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David Peterson, Ph.D.
The MoDa Group and Director, Samara Ancient Metals Project
Eurasia Before the Golden Age
Metal Technology and Metal Networks, ca. 3000-1500 BC
	
AIA, Minnesota Society and Macalester College
September 24, 2015
structure									+						composi-on
Source: http://thehistoryofeuropepodcast.blogspot.com/2012/06/incredible-khvalynsk-culture-of-lower.html
Khvalynsk
Khvalynsk	Cemetery	Eneolithic,	5000-4500	BCE
circumpon-c	metallurgical	province	
P r o v i n c e
Metallurgical
Focus
Metalworking
Focus
Metalworking
Focus
Metallurgical
Focus
Metallurgical
Focus
Eurasian Steppe ZoneCaucasus Zone
Metallurgical
Focus
Metalworking
Focus
Metalworking
Focus
Metallurgical
Focus
Metallurgical
Focus
Province
ca.	3500-2000	BC	(E.	N.	Chernykh	1992)	
Caspian	Sea	
.	Samara
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology	
lead	isotopes		
T.	Stöllner,	et	al.	Anatolian	Metal	V	(2011)
arc	OES	studies	of	copper	and	bronze	from	the	
Eurasian	steppes		
E.	N.	Chernykh	(1970,	1992);	Chernykh	and	Kuzminykh	(1987)	
cri-que	of	method		
M.	Pollard,	C.	BaS,	B.	Stearn,	and	S.	Young,	Analy/cal	Chemistry	in	
Archaeology	
lead	isotopes		
T.	Stöllner,	et	al.	Anatolian	Metal	V	(2011)	
used	in	recent	major	syntheses	
2	published	by	CUP	(both	in	2007),	1	by	U	of	CA	(2008)
Kamyshla	sites			Samara,	Russia,	15th	century	BCE
Samara	Valley	Project	
The	Samara	Valley	Project:		A	Bronze	Age	Landscape	in	the	Russian	
Steppes,	edited	by	D.	Anthony,	D.	Brown,	A.	Khokhlov,	P.	Kuznetsov,	
and	O.	Mochalov.	Los	Angeles:	Cotsen	Ins-tute	of	Archaeology,	
UCLA.
‘Moonscape’	of	ancient	mine	pits																									Excavated	copper	mine	shad	
Kargaly	complex			Orenburg,	Russia
Dri&	mine	in	Kargaly			ca.	1800-1400	BCE	
																												
Drid	mine	at	Kargaly			ca.	1800-1400	BC
samples	
removed	by	hand	with	jeweler’s	
saw,	mounted	in	bakelite,	ground	
and	polished		
•  samples	are	preserved	
•  analysis	is	repeatable	
•  the	same	samples	are	used	for	
electron	microprobe,	
metallography,	SEM-EDS,	and	
nanoSIMS	
16	elements	were	analyzed	by	electron	microprobe	wavelength-	
dispersive	spectrometry	(WDS),	200	ppm	resolu-on:	
•  iron	
•  cobalt	
•  nickel	
•  copper	
•  zinc	
•  arsenic	
•  an-mony	
•  -n	
•  sulfur	
•  aluminum	
•  silicon	
•  manganese	
•  silver	
•  bismuth	
•  lead	
•  gold
cm
metalworking
casting
annealing
forging
ingot
object
process
product /
by-product
slag
mining
ore processing
sorting
crushing
roasting
smelting
ore
ore
alloying
recycling
splash
scrap
co-smelting
metallurgical	
cycle:	
processes	
and	products
metalworking
casting
annealing
forging
ingot
object
process
product /
by-product
slag
mining
ore processing
sorting
crushing
roasting
smelting
ore
ore
alloying
recycling
splash
scrap
co-smelting
metallurgical	
cycle:	
processes	
and	products	
recycling
Utevka	VI	kurgan	cemetery			ca.	2000	BC	
kurgan	6,	grave	6	
Kurgan	6
arsenic	values			electron	microprobe	results												
metalwork	from	burial	assemblages	(Samara,	Russia,	3rd	and	2nd	
millennium	BCE)
iron	and	
an-mony	
electron	microprobe	
results	
	
metalwork	from	burials	in	
the	Utevka	VI	and	
Potapovka	I	kurgan	
cemeteries	(Samara,	
Russia)
Potapovka	I	
Utevka	VI	
Samara	R.		
Volga	R.
work	paSern	2	
worked	+	annealed	+	light-moderate	
cold	work	(hammering)	
work	paSern	3	
worked	+	annealed	+	heavy	cold	work	
	
chisel,	Utevka	VI,	kurgan	6,	grave	6	 knife,	Utevka	VI,	kurgan	6,	grave	6	
	
	
	
chisel
0
5
10
15
20
25
Potapovka I Utevka VI
WP 2
WP 3
21	
12	
16	
9	
comparison	of	work	paSerns			copper	and	
bronze	metalwork	from	Potapovka	I	and	Utevka	VI
Nizhnyaya	Orlyanka	
Spiridonovka	II	 Samara	R.		
Volga	R.		
Potapovka	I	
Utevka	VI
electrum	foil-covered	
pendants			from	Early	
Srubnaya-Pokrovka	kurgan	
burials																									
Middle	Volga,	ca.	1850-1700	BCE	
Spiridonovka	II	
Nizhnyaya		
Orlyanka
electron	microprobe	results*	
foil-covered	pendants,	Nizhnyaya	Orlyanka	and	Spiridonovka	II	
gold	content	is	over	20x	greater	near	the	surface	
*Dr.	Peter	Northover	and	Dr.	Chris	Salter	
Department	of	Materials,	Oxford	University
the	SEM	image	shows	that	the	gold-
silver	crystal	structure	goes	to	surface	
gold	enrichment	was	not	caused	
by	adding	a	new	layer	of	gold	to	
outside	of	the	foil	
gold	enrichment	was	caused	by	
removing	silver	from	the	surface	
of	the	foil	to	a	depth	of	5μm		
Spiridonovka	II	pendant		DP94				
backscaSer	SEM	image
nanoSIMS	
map	of	foil*	
Spiridonovka	II	
pendant	
	
											
										gold	
										silver	
										copper	
*Dr.	Zihua	Zhu,	EMSL	(DoE),	Richland,	WA	
ca.	7	μm		
there	is	no	
diffusion	
bond	
there	is	overlap	
between	gold-	
and	silver-
enriched	zones	
	
this	supports	the	
hypothesis	of	
deple-on	gilding
Gold-covered	ornaments	from	other	
LBA		kurgan	graves	in	the	Middle	
Volga	(untested)	
ancient	deple-on	
gilding	
	
Andes									H.	Lechtman	(1973)	The	
Gilding	of	Metals	in	Pre-Columbian	
Peru.	Applica/on	of	Science	in	
Examina/on	of	Works	of	Art	(W.	
Young,	ed.),	pp.	38-52		
Mesopotamia						S.	La	Niece	(1995)	
Deple-on	Gilding	from	Third	
Millennium	BC	Ur.	Iraq	57:	41-47	
		A.	Hauptmann	et	al.	(2010)	Gold	
from	the	Royal	Tombs	of	Ur,	2600	
BC:	Gilding	Techniques,	Tumbaga	
Alloys,	Deple-on	Gilding	–	on	the	
Use	of	a	Hand-Held	XRF	
Spectrometer.	Metalla	SonderheH	
3:	57-59
Badakhshan
Royal Cemetery of Ur
ca. 2600 BC
Samara
Samara, ca. 1800 BC
was	the	deple-on	gilding	technique	
transferred	along	the	same	routes	as	lapis?
‘pearls’
DP88
DP89
‘pearls’
DP88
DP89
Kutuluk	I	
EBA	(Yamnaya),		
ca.	1950	BCE
Inventory from Sintashta
grave 30
Reconstruction of the Arkaim Settlement
Sintashta	paSern	MBA	II,	ca.	2100-1800	BCE
Funding	
² Wenner-Gren	Founda-on	
² Na-onal	Science	Founda-on	
² Office	of	Research,	Faculty	Research																																																																	
CommiSee,	Humani-es	and	Social	Sciences																																																								
Research	CommiSee,	and	College	of	Art	&	LeSers,	Idaho	State	University	
Research	Centers	and	Ins2tutes	
² Environmental	Molecular	Sciences	Laboratory	(Richland,	Washington)	
² Ins-tute	for	the	History	and	Archaeology	of	the	Volga	(Samara,	Russia)		
² Center	for	Archaeology,	Materials	and	Applied	Spectroscopy,	Idaho	State	
University	
Students	and	Colleagues	from	
² University	of	Chicago	
² Hartwick	College	
te  University’s  
ch  pixel  in  the  
t  pa ern.  Sig-­‐
  in  Fig.  4.  The  
of  silver  in  the  
.  4,  right)  also  
.  Gold  enrich-­‐
d  on  to  it  as  is  
the  par cipa on  Ur  and  the  Bronze  Age  steppes  in  networks  for  the  distribu on  of  lapis  lazuli  [3]  suggest  
that  knowledge  of  this  technique  may  have  traveled  the  prehistoric  Silk  Road  with  early  luxuries.  Deple on  
gilding  implies  the  associa on  of  gold  with  beauty  and  greater  value  than  the  other  metals  that  were  re-­‐
moved  and  hidden  below  the  surface  of  the  object.  It  was  2000  years  before  technology  for  "gilding  the  
lily"—giving  the  surface  of  a  rare  and  valuable  material,  electrum,  a  more  golden  color—was  used  to  refine  
gold.  If  gold  was  so  valuable,  why  did  it  take  so  long  for  this  shi   to  occur?  The  uses  of  gold  went  beyond  
the  desire  to  acquire  more  of  the  precious  material.  Gold  refinement  produces  a  color  change  and  a  loss  of  
mass  from  the  removal  of  silver.  The  manipula on  of  electrum  for  bodily  adornment  in  the  Spiridonovka  II  
pendant  would  have  been  made  more  difficult  by  purifica on;  removal  of  all  of  the  silver  would  have  result-­‐
ed  in  loss  of  95%  of  a  scarce  material  that  was  already  worked  into  a  very  thin  foil.  The  mo va on  for  re-­‐
finement  was  not  adornment,  but  control  of  the  composi on  of  the  material  itself.  Analysis  of  the  earliest  
Lydian  coins  shows  that  slightly  before  refinement  was  introduced,  electrum  was  struck  into  coins  of  regular  
weight  and  form  as  assurance  of  redeemability  by  the  Lydian  state  [12].  Faith  in  this  new  medium  for  mar-­‐
ket  interac ons,  tax,  and  tribute  was  tested  in  its  early  years,  crea ng  a  greater  need  to  control  the  make-
up  of  official  currency  and  to  sustain  permanent  shops  [13].  Size  and  weight  were  not  enough.  The  ideal  be-­‐
came  a  pure  material  that  remained  as  a  commodity  itself  when  faith  in  coin  and  state  was  challenged.
ONGOING  RESEARCH
Iden fica on  of  deple on  gilding  during  the  Bronze  Age  in  the  Volga-Ural  steppes  has  led  to  the  ques on  of  
how  widespread  these  techniques  were  in  the  prehistory  of  the  surrounding  region.  Peterson  will  travel  to  
Kazakhstan  to  collect  samples  from  Bronze  and  Iron  Age  contexts  in  May  2013  for  new  analyses.      
ck  and  white  
vka  II  pendant  
foil
,          
g)                                                          
ACKNOWLEDGMENTS
A  por on  of  the  research  was  performed  using  EMSL,  a  na onal  scien fic  user  facility  sponsored  by  the  Department  of  Energy’s  office  of  Biological  and  Environmental  Research  and  locat-­‐
ed  at  Pacific  Northwest  Na onal  Laboratory.  Acquisi on  of  the  samples  was  facilitated  by  Peterson’s  par cipa on  in  the  Samara  Valley  Project  (Dr.  David  Anthony,  PI),  and  collec on  of  
new  samples  in  Kazakhstan  will  be  done  in  coordina on  with  the  Tuzusai  project  directed  by  Dr.  Claudia  Chang  (Sweet  Briar  College.    EPMA  was  performed  at  Oxford  Materials  by  Dr.  Pe-­‐
ter  Northover  and  Dr.  Chris  Salter,  with  assistance  from  Dr.  Blanca  Maldonado.  Funding  was  provided  by  the  Wenner-Gren  Founda on  for  Anthropological  Research  through  Individual  Re-­‐
search  Grant  6760.  This  material  is  based  upon  work  supported  by  the  Na onal  Science  Founda on  under  Grant  No.  0431940.  Any  opinions,  findings,  and  conclusions  or  recommenda-­‐
ons  expressed  in  this  material  are  those  of  the  authors  and  do  not  necessarily  reflect  the  views  of  the  Na onal  Science  Founda on.  This  work  was  also  partly  supported  by  the  Na onal  
Science  Founda on  under  Grant  No.  BSC  0821783,  PHY  0852060,  and  the  Office  of  Research  and  College  of  Arts  and  Le ers,  Idaho  State  University.  
  III:  67-77.  
the  Altai  Moun-­‐
i  Kul’tury  v  Samar-­‐
-60.
93-97.  
D.  disserta on,  Uni-­‐
Boston,  pp.  38-52.
² Samara	State	Pedagogical	
University	
² 	Oxford	Materials	
² 	Idaho	State	University

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AIA Presentation 2015