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Zinc Oxide Eugenol
Cement
Toor-e-Cina Jadoon
1480
2nd Year BDS
SBDC, Peshawar
Learning Objectives
Zinc Oxide Eugenol Cement in detail
Presentation, Availability
Composition, Types, Uses
Manipulation
Setting Reaction
Properties
Introduction
 Since 1890s , Zinc Oxide based cements are in use
extensively
 Oil based cements
 Most biocompatible among
cements
 Have sedative effect on pulp
 Especially used for Temporary
cementation
 Availability
• Two Bottle System
• Two Paste System
Presentation
• Powder-Liquid
• Paste-Paste
Types
1. Simple/conventional zinc oxide eugenol
2. Reinforced/modified zinc oxide eugenol
a. EBA reinforced cements
b. Resin reinforced cements
Composition
Powder
i. Zinc oxide (69%)
-Primary reactive ingredient
ii. Rosin (29%)
-Reduces brittleness
iii. Zinc Acetate (1-5%)
Acts as an accelerator
 Liquid
i. Eugenol 85%
- Primary reactive ingredient
ii. Olive oil (5-15%)
- Controls viscosity
Setting Reaction
Zinc Oxide + Water Zinc Hydroxide
Zinc Hydroxide + Eugenol ZincEugenolate+Water
 Water is essential for the reaction
 Reaction is slightly exothermic
 An Amorphous chelate of Zinc Eugenolate (end
product) is formed
 Chelate formed is an amorphous gel
 tends to crystallize
 imparting strength to the set mass
 set cement consists of particles of zinc oxide
 embedded in a matrix of zinc eugenolate
Reaction is reversible
• Because the zinc eugenolate is easily hydrolyzed
• Cement disintegrates rapidly
• when exposed to oral conditions
• Heat and water accelerates reaction
Properties
• Manipulative properties
• Mechanical properties
• Biological properties
• Solubility
• Thermal properties
• Adhesion
Manipulative properties
• Ideal setting characteristic
• Offer adequate working time
• Very little increase in viscosity occurs
• After placing into the cavity
 Sets quickly in oral cavity due to
1. Higher temperature
2. Humidity comparatively
• Setting time: 4-10 minutes
• Complete setting between zinc oxide and eugenol takes
about 12 hours
Mechanical properties
• Compressive strength is 20 MPa for un-reinforced
cement
• 40 MPa for reinforced zinc oxide cements
• Ultimate strength is lower than Zinc phosphaste cement
• Tensile strength ranges from 0.32 to 5.3MPa
Biological properties
• PH during placement is 7
• Use in deep cavities (liner)
• without harming the dental pulp
• Unconsumed eugenol is irritant
• under certain conditions
• Able to leach out from the set material
• Eugenol has sedative effect on pulp
• Helps to minimize
• the effects of bacterial ingress
Solubility
• Leaching of eugenol is responsible for its relatively high
solubility
• Leached eugenol replaced by water can cause
hydrolysis of the Zinc eugenolate
• Then disintegration of the cement structure occurs
• Therefore not suitable as permanent luting agent
Thermal properties
• Excellent thermal insulating properties
• Can form effective barrier
• under metallic restoration
• Thermal diffusivity is similar to that of dentine
Adhesion
• Don’t adhere well to the enamel and dentine
• Therefore they are not often
• used for final cementation of crowns and bridges
Manipulation
Armamentarium
 Powder/Liquid or paste /paste
 Mixing pad
 Condenser
 Spatula
Procedure
• Shake the bottle for even distribution
• Powder-liquid ratio 3:1 or 4:1
• Place 3 scoops of powder on mixing pad/glass
slab
• Place four drops of eugenol next to powder
• Incorporate half of the powder into the liquid
• Fold it in using stiff side of spatula
• Apply heavy force to ensure even mix
• Add the remaining powder
• Final mixture should be putty like
• Should be tacky
• Roll the mixed cement into a long roll
• Cut it into small pieces
• Using spatula
Applications
• Temporary luting of restorations
• Temporary filling of teeth
• Cavity liner or base
• Root canal sealer
Root canal sealer
Luting of Restoration
Ethoxy-benzoic acid
(EBA) reinforced cements
 Availability
-Two bottle system
 Presentation
-Powder / Liquid
Composition
 Powder
i. Zinc Oxide 60%
ii. Quartz 35%
iii. Hydrogenated rosin 5%
 Liquid
i. Ethoxy-benzoic acid
62.5%
ii. Eugenol 37.5%
-Primary Reactive Ingredient
-Reinforcing Agent
-Reinforcing Agent
-Reactive ingredient
-Reactive ingredient
Properties
• Setting characteristics similar to zinc oxide
eugenol cement
• Set material is stronger
• Compressive strength of upto 85MPa
• Comparatively lower solubility
Application
• Cavity liner
• Luting agent
• Can be use as permanent cementation
Polymer reinforced zinc
oxide eugenol cement
 Availability
-Two bottle system
 Presentation
-Powder / liquid
Composition
 Powder
i. Zinc oxide 80%
ii. Acrylic resin 20%
 Liquid
i. Eugenol
Reference
Text from
Dental material book by Dr Tahir Ali khan
www.slideshare.net
Images from;
pocketdentistry
Dental dost
Thank You

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Zinc Oxide Eugenol Cement

  • 1. Zinc Oxide Eugenol Cement Toor-e-Cina Jadoon 1480 2nd Year BDS SBDC, Peshawar
  • 2. Learning Objectives Zinc Oxide Eugenol Cement in detail Presentation, Availability Composition, Types, Uses Manipulation Setting Reaction Properties
  • 3. Introduction  Since 1890s , Zinc Oxide based cements are in use extensively  Oil based cements  Most biocompatible among cements  Have sedative effect on pulp  Especially used for Temporary cementation
  • 4.
  • 5.  Availability • Two Bottle System • Two Paste System Presentation • Powder-Liquid • Paste-Paste
  • 6. Types 1. Simple/conventional zinc oxide eugenol 2. Reinforced/modified zinc oxide eugenol a. EBA reinforced cements b. Resin reinforced cements
  • 7. Composition Powder i. Zinc oxide (69%) -Primary reactive ingredient ii. Rosin (29%) -Reduces brittleness iii. Zinc Acetate (1-5%) Acts as an accelerator
  • 8.  Liquid i. Eugenol 85% - Primary reactive ingredient ii. Olive oil (5-15%) - Controls viscosity
  • 9. Setting Reaction Zinc Oxide + Water Zinc Hydroxide Zinc Hydroxide + Eugenol ZincEugenolate+Water  Water is essential for the reaction  Reaction is slightly exothermic  An Amorphous chelate of Zinc Eugenolate (end product) is formed
  • 10.  Chelate formed is an amorphous gel  tends to crystallize  imparting strength to the set mass  set cement consists of particles of zinc oxide  embedded in a matrix of zinc eugenolate
  • 11. Reaction is reversible • Because the zinc eugenolate is easily hydrolyzed • Cement disintegrates rapidly • when exposed to oral conditions • Heat and water accelerates reaction
  • 12. Properties • Manipulative properties • Mechanical properties • Biological properties • Solubility • Thermal properties • Adhesion
  • 13. Manipulative properties • Ideal setting characteristic • Offer adequate working time • Very little increase in viscosity occurs • After placing into the cavity  Sets quickly in oral cavity due to 1. Higher temperature 2. Humidity comparatively
  • 14. • Setting time: 4-10 minutes • Complete setting between zinc oxide and eugenol takes about 12 hours
  • 15. Mechanical properties • Compressive strength is 20 MPa for un-reinforced cement • 40 MPa for reinforced zinc oxide cements • Ultimate strength is lower than Zinc phosphaste cement • Tensile strength ranges from 0.32 to 5.3MPa
  • 16. Biological properties • PH during placement is 7 • Use in deep cavities (liner) • without harming the dental pulp • Unconsumed eugenol is irritant • under certain conditions • Able to leach out from the set material
  • 17. • Eugenol has sedative effect on pulp • Helps to minimize • the effects of bacterial ingress
  • 18. Solubility • Leaching of eugenol is responsible for its relatively high solubility • Leached eugenol replaced by water can cause hydrolysis of the Zinc eugenolate • Then disintegration of the cement structure occurs • Therefore not suitable as permanent luting agent
  • 19.
  • 20. Thermal properties • Excellent thermal insulating properties • Can form effective barrier • under metallic restoration • Thermal diffusivity is similar to that of dentine
  • 21. Adhesion • Don’t adhere well to the enamel and dentine • Therefore they are not often • used for final cementation of crowns and bridges
  • 22. Manipulation Armamentarium  Powder/Liquid or paste /paste  Mixing pad  Condenser  Spatula
  • 23. Procedure • Shake the bottle for even distribution • Powder-liquid ratio 3:1 or 4:1 • Place 3 scoops of powder on mixing pad/glass slab • Place four drops of eugenol next to powder • Incorporate half of the powder into the liquid • Fold it in using stiff side of spatula
  • 24. • Apply heavy force to ensure even mix • Add the remaining powder • Final mixture should be putty like • Should be tacky • Roll the mixed cement into a long roll • Cut it into small pieces • Using spatula
  • 25.
  • 26.
  • 27. Applications • Temporary luting of restorations • Temporary filling of teeth • Cavity liner or base • Root canal sealer
  • 28.
  • 31. Ethoxy-benzoic acid (EBA) reinforced cements  Availability -Two bottle system  Presentation -Powder / Liquid
  • 32. Composition  Powder i. Zinc Oxide 60% ii. Quartz 35% iii. Hydrogenated rosin 5%  Liquid i. Ethoxy-benzoic acid 62.5% ii. Eugenol 37.5% -Primary Reactive Ingredient -Reinforcing Agent -Reinforcing Agent -Reactive ingredient -Reactive ingredient
  • 33. Properties • Setting characteristics similar to zinc oxide eugenol cement • Set material is stronger • Compressive strength of upto 85MPa • Comparatively lower solubility
  • 34. Application • Cavity liner • Luting agent • Can be use as permanent cementation
  • 35. Polymer reinforced zinc oxide eugenol cement  Availability -Two bottle system  Presentation -Powder / liquid
  • 36. Composition  Powder i. Zinc oxide 80% ii. Acrylic resin 20%  Liquid i. Eugenol
  • 37. Reference Text from Dental material book by Dr Tahir Ali khan www.slideshare.net Images from; pocketdentistry Dental dost

Editor's Notes

  1. Rosin : a substance added to a synthetic resin to promote plasticity and flexibility +,to reduce brittleness
  2. Chelate ; a ring like compound formed from the organic groups and the ZnO Reaction is Reversible