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LNG Basics
for Petroleum Engineers
Michael Choi
1
Retired
Primary funding is provided by
The SPE Foundation through member donations
and a contribution from Offshore Europe
The Society is grateful to those companies that allow their
professionals to serve as lecturers
Additional support provided by AIME
Society of Petroleum Engineers
Distinguished Lecturer Program
www.spe.org/dl
2
Present an Overview of LNG Plant
Oman LNG Plant
• Why LNG?
• Pre-Treatment Required
• Typical Multi-Trains Plant
• Natural Gas Liquefaction
Thermodynamics
• Commercial Liquefaction
Processes
• Equipment for Liquefaction
• Unique Auxiliary Facilities
• Novel Plant Concepts
• Concluding Remarks
3
Stranded Gas Looking for Markets
• LNG Proved to be Most Economic for Distances >1,500 Mile
• Volume Reduction of 600:1
• Transported in Insulated Tankers @ -162C & 1 atm.
4
Supply
Demand
LNG Process & Equipment ?
• Compressor/Driver
• Refrigerant Condenser
• Evaporator (Process
Heat Exchanger)
Big Refrigeration System
Similar to the AC System
in Our Home!
5
Inlet Gas
Reception
Condensate
Stabilization
Inlet Gas
Treating
NGL
Recovery
Liquefaction
NGL
Fractionation
LNG Storage
Fuel
Propane
Storage
Butane
Storage
Condensate
Storage
Make-
Up Fuel
LNG
Propane
Butane
Condensate
Typical 2-Train LNG Plant
Gas
Liquid
Gas
Gathering
Train 2
8 Mtpa
(1.1 Bcfd)
.73 Mtpa
(17 Mbpd)
(34 Mbpd)
(27 Mbpd)
.5 Mtpa
1.2 Mtpa
Train 1
1.5 Bcfd
6
Inlet Gas
Reception
Condensate
Stabilization
Inlet Gas
Treating
NGL
Recovery
Liquefaction
NGL
Fractionation
LNG Storage
Fuel
Propane
Storage
Butane
Storage
Condensate
Storage
Make-
Up Fuel
LNG
Propane
Butane
Condensate
Typical 2-Train LNG Plant
Gas
Liquid
Gas
Gathering
Train 2
9 Mtpa
(1.2 Bcfd)
.73 Mtpa
(17 Mbpd)
(34 Mbpd)
(27 Mbpd)
.5 Mtpa
1.2 Mtpa
Train 1
1.7 Bcfd
Inlet Gas Reception
• Pipeline Manifold
• Pig Receivers
• Inlet Separator
• Slug Catcher
Condensate Stabilization
• Multi-Stage Column
• Vapor Compressor
• 10-12 psia RVP
• De-Odorized
7
Inlet Gas Treating
• Amine for CO2 & H2S Removal
• <50 ppm & < 4 ppm
• Sulfur Recovery Unit if H2S
• Mol Sieve Dehydration*
• < 100 ppb
• Mercury Vapor Removal*
• Activated Carbon Adsorber
NGL Recovery
• Scrub Column/KO after C3 Pre-Cool
• Primarily C4+ to Prevent Freezing
• LNG Heat Value Important for US &
European Markets
• 1,070 btu/scf Max
• Need Turbo-Expander for High
C3+ Removal
NGL Fractionation
• Deethanizer
• Vapor Compression
• Depropanizer & Treating
• 95% & 200 psig VP
• <.5ppm H2S & <15ppm S
• Debutanizer & Treating
• 95% & 70 psig VP @100F
• <.5ppm H2S & <15ppm S
180,000 M3 LNG Tank
• Full-Containment Tank to Reduce
Impound Area & Improve Safety
• Approx. 75M Dia x 40M H
• Insulated for <.05%/D of Boil-off
• Top Entry In-Tank Pumps
• Total Capacity Based on
Tanker Size (135,000 M3)
• Plus 4+ Days Production
8
Inside the Tanks
Single-Stage Multi-Stage
Tank with Pump Caissons
9
LNG Loading System
• 16” Chiksan Type
• 3+1 – LNG Arms
• 3,500 M3/Hr/Ea.
• 10,500 M3/Hr
• 140K M3 Tanker
• 4+1 – Systems
• 14,000 M3/Hr
• Qmax & Qflex
• 200K+ M3
• 1 – Vapor Return
10
Cost of Refrigeration
Cost/Btu
Removed
-162C 25C
Temperature
Air/Water
Propane
Ethylene
Methane
or Nitrogen
11
Natural Gas Liquefaction Processes
Temperature
-162C
25C
H (Enthalpy - Heat Removed)
Gas Cooling
Condensation
Liquid
Sub-cooling
Min. DT
12
Cascade LNG Process
• Most Straight Forward of All Processes
• Kenai Plant Continuous Operation 1969
• CoP License, Plant Build by Bechtel
Kenai, Alaska
Temperature
-260F
80F
H (Enthalpy - Heat Removed)
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
1st Stage
2nd Stage
Methane Refrig. .
CoP Optimized
Cascade Refrigerant Cycle
Temperature
-260F
80F
H (Enthalpy - Heat Removed)
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
1st Stage
2nd Stage
.
CoP Optimized
Cascade Refrigerant Cycle
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
EthyleneRefrig
1st Stage
2nd Stage
.
CoP Optimized
Cascade Refrigerant Cycle
1st Stage
2nd Stage
3th Stage
13
C3 Precooled – Mixed Refrigerant Process
Temperature
-260F
80F
H (Enthalpy - Heat Removed)
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
Mixed Refrigerant
Propane PreCooled
Mixed Refrigerant Cycle
Temperature
-260F
80F
H (Enthalpy - Heat Removed)
Temperature
-260F
80F
H (Enthalpy - Heat Removed)
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
Mixed Refrigerant
Propane PreCooled
Mixed Refrigerant Cycle
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
Propane
Refrig.
1st Stage
2nd Stage
3th Stage
Mixed Refrigerant
Propane PreCooled
Mixed Refrigerant Cycle
• Most Widely Used Licensed by APCI
• 1st Plant in Algeria Operating Since 1972
• Plants Built by KBR, Chiyoda, JGC, FW
QatarGas LNG Plant
14
APCI AP-X Process
• Largest Train Capacity @ 8 Mtpa
• Overcome Spiral Wound MCHE Limit
• First Unit Started in 2009 (QG-II)
• No Plants Outside of Qatar
• Process Design
• Cold Boxes
• Spiral Wound Exchanger
• Turbo-Expanders
APCI Supplies
15
All Processes Use Similar Equipment
• Most New Plants Use Large Gas Turbine (& Combined
Cycle) to Drive Refrigerant Compressors
• Some Older & Smaller Trains Have Steam Turbine Drives
• Many Peak Shaving Plants on Electric Drives
• Use Large Process Type Centrifugal Compressors
GE MS7001 FB Gas Turbine
• Main Difference is in the Cryogenic Heat Exchangers
16
Main Cryogenic Heat Exchanger
Use by Mixed Refrigerant Process
Air Products & Chemicals
& Linde: Spiral Wound Ex.
• Max. Diameter: 5,030mm
• Height: ~55m
• Stainless Steel Core
• 25mm Aluminum Tubing
• Externally Insulated
• Chill & Liquefy Gas
– From –34ºC to –152ºC
– At 55 to 69 Barg
17
APCI’s MR Main Cryogenic Heat Exchanger (MCHE)
Spiral Wound Design
18
Cold Box Configuration
Heat Exchanger for Cascade Process
• Many Manufacturers
• Use Extensively in Air Separation
• Cascade & Other LNG Processes
Plate Fin
Exchanger
19
Advances in LNG Plants
Near-shore
GBS Design
Onshore
Conventional Design
Offshore
Steel or Concrete
Floater
20
21
FLNG is about to be Reality
Shell Prelude
•Floated out of dry dock in
Dec. 2013
•3.6 mtpa of LNG capacity
•Start-up expected in 2016
Petronas Kanowit
•EPC in progress
•1.2 mtpa of LNG Capacity
•Scheduled for deployment
in 2015 ?
Conclusions
• LNG Liquefaction Process Same as AC System in Our Home
• Pre-Treatment Facilities Can Dwarf Liquefaction System
– Mole Sieve Dehydration & Mercury Removal Required
– Gas Treating & NGL Extraction May be Needed
– Stabilized Condensate & Fractionated NGL Add Value
• LNG Exchangers, Storage & Loading Systems Are Unique
• Commercial Liquefaction Processes Well Proven, Robust & Can
be Optimized for Plant Size, Gas Composition, Sales &
Commercial Needs
• Novel Near-Shore & Offshore Floating Concepts Are Developed
22
LNG ?
23
Society of Petroleum Engineers
Distinguished Lecturer Program
www.spe.org/dl 24
Your Feedback is Important
Enter your section in the DL Evaluation Contest by completing the
evaluation form for this presentation
Visit SPE.org/dl

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Choi.ppt

  • 1. LNG Basics for Petroleum Engineers Michael Choi 1 Retired
  • 2. Primary funding is provided by The SPE Foundation through member donations and a contribution from Offshore Europe The Society is grateful to those companies that allow their professionals to serve as lecturers Additional support provided by AIME Society of Petroleum Engineers Distinguished Lecturer Program www.spe.org/dl 2
  • 3. Present an Overview of LNG Plant Oman LNG Plant • Why LNG? • Pre-Treatment Required • Typical Multi-Trains Plant • Natural Gas Liquefaction Thermodynamics • Commercial Liquefaction Processes • Equipment for Liquefaction • Unique Auxiliary Facilities • Novel Plant Concepts • Concluding Remarks 3
  • 4. Stranded Gas Looking for Markets • LNG Proved to be Most Economic for Distances >1,500 Mile • Volume Reduction of 600:1 • Transported in Insulated Tankers @ -162C & 1 atm. 4 Supply Demand
  • 5. LNG Process & Equipment ? • Compressor/Driver • Refrigerant Condenser • Evaporator (Process Heat Exchanger) Big Refrigeration System Similar to the AC System in Our Home! 5
  • 6. Inlet Gas Reception Condensate Stabilization Inlet Gas Treating NGL Recovery Liquefaction NGL Fractionation LNG Storage Fuel Propane Storage Butane Storage Condensate Storage Make- Up Fuel LNG Propane Butane Condensate Typical 2-Train LNG Plant Gas Liquid Gas Gathering Train 2 8 Mtpa (1.1 Bcfd) .73 Mtpa (17 Mbpd) (34 Mbpd) (27 Mbpd) .5 Mtpa 1.2 Mtpa Train 1 1.5 Bcfd 6
  • 7. Inlet Gas Reception Condensate Stabilization Inlet Gas Treating NGL Recovery Liquefaction NGL Fractionation LNG Storage Fuel Propane Storage Butane Storage Condensate Storage Make- Up Fuel LNG Propane Butane Condensate Typical 2-Train LNG Plant Gas Liquid Gas Gathering Train 2 9 Mtpa (1.2 Bcfd) .73 Mtpa (17 Mbpd) (34 Mbpd) (27 Mbpd) .5 Mtpa 1.2 Mtpa Train 1 1.7 Bcfd Inlet Gas Reception • Pipeline Manifold • Pig Receivers • Inlet Separator • Slug Catcher Condensate Stabilization • Multi-Stage Column • Vapor Compressor • 10-12 psia RVP • De-Odorized 7 Inlet Gas Treating • Amine for CO2 & H2S Removal • <50 ppm & < 4 ppm • Sulfur Recovery Unit if H2S • Mol Sieve Dehydration* • < 100 ppb • Mercury Vapor Removal* • Activated Carbon Adsorber NGL Recovery • Scrub Column/KO after C3 Pre-Cool • Primarily C4+ to Prevent Freezing • LNG Heat Value Important for US & European Markets • 1,070 btu/scf Max • Need Turbo-Expander for High C3+ Removal NGL Fractionation • Deethanizer • Vapor Compression • Depropanizer & Treating • 95% & 200 psig VP • <.5ppm H2S & <15ppm S • Debutanizer & Treating • 95% & 70 psig VP @100F • <.5ppm H2S & <15ppm S
  • 8. 180,000 M3 LNG Tank • Full-Containment Tank to Reduce Impound Area & Improve Safety • Approx. 75M Dia x 40M H • Insulated for <.05%/D of Boil-off • Top Entry In-Tank Pumps • Total Capacity Based on Tanker Size (135,000 M3) • Plus 4+ Days Production 8
  • 9. Inside the Tanks Single-Stage Multi-Stage Tank with Pump Caissons 9
  • 10. LNG Loading System • 16” Chiksan Type • 3+1 – LNG Arms • 3,500 M3/Hr/Ea. • 10,500 M3/Hr • 140K M3 Tanker • 4+1 – Systems • 14,000 M3/Hr • Qmax & Qflex • 200K+ M3 • 1 – Vapor Return 10
  • 11. Cost of Refrigeration Cost/Btu Removed -162C 25C Temperature Air/Water Propane Ethylene Methane or Nitrogen 11
  • 12. Natural Gas Liquefaction Processes Temperature -162C 25C H (Enthalpy - Heat Removed) Gas Cooling Condensation Liquid Sub-cooling Min. DT 12
  • 13. Cascade LNG Process • Most Straight Forward of All Processes • Kenai Plant Continuous Operation 1969 • CoP License, Plant Build by Bechtel Kenai, Alaska Temperature -260F 80F H (Enthalpy - Heat Removed) Propane Refrig. 1st Stage 2nd Stage 3th Stage 1st Stage 2nd Stage Methane Refrig. . CoP Optimized Cascade Refrigerant Cycle Temperature -260F 80F H (Enthalpy - Heat Removed) Propane Refrig. 1st Stage 2nd Stage 3th Stage 1st Stage 2nd Stage . CoP Optimized Cascade Refrigerant Cycle Propane Refrig. 1st Stage 2nd Stage 3th Stage Propane Refrig. 1st Stage 2nd Stage 3th Stage EthyleneRefrig 1st Stage 2nd Stage . CoP Optimized Cascade Refrigerant Cycle 1st Stage 2nd Stage 3th Stage 13
  • 14. C3 Precooled – Mixed Refrigerant Process Temperature -260F 80F H (Enthalpy - Heat Removed) Propane Refrig. 1st Stage 2nd Stage 3th Stage Mixed Refrigerant Propane PreCooled Mixed Refrigerant Cycle Temperature -260F 80F H (Enthalpy - Heat Removed) Temperature -260F 80F H (Enthalpy - Heat Removed) Propane Refrig. 1st Stage 2nd Stage 3th Stage Mixed Refrigerant Propane PreCooled Mixed Refrigerant Cycle Propane Refrig. 1st Stage 2nd Stage 3th Stage Propane Refrig. 1st Stage 2nd Stage 3th Stage Mixed Refrigerant Propane PreCooled Mixed Refrigerant Cycle • Most Widely Used Licensed by APCI • 1st Plant in Algeria Operating Since 1972 • Plants Built by KBR, Chiyoda, JGC, FW QatarGas LNG Plant 14
  • 15. APCI AP-X Process • Largest Train Capacity @ 8 Mtpa • Overcome Spiral Wound MCHE Limit • First Unit Started in 2009 (QG-II) • No Plants Outside of Qatar • Process Design • Cold Boxes • Spiral Wound Exchanger • Turbo-Expanders APCI Supplies 15
  • 16. All Processes Use Similar Equipment • Most New Plants Use Large Gas Turbine (& Combined Cycle) to Drive Refrigerant Compressors • Some Older & Smaller Trains Have Steam Turbine Drives • Many Peak Shaving Plants on Electric Drives • Use Large Process Type Centrifugal Compressors GE MS7001 FB Gas Turbine • Main Difference is in the Cryogenic Heat Exchangers 16
  • 17. Main Cryogenic Heat Exchanger Use by Mixed Refrigerant Process Air Products & Chemicals & Linde: Spiral Wound Ex. • Max. Diameter: 5,030mm • Height: ~55m • Stainless Steel Core • 25mm Aluminum Tubing • Externally Insulated • Chill & Liquefy Gas – From –34ºC to –152ºC – At 55 to 69 Barg 17
  • 18. APCI’s MR Main Cryogenic Heat Exchanger (MCHE) Spiral Wound Design 18
  • 19. Cold Box Configuration Heat Exchanger for Cascade Process • Many Manufacturers • Use Extensively in Air Separation • Cascade & Other LNG Processes Plate Fin Exchanger 19
  • 20. Advances in LNG Plants Near-shore GBS Design Onshore Conventional Design Offshore Steel or Concrete Floater 20
  • 21. 21 FLNG is about to be Reality Shell Prelude •Floated out of dry dock in Dec. 2013 •3.6 mtpa of LNG capacity •Start-up expected in 2016 Petronas Kanowit •EPC in progress •1.2 mtpa of LNG Capacity •Scheduled for deployment in 2015 ?
  • 22. Conclusions • LNG Liquefaction Process Same as AC System in Our Home • Pre-Treatment Facilities Can Dwarf Liquefaction System – Mole Sieve Dehydration & Mercury Removal Required – Gas Treating & NGL Extraction May be Needed – Stabilized Condensate & Fractionated NGL Add Value • LNG Exchangers, Storage & Loading Systems Are Unique • Commercial Liquefaction Processes Well Proven, Robust & Can be Optimized for Plant Size, Gas Composition, Sales & Commercial Needs • Novel Near-Shore & Offshore Floating Concepts Are Developed 22
  • 24. Society of Petroleum Engineers Distinguished Lecturer Program www.spe.org/dl 24 Your Feedback is Important Enter your section in the DL Evaluation Contest by completing the evaluation form for this presentation Visit SPE.org/dl