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IITian ACADEMY CHARTHAWAL, MUZAFFARNAGAR
Reagent RCOCl RCHO RCOOR RCONH2 RCOOH RCN RNO2 Double bond
LiAlH4 Yes Yes Yes Yes Yes Yes Yes No
LiBH4 Yes Yes Yes No No No No No
NaBH4 Yes Yes No No No No No No
BH3/THF No Yes No Yes Yes Yes No Yes
DIBAL Yes Yes Yes Yes Yes Yes Yes No
H2 Yes Yes Yes Yes No Yes Yes Yes
NOTE:-
1-This is valid for only Reduction reaction.
2-RCONH2 converts also RCH2 NH2.
3-RCOOH converts also RCH2 OH.
4-RCN converts also RCH2 NH2.
5-RNO2 converts also RNH2.
6-Double bonds convert also single bond.
i.e. H2C=CH2 → H3C-CH3
7-Any others also convert to RCH2 OH.
8-
2 – Naphthol (ArOH)
9-Relation b/w Enthalpy and Entropy, ∆G = ∆H - T∆S = -RT ln Ka
AMIT KUMAR MAINWAL
M.Sc (Organic Chemistry)
NIT, Warangal-506004
kamit7@student.nitw.ac.in
Mobile No. 9897263989

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Reduction reaction

  • 1. IITian ACADEMY CHARTHAWAL, MUZAFFARNAGAR Reagent RCOCl RCHO RCOOR RCONH2 RCOOH RCN RNO2 Double bond LiAlH4 Yes Yes Yes Yes Yes Yes Yes No LiBH4 Yes Yes Yes No No No No No NaBH4 Yes Yes No No No No No No BH3/THF No Yes No Yes Yes Yes No Yes DIBAL Yes Yes Yes Yes Yes Yes Yes No H2 Yes Yes Yes Yes No Yes Yes Yes NOTE:- 1-This is valid for only Reduction reaction. 2-RCONH2 converts also RCH2 NH2. 3-RCOOH converts also RCH2 OH. 4-RCN converts also RCH2 NH2. 5-RNO2 converts also RNH2. 6-Double bonds convert also single bond. i.e. H2C=CH2 → H3C-CH3 7-Any others also convert to RCH2 OH. 8- 2 – Naphthol (ArOH) 9-Relation b/w Enthalpy and Entropy, ∆G = ∆H - T∆S = -RT ln Ka AMIT KUMAR MAINWAL M.Sc (Organic Chemistry) NIT, Warangal-506004 kamit7@student.nitw.ac.in Mobile No. 9897263989