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PRESENTATION ON
SYNTHESIS AND CHARACTERIZATION OF
COPPER OXIDE NANOMATERIAL
SUBMITTED TO;
DR. NAVIN CHAURASIA
(ASSISTANT PROFESSOR)
MECHANICAL ENGINEERING
DEPARTMENT, UNSIET, VBSPU
SUBMITTED BY;
SHIKHAR SINGH(195141)
CHANDRA KANT SHUKLA(195122)
SHUBHAM GUPTA(195120)
NITESH YADAV(2085164)
B.TECH.(ME) 8TH SEM.
2
INTRODUCTION SYNTHESIS CHARACTERISATION
ENGINEERING
APPLICATION REFERENCE
23-08-2023
23-08-2023 3
• NANO MATERIALS:
• Nanomaterials refer to materials that have been make at the nanoscale,
typically with dimensions ranging from 1 to 100 nanometers (nm). At this
scale, materials shows unique physical, chemical, and biological properties.
These properties grow due to the increased surface area-to-volume ratio,
quantum effects, and size-dependent phenomena.
• COPPER OXIDE:
• Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A
black solid, it is one of the two stable oxides of copper, the other being Cu2O
or copper(I) oxide (cuprous oxide).
INTRODUCTION:
4
23-08-2023
23-08-2023 5
6
23-08-2023
23-08-2023 7
SYNTHESIS:
• In general, the term synthesis related to the creation of something. It is the process of combining two or
more components to produce a substance.
• METHOD OF SYNTHESIS:
1. TOP-DOWN METHOD:
 Ball Milling Method
 Cutting Method
 Grinding Method
2. BOTTOM-UP METHOD:
• Sol- gel Method
• Sono Chemical Precipitation Method
• Thermal Decomposition Method
8
23-08-2023
23-08-2023 9
• MATERIAL REQUIRED:
• Copper (II) Nitrate Trihydrate (Cu(NO3)2.3H2O)
• Sodium Hydroxide (NaOH)
• Distilled Water
• Ethanol
• Equipment required:
• Magnetic Stirrer
• Muffle furnace
• Beaker
• Spatula
• Keep
• Crucible
• Tong
• Borosil glass
SYNTHESIS OF COPPER OXIDE NANOMATERIAL BY
SOL-GEL METHOD:
STEP 1:
Copper nitrate tetrahydrate dissolved in 100 ml
Ethanol
10
23-08-2023
23-08-2023 11
STEP 2:
In this solution, we mix NaOH
dropwise for 30 minutes with rotation
of 600 rpm.
STEP 3:
Filtration process
12
23-08-2023
STEP 4:
Drying process
13 23-08-2023
STEP 5:
Grinding and Annealing
14
23-08-2023
15
23-08-2023
23-08-2023 16
CHARACTERIZATION OF
NANOMATERIALS:
• X-ray Diffraction (XRD)
• Fourier-transform Infrared Spectroscopy (FTIR)
• UV-visible Spectroscopy
• Scanning Electron Microscopy (SEM)
• Energy-dispersive X-ray Spectroscopy(EDX)
23-08-2023 17
X-RAY DIFFRACTION (XRD):
17
XRD finds the geometry or shape of a
molecule using X-rays. It is a
nondestructive technique that provides
detailed information about the
crystallographic structure, chemical
composition, and physical properties
of a material
23-08-2023
23-08-2023 18
SCANNING ELECTRON MICROSCOPE (SEM):
The scanning electron microscope (SEM)
uses a focused beam of high-energy
electrons to generate a variety of signals at
the surface of solid specimens. Scanning
electron microscope (SEM) is one of the
most widely used instrumental methods for
the examination and analysis of micro- and
nanoparticle imaging characterization of
solid objects. One of the reasons that SEM
is preferred for particle size analysis is due
to its resolution of 10 nm, that is, 100 Å.
CuO nanomaterials at 10μm
23-08-2023 19
CuO Nanomaterial at 1μm CuO Nanomaterial at 2μm
23-08-2023 20
CuO Nanomaterial at 0.5μm
23-08-2023 21
ENERGY DISPERSIVE SPECTROMETER(EDS):
Energy-dispersive X-ray
spectroscopy (also known
as EDS, EDX, or EDXA)
is a powerful technique
that enables the user to
analyze the elemental
composition of a desired
sample.
23-08-2023 22
23-08-2023 23
FOURIER-TRANSFORM INFRARED
SPECTROSCOPY (FTIR):
It is a technique used to obtain
an infrared spectrum of
absorption or emission of a
solid, liquid, or gas. The most
common use is in
the identification of unknown
materials and confirmation of
production materials(incoming
or outgoing).
23-08-2023 24
23-08-2023 25
ENGINEERING APPLICATIONS:
• Copper Oxide Nanomaterials Have Various Engineering Applications-
• Catalysts In Chemical Reactions.
• Gas Sensors For Detecting Harmful Gases.
• Antibacterial Agents In Biomedical Applications.
• Solar Cells For Converting Solar Energy Into Electrical Energy.
• Lubricants In The Automotive Industry.
23-08-2023 26
REFERENCE:
• Sneha R. Bhosale, Rakhee R. Bhosale, Devashree N. Patil, Rushikesh P. Dhavale, Govind B. Kolekar, Vinod B.
Shimpale, Prashant V. Anbhule. Bioderived Mesoporous Carbon@Tungsten Oxide Nanocomposite as a Drug Carrier
Vehicle of Doxorubicin for Potent Cancer Therapy. Langmuir 2023, 39 (33) , 11910-11924
• Jahanzeb Khan, Saiqa Bibi, Irsa Naseem, Shakeel Ahmed, Muhammad Hafeez, Khalil Ahmed, Faizah Altaf, Davoud
Dastan, Asad Syed, Majid S. Jabir, Mustafa K. A. Mohammed, Lin Tao. Ternary Metal (Cu–Ni–Zn) Oxide
Nanocomposite via an Environmentally Friendly Route. ACS Omega 2023, 8 (23) , 21032-21041.
https://doi.org/10.1021/acsomega.3c01896
• Manish Rawat, Diwan S. Rawat. Mesoporous Copper–Magnesium Oxide Hybrid Nanocatalyzed Synthesis of 3-
Substituted Isocoumarins from 2-Iodobenzoic Acid and Terminal Alkyne under Green Conditions. ACS Omega 2023,
8 (18) , 16263-16272. https://doi.org/10.1021/acsomega.3c00710
• Shahid ul Islam, Gang Sun. Biological Chemicals as Sustainable Materials to Synthesize Metal and Metal Oxide
Nanoparticles for Textile Surface Functionalization. ACS Sustainable Chemistry & Engineering 2022, 10 (31) ,
10084-10104. https://doi.org/10.1021/acssuschemeng.2c03033
• Sonia Lanzalaco, Pau Gil, Júlia Mingot, Alba Àgueda, Carlos Alemán, Elaine Armelin. Dual-Responsive
Polypropylene Meshes Actuating as Thermal and SERS Sensors. ACS Biomaterials Science & Engineering 2022, 8
(8) , 3329-3340. https://doi.org/10.1021/acsbiomaterials.2c00334
23-08-2023 27
• Yongkang Zhen, Ling Ge, Qiaoqing Chen, Jun Xu, Zhenyu Duan, Juan J. Loor, Mengzhi Wang. Latent Benefits and
Toxicity Risks Transmission Chain of High Dietary Copper along the Livestock–Environment–Plant–Human Health
Axis and Microbial Homeostasis: A Review. Journal of Agricultural and Food Chemistry 2022, 70 (23) , 6943-
6962. https://doi.org/10.1021/acs.jafc.2c01367
• Yanan Zhang, GeYuan Qi, Lu Yao, Luqi Huang, Juan Wang, Wenyuan Gao. Effects of Metal Nanoparticles and Other
Preparative Materials in the Environment on Plants: From the Perspective of Improving Secondary Metabolites. Journal
of Agricultural and Food Chemistry 2022, 70 (4) , 916-933. https://doi.org/10.1021/acs.jafc.1c05152
• Ifijen I.H., Ikhuoria E.U., Maliki M., Otabor G.O., Aigbodion A.I.: Nanostructured materials: a review on its
application in water treatment. In: The Minerals, Metals & Materials Society (eds) TMS 2022 151st Annual Meeting &
Exhibition Supplemental Proceedings. The Minerals, Metals & Materials Series. Springer, Cham, pp 1172–1180 (2022)
• Wu, D.J.: Oversupply of limiting cell resources and the evolution of cancer cells: a review. Front. Ecol. Evol. 9, 653622
(2021)
• Sarangi, B., Mishra, P.S., Behera, N.: Advances in green synthesis of ZnS nanoparticles: an overview. Mater. Sci.
Semicond. Process. 147, 106723 (2022)
• Boscarino, S., Censabella, M., Micali, M., Russo, M., Terrasi, A., Grimaldi, M.G., Ruffino, F.: Morphology, electrical
and optical properties of Cu nanostructures embedded in azo: a comparison between dry and wet methods.
Micromachines 13, 247 (2022)
THANK YOU
28
23-08-2023

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Synthesis of copper oxide.pptx

  • 1. PRESENTATION ON SYNTHESIS AND CHARACTERIZATION OF COPPER OXIDE NANOMATERIAL SUBMITTED TO; DR. NAVIN CHAURASIA (ASSISTANT PROFESSOR) MECHANICAL ENGINEERING DEPARTMENT, UNSIET, VBSPU SUBMITTED BY; SHIKHAR SINGH(195141) CHANDRA KANT SHUKLA(195122) SHUBHAM GUPTA(195120) NITESH YADAV(2085164) B.TECH.(ME) 8TH SEM.
  • 3. 23-08-2023 3 • NANO MATERIALS: • Nanomaterials refer to materials that have been make at the nanoscale, typically with dimensions ranging from 1 to 100 nanometers (nm). At this scale, materials shows unique physical, chemical, and biological properties. These properties grow due to the increased surface area-to-volume ratio, quantum effects, and size-dependent phenomena. • COPPER OXIDE: • Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). INTRODUCTION:
  • 7. 23-08-2023 7 SYNTHESIS: • In general, the term synthesis related to the creation of something. It is the process of combining two or more components to produce a substance. • METHOD OF SYNTHESIS: 1. TOP-DOWN METHOD:  Ball Milling Method  Cutting Method  Grinding Method 2. BOTTOM-UP METHOD: • Sol- gel Method • Sono Chemical Precipitation Method • Thermal Decomposition Method
  • 9. 23-08-2023 9 • MATERIAL REQUIRED: • Copper (II) Nitrate Trihydrate (Cu(NO3)2.3H2O) • Sodium Hydroxide (NaOH) • Distilled Water • Ethanol • Equipment required: • Magnetic Stirrer • Muffle furnace • Beaker • Spatula • Keep • Crucible • Tong • Borosil glass SYNTHESIS OF COPPER OXIDE NANOMATERIAL BY SOL-GEL METHOD:
  • 10. STEP 1: Copper nitrate tetrahydrate dissolved in 100 ml Ethanol 10 23-08-2023
  • 11. 23-08-2023 11 STEP 2: In this solution, we mix NaOH dropwise for 30 minutes with rotation of 600 rpm.
  • 14. STEP 5: Grinding and Annealing 14 23-08-2023
  • 16. 23-08-2023 16 CHARACTERIZATION OF NANOMATERIALS: • X-ray Diffraction (XRD) • Fourier-transform Infrared Spectroscopy (FTIR) • UV-visible Spectroscopy • Scanning Electron Microscopy (SEM) • Energy-dispersive X-ray Spectroscopy(EDX)
  • 17. 23-08-2023 17 X-RAY DIFFRACTION (XRD): 17 XRD finds the geometry or shape of a molecule using X-rays. It is a nondestructive technique that provides detailed information about the crystallographic structure, chemical composition, and physical properties of a material 23-08-2023
  • 18. 23-08-2023 18 SCANNING ELECTRON MICROSCOPE (SEM): The scanning electron microscope (SEM) uses a focused beam of high-energy electrons to generate a variety of signals at the surface of solid specimens. Scanning electron microscope (SEM) is one of the most widely used instrumental methods for the examination and analysis of micro- and nanoparticle imaging characterization of solid objects. One of the reasons that SEM is preferred for particle size analysis is due to its resolution of 10 nm, that is, 100 Å. CuO nanomaterials at 10μm
  • 19. 23-08-2023 19 CuO Nanomaterial at 1μm CuO Nanomaterial at 2μm
  • 21. 23-08-2023 21 ENERGY DISPERSIVE SPECTROMETER(EDS): Energy-dispersive X-ray spectroscopy (also known as EDS, EDX, or EDXA) is a powerful technique that enables the user to analyze the elemental composition of a desired sample.
  • 23. 23-08-2023 23 FOURIER-TRANSFORM INFRARED SPECTROSCOPY (FTIR): It is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. The most common use is in the identification of unknown materials and confirmation of production materials(incoming or outgoing).
  • 25. 23-08-2023 25 ENGINEERING APPLICATIONS: • Copper Oxide Nanomaterials Have Various Engineering Applications- • Catalysts In Chemical Reactions. • Gas Sensors For Detecting Harmful Gases. • Antibacterial Agents In Biomedical Applications. • Solar Cells For Converting Solar Energy Into Electrical Energy. • Lubricants In The Automotive Industry.
  • 26. 23-08-2023 26 REFERENCE: • Sneha R. Bhosale, Rakhee R. Bhosale, Devashree N. Patil, Rushikesh P. Dhavale, Govind B. Kolekar, Vinod B. Shimpale, Prashant V. Anbhule. Bioderived Mesoporous Carbon@Tungsten Oxide Nanocomposite as a Drug Carrier Vehicle of Doxorubicin for Potent Cancer Therapy. Langmuir 2023, 39 (33) , 11910-11924 • Jahanzeb Khan, Saiqa Bibi, Irsa Naseem, Shakeel Ahmed, Muhammad Hafeez, Khalil Ahmed, Faizah Altaf, Davoud Dastan, Asad Syed, Majid S. Jabir, Mustafa K. A. Mohammed, Lin Tao. Ternary Metal (Cu–Ni–Zn) Oxide Nanocomposite via an Environmentally Friendly Route. ACS Omega 2023, 8 (23) , 21032-21041. https://doi.org/10.1021/acsomega.3c01896 • Manish Rawat, Diwan S. Rawat. Mesoporous Copper–Magnesium Oxide Hybrid Nanocatalyzed Synthesis of 3- Substituted Isocoumarins from 2-Iodobenzoic Acid and Terminal Alkyne under Green Conditions. ACS Omega 2023, 8 (18) , 16263-16272. https://doi.org/10.1021/acsomega.3c00710 • Shahid ul Islam, Gang Sun. Biological Chemicals as Sustainable Materials to Synthesize Metal and Metal Oxide Nanoparticles for Textile Surface Functionalization. ACS Sustainable Chemistry & Engineering 2022, 10 (31) , 10084-10104. https://doi.org/10.1021/acssuschemeng.2c03033 • Sonia Lanzalaco, Pau Gil, Júlia Mingot, Alba Àgueda, Carlos Alemán, Elaine Armelin. Dual-Responsive Polypropylene Meshes Actuating as Thermal and SERS Sensors. ACS Biomaterials Science & Engineering 2022, 8 (8) , 3329-3340. https://doi.org/10.1021/acsbiomaterials.2c00334
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