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International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1243
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
Abstract: This study investigates the performance of Hot Mix Asphalt concrete mixtures modified using different types of traditional and Nano
additives. The traditional modifiers include rubber, polyethylene and lime while the Nano modifiers include Nano Silica (NS) and Silica Fume (SF).
The performance of the modified mixtures is comparatively evaluated in order to find the best modifier. The evaluation is done through conducting
the comparison between results obtained on samples using Marshall, Indirect Tensile Strength, Direct Compression, and Wheel Tracking tests. The
used samples are prepared and compacted at the optimum modifier percentage previously founded by other research studies. An economic study
analysis for the direct cost of materials for production of 1 ton of the unmodified and modified mixtures is conducted. The results indicate that NS is
considered the best modifier that achieved maximum stability, minimum flow, higher tensile strength; higher direct compression strength and lower
rutting depth. On the second basis, SF is following NS in achieving relatively nearer results as NS whereas the other modifiers achieved lower
mixture performance rates. The economic analysis indicates that the cost of producing 1 ton of mixture shall be very high cost and not capable to be
applicable solution since it shall cost 27192 L.E using NS as a modifier of HMA. Excluding the NS from the economic analysis rating leads to bring
the SF to be 14% increase in cost compared with the unmodified mixtures but with achieving most applicable improvement in mixture performance
represented by mix stability, flow, direct compression resistance, indirect tensile strength and rutting resistance.
Keywords: Asphalt Mixes, Comparative Study, Nano Silica, Performance, Polymer, Rubber, Silica Fume.
1- INTRODUCTION
Asphalt pavements suffered from different distresses due to
deficiencies in its characteristics and the effect of weather on
the properties of the asphalt binder. Many studies were
conducting to improve the performance of asphalt mixtures to
achieve more resistant to cracking and deficiencies. The most
deficiencies types in asphalt pavements include fatigue, creep,
cracks and rutting which resulted from the shortage in the mix
characteristics and/or the excessive traffic loads.
Kim et al. (2010) studied the effect of using crumb rubber on
asphalt mixture properties. The results indicated that the use
of crumb rubber as a modifier seemed to improve the
penetration resistance of the asphalt binder because of
increasing viscosity at 60ΒΊC. Also, its advantage was more
appear at lower frequencies of loading, and the asphalt binder
with higher crumb rubber contents was observed to have
better resistance to permanent deformation at higher
temperatures and elasticity at lower temperatures, [1].
Crumb rubber is light in weight, durable and can last for a long
period in a natural environment. The utilization of crumb
rubber has proven to be economical, environmentally sound
and effective in increasing the performance of the asphalt
mixtures. Xiao et al. (2010) concluded that increasing the
rubber content improved the aging resistance of the binder
and prolonged the fatigue life of the mixtures, while it caused
decreasing in both the Indirect Tensile Strength (ITS) and the
resilient modulus (Mr). Therefore, rubber was used to enhance
the flexibility of HMA to improve cracking resistance, [2].
Yazan Issa, (2016) investigated the characteristics of asphalt
mixtures using waste tires. It was found that the suitable
percentage of the additive is 10% of aggregate weight. The
additive leaded to increase stability compared to the
unmodified mixture, [3].
Mohamady et al. (2014) studied the effect of using polymers
on bituminous mixtures characteristics in Egypt. The study
presented the effect of polymers on the stability and flow
values for all HMA samples. The results indicated that adding
polymers to asphalt mixes significantly improved stability,
flow and density of HMA up to 4% polymer percentage; and
then the stability was decreased, [4].
Ahmed A. L. (2007) studied the effect of using polyethylene
on the pavement properties. The higher value of Marshall
stability occurred at 10% polyethylene. Adding polyethylene
increased mixture workability and efficiency of compaction for
modified mixes, [5].
Hinisloglu et al. (2005) studied the effect of using high
density polyethylene (HDPE) in powder form as a binder
modifier on the permanent deformation (rutting) of the
asphalt mixtures using Marshall parameters (stability, flow,
density, air voids, voids in mineral aggregates and voids filled
with asphalt) and creep behavior. Also asphalt binder
properties were evaluated such as penetration, softening point
and ductility. Bitumen was mixed with four percentages 1%,
2%, 3% and 4% (by dry weight of bitumen) of HDPE at 185oC
for 60 minutes using high shear mixer. The results indicated
that the maximum stability occurred at 3% of HDPE, while the
better improvement in permanent deformation occurred at
2% HDPE, so it was difficult to investigate the optimum
content of HDPE. It was concluded that the increase in stability
β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”
1 Metwally G. Al-Taher, Prof. Highways & Airports, Construction
Eng. & Utilities Dept., Zagazig University, Egypt, E-mail:
altaher60@hotmail.com.
2 Hassan D. Hassanin, Lecturer Highways & Airports, Construction
Eng. & Utilities Dept., Zagazig University, Egypt, E-mail:
hnaam2@yahoo.com.
3 Mokhtar F. Ibrahim, Lecturer Highways Engineering, Civil
Engineering Dept., the Higher Institute of Engineering, El-Shorouk
City, Egypt, E-mail: mokhtargendy91@gmail.com.
4 Ahmed M. Sawan, Teaching Assistant Highways Engineering, Civil
Engineering Dept., the Higher Institute of Engineering, El-Shorouk
City, Egypt and Currently Pursuing M.Sc. degree program in Civil
Engineering, Zagazig, Egypt, E-mail: ahmedsawan1991@gmail.com
Comparative Study of Performance of Modified
Asphalt Mixtures Using Different Traditional and
Nano Additives
Metwally G. Al-Taher1
, Hassan D. Hassanin2
, Mokhtar F. Ibrahim3
and Ahmed M. Sawan4
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1244
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
ranged from 3 - 21% while flow decreased in the range of 17 –
25%. The creep resistance of the modified specimens was
better than the values of the conventional specimens, [6].
Sheelan A. Ahmed et al. (2015) investigated the effect of
using fiber in treating asphalt mixes. The results presented
that, adding fiber to asphalt mixes improved performance
characteristics of the mixes. Also, it was indicated that the
1.5% fiber of mix weight is considered the most suitable
percentage. It achieved the higher stability which represented
14% increasing compared to the untreated mix, [7].
Mahrez et al. (2005) studied the effect of using glass fiber to
improve the properties of hot mix asphalt (HMA). It was found
that the addition of fiber decreased the mix stability and
increased the flow and the voids in the mix. The results
indicated that the fiber has the potential to improve the fatigue
life by increasing the resistance to cracking and permanent
deformation of bituminous mixes. It concluded that fiber
content of 0.3% by weight of the total mix resulted in the
highest performance in terms of stiffness, resistance to
permanent deformation and fatigue, [8].
European lime association (2008) studied the effect of using
lime in asphalt pavement mixtures. They noted that by adding
hydrated lime to asphalt, it reacts with aggregates,
strengthening the bond between the bitumen and the stone. In
addition, hydrated lime reacts with highly polar molecules in
the bitumen, blocking the formation of water-soluble soaps.
These soaps result in weaker bond strength, and thus
contribute to moisture damage, [9].
Farag Khodary (2016) studied the effect of adding SF on the
soil properties for base course in highways construction.
Results indicated that adding SF improved both the strength
and stability of the modified soil. Adding SF to the base course
material increased CBR from 54% to 94.5%, [10].
Al-Taher et al. (2018) studied the effect of adding SF on the
asphalt concrete mixtures. It was concluded that using SF in
modifying the HMA has a major effect in improving the
bitumen properties. It decreased the penetration value by
46.15% and increased the viscosity by about 30.16%. Also, it
was found that the mix properties were improved such as,
Marshall stability and flow increased by about 23.61% and
4.67% repectively; and thus, the Marshall stiffness increased
by about 18.58%. The optimum SF content that achieved
optimum mix properties was 6% by weight of bitumen
content. Direct Compression (DC) value was increased by
about 25%. Indirect Tensile Strength (ITS) value was increased
by about 3.83% and rutting depth reduced by about 36%, [11]
Al-Taher et al. (2017) studied the effect of adding NS on the
asphalt concrete mixtures. It was found that adding NS to the
asphalt binder improved the physical characteristics of the
asphalt binder. It decreased the penetration and increased its
viscosity. Modifying the asphalt mixture by 7% NS increased
Marshall stability by 25% and decreases the flow by 19%. Also,
it increased the mixture stiffness by 54%, maintaining the unit
weight and AV% within the accepted limits. It improved the DC
test value by 32%, increased the ITS value by 2.7% and
enhanced the rutting resistance by 40%, [12].
Mostafa (2016) studied the effect of using NS and Nano
Carbon (NC) on asphalt mixtures; the results indicated that the
optimal percentages for NS and NC were 7% and 0.5%
respectively. The optimal percentage of NC decreased the
penetration by 9.4% in case of mechanical mixing and 9.8% in
case of high shears mixing. Whereas optimal percentage NS
decreased the penetration by 7.13% in case of mechanical
mixing and 8.1% in case of high shear mixing. The optimal
percentage of NC increased viscosity by 10% in case of
mechanical mixing and by 11.67% in case of high shear mixing;
whereas 7% NS increased viscosity by 8.33% in case of
mechanical mixing and 10% in case of high shear mixing, [13].
The main objective of this paper is to conduct a comparative
study to investigate the performance of asphalt concrete
mixtures used in Egyptian road pavements using traditional
additives compared to the NS and SF additives. An economic
appraisal and analysis for the used additives is considered the
second objective of this comparative study.
2- MATERIALS
2.1 Aggregates
Crushed aggregates are used in preparing the mixture in
addition to filler and binder asphalt. The qualifications of the
aggregates are shown in Table (1), while the grade of mixed
aggregates is shown in Table (2), the aggregates gradation is
(4C) according to the Egyptian code for highways.
Table (1): Aggregates Properties, [11]
Property
AASHTO
Designation No.
Coarse
Agg.
Size (1)
Coarse
Agg.
Size (2)
Fine
Agg.
AASHTO
Limits
Abrasion AASHTO T 96 35.20% 31.4% - 40 Max
Bulk
Specific
Gravity
AASHTO (85-77) 2.495 2.505 2.640 -
Specific
Gravity
AASHTO (85-77) 2.555 2.562 - -
Apparent
Specific
Gravity
AASHTO (85-77) 2.650 2.655 - -
% Water
Absorption
AASHTO (85-77) 2.00% 2.25% - 5 Max
2.2 Asphalt Binder
Asphalt cement 60-70 is used in preparing the mixtures. Its
unit weight is 1.021, while its penetration and viscosity as well
as other properties are presented in Table (3).
2.3 LDPE
Waste plastic bags are made from Low Density Polyethylene
(LDPE). LDPE has a high degree of short and long chain
branching, which means that the chains do not pack into the
crystal structure as well. The properties of LDPE are shown in
Table (7) and its shape is shown in Figure (1-a).
2.4 Lime
Limestone dust filler with bulk specific gravity of 2.75 is used
in samples preparation, its gradation is shown in Table (4),
while its shape is shown in Figure (1-a).
2.5 Silica Fume (SF)
SF or micro-silica is a byproduct material. It can be produced
by reduction of high-purity quartz with coal in electric
furnaces in the production of silicon and ferrosilicon alloys.
The physical composition of the used SF minerals is shown in
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1245
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
Tables (5) and (6), while its shape is shown in Figure (1-b),
[14].
Table (2): Aggregate Gradation, [11]
Type
Coarse Agg.
Fine Agg.
Mineral
Filler
Agg.
Mix
Limits
Agg. 1 Agg. 2
Sieve
Size
(inch)
Sieve
Size
(mm)
%
Pass.
25%
%
Pass.
26%
%
Pass.
45%
%
Pass.
4%
1 26.5 100 25 100 26 100 45 100 4 100 100
3/4 19.0 95 23.75 100 26 100 45 100 4 98.75
80-
100
1/2 13.2 38 9.5 100 26 100 45 100 4 84.50 -
3/8 9.52 8 2 80 20.8 100 45 100 4 71.80 60-80
#4 4.75 - - 8.4 2.18 95 42.75 100 4 48.93 48-65
#8 2.36 - - - - 71.8 32.31 100 4 36.31 35-50
#30 0.60 - - - - 44.3 19.49 100 4 23.94 19-30
#50 0.30 - - - - 26.2 11.79 100 4 15.79 13-23
#100 0.15 - - - - 8 3.6 90 3.6 7.20 7-15
#200 0.075 - - - - - - 75 3 3.00 3-8
Table (3): Properties of Asphalt Binder [11]
Property
AASHTO
Designation
No.
Result
Specifications
Limits
Penetration at 25oc,
(0.1mm)
T-49 65 60-70
Rotation Viscosity
at 13oc, (Cst)
T-201 378 β‰₯ 320
Flash Point, (oC) T-48 268 β‰₯ 250
Softening Point,
(oC)
T-53 52 45-55
Table (4): Gradation of Lime
Sieve Size %
Passing
Specifications
Limits(inch) (mm)
No 30 0.6 100 β‰₯ 100
No 50 0.3 100 -
No 100 0.15 90 β‰₯ 85
No 200 0.075 75 β‰₯ 65
Table (5): Chemical Properties of SF, [14]
No. Parameters Test Value
1 Silica as SiO2, % by mass 89.90
2 Total Sulphur Content as
SO3, % by mass
0.58
3 Lime as CaO, % by mass 7.85
4 Magnesia as MgO, % by mass 4.03
5 Alumina as AL2O3, % by mass Nil
6 Iron Oxide as Fe2O3, % by mass Nil
Table (6): Physical Properties of SF, [14]
No. Parameters Test Value
1 Density (gm/cm3) 2.07
2 Physical state
Clear grey
powder
3 Practical Size Distribution (%) 59
Polymer (LDPE) Rubber Lime
Figure (1-a): LDPE , Rubber and Lime Shape.
Silica Fume Nano Silica
Figure (1-b): SF and NS Shape.
Table (7): Properties of Additives
Type Plastic Bags Rubber Lime
Silica
Fume
Nano
Silica
Molecular
Formula
(-CH2-CH2-) n C5H8 Ca(OH)2
Miro
(SiO2)
Nano
(SiO2)
Density
(gm/cm3)
0.910 - 0.940 1.07 2.75 2.07 -----
Melting
point (oC)
170oC 125oC ----- ----- -----
Physical
State
-----
Clear
Black
Powder
Clear
White
Powder
Clear
Grey
Powder
Clear
White
Powder
Solubility Insoluble Insoluble Soluble Soluble Soluble
Table (8): Chemical Composition of NS, [12]
Sample Name SI Calcite 0.28
Date 16-09-2015 Mulite 0
Time 23:28:32 PM Magnetite 0
R_wp 6.64 Hematite 0
Alite_Sum 0 Thenardite 0
Lime 0.06 Rutile 0
Periclase 0.09 Si_amorph 99.15
Quartz 0.19
Anhydrite 0.24
2.6 Nano Silica (N.S)
NS used in this research is produced in Faculty of science –
Beni-Suef University. The chemical composition of NS is
presented in Table (8). Figure (2-a) shows X-ray test results of
Nano Silica, while Figure (2-b) shows Nano Silica under
Scanning Electron Microscopic (SEM).
Figure (2-a): X-Rays Test of NS, [12].
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1246
ISSN 2229-5518
IJSER Β© 2018
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Figure (2-b): NS under SEM, [12].
3- Testing Methods
Four test methods are used to evaluate and compare the
obtained results of the asphalt concrete mixtures modified by
the different stated modifiers. The test methods include
Marshall test as per ASTM D 6927-06 to determine the
properties of asphalt mixes. It is conducted on the control mix
to get the optimum asphalt content and define the basic
properties of such as stability, flow, unit weight, air voids (AV
%), voids of mineral aggregates percentage (VMA%) and voids
filled with bitumen (VFB%). Then the test is conducted on the
modified mixes using SF, NS, Rubber, Lime, and polymer with
optimum percentages 6, 7, 10, 5 and 4% respectively. The
optimum percentages of the added modifiers are defined from
the literature review. The second test is the Indirect Tensile
Strength (ITS) test as per AASHTO T322-03 which used to
evaluate the resistance of the asphalt concrete mixtures to the
applied tensile stresses. This tensile stress causes the
specimen to fail by splitting or rupturing along the vertical
diameter.
The Direct Compression (DC) Test as per ASTM D-1074 is
conducted on the modified asphalt concrete mix specimens to
investigate the behavior of both control and modified
specimens under crushing loads. DC test is used to evaluate
compression strength of control asphalt mix and comparison
with another treated mixes. The specimen is placed under
compression force with an incremental of load values. Three
specimens are prepared for this test for the control mix and
similar three specimens are prepared and tested for each of
the five types of modifiers. ITS value (St) is determined using
the following equation: St = 2P/(Ο€HD), (kg/cm2), where: P is
the applied load in kg, H is the specimen height in cm, and D is
the specimen diameter in cm.
The fourth test is the Wheel Tracking (WT) test which used to
measure the rutting depth of hot mix asphalt mixtures in the
wheel-tracking device as per AASHTO (T324-04). The method
describes the compaction procedure of asphalt mixtures in a
reciprocating rolling-wheel device. This test provides
information about the rate of permanent deformation from a
moving concentrated load.
4. RESULTS AND DISCUSSIONS
4.1 Asphalt Cement Properties Evaluation
Characteristics of asphalt cement are examined for the
modified specimens with different traditional and Nano
additives. The comparison is made through conducting the
penetration and viscosity tests on both control specimens (C.S)
and modified specimens (M.S). Figure (3) shows the effect of
adding different percentages of waste plastic bags, rubber,
lime, SF and NS to the asphalt cement on the penetration test
values. Results of penetration test indicate that the penetration
value is decreased for all modified samples. Waste plastic bags
and lime record the lowest penetration values, the penetration
is decreased by 68% and 55.4% respectively. Adding SF,
Rubber, and NS decrease the penetration value by 46.2%,
21.5%, and 17% respectively.
Figure (4) shows the effect of adding different additives to
asphalt cement on the viscosity value. Viscosity test results
indicate that the viscosity increases for all modified specimens
using the different additives. Adding waste plastic bags and
lime achieve the highest viscosity values; the viscosity
increases by 44.18% and 35.0% respectively. SF, Rubber, and
NS increase the viscosity value by 30.16%, 15.1%, and 9.8%
respectively.
65
21
51
29
35
54
0
10
20
30
40
50
60
70
Penetration(1/10)mm
C.M"no additives" C.M+ 4% LDPE C.M + 10% Rubber
C.M+ 5% Lime C.M+ 6% S.F C.M + 7% N.S
Figure (3): Effect of Adding Lime, LDPE, Rubber, SF
and NS on Penetration.
378
545
435
510
492
415
300
350
400
450
500
550
Viscosity(Cst)
C.M"no additives" C.M+ 4% LDPE C.M + 10% Rubber
C.M+ 5% Lime C.S + 6% S.F C.S + 7% N.S
Figure (4): Effect of Adding Lime, LDPE, Rubber, SF and
NS on Rotational Viscosity.
4.2 Asphalt Mixtures Properties Evaluation
4.2.1 Stability/Flow Evaluation
Figure (5) shows the effect of using different additives
including traditional and Nano on the stability of asphalt
mixtures. The additives are added to the mix at its optimum
percentage as founded previously and the percentage of
asphalt content is chosen as the optimum from Marshall
control mix (C.M). Results indicate that the maximum stability
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1247
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
of modified mixture using NS and SF is improved by 25% and
23.61% respectively. Waste plastic bags, lime, and rubber
increase the stability by 21.32%, 19.69% and 12.84%
respectively. Accordingly, NS and SF are the best additives in
improving the stability of asphalt mixtures.
2880
3494
3250
3447
3560
3600
2500
2700
2900
3100
3300
3500
3700
Stability(Ib)
C.M" no additives" C.M + 4% LDPE C.M + 10% Rubber
C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S
Figure (5): Effect of Adding Lime, LDPE, Rubber, SF and
NS on Marshall Stability.
Figure (6) shows the effect of using different types of
additives on the flow values of asphalt mixtures
compacted at the optimum asphalt content (OAC) and
optimum additive content for each type. Results
indicate that all types of additives decrease the flow
value compared to the control mix value except the case
of adding SF which increases the flow value by 3.29%.
Waste plastic bags, rubber and lime decrease flow value
by 10.5%, 12.5% and 14.47% respectively, also NS
decreases flow value by 19.08%. Accordingly, NS is
considered the best additive in improving the flow of
asphalt mixtures.
0.152
0.133
0.136
0.130
0.157
0.123
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
Flow(inch)
C.M" no additives" C.M + 4% LDPE C.M+ 10% Rubber
C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S
Figure (6): Effect of Adding Lime, LDPE, Rubber, SF and
NS on Marshall Flow.
4.2.2 Unit Weight and Air Voids
Figure (7) shows the effect of using different types of additives
on the AV% of asphalt mixtures at OAC. The Figure shows that
at OAC, the air voids % for all types of additives increases
compared to the control mix air void percentage. However, all
obtained air voids percentages for all types of additives are
still within the accepted specification limits. Waste plastic
bags, rubber and lime increase AV% by 8.75%, 7.5% and
1.88% respectively. As well as adding SF and NS to asphalt
mixtures increase AV% by 3.13% and 14% respectively.
3.20
3.48
3.44
3.26
3.30
3.65
2.90
3.00
3.10
3.20
3.30
3.40
3.50
3.60
3.70
AirVoids(%)
C.M" no additives" C.M+ 4% LDPE C.M + 10% Rubber
C.M + 5% Lime C.M + 6% S.F C.M + 7% N.S
Figure (7): Effect of Adding Lime, LDPE, Rubber, SF and
NS on AV%.
Figure (8) shows the effect of using lime, LDPE, rubber, SF and
NS on the unit weight values of asphalt mixtures at OAC.
Results indicate that the obtained unit weight for all types of
additives ranges from 2.299 to 2.305 gm/cm3. The higher unit
weight is occurred when adding SF to the asphalt mix ,while
the lower unit weight is occurred by adding rubber and NS.
2.304
2.299
2.300
2.303
2.305
2.299
2.296
2.297
2.298
2.299
2.3
2.301
2.302
2.303
2.304
2.305
2.306
Unitweight(gm/cm3)
C.M" no additives" C.M+ 4% LDPE C.M+ 10% Rubber
C.M + 5% Lime C.M+6% S.F C.M + 7% N.S
Figure (8): Effect of Adding Lime, LDPE, Rubber, SF and
NS on Unit Weight.
Figures (9) and (10) show the effect of adding different types
of additives on both of the voids in mineral aggregates
percentage (VMA %) and the percentage of voids filled with
bitumen (VFB %). Results indicate that the % VMA value is
increased for all types of additives except using SF which
decreases the % VMA. Also Results indicate that the % VFB is
decreased for all types of additives.
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International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1248
ISSN 2229-5518
IJSER Β© 2018
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15.18
15.32
15.28
15.21
15.10
15.20
14.95
15.00
15.05
15.10
15.15
15.20
15.25
15.30
15.35VMA%
C.M" no additives" C.M+ 4% LDPE C.M+ 10% Rubber
C.M + 5% Lime C.M + 6% Silica Fume C.M + 7% Nano Silica
Figure (9): Effect of Adding Lime, LDPE, Rubber, SF and NS
on VMA%.
79.00
77.28
77.50
78.60
78.00
76.00
74.50
75.00
75.50
76.00
76.50
77.00
77.50
78.00
78.50
79.00
79.50
VFB%
C.M" no additives" C.M + 4% LDPE C.M+ 10% Rubber
C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S
Figure (10): Effect of Adding Lime, LDPE, Rubber, SF and NS
on VFB%.
Figure (11) shows the significant change in asphalt mixtures
stiffness values by adding both traditional and nano additives
to HMA. Results investigate that the values of stiffness increase
with all types of additives. NS seems to be the best additive
that improves stiffness of asphalt mixtures by about 54.5%.
18947.37
26270.68
23897.06
26515.38
22675.16
29268.293
11500.00
13500.00
15500.00
17500.00
19500.00
21500.00
23500.00
25500.00
27500.00
29500.00
31500.00
Sstability/Flow(Ib/in)
C.M" no additives" C.M+ 4% LDPE C.M + 10% Rubber
C.M + 5% Lime C.M + 6% S.F C.M+ 7% N.S
Figure (11): Effect of Adding Lime, LDPE, Rubber, SF
and NS on Marshall Stiffness.
4.2.3 DC & ITS Evaluation
Figures (12) and (13) present the comparison between the DC
and the ITS values for the different used additives. Figures
show that SF achieves compressive strength by about 26.80%
increase compared with the control mix. Figures show also
that SF, LDPE and NS achieve approximately nearer ITS value
by about 7% increase compared with the control mix.
29.19
30.01 30.01
30.43
37.00
31.66
22.00
24.00
26.00
28.00
30.00
32.00
34.00
36.00
38.00
AverageDCT,(kg/cm2) C.M"no additives" C.M + 10% Rubber C.M+ 4% LDPE
C.M+ 5% Lime C.M + 6% Silica Fume C.M + 7% Nano Silica
Figure (12): Effect of Adding Lime, LDPE, Rubber, SF and NS on
DC values.
9.36
10.38
10.06
8.19
9.99
10.21
5.00
6.00
7.00
8.00
9.00
10.00
11.00
AverageITS,(kg/cm2)
C.M "no additives" C.M + 10% Rubber C.M + 4% LDPE
C.M + 5% Lime C.M + 6% Silica Fume C.M+ 7% Nano Silica
Figure (13): Effect of Adding Lime, LDPE, Rubber, SF and NS on
ITS values.
4.2.4 Evaluation of Rutting Depth
Wheel Tracking (WT) Test is performed on asphalt mix
samples prepared at the optimum asphalt content obtained
from Marshall test. WT test value is considered an important
result, so it reflects to the ability of the asphalt mixture to
resist rutting. The WT test is performed on asphalt mix
samples containing optimum percentage of different types of
additives. The obtained results of WT test are shown in Figure
(14). Results indicate that rutting depth increases with the
increasing of time (direct relationship). The rutting depth
values, at the end of the test, of modified asphalt mixes
decrease the depth of rutting. All of the used additives
decrease the rutting depth but waste plastic bags are the best
additive because it decreases the rutting depth to 4.572 mm. In
addition, rubber and SF record the same value of the rutting
depth of 5.46 mm.
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1249
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
8.51
5.46
4.57
7.24
5.46
5.08
0
2
4
6
8
10
RuttingDepth,mm
C.M"no additives" C.M+ 10% Rubber C.M+ 4% LDPE
C.M+ 5% Lime C.M+ 6% S.F C.M+ 7% N.S
Figure (14): Effect of Adding Lime, LDPE, Rubber, SF and NS on
Rutting Depth.
4.3 Economic Evaluation of Modified Mixtures
An economic study is conducting to differentiate between the
direct costs of producing a constant quantity of asphalt
mixture (1m3) using the different evaluated types of
investigated additives. The cost analysis is based only on the
direct cost of the materials constitutes the mixtures which
includes Coarse Aggregate (CA), Fine Aggregate (FA), Mineral
Filler (MF), Asphalt Cement (AC), and the used modifiers. The
indirect production cost and profits are not included in this
analysis since it shall be approximately constant for all
mixtures.
Table (9) presents the properties of different modified
mixtures using different modifiers. It shows the type of
modifier and its related OAC, optimum modifier percentage,
and the obtained mixture unit weight.
Table 10 presents the calculation of the materials direct cost of
both of 1 m3 and 1 Ton of each of the modified mixtures as well
as the unmodified mix. The calculations were conducted based
on the mix gradation shown in Table (2) as well as the
obtained mixtures properties are shown in Table (9).
Table (9): OAC and Unit Weight of Asphalt Mixes and Modifiers
Prices.
Additive
Type
OAC
Additive,
%
Unit Weight,
Kg/m3
Cost of Modifier,
LE/ton
No Additive 5.65 0 2304 0
LDPE 5.65 4 2299 15000
Rubber 5.65 10 2300 30000
Lime 5.65 5 2303 500
SF 5.55 6 2305 25000
NS 5.45 7 2299 7000000
As shown in Table (10), the cost of production of 1 ton of the
unmodified mix is 503 L.E., the same cost as using lime. While
that for using LDPE is 537 L.E. and that for using SF is 578 L.E.
and 672 L.E. using rubber. The cost of using NS in producing 1
ton is very high, it is about 27192 L.E. which represent about
5000 time the cost of unmodified mix.
Table (11) presents the percentage of increase in the materials
direct cost while Figures (15) and (16) present the relative
direct cost of them.
Table (10): Cost Analysis Calculation of Direct Cost of Modified
Mixtures Materials
Modifier Type None LDPE Rubber Lime SF NS
Modifier, % 0 4 10 5 6 7
Mix Unit Weight, Kg/m3 2304 2299 2300 2303 2305 2299
OAC, % 5.65 5.65 5.65 5.65 5.55 5.45
Weight of m3 of Mix, Kg 2304 2299 2300 2303 2305 2299
Weight of AC, Kg 130 130 130.0 130 128 125
Weight of CA, Kg 1109 1106 1107 1108 1110 1109
Weight of FA, Kg 978 976 977 978 980 978
Weight of Filler, Kg 87 87 87 87 87 87
Weight of Modifier, Kg 0.00 5.20 13.00 6.51 7.68 8.77
Cost of Modifier,
L.E./Kg
0 15 30 0.5 25 7000
Cost of AC L.E./Kg 8 8 8 8 8 8
Cost of CA L.E./Kg 0.04 0.04 0.04 0.04 0.04 0.04
Cost of FA L.E./Kg 0.03 0.03 0.03 0.03 0.03 0.03
Cost of Filler L.E./Kg 0.5 0.5 0.5 0.5 0.5 0.5
Cost of 1 m3 , L.E. 1159 1234 1546 1161 1333 62514
Cost of 1 Ton, L.E. 503 537 672 504 578 27192
Table (11): % increase in Cost of 1 ton of Modified
Mixtures
Additives Type
Total Cost
(LE/ton)
% increase
No Additive 503 0.00
Lime 504 0.20
LDPE 537 6.76
SF 578 14.91
Rubber 672 33.60
NS 27192 5305.96
503 504 537 578 672
27192
0
5000
10000
15000
20000
25000
30000
Costof1TonofMix,L.E.
C.M"no additives" C.M+ 5% Lime C.M+ 4% LDPE
C.M+ 6% S.F C.M+ 10% Rubber C.M+ 7% N.S
Figure (15): Cost of Production of 1 ton of Asphalt Mixes Using
Lime, LDPE, Rubber, SF and NS as Modifiers.
IJSER
International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1250
ISSN 2229-5518
IJSER Β© 2018
http://www.ijser.org
503 504
537
578
672
0
100
200
300
400
500
600
700
800
Costof1TonofMix,L.E.
C.M"no additives" C.M+ 5% Lime C.M+ 4% LDPE
C.M+ 6% S.F C.M+ 10% Rubber
Figure (16): Cost of Production of 1 ton of Asphalt Mixes Using
Lime, LDPE, Rubber and SF as Modifiers, (Excluding NS).
5. CONCLUSIONS
In this study, the performance of asphalt concrete mixtures is
evaluated using different types of traditional and Nano
materials. NS is considered the best modifiers since they
achieve the best performance.
Economic analysis of the materials direct cost of the used
additives indicates that NS is not applicable for use since it is
very costly. It costs about 5000 times the unmodified mixture.
SF is considered the most appraisable additive in obtaining the
good performance with moderate cost increase (about 14%).
Also, Lime, LDPE and rubber provide a significant change in
physical and mechanical properties of asphalt mixes.
REFERENCES
[1] Hak-Seo Kim, Soon-Jae Lee, and Serji Amir khanian,
(2010),"Rheology Investigation of Crumb Rubber Modified
Asphalt Binders", KSCE Journal of Civil Engineering -
14(6):839-843.
[2] Xiao F and Amirkhanian S N (2010), "Laboratory
investigation of utilizing high percentage of RAP in
rubberized asphalt mixture", Materials and Structures
43:223–233.
[3] Yazan Issa, (May 2016), "Effect of Adding Waste Tires
Rubber to Asphalt Mix", Civil Engineering Department,
Fahd Bin Sultan University, Saudi Arabia, International
Journal of Scientific Research and Innovative Technology
ISSN: 2313-3759.
[4] Ahmed Mohamady, Mohamed Ibrahim EL-Sharkawi,
Mahmoud Fathy and Eslam Magdy, construction Eng. And
Utilities Dept. (July-Aug 2014),"Effecting of Using
Polymers on Bituminous Mixtures Characteristics in
Egypt", IOSR Journal of Mechanical and Civil Engineering,
Vol.11, Issue 4.
[5] Ahmed A.L, (2007), "Improvement of Marshall Properties
of the Asphalt Concrete Mixtures Using the Polyethylene
as Additive", College of Engineering, Basrah University,
Basrah-IRAQ Eng. & Technology, Vol. 25, No.3.
[6] Sinan Hinislioglu, Hatice Nur Aras and Osman Unsal
bayrak ,(2005) , "Effects of High Densit Polyethylene on
Permanent Deformation of Asphalt Concrete", Department
of Civil Engineering Faculty of Engineering – Ataturk
University.
[7] Sheelan A. Ahmed and Omar T. Mahmood (August 2015),
"Influence of Mineral Fibers Properties on the
Performance of Hot Mix Asphalt for the Surface Layer of
Pavement", Department of Civil Engineering, Faculty of
Engineering, Koya University, Erbil, Iraq, International
Journal of Engineering Trends and Technology (IJETT) –
Volume 26 Number 3.
[8] Abdelaziz Mahrez , Mohamed Rehan Karim and Herda Yati
bt Katman , (2005), "Fatigue And Deformation Properties
Of Glass Fiber Reinforced Bituminous Mixes", Dept. of Civil
Engineering University Malaya - 50603 Kuala Lumpur –
Malaysia.
[9] European lime association, (2008), "Hydrated lime a
proven additive for durable asphalt pavements.
[10]Farag Khodary (2016), " Impact of Silica fume on the
properties of Asphalt pavement base course", Civil
Engineering Department, Qena Faculty of Engineering,
South Valley University, Qena, Egypt, International Journal
of Engineering Trends and Technology (IJETT).
[11]Metwally G. Al-Taher, Hassan D. Hassanin, Mokhtar F.
Elgendy and Ahmed M. Sawan (April 2018), "Investigation
of the Effect of Adding Silica Fume on Asphalt Concrete
Properties", International Journal of Engineering
Research, Volume (7), Issue (4), ISSN 2319-6890.
[12] Metwally G. Al-Taher, Hassan D. Hassanin, Mokhtar F.
Elgendy and Ahmed M. Sawan, (December 2017)
"Improving the Performance of Asphalt Mixtures Using
Nano Silica", World Applied Sciences Journal, Volume (35),
ISSN 1818-4952.
[13]Abdelzaher E. A. Mostafa, 2016, "Examining the
Performance of Hot Mix Asphalt Using Nano-Materials",
Associate Professor, Civil Engineering, Mataria School of
Engineering, Helwan University, Cairo, Egypt.
[14]Chhaya Negi R.K.Yadav and A.K. Singhai, (July 2013),
"Effect of Silica Fume on Engineering Properties of Black
Cotton Soil", Geotechnical Engineering, JEC Jabalpur,
(M.P.), India, International Journal of Computational
Engineering Research, Vol, 03.
IJSER

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Comparative study-of-performance-of-modified-asphalt-mixtures-using-different-traditional-and-nano-additives

  • 1. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1243 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org Abstract: This study investigates the performance of Hot Mix Asphalt concrete mixtures modified using different types of traditional and Nano additives. The traditional modifiers include rubber, polyethylene and lime while the Nano modifiers include Nano Silica (NS) and Silica Fume (SF). The performance of the modified mixtures is comparatively evaluated in order to find the best modifier. The evaluation is done through conducting the comparison between results obtained on samples using Marshall, Indirect Tensile Strength, Direct Compression, and Wheel Tracking tests. The used samples are prepared and compacted at the optimum modifier percentage previously founded by other research studies. An economic study analysis for the direct cost of materials for production of 1 ton of the unmodified and modified mixtures is conducted. The results indicate that NS is considered the best modifier that achieved maximum stability, minimum flow, higher tensile strength; higher direct compression strength and lower rutting depth. On the second basis, SF is following NS in achieving relatively nearer results as NS whereas the other modifiers achieved lower mixture performance rates. The economic analysis indicates that the cost of producing 1 ton of mixture shall be very high cost and not capable to be applicable solution since it shall cost 27192 L.E using NS as a modifier of HMA. Excluding the NS from the economic analysis rating leads to bring the SF to be 14% increase in cost compared with the unmodified mixtures but with achieving most applicable improvement in mixture performance represented by mix stability, flow, direct compression resistance, indirect tensile strength and rutting resistance. Keywords: Asphalt Mixes, Comparative Study, Nano Silica, Performance, Polymer, Rubber, Silica Fume. 1- INTRODUCTION Asphalt pavements suffered from different distresses due to deficiencies in its characteristics and the effect of weather on the properties of the asphalt binder. Many studies were conducting to improve the performance of asphalt mixtures to achieve more resistant to cracking and deficiencies. The most deficiencies types in asphalt pavements include fatigue, creep, cracks and rutting which resulted from the shortage in the mix characteristics and/or the excessive traffic loads. Kim et al. (2010) studied the effect of using crumb rubber on asphalt mixture properties. The results indicated that the use of crumb rubber as a modifier seemed to improve the penetration resistance of the asphalt binder because of increasing viscosity at 60ΒΊC. Also, its advantage was more appear at lower frequencies of loading, and the asphalt binder with higher crumb rubber contents was observed to have better resistance to permanent deformation at higher temperatures and elasticity at lower temperatures, [1]. Crumb rubber is light in weight, durable and can last for a long period in a natural environment. The utilization of crumb rubber has proven to be economical, environmentally sound and effective in increasing the performance of the asphalt mixtures. Xiao et al. (2010) concluded that increasing the rubber content improved the aging resistance of the binder and prolonged the fatigue life of the mixtures, while it caused decreasing in both the Indirect Tensile Strength (ITS) and the resilient modulus (Mr). Therefore, rubber was used to enhance the flexibility of HMA to improve cracking resistance, [2]. Yazan Issa, (2016) investigated the characteristics of asphalt mixtures using waste tires. It was found that the suitable percentage of the additive is 10% of aggregate weight. The additive leaded to increase stability compared to the unmodified mixture, [3]. Mohamady et al. (2014) studied the effect of using polymers on bituminous mixtures characteristics in Egypt. The study presented the effect of polymers on the stability and flow values for all HMA samples. The results indicated that adding polymers to asphalt mixes significantly improved stability, flow and density of HMA up to 4% polymer percentage; and then the stability was decreased, [4]. Ahmed A. L. (2007) studied the effect of using polyethylene on the pavement properties. The higher value of Marshall stability occurred at 10% polyethylene. Adding polyethylene increased mixture workability and efficiency of compaction for modified mixes, [5]. Hinisloglu et al. (2005) studied the effect of using high density polyethylene (HDPE) in powder form as a binder modifier on the permanent deformation (rutting) of the asphalt mixtures using Marshall parameters (stability, flow, density, air voids, voids in mineral aggregates and voids filled with asphalt) and creep behavior. Also asphalt binder properties were evaluated such as penetration, softening point and ductility. Bitumen was mixed with four percentages 1%, 2%, 3% and 4% (by dry weight of bitumen) of HDPE at 185oC for 60 minutes using high shear mixer. The results indicated that the maximum stability occurred at 3% of HDPE, while the better improvement in permanent deformation occurred at 2% HDPE, so it was difficult to investigate the optimum content of HDPE. It was concluded that the increase in stability β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€”β€” 1 Metwally G. Al-Taher, Prof. Highways & Airports, Construction Eng. & Utilities Dept., Zagazig University, Egypt, E-mail: altaher60@hotmail.com. 2 Hassan D. Hassanin, Lecturer Highways & Airports, Construction Eng. & Utilities Dept., Zagazig University, Egypt, E-mail: hnaam2@yahoo.com. 3 Mokhtar F. Ibrahim, Lecturer Highways Engineering, Civil Engineering Dept., the Higher Institute of Engineering, El-Shorouk City, Egypt, E-mail: mokhtargendy91@gmail.com. 4 Ahmed M. Sawan, Teaching Assistant Highways Engineering, Civil Engineering Dept., the Higher Institute of Engineering, El-Shorouk City, Egypt and Currently Pursuing M.Sc. degree program in Civil Engineering, Zagazig, Egypt, E-mail: ahmedsawan1991@gmail.com Comparative Study of Performance of Modified Asphalt Mixtures Using Different Traditional and Nano Additives Metwally G. Al-Taher1 , Hassan D. Hassanin2 , Mokhtar F. Ibrahim3 and Ahmed M. Sawan4 IJSER
  • 2. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1244 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org ranged from 3 - 21% while flow decreased in the range of 17 – 25%. The creep resistance of the modified specimens was better than the values of the conventional specimens, [6]. Sheelan A. Ahmed et al. (2015) investigated the effect of using fiber in treating asphalt mixes. The results presented that, adding fiber to asphalt mixes improved performance characteristics of the mixes. Also, it was indicated that the 1.5% fiber of mix weight is considered the most suitable percentage. It achieved the higher stability which represented 14% increasing compared to the untreated mix, [7]. Mahrez et al. (2005) studied the effect of using glass fiber to improve the properties of hot mix asphalt (HMA). It was found that the addition of fiber decreased the mix stability and increased the flow and the voids in the mix. The results indicated that the fiber has the potential to improve the fatigue life by increasing the resistance to cracking and permanent deformation of bituminous mixes. It concluded that fiber content of 0.3% by weight of the total mix resulted in the highest performance in terms of stiffness, resistance to permanent deformation and fatigue, [8]. European lime association (2008) studied the effect of using lime in asphalt pavement mixtures. They noted that by adding hydrated lime to asphalt, it reacts with aggregates, strengthening the bond between the bitumen and the stone. In addition, hydrated lime reacts with highly polar molecules in the bitumen, blocking the formation of water-soluble soaps. These soaps result in weaker bond strength, and thus contribute to moisture damage, [9]. Farag Khodary (2016) studied the effect of adding SF on the soil properties for base course in highways construction. Results indicated that adding SF improved both the strength and stability of the modified soil. Adding SF to the base course material increased CBR from 54% to 94.5%, [10]. Al-Taher et al. (2018) studied the effect of adding SF on the asphalt concrete mixtures. It was concluded that using SF in modifying the HMA has a major effect in improving the bitumen properties. It decreased the penetration value by 46.15% and increased the viscosity by about 30.16%. Also, it was found that the mix properties were improved such as, Marshall stability and flow increased by about 23.61% and 4.67% repectively; and thus, the Marshall stiffness increased by about 18.58%. The optimum SF content that achieved optimum mix properties was 6% by weight of bitumen content. Direct Compression (DC) value was increased by about 25%. Indirect Tensile Strength (ITS) value was increased by about 3.83% and rutting depth reduced by about 36%, [11] Al-Taher et al. (2017) studied the effect of adding NS on the asphalt concrete mixtures. It was found that adding NS to the asphalt binder improved the physical characteristics of the asphalt binder. It decreased the penetration and increased its viscosity. Modifying the asphalt mixture by 7% NS increased Marshall stability by 25% and decreases the flow by 19%. Also, it increased the mixture stiffness by 54%, maintaining the unit weight and AV% within the accepted limits. It improved the DC test value by 32%, increased the ITS value by 2.7% and enhanced the rutting resistance by 40%, [12]. Mostafa (2016) studied the effect of using NS and Nano Carbon (NC) on asphalt mixtures; the results indicated that the optimal percentages for NS and NC were 7% and 0.5% respectively. The optimal percentage of NC decreased the penetration by 9.4% in case of mechanical mixing and 9.8% in case of high shears mixing. Whereas optimal percentage NS decreased the penetration by 7.13% in case of mechanical mixing and 8.1% in case of high shear mixing. The optimal percentage of NC increased viscosity by 10% in case of mechanical mixing and by 11.67% in case of high shear mixing; whereas 7% NS increased viscosity by 8.33% in case of mechanical mixing and 10% in case of high shear mixing, [13]. The main objective of this paper is to conduct a comparative study to investigate the performance of asphalt concrete mixtures used in Egyptian road pavements using traditional additives compared to the NS and SF additives. An economic appraisal and analysis for the used additives is considered the second objective of this comparative study. 2- MATERIALS 2.1 Aggregates Crushed aggregates are used in preparing the mixture in addition to filler and binder asphalt. The qualifications of the aggregates are shown in Table (1), while the grade of mixed aggregates is shown in Table (2), the aggregates gradation is (4C) according to the Egyptian code for highways. Table (1): Aggregates Properties, [11] Property AASHTO Designation No. Coarse Agg. Size (1) Coarse Agg. Size (2) Fine Agg. AASHTO Limits Abrasion AASHTO T 96 35.20% 31.4% - 40 Max Bulk Specific Gravity AASHTO (85-77) 2.495 2.505 2.640 - Specific Gravity AASHTO (85-77) 2.555 2.562 - - Apparent Specific Gravity AASHTO (85-77) 2.650 2.655 - - % Water Absorption AASHTO (85-77) 2.00% 2.25% - 5 Max 2.2 Asphalt Binder Asphalt cement 60-70 is used in preparing the mixtures. Its unit weight is 1.021, while its penetration and viscosity as well as other properties are presented in Table (3). 2.3 LDPE Waste plastic bags are made from Low Density Polyethylene (LDPE). LDPE has a high degree of short and long chain branching, which means that the chains do not pack into the crystal structure as well. The properties of LDPE are shown in Table (7) and its shape is shown in Figure (1-a). 2.4 Lime Limestone dust filler with bulk specific gravity of 2.75 is used in samples preparation, its gradation is shown in Table (4), while its shape is shown in Figure (1-a). 2.5 Silica Fume (SF) SF or micro-silica is a byproduct material. It can be produced by reduction of high-purity quartz with coal in electric furnaces in the production of silicon and ferrosilicon alloys. The physical composition of the used SF minerals is shown in IJSER
  • 3. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1245 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org Tables (5) and (6), while its shape is shown in Figure (1-b), [14]. Table (2): Aggregate Gradation, [11] Type Coarse Agg. Fine Agg. Mineral Filler Agg. Mix Limits Agg. 1 Agg. 2 Sieve Size (inch) Sieve Size (mm) % Pass. 25% % Pass. 26% % Pass. 45% % Pass. 4% 1 26.5 100 25 100 26 100 45 100 4 100 100 3/4 19.0 95 23.75 100 26 100 45 100 4 98.75 80- 100 1/2 13.2 38 9.5 100 26 100 45 100 4 84.50 - 3/8 9.52 8 2 80 20.8 100 45 100 4 71.80 60-80 #4 4.75 - - 8.4 2.18 95 42.75 100 4 48.93 48-65 #8 2.36 - - - - 71.8 32.31 100 4 36.31 35-50 #30 0.60 - - - - 44.3 19.49 100 4 23.94 19-30 #50 0.30 - - - - 26.2 11.79 100 4 15.79 13-23 #100 0.15 - - - - 8 3.6 90 3.6 7.20 7-15 #200 0.075 - - - - - - 75 3 3.00 3-8 Table (3): Properties of Asphalt Binder [11] Property AASHTO Designation No. Result Specifications Limits Penetration at 25oc, (0.1mm) T-49 65 60-70 Rotation Viscosity at 13oc, (Cst) T-201 378 β‰₯ 320 Flash Point, (oC) T-48 268 β‰₯ 250 Softening Point, (oC) T-53 52 45-55 Table (4): Gradation of Lime Sieve Size % Passing Specifications Limits(inch) (mm) No 30 0.6 100 β‰₯ 100 No 50 0.3 100 - No 100 0.15 90 β‰₯ 85 No 200 0.075 75 β‰₯ 65 Table (5): Chemical Properties of SF, [14] No. Parameters Test Value 1 Silica as SiO2, % by mass 89.90 2 Total Sulphur Content as SO3, % by mass 0.58 3 Lime as CaO, % by mass 7.85 4 Magnesia as MgO, % by mass 4.03 5 Alumina as AL2O3, % by mass Nil 6 Iron Oxide as Fe2O3, % by mass Nil Table (6): Physical Properties of SF, [14] No. Parameters Test Value 1 Density (gm/cm3) 2.07 2 Physical state Clear grey powder 3 Practical Size Distribution (%) 59 Polymer (LDPE) Rubber Lime Figure (1-a): LDPE , Rubber and Lime Shape. Silica Fume Nano Silica Figure (1-b): SF and NS Shape. Table (7): Properties of Additives Type Plastic Bags Rubber Lime Silica Fume Nano Silica Molecular Formula (-CH2-CH2-) n C5H8 Ca(OH)2 Miro (SiO2) Nano (SiO2) Density (gm/cm3) 0.910 - 0.940 1.07 2.75 2.07 ----- Melting point (oC) 170oC 125oC ----- ----- ----- Physical State ----- Clear Black Powder Clear White Powder Clear Grey Powder Clear White Powder Solubility Insoluble Insoluble Soluble Soluble Soluble Table (8): Chemical Composition of NS, [12] Sample Name SI Calcite 0.28 Date 16-09-2015 Mulite 0 Time 23:28:32 PM Magnetite 0 R_wp 6.64 Hematite 0 Alite_Sum 0 Thenardite 0 Lime 0.06 Rutile 0 Periclase 0.09 Si_amorph 99.15 Quartz 0.19 Anhydrite 0.24 2.6 Nano Silica (N.S) NS used in this research is produced in Faculty of science – Beni-Suef University. The chemical composition of NS is presented in Table (8). Figure (2-a) shows X-ray test results of Nano Silica, while Figure (2-b) shows Nano Silica under Scanning Electron Microscopic (SEM). Figure (2-a): X-Rays Test of NS, [12]. IJSER
  • 4. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1246 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org Figure (2-b): NS under SEM, [12]. 3- Testing Methods Four test methods are used to evaluate and compare the obtained results of the asphalt concrete mixtures modified by the different stated modifiers. The test methods include Marshall test as per ASTM D 6927-06 to determine the properties of asphalt mixes. It is conducted on the control mix to get the optimum asphalt content and define the basic properties of such as stability, flow, unit weight, air voids (AV %), voids of mineral aggregates percentage (VMA%) and voids filled with bitumen (VFB%). Then the test is conducted on the modified mixes using SF, NS, Rubber, Lime, and polymer with optimum percentages 6, 7, 10, 5 and 4% respectively. The optimum percentages of the added modifiers are defined from the literature review. The second test is the Indirect Tensile Strength (ITS) test as per AASHTO T322-03 which used to evaluate the resistance of the asphalt concrete mixtures to the applied tensile stresses. This tensile stress causes the specimen to fail by splitting or rupturing along the vertical diameter. The Direct Compression (DC) Test as per ASTM D-1074 is conducted on the modified asphalt concrete mix specimens to investigate the behavior of both control and modified specimens under crushing loads. DC test is used to evaluate compression strength of control asphalt mix and comparison with another treated mixes. The specimen is placed under compression force with an incremental of load values. Three specimens are prepared for this test for the control mix and similar three specimens are prepared and tested for each of the five types of modifiers. ITS value (St) is determined using the following equation: St = 2P/(Ο€HD), (kg/cm2), where: P is the applied load in kg, H is the specimen height in cm, and D is the specimen diameter in cm. The fourth test is the Wheel Tracking (WT) test which used to measure the rutting depth of hot mix asphalt mixtures in the wheel-tracking device as per AASHTO (T324-04). The method describes the compaction procedure of asphalt mixtures in a reciprocating rolling-wheel device. This test provides information about the rate of permanent deformation from a moving concentrated load. 4. RESULTS AND DISCUSSIONS 4.1 Asphalt Cement Properties Evaluation Characteristics of asphalt cement are examined for the modified specimens with different traditional and Nano additives. The comparison is made through conducting the penetration and viscosity tests on both control specimens (C.S) and modified specimens (M.S). Figure (3) shows the effect of adding different percentages of waste plastic bags, rubber, lime, SF and NS to the asphalt cement on the penetration test values. Results of penetration test indicate that the penetration value is decreased for all modified samples. Waste plastic bags and lime record the lowest penetration values, the penetration is decreased by 68% and 55.4% respectively. Adding SF, Rubber, and NS decrease the penetration value by 46.2%, 21.5%, and 17% respectively. Figure (4) shows the effect of adding different additives to asphalt cement on the viscosity value. Viscosity test results indicate that the viscosity increases for all modified specimens using the different additives. Adding waste plastic bags and lime achieve the highest viscosity values; the viscosity increases by 44.18% and 35.0% respectively. SF, Rubber, and NS increase the viscosity value by 30.16%, 15.1%, and 9.8% respectively. 65 21 51 29 35 54 0 10 20 30 40 50 60 70 Penetration(1/10)mm C.M"no additives" C.M+ 4% LDPE C.M + 10% Rubber C.M+ 5% Lime C.M+ 6% S.F C.M + 7% N.S Figure (3): Effect of Adding Lime, LDPE, Rubber, SF and NS on Penetration. 378 545 435 510 492 415 300 350 400 450 500 550 Viscosity(Cst) C.M"no additives" C.M+ 4% LDPE C.M + 10% Rubber C.M+ 5% Lime C.S + 6% S.F C.S + 7% N.S Figure (4): Effect of Adding Lime, LDPE, Rubber, SF and NS on Rotational Viscosity. 4.2 Asphalt Mixtures Properties Evaluation 4.2.1 Stability/Flow Evaluation Figure (5) shows the effect of using different additives including traditional and Nano on the stability of asphalt mixtures. The additives are added to the mix at its optimum percentage as founded previously and the percentage of asphalt content is chosen as the optimum from Marshall control mix (C.M). Results indicate that the maximum stability IJSER
  • 5. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1247 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org of modified mixture using NS and SF is improved by 25% and 23.61% respectively. Waste plastic bags, lime, and rubber increase the stability by 21.32%, 19.69% and 12.84% respectively. Accordingly, NS and SF are the best additives in improving the stability of asphalt mixtures. 2880 3494 3250 3447 3560 3600 2500 2700 2900 3100 3300 3500 3700 Stability(Ib) C.M" no additives" C.M + 4% LDPE C.M + 10% Rubber C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S Figure (5): Effect of Adding Lime, LDPE, Rubber, SF and NS on Marshall Stability. Figure (6) shows the effect of using different types of additives on the flow values of asphalt mixtures compacted at the optimum asphalt content (OAC) and optimum additive content for each type. Results indicate that all types of additives decrease the flow value compared to the control mix value except the case of adding SF which increases the flow value by 3.29%. Waste plastic bags, rubber and lime decrease flow value by 10.5%, 12.5% and 14.47% respectively, also NS decreases flow value by 19.08%. Accordingly, NS is considered the best additive in improving the flow of asphalt mixtures. 0.152 0.133 0.136 0.130 0.157 0.123 0.1 0.11 0.12 0.13 0.14 0.15 0.16 0.17 Flow(inch) C.M" no additives" C.M + 4% LDPE C.M+ 10% Rubber C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S Figure (6): Effect of Adding Lime, LDPE, Rubber, SF and NS on Marshall Flow. 4.2.2 Unit Weight and Air Voids Figure (7) shows the effect of using different types of additives on the AV% of asphalt mixtures at OAC. The Figure shows that at OAC, the air voids % for all types of additives increases compared to the control mix air void percentage. However, all obtained air voids percentages for all types of additives are still within the accepted specification limits. Waste plastic bags, rubber and lime increase AV% by 8.75%, 7.5% and 1.88% respectively. As well as adding SF and NS to asphalt mixtures increase AV% by 3.13% and 14% respectively. 3.20 3.48 3.44 3.26 3.30 3.65 2.90 3.00 3.10 3.20 3.30 3.40 3.50 3.60 3.70 AirVoids(%) C.M" no additives" C.M+ 4% LDPE C.M + 10% Rubber C.M + 5% Lime C.M + 6% S.F C.M + 7% N.S Figure (7): Effect of Adding Lime, LDPE, Rubber, SF and NS on AV%. Figure (8) shows the effect of using lime, LDPE, rubber, SF and NS on the unit weight values of asphalt mixtures at OAC. Results indicate that the obtained unit weight for all types of additives ranges from 2.299 to 2.305 gm/cm3. The higher unit weight is occurred when adding SF to the asphalt mix ,while the lower unit weight is occurred by adding rubber and NS. 2.304 2.299 2.300 2.303 2.305 2.299 2.296 2.297 2.298 2.299 2.3 2.301 2.302 2.303 2.304 2.305 2.306 Unitweight(gm/cm3) C.M" no additives" C.M+ 4% LDPE C.M+ 10% Rubber C.M + 5% Lime C.M+6% S.F C.M + 7% N.S Figure (8): Effect of Adding Lime, LDPE, Rubber, SF and NS on Unit Weight. Figures (9) and (10) show the effect of adding different types of additives on both of the voids in mineral aggregates percentage (VMA %) and the percentage of voids filled with bitumen (VFB %). Results indicate that the % VMA value is increased for all types of additives except using SF which decreases the % VMA. Also Results indicate that the % VFB is decreased for all types of additives. IJSER
  • 6. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1248 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org 15.18 15.32 15.28 15.21 15.10 15.20 14.95 15.00 15.05 15.10 15.15 15.20 15.25 15.30 15.35VMA% C.M" no additives" C.M+ 4% LDPE C.M+ 10% Rubber C.M + 5% Lime C.M + 6% Silica Fume C.M + 7% Nano Silica Figure (9): Effect of Adding Lime, LDPE, Rubber, SF and NS on VMA%. 79.00 77.28 77.50 78.60 78.00 76.00 74.50 75.00 75.50 76.00 76.50 77.00 77.50 78.00 78.50 79.00 79.50 VFB% C.M" no additives" C.M + 4% LDPE C.M+ 10% Rubber C.M+ 5% Lime C.M + 6% S.F C.M + 7% N.S Figure (10): Effect of Adding Lime, LDPE, Rubber, SF and NS on VFB%. Figure (11) shows the significant change in asphalt mixtures stiffness values by adding both traditional and nano additives to HMA. Results investigate that the values of stiffness increase with all types of additives. NS seems to be the best additive that improves stiffness of asphalt mixtures by about 54.5%. 18947.37 26270.68 23897.06 26515.38 22675.16 29268.293 11500.00 13500.00 15500.00 17500.00 19500.00 21500.00 23500.00 25500.00 27500.00 29500.00 31500.00 Sstability/Flow(Ib/in) C.M" no additives" C.M+ 4% LDPE C.M + 10% Rubber C.M + 5% Lime C.M + 6% S.F C.M+ 7% N.S Figure (11): Effect of Adding Lime, LDPE, Rubber, SF and NS on Marshall Stiffness. 4.2.3 DC & ITS Evaluation Figures (12) and (13) present the comparison between the DC and the ITS values for the different used additives. Figures show that SF achieves compressive strength by about 26.80% increase compared with the control mix. Figures show also that SF, LDPE and NS achieve approximately nearer ITS value by about 7% increase compared with the control mix. 29.19 30.01 30.01 30.43 37.00 31.66 22.00 24.00 26.00 28.00 30.00 32.00 34.00 36.00 38.00 AverageDCT,(kg/cm2) C.M"no additives" C.M + 10% Rubber C.M+ 4% LDPE C.M+ 5% Lime C.M + 6% Silica Fume C.M + 7% Nano Silica Figure (12): Effect of Adding Lime, LDPE, Rubber, SF and NS on DC values. 9.36 10.38 10.06 8.19 9.99 10.21 5.00 6.00 7.00 8.00 9.00 10.00 11.00 AverageITS,(kg/cm2) C.M "no additives" C.M + 10% Rubber C.M + 4% LDPE C.M + 5% Lime C.M + 6% Silica Fume C.M+ 7% Nano Silica Figure (13): Effect of Adding Lime, LDPE, Rubber, SF and NS on ITS values. 4.2.4 Evaluation of Rutting Depth Wheel Tracking (WT) Test is performed on asphalt mix samples prepared at the optimum asphalt content obtained from Marshall test. WT test value is considered an important result, so it reflects to the ability of the asphalt mixture to resist rutting. The WT test is performed on asphalt mix samples containing optimum percentage of different types of additives. The obtained results of WT test are shown in Figure (14). Results indicate that rutting depth increases with the increasing of time (direct relationship). The rutting depth values, at the end of the test, of modified asphalt mixes decrease the depth of rutting. All of the used additives decrease the rutting depth but waste plastic bags are the best additive because it decreases the rutting depth to 4.572 mm. In addition, rubber and SF record the same value of the rutting depth of 5.46 mm. IJSER
  • 7. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1249 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org 8.51 5.46 4.57 7.24 5.46 5.08 0 2 4 6 8 10 RuttingDepth,mm C.M"no additives" C.M+ 10% Rubber C.M+ 4% LDPE C.M+ 5% Lime C.M+ 6% S.F C.M+ 7% N.S Figure (14): Effect of Adding Lime, LDPE, Rubber, SF and NS on Rutting Depth. 4.3 Economic Evaluation of Modified Mixtures An economic study is conducting to differentiate between the direct costs of producing a constant quantity of asphalt mixture (1m3) using the different evaluated types of investigated additives. The cost analysis is based only on the direct cost of the materials constitutes the mixtures which includes Coarse Aggregate (CA), Fine Aggregate (FA), Mineral Filler (MF), Asphalt Cement (AC), and the used modifiers. The indirect production cost and profits are not included in this analysis since it shall be approximately constant for all mixtures. Table (9) presents the properties of different modified mixtures using different modifiers. It shows the type of modifier and its related OAC, optimum modifier percentage, and the obtained mixture unit weight. Table 10 presents the calculation of the materials direct cost of both of 1 m3 and 1 Ton of each of the modified mixtures as well as the unmodified mix. The calculations were conducted based on the mix gradation shown in Table (2) as well as the obtained mixtures properties are shown in Table (9). Table (9): OAC and Unit Weight of Asphalt Mixes and Modifiers Prices. Additive Type OAC Additive, % Unit Weight, Kg/m3 Cost of Modifier, LE/ton No Additive 5.65 0 2304 0 LDPE 5.65 4 2299 15000 Rubber 5.65 10 2300 30000 Lime 5.65 5 2303 500 SF 5.55 6 2305 25000 NS 5.45 7 2299 7000000 As shown in Table (10), the cost of production of 1 ton of the unmodified mix is 503 L.E., the same cost as using lime. While that for using LDPE is 537 L.E. and that for using SF is 578 L.E. and 672 L.E. using rubber. The cost of using NS in producing 1 ton is very high, it is about 27192 L.E. which represent about 5000 time the cost of unmodified mix. Table (11) presents the percentage of increase in the materials direct cost while Figures (15) and (16) present the relative direct cost of them. Table (10): Cost Analysis Calculation of Direct Cost of Modified Mixtures Materials Modifier Type None LDPE Rubber Lime SF NS Modifier, % 0 4 10 5 6 7 Mix Unit Weight, Kg/m3 2304 2299 2300 2303 2305 2299 OAC, % 5.65 5.65 5.65 5.65 5.55 5.45 Weight of m3 of Mix, Kg 2304 2299 2300 2303 2305 2299 Weight of AC, Kg 130 130 130.0 130 128 125 Weight of CA, Kg 1109 1106 1107 1108 1110 1109 Weight of FA, Kg 978 976 977 978 980 978 Weight of Filler, Kg 87 87 87 87 87 87 Weight of Modifier, Kg 0.00 5.20 13.00 6.51 7.68 8.77 Cost of Modifier, L.E./Kg 0 15 30 0.5 25 7000 Cost of AC L.E./Kg 8 8 8 8 8 8 Cost of CA L.E./Kg 0.04 0.04 0.04 0.04 0.04 0.04 Cost of FA L.E./Kg 0.03 0.03 0.03 0.03 0.03 0.03 Cost of Filler L.E./Kg 0.5 0.5 0.5 0.5 0.5 0.5 Cost of 1 m3 , L.E. 1159 1234 1546 1161 1333 62514 Cost of 1 Ton, L.E. 503 537 672 504 578 27192 Table (11): % increase in Cost of 1 ton of Modified Mixtures Additives Type Total Cost (LE/ton) % increase No Additive 503 0.00 Lime 504 0.20 LDPE 537 6.76 SF 578 14.91 Rubber 672 33.60 NS 27192 5305.96 503 504 537 578 672 27192 0 5000 10000 15000 20000 25000 30000 Costof1TonofMix,L.E. C.M"no additives" C.M+ 5% Lime C.M+ 4% LDPE C.M+ 6% S.F C.M+ 10% Rubber C.M+ 7% N.S Figure (15): Cost of Production of 1 ton of Asphalt Mixes Using Lime, LDPE, Rubber, SF and NS as Modifiers. IJSER
  • 8. International Journal of Scientific & Engineering Research Volume 9, Issue 3, March-2018 1250 ISSN 2229-5518 IJSER Β© 2018 http://www.ijser.org 503 504 537 578 672 0 100 200 300 400 500 600 700 800 Costof1TonofMix,L.E. C.M"no additives" C.M+ 5% Lime C.M+ 4% LDPE C.M+ 6% S.F C.M+ 10% Rubber Figure (16): Cost of Production of 1 ton of Asphalt Mixes Using Lime, LDPE, Rubber and SF as Modifiers, (Excluding NS). 5. CONCLUSIONS In this study, the performance of asphalt concrete mixtures is evaluated using different types of traditional and Nano materials. NS is considered the best modifiers since they achieve the best performance. Economic analysis of the materials direct cost of the used additives indicates that NS is not applicable for use since it is very costly. It costs about 5000 times the unmodified mixture. SF is considered the most appraisable additive in obtaining the good performance with moderate cost increase (about 14%). Also, Lime, LDPE and rubber provide a significant change in physical and mechanical properties of asphalt mixes. REFERENCES [1] Hak-Seo Kim, Soon-Jae Lee, and Serji Amir khanian, (2010),"Rheology Investigation of Crumb Rubber Modified Asphalt Binders", KSCE Journal of Civil Engineering - 14(6):839-843. [2] Xiao F and Amirkhanian S N (2010), "Laboratory investigation of utilizing high percentage of RAP in rubberized asphalt mixture", Materials and Structures 43:223–233. [3] Yazan Issa, (May 2016), "Effect of Adding Waste Tires Rubber to Asphalt Mix", Civil Engineering Department, Fahd Bin Sultan University, Saudi Arabia, International Journal of Scientific Research and Innovative Technology ISSN: 2313-3759. [4] Ahmed Mohamady, Mohamed Ibrahim EL-Sharkawi, Mahmoud Fathy and Eslam Magdy, construction Eng. And Utilities Dept. (July-Aug 2014),"Effecting of Using Polymers on Bituminous Mixtures Characteristics in Egypt", IOSR Journal of Mechanical and Civil Engineering, Vol.11, Issue 4. [5] Ahmed A.L, (2007), "Improvement of Marshall Properties of the Asphalt Concrete Mixtures Using the Polyethylene as Additive", College of Engineering, Basrah University, Basrah-IRAQ Eng. & Technology, Vol. 25, No.3. [6] Sinan Hinislioglu, Hatice Nur Aras and Osman Unsal bayrak ,(2005) , "Effects of High Densit Polyethylene on Permanent Deformation of Asphalt Concrete", Department of Civil Engineering Faculty of Engineering – Ataturk University. [7] Sheelan A. Ahmed and Omar T. Mahmood (August 2015), "Influence of Mineral Fibers Properties on the Performance of Hot Mix Asphalt for the Surface Layer of Pavement", Department of Civil Engineering, Faculty of Engineering, Koya University, Erbil, Iraq, International Journal of Engineering Trends and Technology (IJETT) – Volume 26 Number 3. [8] Abdelaziz Mahrez , Mohamed Rehan Karim and Herda Yati bt Katman , (2005), "Fatigue And Deformation Properties Of Glass Fiber Reinforced Bituminous Mixes", Dept. of Civil Engineering University Malaya - 50603 Kuala Lumpur – Malaysia. [9] European lime association, (2008), "Hydrated lime a proven additive for durable asphalt pavements. [10]Farag Khodary (2016), " Impact of Silica fume on the properties of Asphalt pavement base course", Civil Engineering Department, Qena Faculty of Engineering, South Valley University, Qena, Egypt, International Journal of Engineering Trends and Technology (IJETT). [11]Metwally G. Al-Taher, Hassan D. Hassanin, Mokhtar F. Elgendy and Ahmed M. Sawan (April 2018), "Investigation of the Effect of Adding Silica Fume on Asphalt Concrete Properties", International Journal of Engineering Research, Volume (7), Issue (4), ISSN 2319-6890. [12] Metwally G. Al-Taher, Hassan D. Hassanin, Mokhtar F. Elgendy and Ahmed M. Sawan, (December 2017) "Improving the Performance of Asphalt Mixtures Using Nano Silica", World Applied Sciences Journal, Volume (35), ISSN 1818-4952. [13]Abdelzaher E. A. Mostafa, 2016, "Examining the Performance of Hot Mix Asphalt Using Nano-Materials", Associate Professor, Civil Engineering, Mataria School of Engineering, Helwan University, Cairo, Egypt. [14]Chhaya Negi R.K.Yadav and A.K. Singhai, (July 2013), "Effect of Silica Fume on Engineering Properties of Black Cotton Soil", Geotechnical Engineering, JEC Jabalpur, (M.P.), India, International Journal of Computational Engineering Research, Vol, 03. IJSER