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Engineering Materials
For further volumes:
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Rafat Siddique • Mohammad Iqbal Khan
Supplementary Cementing
Materials
123
Dr. Rafat Siddique
Department of Civil Engineering
Thapar University
Patiala 147004
India
e-mail: rsiddique@thapar.edu
siddique_66@yahoo.com
Dr. Mohammad Iqbal Khan
Structural Engineering
Center of Excellence for Concrete Research
and Testing College of Engineering
King Saud University
Riyadh 11421
Saudi Arabia
e-mail: miqbal@ksu.edu.sa
ISSN 1612-1317 e-ISSN 1868-1212
ISBN 978-3-642-17865-8 e-ISBN 978-3-642-17866-5
DOI 10.1007/978-3-642-17866-5
Springer Heidelberg Dordrecht London New York
Ó Springer-Verlag Berlin Heidelberg 2011
This work is subject to copyright. All rights are reserved, whether the whole or part of the material is
concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation,
broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication
of this publication or parts thereof is permitted only under the provisions of the German Copyright Law
of September 9, 1965, in its current version, and permission for use must always be obtained from
Springer. Violations are liable to prosecution under the German Copyright Law.
The use of general descriptive names, registered names, trademarks, etc. in this publication does not
imply, even in the absence of a specific statement, that such names are exempt from the relevant
protective laws and regulations and therefore free for general use.
Cover design: deblik, Berlin
Printed on acid-free paper
Springer is part of Springer Science+Business Media (www.springer.com)
Dedicated to Our Parents and Families
Preface
Concrete is the most widely used construction material because of its versatility,
economy, availability of raw materials, strength, and durability. Concrete can be
designed to withstand the harshest environmental conditions while taking on the
most inspirational and imaginable shapes and forms. Scientist/Engineers and
academicians are continuously working for better concrete from strength and
durability standpoint with the help of innovative chemical admixtures and sup-
plementary cementing materials (SCMs). In addition, the use of SCMs conserves
energy and has environmental benefits because of reduction in carbon dioxide
emission as a result of reduction in manufacture of Portland cement. Strict air-
pollution controls and regulations have produced an abundance of industrial
byproducts that can be used as supplementary cementitious materials. Typical
examples are fly ash, silica fume, ground granulated blastfurnace slag, metakaolin,
rice husk ash and natural pozzolans which can be used incorporated in concrete
addition or as partial cement replacement.
Supplementary cementing materials are often used in concrete mixes to reduce
cement contents, improve workability, increase strength and enhance durability
through hydraulic or pozzolanic activity. Utilization of these byproducts in
cement/concrete not only prevents them from being land-filled but also enhances
the properties of concrete in the fresh and hardened states.
This book is an attempt to consolidate the published research related to the use
of SCMs in cement and concrete. This book is intended to cater to the needs of
graduate students, researchers, concrete technologists and practicing engineers.
The book comprises of five chapters. Each chapter is devoted to a particular
supplementing cementing material. It is based on the literature/research findings
published in journals/conference proceeding, etc. Topics covered in the book are;
coal fly ash, silica fume (SF), granulated blast furnace slag (GGBS), metakaolin
(MK), and rice husk ash (RHA). Each chapter contains introduction, properties of
the waste material/by-product, its potential usage, and its effect on the properties
of fresh and hardened concrete and other cement based materials.
We would like to place on record our immense sense of gratitude to acade-
micians, scientists, concrete technologists, and our colleagues and friends globally
vii
who have contributed significantly in the broader area of concrete technology, and
our sincere appreciation and acknowledgement to the published work of the
researchers on the subject, which has been referred in this book.
We are also extremely grateful to Springer for publishing the book in an
excellent form in the shortest possible time.
We owe our sincere thanks and irrepayable gratitude to our families and friends
whose consistent encouragement and love have been a tremendous impetus for the
completion of this book.
Dr. Rafat Siddique
Dr. Mohammad Iqbal Khan
viii Preface
Contents
1 Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.1.1 Handling of Fly Ash. . . . . . . . . . . . . . . . . . . . . . . . . 2
1.1.2 Environmental Benefits of Using Fly Ash . . . . . . . . . . 2
1.2 Properties of Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.2.1 Size, Shape and Colour. . . . . . . . . . . . . . . . . . . . . . . 2
1.2.2 Fineness . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.2.3 Specific Gravity. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
1.2.4 Pozzolanic Activity . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.2.5 Particle Morphology . . . . . . . . . . . . . . . . . . . . . . . . . 4
1.2.6 Moisture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.2.7 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 5
1.2.8 Mineralogical Characteristics. . . . . . . . . . . . . . . . . . . 5
1.3 Classification of Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.4 Reaction Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.5 Uses of Fly Ash. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.5.1 Uses of Fly Ash in Cement Concrete . . . . . . . . . . . . . 9
1.6 Objectives of Using Fly Ash in Cement/Concrete . . . . . . . . . . 10
1.7 Benefits of Using Fly Ash in Cement/Concrete . . . . . . . . . . . . 10
1.7.1 Reduced Bleeding and Segregation. . . . . . . . . . . . . . . 11
1.7.2 Improved Workability. . . . . . . . . . . . . . . . . . . . . . . . 11
1.7.3 Reduced Heat of Hydration . . . . . . . . . . . . . . . . . . . . 11
1.7.4 Higher Ultimate Strength . . . . . . . . . . . . . . . . . . . . . 11
1.7.5 Reduced Permeability . . . . . . . . . . . . . . . . . . . . . . . . 11
1.7.6 Increased Resistance to Sulfate Attack . . . . . . . . . . . . 12
1.7.7 Improved Resistance to Corrosion . . . . . . . . . . . . . . . 12
1.7.8 Increased Resistance to Alkali-Silica
Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
ix
1.8 Effect of Fly Ash on the Fresh Properties
of Cement Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
1.8.1 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
1.8.2 Bleeding and Segregation . . . . . . . . . . . . . . . . . . . . . 14
1.8.3 Air Entrainment . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
1.8.4 Temperature Rise . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
1.8.5 Setting Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
1.9 Effect of Fly Ash on Properties of Cement Concrete
in Hardened State. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
1.9.1 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 19
1.9.2 Effect of Curing Temperature at Early Age
on Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
1.9.3 Effects of Curing Conditions on Compressive
Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
1.9.4 Tensile Strength Properties . . . . . . . . . . . . . . . . . . . . 30
1.9.5 Elastic Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
1.9.6 Sorptivity and Porosity . . . . . . . . . . . . . . . . . . . . . . . 33
1.9.7 Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
1.9.8 Creep . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
1.9.9 Thermal Conductivity . . . . . . . . . . . . . . . . . . . . . . . . 37
1.10 Durability Properties of Concrete Made with Fly Ash . . . . . . . 38
1.10.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
1.10.2 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44
1.10.3 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 47
1.10.4 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 50
1.10.5 Alkali-Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 52
1.10.6 Resistance to Aggressive Chemicals . . . . . . . . . . . . . . 55
1.10.7 Sulphate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 55
1.10.8 Abrasion Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 59
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
2 Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
2.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
2.1.1 Availability and Handling . . . . . . . . . . . . . . . . . . . . . 68
2.2 Properties of Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . . . 68
2.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 68
2.2.2 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 68
2.3 Reaction Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
2.4 Heat of Hydration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
2.5 Silica Fume Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
2.6 Advantages of Using Silica Fume . . . . . . . . . . . . . . . . . . . . . 73
2.7 Applications of Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . 74
2.8 Effect of Silica Fume on Fresh Properties
of Cement/Mortar/Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 75
x Contents
2.8.1 Consistency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
2.8.2 Setting Times . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
2.8.3 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
2.9 Effect of Silica Fume on the Hardened Properties
of Cement/Mortar/Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 81
2.9.1 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 81
2.9.2 Tensile Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
2.9.3 Flexural Tensile Strength . . . . . . . . . . . . . . . . . . . . . 92
2.9.4 Modulus of Elasticity . . . . . . . . . . . . . . . . . . . . . . . . 94
2.9.5 Toughness. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
2.9.6 Absorption . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
2.9.7 Porosity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
2.9.8 Thermal Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 100
2.9.9 Creep . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
2.9.10 Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
2.10. Effect of Silica Fume on the Durability Properties
of Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
2.10.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
2.10.2 Freezing and Thawing . . . . . . . . . . . . . . . . . . . . . . . 106
2.10.3 Corrosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108
2.10.4 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 110
2.10.5 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
2.10.6 Alkali-Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 114
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
3 Ground Granulated Blast Furnace Slag . . . . . . . . . . . . . . . . . . . . 121
3.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
3.1.1 Storage and Handling of GGBS . . . . . . . . . . . . . . . . . 121
3.1.2 Environmental Benefits of Using GGBS . . . . . . . . . . . 122
3.2 Characteristics of GGBS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
3.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 122
3.2.2 Particle Morphology . . . . . . . . . . . . . . . . . . . . . . . . . 123
3.2.3 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 124
3.2.4 Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124
3.2.5 Specifications of GGBS . . . . . . . . . . . . . . . . . . . . . . 129
3.2.6 Advantages of Using GGBS . . . . . . . . . . . . . . . . . . . 129
3.3 Fresh Properties of Mortar/Paste/Concrete Containing GGBS. . . 130
3.3.1 Bleeding Characteristics . . . . . . . . . . . . . . . . . . . . . . 130
3.3.2 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
3.3.3 Setting Times . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
3.4 Properties of Hardened Concrete Containing GGBS . . . . . . . . . 134
3.4.1 Water Absorption. . . . . . . . . . . . . . . . . . . . . . . . . . . 134
3.4.2 Microstructure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
3.4.3 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 141
3.4.4 Tensile and Flexural Strength . . . . . . . . . . . . . . . . . . 148
Contents xi
3.5 Durability Properties of Concrete Containing GGBS . . . . . . . . 151
3.5.1 Creep and Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . 151
3.5.2 Chloride Binding Capacity/ Resistance . . . . . . . . . . . . 152
3.5.3 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 155
3.5.4 Alkali Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 160
3.5.5 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 163
3.5.6 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 165
3.5.7 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170
4 Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
4.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
4.1.1 Uses of Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . 175
4.1.2 Advantages of Using Metakaolin . . . . . . . . . . . . . . . . 176
4.2 Properties of Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176
4.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 176
4.2.2 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 178
4.2.3 Mineralogical Composition . . . . . . . . . . . . . . . . . . . . 178
4.3 Hydration Reaction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
4.3.1 Temperature Effect. . . . . . . . . . . . . . . . . . . . . . . . . . 188
4.3.2 Effect of Dehydroxylation . . . . . . . . . . . . . . . . . . . . . 190
4.4 Fresh Properties of Mortar/Concrete Containing Metakaolin . . . 191
4.5 Properties of Hardened Mortar/Concrete
Containing Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
4.5.1 Pore Size Distribution. . . . . . . . . . . . . . . . . . . . . . . . 195
4.5.2 Water Absorption and Sorptivity . . . . . . . . . . . . . . . . 199
4.5.3 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 201
4.5.4 Tensile Strength and Elastic Modulus. . . . . . . . . . . . . 207
4.5.5 Bending Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
4.5.6 Micro-Hardness . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
4.6 Durability Properties of Concrete Containing Metakaolin . . . . . 212
4.6.1 Alkali–Silica Reaction . . . . . . . . . . . . . . . . . . . . . . . 212
4.6.2 Chloride-Ion Diffusion/Permeability . . . . . . . . . . . . . . 213
4.6.3 Hydroxide Ion Diffusion . . . . . . . . . . . . . . . . . . . . . . 217
4.6.4 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 219
4.6.5 Corrosion Résistance . . . . . . . . . . . . . . . . . . . . . . . . 223
4.6.6 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
4.6.7 Creep and Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . 224
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
5 Rice Husk Ash. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
5.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
5.1.1 Advantages of Using RHA . . . . . . . . . . . . . . . . . . . . 232
5.1.2 Applications of Rice Husk Ash . . . . . . . . . . . . . . . . . 232
xii Contents
5.2 Properties of RHA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
5.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 233
5.2.2 Particle Size Distribution . . . . . . . . . . . . . . . . . . . . . 233
5.2.3 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 236
5.3 Pozzolanic Activity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
5.4 Fresh Properties of Paste/Concrete Containing RHA . . . . . . . . 241
5.4.1 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241
5.4.2 Air-Entrainment . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
5.4.3 Consistency and Setting Times . . . . . . . . . . . . . . . . . 243
5.5 Properties of Hardened Concrete Containing RHA. . . . . . . . . . 246
5.5.1 Porosity and Water Absorption Capacity. . . . . . . . . . . 246
5.5.2 Compressive Properties. . . . . . . . . . . . . . . . . . . . . . . 248
5.5.3 Tensile Strength and Modulus of Elasticity . . . . . . . . . 259
5.5.4 Drying Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
5.5.5 Electrical Resistivity and Conductivity . . . . . . . . . . . . 265
5.6 Durability Properties of Concrete Containing RHA . . . . . . . . . 266
5.6.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
5.6.2 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 271
5.6.3 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273
5.6.4 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 275
5.6.5 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 275
5.6.6 Deicing Salt Scaling Resistance . . . . . . . . . . . . . . . . . 277
5.6.7 Alkali–Silica Reaction . . . . . . . . . . . . . . . . . . . . . . . 278
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283
Contents xiii
About the Authors
Dr. Rafat Siddique is Senior Professor of Civil Engineering & Dean of Faculty
Affairs at Thapar University, Patiala, India. He earned Ph.D. degree from Birla
Institute of Technology & Science, Pilani, India, and did 22-months post-doctoral
work at the University of Wisconsin-Milwaukee, USA. He has been Visiting
Professor to University of Cergy Pontoise, France; INSA Rennes, France;
University of Wolverhampton, U.K.; Consolis Technology, Finland; and BAM
Berlin, Germany. He is the author of a booktitled ‘‘Waste Materials & Byproducts
in Concrete’’, by SPRINGER. He has published more than 125 research papers in
journals and conference proceedings. He is reviewer of 20 leading International
Journals.
Dr. Mohammad Iqbal Khan is Associate Professor in Structural Engineering,
Department of Civil Engineering, King Saud University, Saudi Arabia. He is
founding member and Managing Director of Center of Excellence for Concrete
Research and Testing at King Saud University. He is formerly Lecturer of
Structural Engineering, School of Civil Engineering, University of Nottingham,
UK. He received his Ph.D. degree from the University of Sheffield, UK in 1999.
He is actively involved in research since 1990 and has published more than 70
research papers in refereed international journals and conferences proceedings. He
is reviewer of five leading International Journals. He has one granted United States
Patent and two pending United States Patents.
xv

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Ref#11.pdf

  • 1. Engineering Materials For further volumes: http://www.springer.com/series/4288
  • 2. Rafat Siddique • Mohammad Iqbal Khan Supplementary Cementing Materials 123
  • 3. Dr. Rafat Siddique Department of Civil Engineering Thapar University Patiala 147004 India e-mail: rsiddique@thapar.edu siddique_66@yahoo.com Dr. Mohammad Iqbal Khan Structural Engineering Center of Excellence for Concrete Research and Testing College of Engineering King Saud University Riyadh 11421 Saudi Arabia e-mail: miqbal@ksu.edu.sa ISSN 1612-1317 e-ISSN 1868-1212 ISBN 978-3-642-17865-8 e-ISBN 978-3-642-17866-5 DOI 10.1007/978-3-642-17866-5 Springer Heidelberg Dordrecht London New York Ó Springer-Verlag Berlin Heidelberg 2011 This work is subject to copyright. All rights are reserved, whether the whole or part of the material is concerned, specifically the rights of translation, reprinting, reuse of illustrations, recitation, broadcasting, reproduction on microfilm or in any other way, and storage in data banks. Duplication of this publication or parts thereof is permitted only under the provisions of the German Copyright Law of September 9, 1965, in its current version, and permission for use must always be obtained from Springer. Violations are liable to prosecution under the German Copyright Law. The use of general descriptive names, registered names, trademarks, etc. in this publication does not imply, even in the absence of a specific statement, that such names are exempt from the relevant protective laws and regulations and therefore free for general use. Cover design: deblik, Berlin Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com)
  • 4. Dedicated to Our Parents and Families
  • 5. Preface Concrete is the most widely used construction material because of its versatility, economy, availability of raw materials, strength, and durability. Concrete can be designed to withstand the harshest environmental conditions while taking on the most inspirational and imaginable shapes and forms. Scientist/Engineers and academicians are continuously working for better concrete from strength and durability standpoint with the help of innovative chemical admixtures and sup- plementary cementing materials (SCMs). In addition, the use of SCMs conserves energy and has environmental benefits because of reduction in carbon dioxide emission as a result of reduction in manufacture of Portland cement. Strict air- pollution controls and regulations have produced an abundance of industrial byproducts that can be used as supplementary cementitious materials. Typical examples are fly ash, silica fume, ground granulated blastfurnace slag, metakaolin, rice husk ash and natural pozzolans which can be used incorporated in concrete addition or as partial cement replacement. Supplementary cementing materials are often used in concrete mixes to reduce cement contents, improve workability, increase strength and enhance durability through hydraulic or pozzolanic activity. Utilization of these byproducts in cement/concrete not only prevents them from being land-filled but also enhances the properties of concrete in the fresh and hardened states. This book is an attempt to consolidate the published research related to the use of SCMs in cement and concrete. This book is intended to cater to the needs of graduate students, researchers, concrete technologists and practicing engineers. The book comprises of five chapters. Each chapter is devoted to a particular supplementing cementing material. It is based on the literature/research findings published in journals/conference proceeding, etc. Topics covered in the book are; coal fly ash, silica fume (SF), granulated blast furnace slag (GGBS), metakaolin (MK), and rice husk ash (RHA). Each chapter contains introduction, properties of the waste material/by-product, its potential usage, and its effect on the properties of fresh and hardened concrete and other cement based materials. We would like to place on record our immense sense of gratitude to acade- micians, scientists, concrete technologists, and our colleagues and friends globally vii
  • 6. who have contributed significantly in the broader area of concrete technology, and our sincere appreciation and acknowledgement to the published work of the researchers on the subject, which has been referred in this book. We are also extremely grateful to Springer for publishing the book in an excellent form in the shortest possible time. We owe our sincere thanks and irrepayable gratitude to our families and friends whose consistent encouragement and love have been a tremendous impetus for the completion of this book. Dr. Rafat Siddique Dr. Mohammad Iqbal Khan viii Preface
  • 7. Contents 1 Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.1.1 Handling of Fly Ash. . . . . . . . . . . . . . . . . . . . . . . . . 2 1.1.2 Environmental Benefits of Using Fly Ash . . . . . . . . . . 2 1.2 Properties of Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 1.2.1 Size, Shape and Colour. . . . . . . . . . . . . . . . . . . . . . . 2 1.2.2 Fineness . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.2.3 Specific Gravity. . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 1.2.4 Pozzolanic Activity . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.2.5 Particle Morphology . . . . . . . . . . . . . . . . . . . . . . . . . 4 1.2.6 Moisture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5 1.2.7 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 5 1.2.8 Mineralogical Characteristics. . . . . . . . . . . . . . . . . . . 5 1.3 Classification of Fly Ash . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 1.4 Reaction Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 1.5 Uses of Fly Ash. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 1.5.1 Uses of Fly Ash in Cement Concrete . . . . . . . . . . . . . 9 1.6 Objectives of Using Fly Ash in Cement/Concrete . . . . . . . . . . 10 1.7 Benefits of Using Fly Ash in Cement/Concrete . . . . . . . . . . . . 10 1.7.1 Reduced Bleeding and Segregation. . . . . . . . . . . . . . . 11 1.7.2 Improved Workability. . . . . . . . . . . . . . . . . . . . . . . . 11 1.7.3 Reduced Heat of Hydration . . . . . . . . . . . . . . . . . . . . 11 1.7.4 Higher Ultimate Strength . . . . . . . . . . . . . . . . . . . . . 11 1.7.5 Reduced Permeability . . . . . . . . . . . . . . . . . . . . . . . . 11 1.7.6 Increased Resistance to Sulfate Attack . . . . . . . . . . . . 12 1.7.7 Improved Resistance to Corrosion . . . . . . . . . . . . . . . 12 1.7.8 Increased Resistance to Alkali-Silica Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 ix
  • 8. 1.8 Effect of Fly Ash on the Fresh Properties of Cement Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 1.8.1 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 1.8.2 Bleeding and Segregation . . . . . . . . . . . . . . . . . . . . . 14 1.8.3 Air Entrainment . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 1.8.4 Temperature Rise . . . . . . . . . . . . . . . . . . . . . . . . . . . 16 1.8.5 Setting Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 1.9 Effect of Fly Ash on Properties of Cement Concrete in Hardened State. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19 1.9.1 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 19 1.9.2 Effect of Curing Temperature at Early Age on Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 1.9.3 Effects of Curing Conditions on Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26 1.9.4 Tensile Strength Properties . . . . . . . . . . . . . . . . . . . . 30 1.9.5 Elastic Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 1.9.6 Sorptivity and Porosity . . . . . . . . . . . . . . . . . . . . . . . 33 1.9.7 Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 1.9.8 Creep . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 1.9.9 Thermal Conductivity . . . . . . . . . . . . . . . . . . . . . . . . 37 1.10 Durability Properties of Concrete Made with Fly Ash . . . . . . . 38 1.10.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 1.10.2 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 1.10.3 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 47 1.10.4 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 50 1.10.5 Alkali-Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 52 1.10.6 Resistance to Aggressive Chemicals . . . . . . . . . . . . . . 55 1.10.7 Sulphate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 55 1.10.8 Abrasion Resistance . . . . . . . . . . . . . . . . . . . . . . . . . 59 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61 2 Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 2.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 2.1.1 Availability and Handling . . . . . . . . . . . . . . . . . . . . . 68 2.2 Properties of Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 2.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 68 2.2.2 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 68 2.3 Reaction Mechanism . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69 2.4 Heat of Hydration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70 2.5 Silica Fume Efficiency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 72 2.6 Advantages of Using Silica Fume . . . . . . . . . . . . . . . . . . . . . 73 2.7 Applications of Silica Fume . . . . . . . . . . . . . . . . . . . . . . . . . 74 2.8 Effect of Silica Fume on Fresh Properties of Cement/Mortar/Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 75 x Contents
  • 9. 2.8.1 Consistency . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75 2.8.2 Setting Times . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76 2.8.3 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 78 2.9 Effect of Silica Fume on the Hardened Properties of Cement/Mortar/Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . 81 2.9.1 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 81 2.9.2 Tensile Strength. . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 2.9.3 Flexural Tensile Strength . . . . . . . . . . . . . . . . . . . . . 92 2.9.4 Modulus of Elasticity . . . . . . . . . . . . . . . . . . . . . . . . 94 2.9.5 Toughness. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 2.9.6 Absorption . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 96 2.9.7 Porosity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98 2.9.8 Thermal Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 100 2.9.9 Creep . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100 2.9.10 Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101 2.10. Effect of Silica Fume on the Durability Properties of Concrete . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 2.10.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 2.10.2 Freezing and Thawing . . . . . . . . . . . . . . . . . . . . . . . 106 2.10.3 Corrosion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 108 2.10.4 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 110 2.10.5 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113 2.10.6 Alkali-Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 114 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115 3 Ground Granulated Blast Furnace Slag . . . . . . . . . . . . . . . . . . . . 121 3.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 121 3.1.1 Storage and Handling of GGBS . . . . . . . . . . . . . . . . . 121 3.1.2 Environmental Benefits of Using GGBS . . . . . . . . . . . 122 3.2 Characteristics of GGBS . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122 3.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 122 3.2.2 Particle Morphology . . . . . . . . . . . . . . . . . . . . . . . . . 123 3.2.3 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 124 3.2.4 Reactivity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 124 3.2.5 Specifications of GGBS . . . . . . . . . . . . . . . . . . . . . . 129 3.2.6 Advantages of Using GGBS . . . . . . . . . . . . . . . . . . . 129 3.3 Fresh Properties of Mortar/Paste/Concrete Containing GGBS. . . 130 3.3.1 Bleeding Characteristics . . . . . . . . . . . . . . . . . . . . . . 130 3.3.2 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132 3.3.3 Setting Times . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133 3.4 Properties of Hardened Concrete Containing GGBS . . . . . . . . . 134 3.4.1 Water Absorption. . . . . . . . . . . . . . . . . . . . . . . . . . . 134 3.4.2 Microstructure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134 3.4.3 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 141 3.4.4 Tensile and Flexural Strength . . . . . . . . . . . . . . . . . . 148 Contents xi
  • 10. 3.5 Durability Properties of Concrete Containing GGBS . . . . . . . . 151 3.5.1 Creep and Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . 151 3.5.2 Chloride Binding Capacity/ Resistance . . . . . . . . . . . . 152 3.5.3 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 155 3.5.4 Alkali Silica Reaction. . . . . . . . . . . . . . . . . . . . . . . . 160 3.5.5 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 163 3.5.6 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 165 3.5.7 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 170 4 Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 4.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175 4.1.1 Uses of Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . 175 4.1.2 Advantages of Using Metakaolin . . . . . . . . . . . . . . . . 176 4.2 Properties of Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . 176 4.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 176 4.2.2 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 178 4.2.3 Mineralogical Composition . . . . . . . . . . . . . . . . . . . . 178 4.3 Hydration Reaction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 179 4.3.1 Temperature Effect. . . . . . . . . . . . . . . . . . . . . . . . . . 188 4.3.2 Effect of Dehydroxylation . . . . . . . . . . . . . . . . . . . . . 190 4.4 Fresh Properties of Mortar/Concrete Containing Metakaolin . . . 191 4.5 Properties of Hardened Mortar/Concrete Containing Metakaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195 4.5.1 Pore Size Distribution. . . . . . . . . . . . . . . . . . . . . . . . 195 4.5.2 Water Absorption and Sorptivity . . . . . . . . . . . . . . . . 199 4.5.3 Compressive Strength . . . . . . . . . . . . . . . . . . . . . . . . 201 4.5.4 Tensile Strength and Elastic Modulus. . . . . . . . . . . . . 207 4.5.5 Bending Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . 209 4.5.6 Micro-Hardness . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210 4.6 Durability Properties of Concrete Containing Metakaolin . . . . . 212 4.6.1 Alkali–Silica Reaction . . . . . . . . . . . . . . . . . . . . . . . 212 4.6.2 Chloride-Ion Diffusion/Permeability . . . . . . . . . . . . . . 213 4.6.3 Hydroxide Ion Diffusion . . . . . . . . . . . . . . . . . . . . . . 217 4.6.4 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 219 4.6.5 Corrosion Résistance . . . . . . . . . . . . . . . . . . . . . . . . 223 4.6.6 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224 4.6.7 Creep and Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . 224 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 5 Rice Husk Ash. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 5.1 Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 5.1.1 Advantages of Using RHA . . . . . . . . . . . . . . . . . . . . 232 5.1.2 Applications of Rice Husk Ash . . . . . . . . . . . . . . . . . 232 xii Contents
  • 11. 5.2 Properties of RHA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 5.2.1 Physical Properties . . . . . . . . . . . . . . . . . . . . . . . . . . 233 5.2.2 Particle Size Distribution . . . . . . . . . . . . . . . . . . . . . 233 5.2.3 Chemical Composition . . . . . . . . . . . . . . . . . . . . . . . 236 5.3 Pozzolanic Activity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237 5.4 Fresh Properties of Paste/Concrete Containing RHA . . . . . . . . 241 5.4.1 Workability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 241 5.4.2 Air-Entrainment . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243 5.4.3 Consistency and Setting Times . . . . . . . . . . . . . . . . . 243 5.5 Properties of Hardened Concrete Containing RHA. . . . . . . . . . 246 5.5.1 Porosity and Water Absorption Capacity. . . . . . . . . . . 246 5.5.2 Compressive Properties. . . . . . . . . . . . . . . . . . . . . . . 248 5.5.3 Tensile Strength and Modulus of Elasticity . . . . . . . . . 259 5.5.4 Drying Shrinkage . . . . . . . . . . . . . . . . . . . . . . . . . . . 263 5.5.5 Electrical Resistivity and Conductivity . . . . . . . . . . . . 265 5.6 Durability Properties of Concrete Containing RHA . . . . . . . . . 266 5.6.1 Permeability . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266 5.6.2 Corrosion Resistance . . . . . . . . . . . . . . . . . . . . . . . . 271 5.6.3 Carbonation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 273 5.6.4 Freezing and Thawing Resistance . . . . . . . . . . . . . . . 275 5.6.5 Sulfate Resistance . . . . . . . . . . . . . . . . . . . . . . . . . . 275 5.6.6 Deicing Salt Scaling Resistance . . . . . . . . . . . . . . . . . 277 5.6.7 Alkali–Silica Reaction . . . . . . . . . . . . . . . . . . . . . . . 278 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279 Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 283 Contents xiii
  • 12. About the Authors Dr. Rafat Siddique is Senior Professor of Civil Engineering & Dean of Faculty Affairs at Thapar University, Patiala, India. He earned Ph.D. degree from Birla Institute of Technology & Science, Pilani, India, and did 22-months post-doctoral work at the University of Wisconsin-Milwaukee, USA. He has been Visiting Professor to University of Cergy Pontoise, France; INSA Rennes, France; University of Wolverhampton, U.K.; Consolis Technology, Finland; and BAM Berlin, Germany. He is the author of a booktitled ‘‘Waste Materials & Byproducts in Concrete’’, by SPRINGER. He has published more than 125 research papers in journals and conference proceedings. He is reviewer of 20 leading International Journals. Dr. Mohammad Iqbal Khan is Associate Professor in Structural Engineering, Department of Civil Engineering, King Saud University, Saudi Arabia. He is founding member and Managing Director of Center of Excellence for Concrete Research and Testing at King Saud University. He is formerly Lecturer of Structural Engineering, School of Civil Engineering, University of Nottingham, UK. He received his Ph.D. degree from the University of Sheffield, UK in 1999. He is actively involved in research since 1990 and has published more than 70 research papers in refereed international journals and conferences proceedings. He is reviewer of five leading International Journals. He has one granted United States Patent and two pending United States Patents. xv