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Products from a surface ocean
CO2 reference network,
SOCONET
Presenter Rik Wanninkhof, NOAA/AOML
Bakker, D. C. E., B. Pfeil, K. Smith, S. Hankin, S. R. Alin, C. Cosca, S. Harasawa, A. Kozyr, Y. Nojiri, K. M. O'Brien, M. Telszewski,
B. Tilbrook, C. Wada, J. Akl, L. Barbero, N. R. Bates, J. Boutin, Y. Bozec, W. J. Cai, R. D. Castle, F. P. Chavez, L. Chen, M. Chierici,
K. Currie, H. J. W. de Baar, W. Evans, R. A. Feely, A. Fransson, Z. Gao, B. Hales, N. J. Hardman-Mountford, M. Hoppema, W. J.
Huang, C. W. Hunt, B. Huss, T. Ichikawa, T. Johannessen, E. M. Jones, S. D. Jones, S. Jutterström, V. Kitidis, A. Körtzinger, P.
Landschützer, S. K. Lauvset, N. Lefevre, A. B. Manke, J. T. Mathis, L. Merlivat, N. Metzl, A. Murata, P. Monteiro, T. Newberger,
A. M. Omar, T. Ono, G. H. Park, K. Paterson, D. Pierrot, A. F. Rios, C. L. Sabine, S. Saito, J. Salisbury, V. V. S. S. Sarma, R.
Schlitzer, R. Sieger, I. Skjelvan, T. Steinhoff, K. F. Sullivan, H. Sun, A. J. Sutton, T. Suzuki, C. Sweeney, T. Takahashi, J. Tjiputra, N.
Tsurushima, S. M. A. C. van Heuven, D. Vandemark, P. Vlahos, D. W. R. Wallace, A. Watson, R. Wanninkhof, P. A. Pickers, A.
M. Omar, A. Sutton, A. Murata, A. Olsen, B. B. Stephens, B. Tilbrook, D. Munro, D. Pierrot, G. Rehder, J. M. Santana-Casiano,
J. D. Müller, J. Trinanes, K. Tedesco, K. O’Brien, K. Currie, L. Barbero, M. Telszewski, M. Hoppema, M. Ishii, M. González-
Dávila, N. R. Bates, N. Metzl, P. Suntharalingam, R. A. Feely, S.-i. Nakaoka, S. K. Lauvset, T. Takahashi, T. Steinhoff and U.
Schuster
➢ Purpose of surface water CO2 reference network
➢ How the network fits into a hierarchy of efforts under the aegis of
Intergovernmental organization
➢ Development of products, example operations from cruise ships.
Outline
The Surface Ocean CO2 Reference Observing Network (SOCONET) is a volunteer group
of established operators who provide sustained quality global surface ocean CO2 and
atmospheric data from SOOP, ASV and moorings. SOCONET will tracks observations and
data following established network principles.
What is SOCONET ?
SOCONET is a subset of a larger surface water CO2 observation campaign
and part of a sustained ocean carbon observation effort (IOCOS-Richard Saunders lead)
Why do we need SOCONET?
quantify air-sea CO2 fluxes
➢ Mitigation of temperature increase and sealevel rise:
➢ Impact ecosystems- ocean acidification:
∆SST ≈ 0.5 ˚C ≈ 8 cm SLR
∆SST ≈0.6 ˚C
= 93 ppm ∆SST ≈ 0.8 ˚C ≈ 14 cm
=208 ppm ∆SST ≈ 1.9 ˚C ≈ 30 cm SLR
www.epa.gov/climate-indicators
110 ppm/˚C; 15 cm/100 ppm
➢ Value- will the ocean sink be counted as a carbon credit:
GCP, 2019
Without CO2 uptake by the ocean,
global temperatures would be ≈ 0.5
˚C warmer and sealevel ≈ 8 cm
higher since 1960
Sequestration of CO2 produced by
man has decreased pH by about 0.12
If the annual 2.5 Pg C of uptake by theocean CO2 was counted as a an “emission allowance” in the European
Union (EU) emission trading scheme (ETS),it would have an annual value of 150 billion Euro
ICOS-OTC
The SOCONET value chain
The creation of products
To sustain a network there must be regular and anticipated products
Products require more input than “just” surface CO2 measurements
Products
Example of a regional timeseries: Northern Caribbean Sea, 2002-2019
Data gap since March 2020: COVID19
>620 cruises
> 1.2 M observations (5 % of data in SOCAT
From observations to data products
Measurement fCO2w gridding Algorithm fCO2w = f(position, SST, SSS,MLD)
Spatial interpolation
From observations to data products
A hierarchy of products from fCO2 observations to derived quantities (based on fCO2
and other observations, inorganic carbon thermodynamics and interpolation)
The solid red lines are the leastsquares linear fit through all the fCO2w and SST data from 2002 to 2018. The black dashed lines are the fits from 2002 to 2010
and 2010 to 2018. For fCO2w the slopes are 1.30 ± 0.003; −1.37 ± 0.017; and 3.69 ± 0.011 μatm/year, respectively. For SST the slopes are −0.0080 ± 0.0003,
−0.178 ± 0.002, and 0.1941 ± 0.001 °C/year, respectively.
Observations Monthly Gridded Monthly mapped
Temporal interpolation- the seasonal cycle in SST dominates variability
Time series
Aragonite saturation State
(strongly correlated with shell and coral growth)
fCO2w [µatm] WAr = f(TA, fCO2w, SST)
Derived products
Higher level products from regional time series
Harmonic fit -18 years De-seasoned
Attribution
Long-term trends, deseasoning
18-year seasonal cycle Monthly fCO2w Residuals Correlation residuals fCO2w and SST
Slope =12 µatm/ ˚C
Thermodynamic =16 µatm/ ˚C
Deconvolution of processes controlling long term trends
Temperature: Red; Air sea gas fluxes: Blue
“The rest” (biology and mixing) : Green
Flux time series and global comparison
The sum of regional magnitudes, variabilities and trends yield the global patterns
Fluxes from the mapped product Greater interannual variability at regional scales than globally
➢ With sufficient observations and regional synoptic coverage of SST, MLD, SSS
and wind, robust information can be obtained regarding, mean, variability and
trends in carbon fluxes and surface ocean carbon products.
➢ This information will be important for monitoring the health of the ocean, and
its ability to provide services.
➢ A coordinated and unified approach based on a firm sustained infrastructure is
critical to continue to provide such information.
Conclusions

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Wanninkhof, Richard: Products from a surface ocean CO2 reference network, SOCONET

  • 1. Products from a surface ocean CO2 reference network, SOCONET Presenter Rik Wanninkhof, NOAA/AOML Bakker, D. C. E., B. Pfeil, K. Smith, S. Hankin, S. R. Alin, C. Cosca, S. Harasawa, A. Kozyr, Y. Nojiri, K. M. O'Brien, M. Telszewski, B. Tilbrook, C. Wada, J. Akl, L. Barbero, N. R. Bates, J. Boutin, Y. Bozec, W. J. Cai, R. D. Castle, F. P. Chavez, L. Chen, M. Chierici, K. Currie, H. J. W. de Baar, W. Evans, R. A. Feely, A. Fransson, Z. Gao, B. Hales, N. J. Hardman-Mountford, M. Hoppema, W. J. Huang, C. W. Hunt, B. Huss, T. Ichikawa, T. Johannessen, E. M. Jones, S. D. Jones, S. Jutterström, V. Kitidis, A. Körtzinger, P. Landschützer, S. K. Lauvset, N. Lefevre, A. B. Manke, J. T. Mathis, L. Merlivat, N. Metzl, A. Murata, P. Monteiro, T. Newberger, A. M. Omar, T. Ono, G. H. Park, K. Paterson, D. Pierrot, A. F. Rios, C. L. Sabine, S. Saito, J. Salisbury, V. V. S. S. Sarma, R. Schlitzer, R. Sieger, I. Skjelvan, T. Steinhoff, K. F. Sullivan, H. Sun, A. J. Sutton, T. Suzuki, C. Sweeney, T. Takahashi, J. Tjiputra, N. Tsurushima, S. M. A. C. van Heuven, D. Vandemark, P. Vlahos, D. W. R. Wallace, A. Watson, R. Wanninkhof, P. A. Pickers, A. M. Omar, A. Sutton, A. Murata, A. Olsen, B. B. Stephens, B. Tilbrook, D. Munro, D. Pierrot, G. Rehder, J. M. Santana-Casiano, J. D. Müller, J. Trinanes, K. Tedesco, K. O’Brien, K. Currie, L. Barbero, M. Telszewski, M. Hoppema, M. Ishii, M. González- Dávila, N. R. Bates, N. Metzl, P. Suntharalingam, R. A. Feely, S.-i. Nakaoka, S. K. Lauvset, T. Takahashi, T. Steinhoff and U. Schuster
  • 2. ➢ Purpose of surface water CO2 reference network ➢ How the network fits into a hierarchy of efforts under the aegis of Intergovernmental organization ➢ Development of products, example operations from cruise ships. Outline
  • 3. The Surface Ocean CO2 Reference Observing Network (SOCONET) is a volunteer group of established operators who provide sustained quality global surface ocean CO2 and atmospheric data from SOOP, ASV and moorings. SOCONET will tracks observations and data following established network principles. What is SOCONET ? SOCONET is a subset of a larger surface water CO2 observation campaign and part of a sustained ocean carbon observation effort (IOCOS-Richard Saunders lead)
  • 4. Why do we need SOCONET? quantify air-sea CO2 fluxes ➢ Mitigation of temperature increase and sealevel rise: ➢ Impact ecosystems- ocean acidification: ∆SST ≈ 0.5 ˚C ≈ 8 cm SLR ∆SST ≈0.6 ˚C = 93 ppm ∆SST ≈ 0.8 ˚C ≈ 14 cm =208 ppm ∆SST ≈ 1.9 ˚C ≈ 30 cm SLR www.epa.gov/climate-indicators 110 ppm/˚C; 15 cm/100 ppm ➢ Value- will the ocean sink be counted as a carbon credit: GCP, 2019 Without CO2 uptake by the ocean, global temperatures would be ≈ 0.5 ˚C warmer and sealevel ≈ 8 cm higher since 1960 Sequestration of CO2 produced by man has decreased pH by about 0.12 If the annual 2.5 Pg C of uptake by theocean CO2 was counted as a an “emission allowance” in the European Union (EU) emission trading scheme (ETS),it would have an annual value of 150 billion Euro
  • 6. The creation of products To sustain a network there must be regular and anticipated products Products require more input than “just” surface CO2 measurements
  • 7. Products Example of a regional timeseries: Northern Caribbean Sea, 2002-2019 Data gap since March 2020: COVID19 >620 cruises > 1.2 M observations (5 % of data in SOCAT
  • 8. From observations to data products Measurement fCO2w gridding Algorithm fCO2w = f(position, SST, SSS,MLD) Spatial interpolation
  • 9. From observations to data products A hierarchy of products from fCO2 observations to derived quantities (based on fCO2 and other observations, inorganic carbon thermodynamics and interpolation) The solid red lines are the leastsquares linear fit through all the fCO2w and SST data from 2002 to 2018. The black dashed lines are the fits from 2002 to 2010 and 2010 to 2018. For fCO2w the slopes are 1.30 ± 0.003; −1.37 ± 0.017; and 3.69 ± 0.011 μatm/year, respectively. For SST the slopes are −0.0080 ± 0.0003, −0.178 ± 0.002, and 0.1941 ± 0.001 °C/year, respectively. Observations Monthly Gridded Monthly mapped Temporal interpolation- the seasonal cycle in SST dominates variability
  • 10. Time series Aragonite saturation State (strongly correlated with shell and coral growth) fCO2w [µatm] WAr = f(TA, fCO2w, SST) Derived products
  • 11. Higher level products from regional time series Harmonic fit -18 years De-seasoned Attribution Long-term trends, deseasoning 18-year seasonal cycle Monthly fCO2w Residuals Correlation residuals fCO2w and SST Slope =12 µatm/ ˚C Thermodynamic =16 µatm/ ˚C
  • 12. Deconvolution of processes controlling long term trends Temperature: Red; Air sea gas fluxes: Blue “The rest” (biology and mixing) : Green
  • 13. Flux time series and global comparison The sum of regional magnitudes, variabilities and trends yield the global patterns Fluxes from the mapped product Greater interannual variability at regional scales than globally
  • 14. ➢ With sufficient observations and regional synoptic coverage of SST, MLD, SSS and wind, robust information can be obtained regarding, mean, variability and trends in carbon fluxes and surface ocean carbon products. ➢ This information will be important for monitoring the health of the ocean, and its ability to provide services. ➢ A coordinated and unified approach based on a firm sustained infrastructure is critical to continue to provide such information. Conclusions