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Utilization of Chloride Bearing
High Enthalpy Geothermal Fluid
Gudrun SAEVARSDOTTIR, Steindór HJARTARSON,
Kristinn INGASON, Bjarni PALSSON, William S.
HARVEY
Reykjavik University, Mannvit Engineering,
Landsvirkjun
GEORG Geothermal Workshop, November
2016
www.hr.is
The heat source - Magma
GEORG Geothermal Workshop, November
2016
www.hr.is
Fluid from Deep Roots of Geothermal systems
GEORG Geothermal Workshop, November
2016
www.hr.is
High enthalpy steam – superheated or SC?
GEORG Geothermal Workshop, November
2016
www.hr.is
Iceland Deep Drilling Project (IDDP)
• Purpose of IDDP:
– Drill deeper to obtain a higher enthalpy steam, preferably supercritical
• T>374 °C
• P>220 bar
– For supercritical drill a 5km deep well
• Why:
– Higher enthalpy and mass flow gives a more powerful well
• IDDP-1
– The first well, IDDP-1, 2.2 km deep
GEORG Geothermal Workshop, November
2016
www.hr.is
IDDP1 at Krafla, north Iceland
GEORG Geothermal Workshop, November
2016
www.hr.is
The wild well IDDP-1
• 12 hours after
opening:
– T=410°C,
P=40bar,
h=3150kJ/kg
• Chemicals in
the steam
– HCl, sulphur,
silica fumes
Tekið af http://georg.hi.is/files/IDDP%20-%20GOF.pdf þann 16.11.11
GEORG Geothermal Workshop, November
2016
www.hr.is
HCl in superheated steam a problem
• HCl dissolves in the first
droplets formed
• Potent hydrocloric acid
• Corrodes metal!
Must be scrubbed from the
steam before it enters
sensitive components
GEORG Geothermal Workshop, November
2016
www.hr.is
Silica fumes
• Fumes from IDDP
condensed as
amorphous silica
particles
• Formed as pressure
dropped below 80 bar
• Similar to industrial
microsilica particles
GEORG Geothermal Workshop, November
2016
www.hr.is
What can be done?
• Dry scrubbing
– Steam lead through a compound which will absorb HCl before it
enters the turbine
• Wel schrubbing
– NaOH or another base sprayed into the steam to dissolve the HCl
• Binary Cycle
– Heat transferred into a binary cycle through a heat exchanger
In any case, the power plant must be designed with
regard to the gas treatment configuration.
GEORG Geothermal Workshop, November
2016
www.hr.is
Wet scrubbing - 1
Chemicals: NaOH
GEORG Geothermal Workshop, November
2016
www.hr.is
Wet scrubbing - 2
GEORG Geothermal Workshop, November
2016
www.hr.is
Wet scrubbing - 3
GEORG Geothermal Workshop, November
2016
www.hr.is
Dry Scrubbing
Chemicals: K2CO3,Ca(OH)2, NaHCO3, CaCO3GEORG Geothermal Workshop, November
2016
www.hr.is
Binary cycle
GEORG Geothermal Workshop, November
2016
www.hr.is
Mass Flow Rate
GEORG Geothermal Workshop, November
2016
www.hr.is
Thermodynamic efficiency as a
function of well head pressure
GEORG Geothermal Workshop, November
2016
www.hr.is
Output as a function of well head pressure
GEORG Geothermal Workshop, November
2016
www.hr.is
Wet scrubbing - 2
GEORG Geothermal Workshop, November
2016
www.hr.is
Er í lagi að ég komi við hjá þér á
morgun í staðinn fyrir í dag?
Er í lagi að ég komi við hjá þér á
morgun í staðinn fyrir í dag?
TTHANK YOU FOR YOUR ATTENTIONGEORG Geothermal Workshop, November
2016

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B1 Guðrún A. Sævarsdóttir Utilization of the Chloride Bearing, Superheated Steam from IDDP-1

  • 1. www.hr.is Utilization of Chloride Bearing High Enthalpy Geothermal Fluid Gudrun SAEVARSDOTTIR, Steindór HJARTARSON, Kristinn INGASON, Bjarni PALSSON, William S. HARVEY Reykjavik University, Mannvit Engineering, Landsvirkjun GEORG Geothermal Workshop, November 2016
  • 2. www.hr.is The heat source - Magma GEORG Geothermal Workshop, November 2016
  • 3. www.hr.is Fluid from Deep Roots of Geothermal systems GEORG Geothermal Workshop, November 2016
  • 4. www.hr.is High enthalpy steam – superheated or SC? GEORG Geothermal Workshop, November 2016
  • 5. www.hr.is Iceland Deep Drilling Project (IDDP) • Purpose of IDDP: – Drill deeper to obtain a higher enthalpy steam, preferably supercritical • T>374 °C • P>220 bar – For supercritical drill a 5km deep well • Why: – Higher enthalpy and mass flow gives a more powerful well • IDDP-1 – The first well, IDDP-1, 2.2 km deep GEORG Geothermal Workshop, November 2016
  • 6. www.hr.is IDDP1 at Krafla, north Iceland GEORG Geothermal Workshop, November 2016
  • 7. www.hr.is The wild well IDDP-1 • 12 hours after opening: – T=410°C, P=40bar, h=3150kJ/kg • Chemicals in the steam – HCl, sulphur, silica fumes Tekið af http://georg.hi.is/files/IDDP%20-%20GOF.pdf þann 16.11.11 GEORG Geothermal Workshop, November 2016
  • 8. www.hr.is HCl in superheated steam a problem • HCl dissolves in the first droplets formed • Potent hydrocloric acid • Corrodes metal! Must be scrubbed from the steam before it enters sensitive components GEORG Geothermal Workshop, November 2016
  • 9. www.hr.is Silica fumes • Fumes from IDDP condensed as amorphous silica particles • Formed as pressure dropped below 80 bar • Similar to industrial microsilica particles GEORG Geothermal Workshop, November 2016
  • 10. www.hr.is What can be done? • Dry scrubbing – Steam lead through a compound which will absorb HCl before it enters the turbine • Wel schrubbing – NaOH or another base sprayed into the steam to dissolve the HCl • Binary Cycle – Heat transferred into a binary cycle through a heat exchanger In any case, the power plant must be designed with regard to the gas treatment configuration. GEORG Geothermal Workshop, November 2016
  • 11. www.hr.is Wet scrubbing - 1 Chemicals: NaOH GEORG Geothermal Workshop, November 2016
  • 12. www.hr.is Wet scrubbing - 2 GEORG Geothermal Workshop, November 2016
  • 13. www.hr.is Wet scrubbing - 3 GEORG Geothermal Workshop, November 2016
  • 14. www.hr.is Dry Scrubbing Chemicals: K2CO3,Ca(OH)2, NaHCO3, CaCO3GEORG Geothermal Workshop, November 2016
  • 15. www.hr.is Binary cycle GEORG Geothermal Workshop, November 2016
  • 16. www.hr.is Mass Flow Rate GEORG Geothermal Workshop, November 2016
  • 17. www.hr.is Thermodynamic efficiency as a function of well head pressure GEORG Geothermal Workshop, November 2016
  • 18. www.hr.is Output as a function of well head pressure GEORG Geothermal Workshop, November 2016
  • 19. www.hr.is Wet scrubbing - 2 GEORG Geothermal Workshop, November 2016
  • 20. www.hr.is Er í lagi að ég komi við hjá þér á morgun í staðinn fyrir í dag? Er í lagi að ég komi við hjá þér á morgun í staðinn fyrir í dag? TTHANK YOU FOR YOUR ATTENTIONGEORG Geothermal Workshop, November 2016

Editor's Notes

  1. K2CO3 – Potassium Carbonate Ca(OH)2 – Calcium Hydroxide NaHCO3 - Sodium bicarbonate CaCO3 – Calcium carbonate