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Eamon Keane
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Hydrogen from aluminium - coming soon to a parallel universe.
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Hydrogen from aluminium for vehicle propulsion
1.
Aluminium as a
Fuel Aluminium Eamon Keane Co-Authors: Dr David Browne & Dr Alun Carr University College Dublin
2.
Water + Aluminium-Gallium
Fuel Pellets
3.
4.
= 1L 2.2L
5.
energy trapped
6.
+ = +
Water Hydrogen on Demand Aluminium Hydroxide
7.
Aluminium Fuel Cycle
Inputs
8.
Calcining Smelting Aluminium
Fuel Cycle 13.5% energy efficiency, not 50% Aluminium Hydroxide Alumina
9.
Energy and CO
2 Per Km Travelled
10.
Pourbaix Diagram
11.
Aluminium-Gallium Phase Diagram
33um Pure gallium in grain boundaries, β phase α phase: solid solution
12.
Fuel Pellet The
Reaction Gallium is not inert in the reaction
13.
Standard Electrode Potential
Large difference, galvanic corrosion expected. Reaction Mechanism Element E°V (V) Lithium -3.04 Aluminium -1.66 Gallium -0.56 Hydrogen 0 Gold +0.80
14.
15.
Surface After Reaction
16.
17.
Gallium Production Enough
for ~ 30,000 cars – not 1 billion!
18.
Elements with very
low worldwide 2008 production (Up to ~ 10,000 tons)
19.
Aluminium as a
Fuel Aluminium Any Questions? Renewable ≠ Green
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