the chloride concentration in the observation well is increasing with time. Also from trnd of
graph, it can be seen that the simulated results of the model are also increasing with time.
IV CONCLUSION
A computer tool MODFLOW was used to simulate the groundwater contamination study. Also the tool was effectively in the study
to study the groundwater contamination caused due to septic tank effluent. . From the study it is observed that chlorides
concentration is increasing with time. Also, MODFLOW simulation tool can be used in different groundwater contamination
simulation studies.
References
1. Buba Sengupta, H.S. & Richard Davis A.(June 2011)," India Groundwater Governance Case Study",Water Partnership
Program .
2. Chakraborty Sukalyan, M. B. (November 2012), "Quality Characterization of Groundwater using Water Quality Index in
Surat City, Gujarat, India", International Research Journal of Environment Sciences ISSN 2319–1414 , 1(4), 14-23.
3. P. Patrick Wang, C. (December 1999) "MT3DMS: A Modular Three-Dimensional Multispecies Tranport Model for
Simulation of Advection, Dispersion and Chemical Reactions of Contaminants in Groundwater Systems, Documentation
and User's guide", US Army Crops of Engineers (Engineering Research development center).
4. Todd, D. K., & Mays, L. W. (2005), "Groundwater Hydrology. John Wily & Sons, Inc"
5. V. S. Singh, N. C. (November 2005), "Modelling for pollutant migration in the tannery belt, Dindigul, Tamil Nadu, India",
Current Science , 89.

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Simulation of Contamination of Groundwater Using Environmental Quality Model

  • 1. International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163 Volume 1 Issue 5 (June 2014) http://ijirae.com __________________________________________________________________________________________________________ © 2014, IJIRAE- All Rights Reserved Page - 188 Simulation of Contamination of Groundwater Using Environmental Quality Model Pallavi A. Patil1 Prof. Pravin S. Chaudhari2 Civil and Environmental Engineering Department Civil and Environmental Engineering Department Veermata Jijabai Technological Institute, Veermata Jijabai Technological Institute, ABSTRACT-- Ground water is an important source of water supply for municipalities, agriculture, and industry. Ground water contamination is the degradation of the natural quality of the ground water. While determining the degree of contamination, both the presence of a substance and its concentration must be considered. The level at which a substance could be harmful is different for each substance. Ground water contamination occurs, or can occur, when ground water in the zone of saturation is recharged with contaminated water or other liquid contaminants, or when a contaminant is placed or buried in the saturated zone. Contamination may result from wells, improperly sealed or abandoned and landfills that allow contaminated surface water to reach an aquifer. Hence hydrological and environmental simulation modelling needs increasing attention from the hydrology and environmental modelling communities. Present case study in a paper emphasises on groundwater contamination due to septic tank effluent. Keywords — Groundwater contamination, Septic tanks, MODFLOW, Simulation I INTRODUCTION Groundwater pollution may be defined as the artificially induced degradation of natural groundwater quality. Pollution can impair the use of water and can create hazards to public health through toxicity or the spread of disease. Most pollution originates from the disposal of waste water which is being used for variety of purposes. Thus, the large number of sources and causes can modify groundwater quality, ranging from septic tanks to irrigated agriculture. In contrast with surface water pollution, subsurface water pollution is difficult to detect and is even more difficult to control, and may persist for decades. With the growing recognition of the importance of underground water resources, efforts are needed to increase to prevent, reduce, and eliminate groundwater pollution. II GROUNDWATER CONTAMINATION The occurrence of groundwater contamination and quality of groundwater has become major issues since some decades. Environmental contamination of groundwater due to extensive use of fertilizers, pesticides in agriculture and toxic chemicals in industry and in manufactured products has magnified the toxicity for plants, animals and society. Contaminants that can dissolve in groundwater will move along with the water, potentially to wells used for drinking water. A combination of moving groundwater and a continuous source of contamination can, therefore, pollute very large volumes and areas of groundwater. This presence and the transport of contaminants constitute a potential threat to human health and ecosystem. The quantity and the suitability of groundwater for human consumption and for irrigation are determined by its physical, chemical and bacteriological properties. A. GROUNDWATER MODELING A groundwater model is a mathematical tool designed to represent a simplified version of the physical, chemical and biological processes taking place in a real field site. It is generally, a computer-based approximation of observed groundwater behaviour. Groundwater modelling requires the development of as good a simplification of the geometry, aquifer properties and source / sink terms of the system as is achievable. The first parts of the modeling involve developing a groundwater model that adequately simulates the groundwater flow observed in long term monitoring. The second phase of model development is to couple the groundwater flow model with a pair of contaminant transport models. B. MODELING OBJECTIVES Ground water models are commonly used to,  Identify data gaps during hydro geologic characterization.  Aid in the design of a monitoring well network.  Determine the potential impacts of contaminated ground water on nearby wells.  Aid in selection and design of remedial actions to control, or remove and treat, contaminated ground water. C. COMPUTER MODEL MODFLOW Three-dimensional numerical model Processing MODFLOW was developed by USGS. MODFLOW numerically evaluates the partial differential equations for groundwater flow. The interface of MODFLOW is divided into three modules, the Input Module, the Run Module, and the Output Module. The input Module provides the ability to create a graphical three-dimensional representation of the study area. The values can be directly assigned to the study area and the software creates the appropriate files.
  • 2. International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163 Volume 1 Issue 5 (June 2014) http://ijirae.com __________________________________________________________________________________________________________ © 2014, IJIRAE- All Rights Reserved Page - 189 The Run Module allows the user to alter the parameters and options that are run specifically, such as the solver package, recharge and wetting applications and the tolerances for convergence. The Output Module provides the display of all the modeling and calibration results. III CASE STUDY A Area of Study Figure 1 Study Area (google earth) Septic tank and soak pit considered in a case study is located near girl’s hostel of the V.J.T.I. college campus and an observation well is located at a distance of 120m from the soak pit. All the wastewater from toilets, latrines and bathrooms of six hostel blocks occupying 500 students is discharged into septic tank. Effluent from the septic tank is then transferred to soak pit. Normal annual rainfall in the area is 1800mm to 2400mm. B Development of Groundwater Flow Model Aquifer type of the study area is confined aquifer consisting of alluvial sand layer of thickness 15m. The total area of 15625m2 is dived in a smaller grids sizes 5m x 5m each with 25 rows and 25 columns. A groundwater flow model is developed using MOFLOW package. Soil parameters, recharge rate and pump rate of the observation well were assigned and the model was run for 1800days. Table 1 Soil characteristics (Todd & Mays, 2005) Soil type Porosity Hydraulic conductivity Specific yield (%) (m/day) (%) Gravel 28 150-450 23-25 Sand 0.43 2.5-45 23-27 Silt 46 0.08 8 Clay 42 0.0002 3 C Solute Transport Modeling For Chloride Concentration With MT3DMS Package The concentration of chlorides in septic tank effluent i.e. at source was determined by experimental analysis which is found to be 2500mg/lit. Daily domestic discharge in a septic tank is 5m3 /day during working days of college and 1.25m3 /day during vacation period. The pump rate of observation well is 1.5m3 /day during its 12 hours operating period. Assigning all these parameters the MODFLOW package was run for 1800 days and hydraulic head and groundwater flow pattern outputs were simulated. Table 2 Details of the parameters used in MT3DMS package Parameter Details Chloride concentration at source 2500 mg/lit Longitudinal dispersivity 12.5m Freundlich equilibrium constant 1 Freundlich Exponent 0.5531
  • 3. International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163 Volume 1 Issue 5 (June 2014) http://ijirae.com __________________________________________________________________________________________________________ © 2014, IJIRAE- All Rights Reserved Page - 190 D Results 1 Model Calibration The present study calibrates the model for groundwater flow. The observed hydraulic head in the observation well is 8.5m and simulated hydraulic head obtained by MODFLOW is 8.3m. Observed hydraulic head is nearly matching with simulated head. Hence software is working effectively. Figure 2 MODFLOW window showing the groundwater flow pattern developed after simulation 2 MODFLOW Application In the present study, concentration of chlorides in observation well for the months January, February, March and April were calculated using experimental analysis. And the solute transport model was run for the same. Also from the simulated results it was found that the chlorides concentration requires 690 days of period to reach up to the observation well. Table 3 Details of observed and calculated chloride concentrations on monthly basis Time Observed concentration using experimental analysis (mg/lit) Simulated concentration using MODFLOW (mg/lit) 15th Jan 2014 76 63.45433 15th Feb 2014 79.5 66.25002 15th March 2014 80 69.26227 15th April 2014 80.5 72.45611
  • 4. International Journal of Innovative Research in Advanced Engineering (IJIRAE) ISSN: 2349-2163 Volume 1 Issue 5 (June 2014) http://ijirae.com __________________________________________________________________________________________________________ © 2014, IJIRAE- All Rights Reserved Page - 191 Figure 3 graph showing observed and simulated chloride concentrations in observation well Fom the graph it can be observed that the chloride concentration in the observation well is increasing with time. Also from trnd of graph, it can be seen that the simulated results of the model are also increasing with time. IV CONCLUSION A computer tool MODFLOW was used to simulate the groundwater contamination study. Also the tool was effectively in the study to study the groundwater contamination caused due to septic tank effluent. . From the study it is observed that chlorides concentration is increasing with time. Also, MODFLOW simulation tool can be used in different groundwater contamination simulation studies. References 1. Buba Sengupta, H.S. & Richard Davis A.(June 2011)," India Groundwater Governance Case Study",Water Partnership Program . 2. Chakraborty Sukalyan, M. B. (November 2012), "Quality Characterization of Groundwater using Water Quality Index in Surat City, Gujarat, India", International Research Journal of Environment Sciences ISSN 2319–1414 , 1(4), 14-23. 3. P. Patrick Wang, C. (December 1999) "MT3DMS: A Modular Three-Dimensional Multispecies Tranport Model for Simulation of Advection, Dispersion and Chemical Reactions of Contaminants in Groundwater Systems, Documentation and User's guide", US Army Crops of Engineers (Engineering Research development center). 4. Todd, D. K., & Mays, L. W. (2005), "Groundwater Hydrology. John Wily & Sons, Inc" 5. V. S. Singh, N. C. (November 2005), "Modelling for pollutant migration in the tannery belt, Dindigul, Tamil Nadu, India", Current Science , 89.