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Groundwater quality and Human health



          Sunderrajan Krishnan
              CAREWATER
           INREM Foundation,
             Anand, Gujarat
Contents
   Introduction

   Main groundwater-health problems in India
   Biological
   Fluoride
   Salinity
   Nitrate
   Arsenic
   Iron
   Emerging problems

   Experiences in Fluorosis mitigation and learnings

   Some debates on RO

   Some thoughts on policy issues
Introduction

• Water borne diseases are a massive burden on society

• The impact of water borne diseases is higher on the poor
  who have poorer nutrition

• Incidences of some water borne diseases are
  decreasing, whereas others are increasing

• Most of these diseases are preventable by consumption
  of safe drinking water
Local picture of drinking water access and variable water quality




     Groundwater
                                           Drinking


     Piped water
       supply                               Cooking


      Tank/Pond
                                           Other uses


         Sources                           Domestic Uses
availability
                                                          time




           Pond
                           supply




Sources
                         Piped water
                                           Groundwater
                                                                 salinity




                                          availability      fluoride
          availability
                               Drinking




                                                           coli form
          coli form                        coli form
Transport processes within the aquifer




                        Fl

                             Human, Animal waste
                      TDS
                 Fl          Fertilizers, Pesticides
   TDS     TDS
                             Groundwater flow
Different contamination problems
Biological contamination
• Child mortality in India is 57/1000

• 9.1% of 0-5 yr mortality due to Diarrhoel diseases

• Overall DALY from Diarrhoel > 22 million years

• Poor sanitation and flood conditions are the main causes

• Several low cost filters are being developed now; yet
  propensity to spend among poor not so high
Nitrate contamination

• Standards are for 45 mg/l

• Studies support Methaemoglobinemia in infants

• Suspicions for being carcinogenic, respiratory problems,
  Diabetes

• Low cost solutions for Nitrate removal do not exist
Salinity

• Ingress and inherent salinity in many parts of India

• But what are the health symptoms from salinity?

• Can kidney stones be attributed to salinity? Though lack
  of proper hydration is linked to Kidney stones, hardness
  by itself is not

• Though there is high incidence of Kidney stone in
  coastal areas
Total costs due to Kidney stones
     In salinity affected villages,

     •   Medical costs = Rs. 5790 per person per year

     •   Wage loss costs = Rs. 2690 per person per year

     •   Drinking water costs = Rs. 750 per household per year




Social costs due to Kidney stones form a significant part of income
Source: ICAR Studies
Arsenic

• Arsenic in eastern parts of country

• Arsenicosis exposure to 16 million people (7 million > 50
  ppb exposure)

• New areas in Nepal Terai, Assam, Bihar

• Linked closely to occurrence of Iron
Source: Jadavpur university
Iron
•   Safe limit of 1 mg/l

•   No health based guideline suggested by WHO

•   People report of gastro-enteritic problems, but not supported by
    medical studies

•   Iron overload, Hereditary Haemochromatosis, Liver Cirrhosis

•   Taste, odour, skin, hair, pipes, cooking

•   People resort to unsafe water due to taste of Iron

•   Link with Arsenic
Fluoride contamination

• Hydro-Fluorosis causes by consumption of high Fluoride
  in water

•   Not just Dental and Skeletal Fluorosis, but variety of
    problems with brain, liver, kidney, heart diseases

• Estimates vary from 10 to 65 million people exposed

• DALY of 38.5 per 1000 population (NEERI, 2007)
Source: CGWB
Food
                  (black tea, rock salt)               Occupation
                                                     (Mines, glass etching)




        Water                                                                 Nutrition
                                                                               (Ca, Mg,
                                                                               Vitamins)




Crops                              Fluorosis
                                                                              Metabolism


            Social, economic, cultural impacts
                (effect of medicines, wage loss, psychological setback)




                                     Society
Fluorosis mitigation programmes
• More than 50% of Fluoride intake can be through food
  grown locally

• Fluorosis is linked much with climatic and nutritive
  factors

• Teaching of Fluorosis is not present in current Indian
  medicine or engineering literature

• Fluorosis patients can incur high costs (wage + medicine
  losses)
Medical and Wage loss costs
               North       Dausa        Kolar       North
                   Gujarat (in 2005)    (in 2005)       Karnataka
               (in 2002)                            (in 2005)
per   capita    Rs. 861     Rs. 1489     Rs. 2807
   annual                                              Rs. 1724
medical cost
per   capita   Rs. 4593     Rs. 19741    Rs. 8719     Rs. 12857
   annual
wage loss
afflicted         1.1          1.3          1.7           2.3
    no/house
    hold
cost/annual      26 %          6%          21 %          16 %
  income
Fluorosis mitigation programmes …. Cont’d

• Most Fluorosis mitigation programmes have been water
  supply programmes

• Mitigation and reversal of symptoms is very slow, so
  patients lose much hope after few years and resign to
  fate
Fluorosis mitigation programmes …. Cont’d

• Started mainly as De-fluoridation programmes

• Nalgonda filter (using Alum) in 1970s … NEERI

• Activated Alumina (AA) as an advancement

• Reverse Osmosis (RO) with proper membrane can
  remove Fluoride ions

• New materials, … Resin, Chitin, Bio-polymer adsorbent,
  etc.
Fluorosis mitigation programmes …. Cont’d

• Water treatment: AA and RO

• Roof top rain water harvesting

• Pipe water supply

• Recharge
Fluorosis mitigation programmes …. Cont’d

• Main options today are AA and RO

• AA
     Minimum of 1mg/g adsorption. Requires regeneration every 4-5
     months
     New materials with 8-9 mg/g adsorption
     Al-Fl complexes a health concern
     Has wide industry application, so is low-cost and available
     AA filters not available in market
     No electricity required

   Two main programs for AA are SWACH and Mytry
Fluorosis mitigation programmes …. Cont’d

•   SWACH and Mytry

UNICEF and IITK tested the AA DDU filters and implemented in 2
  locations

Awareness programmes, village regeneration centres

Mytry later transitioned into filter manufacturing company

Currently some maintenance of filters happens in Rajasthan, but not
  widespread
Fluorosis mitigation programmes …. Cont’d

Health based mitigation measures

Studies say upto 80% bio-available Fluoride enters through food
   (Reddy R, 2008, AP) and 60% through food (Chakma, 2007, MP).

Safe water can prevent Fluorosis, but can it mitigate?

Calcium, Magnesium, Absorbic acid (Vitamin C) are suggested till now

Successes have been achieved for few patients by Dr. AK Susheela,
  Dr. T. Chakma, Dr. Sunil Gupta and Dr. Raja Reddy

But can these be achieved on a larger scale? Nutrition supplements
  through Atta, … other food items ?
Fluorosis mitigation programmes …. Cont’d

Fluorosis mitigation: water and health perspectives

• Understanding of Fluoride mobility and distribution
• Fluorosis needs to be in medical and public health
  curriculum
• Doctors should push patients towards need for safe
  water
• Mitigation needs to be tried in mass trials and
  standardized
• Options for safe water needs to be available: rain water
  storage, low cost treatment and services etc.
Debates with RO
•   Cost/litre
•   Effluent disposal
•   Does it really treat for required contaminants?
•   Maintenance
•   Is it safe for health?
•   Is it really required?
Successfully operating RO plants in south Gujarat
                       Minimum        Average        Maximum-
         Capacity       250 lph       560 lph          1000 lph
          Storage      200 litres    2000 litres     6000 litres
         Plant cost    1.25 lakhs    2.32 lakhs        5 lakhs
         Cost/litre        0          Re 0.28           Re 0.6
         Prod/day      300 litres    1200 litres     2500 litres
         Buyers in         30            86              325
          village
           Reach         10%            42%             100%
        Suppliers of plant are varied (ISO, non-ISO)

        Reach within village shows wide variation,

        Off-shoot water suppliers cover surrounding villages,

        Non-users have very poor drinking water facilities
      Variability in size, cost/litre, % of reach and production
Treatment aspects of RO water


• RO treats only according to the specific membrane capacity

• Pre and post treatment is required

• Although pure distilled water can be harmful for health,
NRC, 1983 reports no health based guideline for RO water

• Effluent for RO should be disposed properly, but currently
no official safety standards exist in India
Monitoring of water quality

• Network of govt agencies insufficient

• NRDWQM program is in progress

• Several tier of monitoring eg. Assam where field kits are
  employed along with 5 PHED labs and IIT G over seeing
  quality control

• New low cost digital instrumentation are being developed
  eg. in IIT B
Issues with policy

• Who is responsible for groundwater quality and health
  problems?



• Do we have enough understanding of mobilization
  processes of contaminants?
Health department’s role

• A framework on water quality should come from a
  concept of overall health

• All water quality problems of a place need to be
  addressed eg. Assam (Iron + Fluoride + Arsenic filter)

• Health agencies need to accept their responsibility
In summary
• Better physical distribution needs to be known

• Bringing people to be concerned on water quality and
  health is not an easy task

• New treatment solutions coming up; but comprehensive
  local solutions to water treatment needs to be developed

• Doctors can play a key role in disseminating water
  quality information

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Groundwater Quality And Human Health: Sunderrajan Krishnan, CAREWATER

  • 1. Groundwater quality and Human health Sunderrajan Krishnan CAREWATER INREM Foundation, Anand, Gujarat
  • 2. Contents Introduction Main groundwater-health problems in India Biological Fluoride Salinity Nitrate Arsenic Iron Emerging problems Experiences in Fluorosis mitigation and learnings Some debates on RO Some thoughts on policy issues
  • 3. Introduction • Water borne diseases are a massive burden on society • The impact of water borne diseases is higher on the poor who have poorer nutrition • Incidences of some water borne diseases are decreasing, whereas others are increasing • Most of these diseases are preventable by consumption of safe drinking water
  • 4. Local picture of drinking water access and variable water quality Groundwater Drinking Piped water supply Cooking Tank/Pond Other uses Sources Domestic Uses
  • 5. availability time Pond supply Sources Piped water Groundwater salinity availability fluoride availability Drinking coli form coli form coli form
  • 6. Transport processes within the aquifer Fl Human, Animal waste TDS Fl Fertilizers, Pesticides TDS TDS Groundwater flow
  • 8. Biological contamination • Child mortality in India is 57/1000 • 9.1% of 0-5 yr mortality due to Diarrhoel diseases • Overall DALY from Diarrhoel > 22 million years • Poor sanitation and flood conditions are the main causes • Several low cost filters are being developed now; yet propensity to spend among poor not so high
  • 9. Nitrate contamination • Standards are for 45 mg/l • Studies support Methaemoglobinemia in infants • Suspicions for being carcinogenic, respiratory problems, Diabetes • Low cost solutions for Nitrate removal do not exist
  • 10. Salinity • Ingress and inherent salinity in many parts of India • But what are the health symptoms from salinity? • Can kidney stones be attributed to salinity? Though lack of proper hydration is linked to Kidney stones, hardness by itself is not • Though there is high incidence of Kidney stone in coastal areas
  • 11. Total costs due to Kidney stones In salinity affected villages, • Medical costs = Rs. 5790 per person per year • Wage loss costs = Rs. 2690 per person per year • Drinking water costs = Rs. 750 per household per year Social costs due to Kidney stones form a significant part of income
  • 13. Arsenic • Arsenic in eastern parts of country • Arsenicosis exposure to 16 million people (7 million > 50 ppb exposure) • New areas in Nepal Terai, Assam, Bihar • Linked closely to occurrence of Iron
  • 15. Iron • Safe limit of 1 mg/l • No health based guideline suggested by WHO • People report of gastro-enteritic problems, but not supported by medical studies • Iron overload, Hereditary Haemochromatosis, Liver Cirrhosis • Taste, odour, skin, hair, pipes, cooking • People resort to unsafe water due to taste of Iron • Link with Arsenic
  • 16. Fluoride contamination • Hydro-Fluorosis causes by consumption of high Fluoride in water • Not just Dental and Skeletal Fluorosis, but variety of problems with brain, liver, kidney, heart diseases • Estimates vary from 10 to 65 million people exposed • DALY of 38.5 per 1000 population (NEERI, 2007)
  • 18. Food (black tea, rock salt) Occupation (Mines, glass etching) Water Nutrition (Ca, Mg, Vitamins) Crops Fluorosis Metabolism Social, economic, cultural impacts (effect of medicines, wage loss, psychological setback) Society
  • 19. Fluorosis mitigation programmes • More than 50% of Fluoride intake can be through food grown locally • Fluorosis is linked much with climatic and nutritive factors • Teaching of Fluorosis is not present in current Indian medicine or engineering literature • Fluorosis patients can incur high costs (wage + medicine losses)
  • 20. Medical and Wage loss costs North Dausa Kolar North Gujarat (in 2005) (in 2005) Karnataka (in 2002) (in 2005) per capita Rs. 861 Rs. 1489 Rs. 2807 annual Rs. 1724 medical cost per capita Rs. 4593 Rs. 19741 Rs. 8719 Rs. 12857 annual wage loss afflicted 1.1 1.3 1.7 2.3 no/house hold cost/annual 26 % 6% 21 % 16 % income
  • 21. Fluorosis mitigation programmes …. Cont’d • Most Fluorosis mitigation programmes have been water supply programmes • Mitigation and reversal of symptoms is very slow, so patients lose much hope after few years and resign to fate
  • 22. Fluorosis mitigation programmes …. Cont’d • Started mainly as De-fluoridation programmes • Nalgonda filter (using Alum) in 1970s … NEERI • Activated Alumina (AA) as an advancement • Reverse Osmosis (RO) with proper membrane can remove Fluoride ions • New materials, … Resin, Chitin, Bio-polymer adsorbent, etc.
  • 23. Fluorosis mitigation programmes …. Cont’d • Water treatment: AA and RO • Roof top rain water harvesting • Pipe water supply • Recharge
  • 24. Fluorosis mitigation programmes …. Cont’d • Main options today are AA and RO • AA Minimum of 1mg/g adsorption. Requires regeneration every 4-5 months New materials with 8-9 mg/g adsorption Al-Fl complexes a health concern Has wide industry application, so is low-cost and available AA filters not available in market No electricity required Two main programs for AA are SWACH and Mytry
  • 25. Fluorosis mitigation programmes …. Cont’d • SWACH and Mytry UNICEF and IITK tested the AA DDU filters and implemented in 2 locations Awareness programmes, village regeneration centres Mytry later transitioned into filter manufacturing company Currently some maintenance of filters happens in Rajasthan, but not widespread
  • 26. Fluorosis mitigation programmes …. Cont’d Health based mitigation measures Studies say upto 80% bio-available Fluoride enters through food (Reddy R, 2008, AP) and 60% through food (Chakma, 2007, MP). Safe water can prevent Fluorosis, but can it mitigate? Calcium, Magnesium, Absorbic acid (Vitamin C) are suggested till now Successes have been achieved for few patients by Dr. AK Susheela, Dr. T. Chakma, Dr. Sunil Gupta and Dr. Raja Reddy But can these be achieved on a larger scale? Nutrition supplements through Atta, … other food items ?
  • 27. Fluorosis mitigation programmes …. Cont’d Fluorosis mitigation: water and health perspectives • Understanding of Fluoride mobility and distribution • Fluorosis needs to be in medical and public health curriculum • Doctors should push patients towards need for safe water • Mitigation needs to be tried in mass trials and standardized • Options for safe water needs to be available: rain water storage, low cost treatment and services etc.
  • 28. Debates with RO • Cost/litre • Effluent disposal • Does it really treat for required contaminants? • Maintenance • Is it safe for health? • Is it really required?
  • 29. Successfully operating RO plants in south Gujarat Minimum Average Maximum- Capacity 250 lph 560 lph 1000 lph Storage 200 litres 2000 litres 6000 litres Plant cost 1.25 lakhs 2.32 lakhs 5 lakhs Cost/litre 0 Re 0.28 Re 0.6 Prod/day 300 litres 1200 litres 2500 litres Buyers in 30 86 325 village Reach 10% 42% 100% Suppliers of plant are varied (ISO, non-ISO) Reach within village shows wide variation, Off-shoot water suppliers cover surrounding villages, Non-users have very poor drinking water facilities Variability in size, cost/litre, % of reach and production
  • 30. Treatment aspects of RO water • RO treats only according to the specific membrane capacity • Pre and post treatment is required • Although pure distilled water can be harmful for health, NRC, 1983 reports no health based guideline for RO water • Effluent for RO should be disposed properly, but currently no official safety standards exist in India
  • 31. Monitoring of water quality • Network of govt agencies insufficient • NRDWQM program is in progress • Several tier of monitoring eg. Assam where field kits are employed along with 5 PHED labs and IIT G over seeing quality control • New low cost digital instrumentation are being developed eg. in IIT B
  • 32. Issues with policy • Who is responsible for groundwater quality and health problems? • Do we have enough understanding of mobilization processes of contaminants?
  • 33. Health department’s role • A framework on water quality should come from a concept of overall health • All water quality problems of a place need to be addressed eg. Assam (Iron + Fluoride + Arsenic filter) • Health agencies need to accept their responsibility
  • 34. In summary • Better physical distribution needs to be known • Bringing people to be concerned on water quality and health is not an easy task • New treatment solutions coming up; but comprehensive local solutions to water treatment needs to be developed • Doctors can play a key role in disseminating water quality information