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Electrolytic process
29-08-2019 2
• DC to drive an otherwise non-spontaneous chemical reaction.
• Electrolysis is commercially important as a stage in the separation of elements from
naturally occurring sources such as ores using an electrolytic cell.
Smelter
• Extraction of metals from its ore
• Production of silver, iron, copper, aluminium etc.
• Smelting uses
• Heat
• A chemical reducing agent to decompose the ore
• Driving off other elements as gases or slag
• Reducing agent is commonly a source of carbon such as coke
• The carbon (or carbon monoxide derived from it) removes oxygen from the
ore, leaving behind the elemental metal
29-08-2019 3
Aluminium smelter
29-08-2019 4
Bauxite Alumina Aluminiumrefinery smelter
Crushing
milling
Bayer’s
process
Hall-Heroult
process
Heat
Power
www.google.com
The real process
29-08-2019 5
𝟐 𝐀𝐥 𝟐 𝐎 𝟑 𝐝𝐢𝐬𝐬𝐨𝐥𝐯𝐞𝐝 + 𝟑 𝐂 𝐬 𝟒 𝐀𝐥(𝐥𝐢𝐪) + 𝟑 𝐎 𝟐(𝐠𝐚𝐬)
Electrolytic reduction not aqueous electrolyte process
Na3AlF6+AlF3
Heat >900o C
Requirement-
Electrolyte
Anode
Cathode
Graphical info.
29-08-2019 6
Details of production
29-08-2019 7
13.460
Real image
29-08-2019 8
Video crust breaking
29-08-2019 9
Video anode change
29-08-2019 10
End product
29-08-2019 11

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Aluminium smelter

Editor's Notes

  1. Alumina is a slippery powder
  2. Hydrogen is much nobler than aluminium