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PhD scholar
NIT Rourkela
Soma Dalbehera
Study on effect of stacking sequence
on the tribological property of woven
jute-glass fiber reinforced epoxy
composite
CONTENTS
 Introduction
 Natural Fiber Composite
 Background/Origin of the work
 Cenosphere
 Experimental Aspects
 Results And Discussion
 Conclusions
3
COMPOSITES
Composites are combinations of two materials in which one of the
material is called the reinforcing phase(discontinuous phase), is in the
form of fibers, sheets, or particles, and is embedded in the other
material called the matrix phase(continuous phase).
Reinforcement: fibers
Glass
Carbon
Organic
Boron
Ceramic
Metallic
Matrix materials
Polymers
Metals
Ceramics
Interface
Bonding
surface
Components of composite materials
ReinforcementIncreases strength,stiffness and the temperature
resistance capacity of the composite.
In a composite,the purpose of matrix is to:
 Matrix acts as the bonding element.
 Its main function is to transfer and distribute the load to the
reinforcements or fibres.
 Protect the fibers from external stresses
The fillers and additives are included in a composite material
to:
 modify the color.
 reduce cost.
 decrease the shrinkage.
 modify certain thermal or electrical properties.
 improve the resistance to ageing.
 modify the density of the material .
4
Composite materials
Fiber reinforced composites Particle reinforced composites
Single layer
composite
Multi layered
composites
Laminates HybridContinuous fiber
reinforced composites
Discontinuous fiber
reinforced composites
Random
orientation
Preferred
orientation
Unidirectional
reinforcement
Bi-directional
reinforcement
Fig: 1 Classification of composites
Random
orientation
Preferred orientation
5
Continuous fiber (long fiber)
reinforced composites
Random fiber (short fiber) reinforced
composites
Particles as the reinforcement
(Particulate composites)
Flat flakes as the reinforcement
(Flake composites)
Fillers as the reinforcement (Filler composites)
Fig:2 Classifications of common composite material
6
Why a Composite?
 It reduces the weight of the components in
comparison to conventional material such as
metal, plastic or ceramic.
 The stiffness or strength needs to be increased.
 The cost may be reduced.
 The fatigue life or operating temperature should be
increased.
 A component with a zero coefficient of thermal
expansion may be obtained.
8
Natural Fibers
Disadvantages
Advantages of Natural fiber
Reinforcement
1. Environmental reasons:
Renewable resource of raw material
Thermally recyclable, biodegradable
Low energy consumption
2. Excellent specific strength &
high modulus
3. Health & safety: less abrasive,
safe manufacturing processes
4. Lower cost & reduced density
of products
1. Variability in strength
2. Hydrophilicity (moisture)
3. Weak interface
9
Flax Hemp Sisal CoirKenaf
Natural Fibers
CONSTITUENTS OF BIO- FIBRE COMPOSITE
+ =
Fiber Resin Composite
Material
NATURAL FIBERS
Jute
Banana
Bamboo Sugarcane
Natural Fibers are
- Low-cost
- Low density fibers
- High specific strength and modulus
- Low priced
- Recyclable
- Biodegradable
- Nonabrasive
- Easily available
- ECO-FRIENDLY
Natural Fibers : Applications
The Aerospace Industry:
• Wing skins
• Fin boxes
• Rotor blade
The Automotive Industry
• Bumper beam
• Seat/load floor
• Hood radiator support
• Roof panel
• Cars, trucks and bus bodies
• Railway coach components
The Sporting Goods Industry
• Golf shafts
• Tennis rackets
• Fishing rods
Cont…
Background/Origin of the
work
14
Jute is used as reinforcement in polymer resin
matrix naturally available having high specific
strength and stiffness.
 Jute, the so-called golden fiber from eastern India and
Bangladesh is one of the most common agro-fibers
having high tensile modulus and low elongation at
break.
 The low density of this fiber is taken in to
consideration, then its specific stiffness and strength
are comparable to the respective quantities of glass
fibers.
 The fiber has a high aspect ratio,high strength to
weight ratio,low in energy conversion and has good
insulation properties.
 The jute fiber composites can be very cost-effective
material especially for building & construction
industry,packing, automobile & railway coach interiors
and storage devices.
TYPICAL COMPOSITION OF JUTE FIBER
16
Substances Weight Percentage(%)
Cellulose 61-72
Hemicellulose 13.6-20.4
Pectin 0.2
Lignin 12-13
Moisture content 12.6
Wax 0.5
Chemical composition of natural fiber
1. Cellulose: - It is a highly crystalline, linear polymer of anhydrous-glucose
molecules with a degree of polymerization(n) of around
10,000.
It provide strength, stiffness, and structural stability to the fiber cells.
Cont…
2. Hemicelluloses:-These are branched polymers containing five to
six numbers of carbon sugars of varied Chemical
structure.
It plays an important roles in fiber bundle integration, fiber bundle strength.
Cont…
3. Lignin: - It is an amorphous, cross-linked polymer network consisting of an
irregular array of variously bonded hydroxy-and methoxy-substituted
phenylpropane units.
It is an organic substance binding the cells.
Cont…
20
Lignin
- Rigidity of the fibers
- High molecular weight
- Three dimensional polymer structure
- Acts as a binder for the cellulose fibers
- Behaves as an energy storage system
Cellulose
- High tensile strength of composite
materials.
Carbon content in fiber provides
- Light weight
- High strength and
- Favourable stiffness
21
LITERATURE SURVEY
22
SL
No
Author
Name
Journal name
& Yr. of Publication
Topic Summary of work
1 Chittaranjan
Deo,S.K.Acharya
Polymer-plastics
Technology and
engineering,2009,
48,1084-1087
Solid particle Erosion of
Lantana Camara fiber-
Reinforced polymer matrix
composite
It is well known that the fibers in
composite is subjected to particle erosion
encountered intensive debonding and
breakage of fibers which were not
supported enough by the matrix from SEM
study.Thecontinuous impingement of silica
sand on fiber breaks the fiber b’cz of
formation of cracks perpendicular to their
length and also bending of fiber becomes
possible due to softening of the
surrounding matrix,which in turn lowers
the strength of the surrounding fibers.
2 B.C.Patel,S.K.Ac
harya,D.Mishra
International
journal of
Engineering,Scien
ce and
Technology,2011,
Vol.3,No.1,pp
213-219
Effect of stacking
sequence on erosive wear
behaviour of jute & jute
glass fabric reinforced
epoxy composite
studied that the erosive wear behaviour of
natural fiber jute can be improved
significantly by hybridizing with synthetic
fiber glass and layering sequence (altering
the position of glass piles) significantly
affects the erosive strength.
3 Mohammed
Ismail,Suresh
Bheemappa
International
conference on
mechanical,autom
otive and
materials
engineering,2012,
January 7-8,Dubai
Investigation on
mechanical & erosive wear
behaviour of cenosphere
filled carbon-epoxy
composite
showed that the tensile and flexural
modulus of cenosphere filled carbon-epoxy
composites has good improvement as
compared to unfilled carbon-epoxy
composites.The addition of cenosphere
filler in carbon fabric reinforcement epoxy
composites have shown marked
improvement in erosion wear behaviour.
23
SL
No
Author
Name
Journal name
& Yr. of
Publication
Topic Summary of work
4 N.-M. Barkoula,
J. Karger-Kocsis
Wear,2002,252,
80–87
Effects of fibre content and
relative fibre-orientation
on the solid particle erosion
of GF/PP composites.
The erosive wear behaviour of glass fibre
(GF) reinforced thermoplastic
polypropylene (PP) composites was
studied in a modified sand blasting
apparatus as a function of the impact angle
(30,60and90◦),relative fibre orientation
(parallel and perpendicular),fibre length
discontinuous, continuous) and fibre
content (40–60 wt.%).The results showed a
strong dependence of the erosive wear on
the relative fibre-orientation at low impact
angles(30◦),but hardly any difference for
60 and 90◦ impact angles. In contrast, the
fibre length did not affect the erosive wear
behaviour especially at high impact angles.
5 N. Miyazaki Journal of
Composite
Materials, 2007
41: 703
Solid Particle Erosion
Behavior of FRPs with
Prior Impact Damage
The test results show that less erosion
resistance of the FRPs with prior impact
damage may be because the FRPs with
prior impact damage have a lot of
transverse cracks and delamination, which
absorb the kinetic energy of the solid
particles used in the erosion tests.
6 U.S.Tewari,A.P.
Harsha,Häger,K.
Friedrich
Wear,2002,252,9
92–1000
Solid particle erosion of
unidirectional carbon fibre
reinforced
polyetheretherketone
composite
The composites exhibited a maximum
erosion rate at an impingement angle of
60◦ under the present experimental
condition.The fibre orientation has a
significant influence on the erosion rate of
24
SL
No
Author
Name
Journal name
& Yr. of
Publication
Topic Summary of work
7 Manish Roy,
G.Sundararajan,
B. Vishvvanathan
Wear, (1994)
171,149-161
The solid particle erosion of
polymer matrix composites
Theglass-reinforced epoxy resin composite
exhibits the lowest erosion rate and glass-
reinforced phenolic resin (modified) shows
the highest erosion rate (at α=30° and 90°,
for V=38 and 45 m/ s). The erosion rates of
glass-polyester resin and glass-
(unmodified) phenolic resin exhibit
intermediatevalues.Composites having
thermoset matrix (epoxy and phenolic)
behave in a brittle way while the
composites with thermoplastic matrix
(polyester) respond in a ductile manner.
Reinforcing fibres reduces the erosion
efficiencies and hence the erosion rates of
the composites most probably by arresting
the crack and controlling the spread of
deformation.
8 A.P.Harsha,Avin
ash A.Thakre
Wear (2007),262
807–818
Investigation on solid
particle erosion behaviour
of polyetherimide and its
composites
The present investigation reports about, the
solid particle erosion behaviour of
randomly oriented short E-glass, carbon
fibre and solid lubricants (PTFE, graphite,
MoS2) filled polyetherimide (PEI)
composites.The erosion rates (ERs) of
these composites have been evaluated at
different impingement angles (15–90◦) and
impact velocities (30–88 m/s).
Polyetherimide and its glass, carbon fibre
 Impingement of solid particle against a target surface causes material
removal due to local damage which is generally known as erosive wear.
 Polymer composites demands in various engineering fields are
increasing day by day because of their high specific mechanical
properties compared to conventional materials.
 These composites are also being used in areas where the components
encounter impact of lot of abrasions from dust, sand, splinters of
materials, slurry of solid particle and the consequence is the material
finally undergoes erosive wear.
 Visualising the importance of polymeric composites,lot of work has
been done to evaluate various types of polymers and their composites
to solid particle erosion (Harsha and Thakre, 2007;Tiwari et al,
2003;Bijwe et al,2001; Bijwe et al,2002).The effect of stacking sequence
on mechanical properties of natural fiber jute, hemp with glass fiber has
been studied in detailed by Sabeel and Vijayarangan (2008),Santulli and
Caruso (2009).
 Recently the erosive wear of woven jute and glass fiber has been
studied by Patel etal(2011).
 In their work they have considered woven bi-directional fiber (0-90º) for
both jute and glass fiber.In this present investigation keeping the glass
fiber direction as constant (0-90º) the jute fiber orientation has been
changed to (45º-450) for preparation of the layered composite.
 The erosive wear experiment has been conducted to find out the effect
of this changed orientation.
OBJECTIVE OF THE WORK
 Study of mechanical properties of jute-glass hybrid epoxy
composite with specific orientation of fiber at different stacking
sequence(JJJJ,GJGJ,JGGJ,GJJG).
 Erosive wear behavior of all composites developed under different
parameters like,
•Percentage of fiber content
•Impact angle
•Impact velocity
•Stand-off distance (SOD)
 SEM analysis for structure,property co-relationship.
 In this present work the effect of stacking sequence on erosive wear behavior
of untreated woven jute and glass fabric reinforced epoxy hybrid composites
has been investigated experimentally.
 The position of glass and jute fabric has been kept as 00-900 and 450-450 for all
stacking sequences.
 All the laminates were made with a total of 4 plies, by varying the number and
position of glass layers so as to obtain four different stacking sequences.
 The erosion rates of these composites have been evaluated at different
impingement angles (30°-90°) and at three different particle speeds (V=48,
70,82m/s).
 The erodent used is silica sand. The impingement angle was found to have a
significant influence on the erosion rate.
 The composite material showed semi ductile behavior with maximum erosion
at 60° impingement angle.
 The morphologies of eroded surface were examined by the scanning electron
microscope (SEM).Possible erosion mechanism were discussed.
EXPERIMENTAL ASPECTS
 Jute fiber.
 E-Glass fiber.
 Cenosphere
 Epoxy resin: LY-556 and
 Hardener HY-951
Materials Required
31
Materials Preparation:
Jute fiber of 90°(a) and 45°(b)
orientation
(a) (b) (c) (d)
Glass fiber of 90°(c)and
45°(d)orientation
E-GLASS
ADVANTAGES
 High strength
 Low cost
 High chemical resistance
 Good insulating properties
DRAW BACKS
Low elastic modulus.
Poor adhesion to polymer.
Low fatigue strength
EPOXY
Epoxy resin (Araldite LY 556) having properties :-
• Excellent Mechanical Properties
• Good Fatigue Resistance
• Low Shrinkage
• Negligible shrinkage.
Hardener
 In the present work Hardener (araldite) HY 951 is
used.
 This has viscosity of 10-20 poise at 25 °c.
 The hardener is taken 10 % of volume of polymer .
34
Preparation of test specimen:
 Hybrid laminates of woven jute and glass mat were prepared by
hand lay-up technique. The type of epoxy resin used in the
present investigation is LY 556 and corresponding hardener is
(HY951).
 Epoxy is mixed with hardener in the ratio 10:1 by weight.
 A wooden mold of dimension (140 x 130 x5) mm was used for
casting the composite sheet.
 A coat of gel was applied on the inner side of the mold and mold
release spray was used for quick and easy removal of the
composite sheet.
 Usual hand lay-up technique was used to manufacture the
composite sheet of 5 mm thickness at room temperature.
 Suitable pieces of the above were cut from the composite plates
for erosion studies. Four groups of laminate composite samples
with total 4 plies were manufactured by varying stacking
sequence of jute and glass fabrics as presented in Table-1
 The composites were cured for 72h at room temperature.
35
Table-1:Laminate stacking sequence
Micro-hardness
 A diamond indenter, in the form of a right pyramid with a square base and an
angle 1360between opposite faces, is forced into the material under a load F.
 The two diagonals X and Y of the indentation left on the surface of the material
after removal of the load are measured and their arithmetic mean L is
calculated.
 In the present study, the load considered F = 10N and Vickers hardness
number is calculated using the following equation
Micro-hardness measurement is done using a Leco
Vickers Hardness tester (LV 700).
The present investigation reveals that the by
varying the number and position of glass and jute
layers four different stacking sequences are
obtained as shown in Figure.
Its maximum value is for sequence S4.
Where F is the applied load (N)
X is the horizontal length (mm)
Y is the vertical length (mm)
L is the diagonal of square impression (mm)
and
38
Test for Erosive wear
Details of erosion test rig. (1) Sand hopper. (2) Conveyor belt
system for sand flow. (3) Pressure transducer. (4) Particle-air
mixing chamber. (5) Nozzle. (6) X–Y axes assembly. (7) Sample
holder
39
The operating parameters were as follows:-
Test parameters value
Erodent Silica sand
Erodent size(µm) 200±50
Erodent shape irregular
Impact velocity(m/s) 48,70,82
Erodent feed rate(gm/min) 10
Test temp 27°
Nozzle to sample distance(mm) 20
40
Test procedure:
 Erosion test rig confirming to ASTM G 76.
 It consists of an air compressor, an air particle mixing
chamber and accelerating chamber.
 Dry compressed air is mixed with the particles which are fed
at constant rate from a sand flow control knob through the
nozzle tube and then accelerated by passing the mixture
through a convergent tungsten carbide nozzle of 4 mm internal
diameter.
These particles impact the specimen which can be held at
different angles with respect to the direction of erodent flow
using a swivel and an adjustable sample clip.
 The velocity of the eroding particles is determined using
standard double disc method.
41
 In the present study, dry silica sand (irregular) of different
particle sizes (200 ± 50 µm ) are used as erodent.
 The samples are cleaned in acetone, dried and weighed to an
accuracy of +/- 1×10‾³ gm before and after the erosion trials
using a precision electronic balance.
 The weight loss is recorded for subsequent calculation of
erosion rate.
 The process is repeated till the erosion rate attains a constant
value called steady state erosion rate.
The erosion rate (Er) is then calculated by using the following
equation
Er= ΔW / We
where ΔW is the mass loss of test sample in gm and We is the
mass of eroding particles (i.e., testing time × particle feed rate ).
RESULTS AND DISCUSSIONS
43
2. Erosion of Jute-Glass hybrid Epoxy composite:
Influence of impingement angle (α) on erosion wear behaviour
Variation of erosion rate with different impingement angle at velocity
(a) 48m/s (b)70m/s and (c) 82 m/s
 Figure 4(a-c) shows the result of the erosion rate for different stacking
sequence of reinforced hybrid composite as function of angle of
impingement. It is evident from the plot that the erosion rate attains
peak value at impingement angle either at 45º or at 60º for all stacking
sequence. It is known that impingement angle is one of the most
important parameters for the erosion behavior of materials.
 In the literature materials as classified as ductile or brittle based on the
dependence of their erosion rate with impingement angle.The ductile
behavior is characterized by maximum erosion rate at low
impingement angle typically 15° < α < 300.
 On the other hand, if the maximum erosion rate occurs at normal
impact (α=900) the behavior of the material is brittle. Reinforced
composites have been found to exhibit semi ductile behavior with
maximum erosion rate at intermediate impingement angles; typically
(450 < α <600).
 However the above classification is not absolute on the erosion behavior of
materials which strongly depends upon the experimental conditions and the
composition of target materials .
 Therefore maximum erosion rate between 45º-60º in the present case
indicates that these composites are neither behaving in a purely ductile nor
in a purely brittle manner. So this behavior of these composites can be
termed as semi-ductile in nature.
 Figures 5 Shows the result of the erosion rate for different stacking
sequence of reinforced hybrid composite as function of angle of
impingement. It is found that the erosion rate of the composite for the
sequence GJJG is minimum and is maximum for all layers of jute fibers .
 Maximum erosion rate between 45º-60º in the present case indicates that
these composites are neither behaving in a purely ductile nor in a purely
brittle manner. So this behavior of these composites can be termed as semi
ductile in nature.
Surface morphology of eroded surface
Figure 5(a): GJGJ (45°) Figure 5(b): GJJG 45° Figure 5(c):
JGGJ 60° Figure 5(a) shows the crater formed and the damage caused to the
composite.It shows extensive damage of fibers.
 Fig (b) also shows the damage of fibers but still fibers are not pull-
out from the matrix.This might have happened due to lower impact
velocity .
 Fig 5(c) shows the chipping out of jute fibers but there is no
damage found to the glass layers.
 It can be justified from this fact that erosion resistance of the
natural fiber jute can be improved significantly by hybridising with
synthetic fiber glass.
 It can be seen from the surface of the samples that material
removal is mainly due to micro-cutting and micro-ploughing.
47
CONCLUSION
The following conclusions are drawn from this study.
1.Incorporation of glass in jute fiber composite enhances the erosive
properties of resulting hybrid composite.
2. SEM studies of worn surfaces support the involved mechanism and
indicated micro-cracking, exposure of fibers, fiber cracking,removal of
the fibers and sand particle embedment.
3. For the same relative weight fraction of jute and glass fiber, layering
sequence has significant effect on erosive wear properties.
5. The influence of impingement angle on erosive wear of all
composites under consideration exhibit semi ductile behavior with
maximum wear rate at 45º-600 impingement angle.
48
REFERENCES
1. B.C. Patel, S.K. Acharya et al 2011.Effect of stacking sequence on the erosive wear
behavior of jute and jute glass fabric reinforced epoxy composite, International
Journal of Engineering, Science and Technology Vol. 3, No. 1, 2011, pp. 213-219.
2. Bijwe J.,Indumathi J.,John Rajesh J.Fahim M. 2001.Friction and wear behavior of
polyetherimide composites in various wear modes, Wear, Vol.249, pp. 715-726.
3. BijweJ.Indumathi J., Ghose A.K. 2002. On the abrasive wear behavior of fabric-
reinforced polyetherimide composites, Wear, Vol.253, pp. 768-777.
4. Harsha A. P.Thakre A.A. 2007.Investigation on solid particle erosion behavior,
wear, Vol.262pp. 8:7-18.
5. Sabeel A.K.,Vijayarangan S. 2008.Tensile, flexuralproperties of woven jute and
jute-glass fabric reinforced polyester composites, Journal of Materials Processing
Technology, Vol.207, No.1-3, pp. 330-335.
6. Santulli A.P. 2009. A Comparative Study on Falling Weight Impact Properties of
Jute/Epoxy and Hemp/Epoxy Laminates, Malaysian Polymer Journal, Vol.4, No.1,
pp. 19-29.
7. Tewari U.S.Harsha A. P.Solid particle erosion of glass fiber epoxy composite,Com
Sci Tech, Vol.63, pp. 549-557
Trppt
Trppt

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Trppt

  • 1. PhD scholar NIT Rourkela Soma Dalbehera Study on effect of stacking sequence on the tribological property of woven jute-glass fiber reinforced epoxy composite
  • 2. CONTENTS  Introduction  Natural Fiber Composite  Background/Origin of the work  Cenosphere  Experimental Aspects  Results And Discussion  Conclusions
  • 3. 3 COMPOSITES Composites are combinations of two materials in which one of the material is called the reinforcing phase(discontinuous phase), is in the form of fibers, sheets, or particles, and is embedded in the other material called the matrix phase(continuous phase). Reinforcement: fibers Glass Carbon Organic Boron Ceramic Metallic Matrix materials Polymers Metals Ceramics Interface Bonding surface Components of composite materials
  • 4. ReinforcementIncreases strength,stiffness and the temperature resistance capacity of the composite. In a composite,the purpose of matrix is to:  Matrix acts as the bonding element.  Its main function is to transfer and distribute the load to the reinforcements or fibres.  Protect the fibers from external stresses The fillers and additives are included in a composite material to:  modify the color.  reduce cost.  decrease the shrinkage.  modify certain thermal or electrical properties.  improve the resistance to ageing.  modify the density of the material . 4
  • 5. Composite materials Fiber reinforced composites Particle reinforced composites Single layer composite Multi layered composites Laminates HybridContinuous fiber reinforced composites Discontinuous fiber reinforced composites Random orientation Preferred orientation Unidirectional reinforcement Bi-directional reinforcement Fig: 1 Classification of composites Random orientation Preferred orientation 5
  • 6. Continuous fiber (long fiber) reinforced composites Random fiber (short fiber) reinforced composites Particles as the reinforcement (Particulate composites) Flat flakes as the reinforcement (Flake composites) Fillers as the reinforcement (Filler composites) Fig:2 Classifications of common composite material 6
  • 7. Why a Composite?  It reduces the weight of the components in comparison to conventional material such as metal, plastic or ceramic.  The stiffness or strength needs to be increased.  The cost may be reduced.  The fatigue life or operating temperature should be increased.  A component with a zero coefficient of thermal expansion may be obtained.
  • 8. 8 Natural Fibers Disadvantages Advantages of Natural fiber Reinforcement 1. Environmental reasons: Renewable resource of raw material Thermally recyclable, biodegradable Low energy consumption 2. Excellent specific strength & high modulus 3. Health & safety: less abrasive, safe manufacturing processes 4. Lower cost & reduced density of products 1. Variability in strength 2. Hydrophilicity (moisture) 3. Weak interface
  • 9. 9 Flax Hemp Sisal CoirKenaf Natural Fibers CONSTITUENTS OF BIO- FIBRE COMPOSITE + = Fiber Resin Composite Material
  • 11. Natural Fibers are - Low-cost - Low density fibers - High specific strength and modulus - Low priced - Recyclable - Biodegradable - Nonabrasive - Easily available - ECO-FRIENDLY
  • 12. Natural Fibers : Applications The Aerospace Industry: • Wing skins • Fin boxes • Rotor blade The Automotive Industry • Bumper beam • Seat/load floor • Hood radiator support • Roof panel • Cars, trucks and bus bodies • Railway coach components The Sporting Goods Industry • Golf shafts • Tennis rackets • Fishing rods Cont…
  • 14. 14 Jute is used as reinforcement in polymer resin matrix naturally available having high specific strength and stiffness.
  • 15.  Jute, the so-called golden fiber from eastern India and Bangladesh is one of the most common agro-fibers having high tensile modulus and low elongation at break.  The low density of this fiber is taken in to consideration, then its specific stiffness and strength are comparable to the respective quantities of glass fibers.  The fiber has a high aspect ratio,high strength to weight ratio,low in energy conversion and has good insulation properties.  The jute fiber composites can be very cost-effective material especially for building & construction industry,packing, automobile & railway coach interiors and storage devices.
  • 16. TYPICAL COMPOSITION OF JUTE FIBER 16 Substances Weight Percentage(%) Cellulose 61-72 Hemicellulose 13.6-20.4 Pectin 0.2 Lignin 12-13 Moisture content 12.6 Wax 0.5
  • 17. Chemical composition of natural fiber 1. Cellulose: - It is a highly crystalline, linear polymer of anhydrous-glucose molecules with a degree of polymerization(n) of around 10,000. It provide strength, stiffness, and structural stability to the fiber cells. Cont…
  • 18. 2. Hemicelluloses:-These are branched polymers containing five to six numbers of carbon sugars of varied Chemical structure. It plays an important roles in fiber bundle integration, fiber bundle strength. Cont…
  • 19. 3. Lignin: - It is an amorphous, cross-linked polymer network consisting of an irregular array of variously bonded hydroxy-and methoxy-substituted phenylpropane units. It is an organic substance binding the cells. Cont…
  • 20. 20 Lignin - Rigidity of the fibers - High molecular weight - Three dimensional polymer structure - Acts as a binder for the cellulose fibers - Behaves as an energy storage system Cellulose - High tensile strength of composite materials. Carbon content in fiber provides - Light weight - High strength and - Favourable stiffness
  • 22. 22 SL No Author Name Journal name & Yr. of Publication Topic Summary of work 1 Chittaranjan Deo,S.K.Acharya Polymer-plastics Technology and engineering,2009, 48,1084-1087 Solid particle Erosion of Lantana Camara fiber- Reinforced polymer matrix composite It is well known that the fibers in composite is subjected to particle erosion encountered intensive debonding and breakage of fibers which were not supported enough by the matrix from SEM study.Thecontinuous impingement of silica sand on fiber breaks the fiber b’cz of formation of cracks perpendicular to their length and also bending of fiber becomes possible due to softening of the surrounding matrix,which in turn lowers the strength of the surrounding fibers. 2 B.C.Patel,S.K.Ac harya,D.Mishra International journal of Engineering,Scien ce and Technology,2011, Vol.3,No.1,pp 213-219 Effect of stacking sequence on erosive wear behaviour of jute & jute glass fabric reinforced epoxy composite studied that the erosive wear behaviour of natural fiber jute can be improved significantly by hybridizing with synthetic fiber glass and layering sequence (altering the position of glass piles) significantly affects the erosive strength. 3 Mohammed Ismail,Suresh Bheemappa International conference on mechanical,autom otive and materials engineering,2012, January 7-8,Dubai Investigation on mechanical & erosive wear behaviour of cenosphere filled carbon-epoxy composite showed that the tensile and flexural modulus of cenosphere filled carbon-epoxy composites has good improvement as compared to unfilled carbon-epoxy composites.The addition of cenosphere filler in carbon fabric reinforcement epoxy composites have shown marked improvement in erosion wear behaviour.
  • 23. 23 SL No Author Name Journal name & Yr. of Publication Topic Summary of work 4 N.-M. Barkoula, J. Karger-Kocsis Wear,2002,252, 80–87 Effects of fibre content and relative fibre-orientation on the solid particle erosion of GF/PP composites. The erosive wear behaviour of glass fibre (GF) reinforced thermoplastic polypropylene (PP) composites was studied in a modified sand blasting apparatus as a function of the impact angle (30,60and90◦),relative fibre orientation (parallel and perpendicular),fibre length discontinuous, continuous) and fibre content (40–60 wt.%).The results showed a strong dependence of the erosive wear on the relative fibre-orientation at low impact angles(30◦),but hardly any difference for 60 and 90◦ impact angles. In contrast, the fibre length did not affect the erosive wear behaviour especially at high impact angles. 5 N. Miyazaki Journal of Composite Materials, 2007 41: 703 Solid Particle Erosion Behavior of FRPs with Prior Impact Damage The test results show that less erosion resistance of the FRPs with prior impact damage may be because the FRPs with prior impact damage have a lot of transverse cracks and delamination, which absorb the kinetic energy of the solid particles used in the erosion tests. 6 U.S.Tewari,A.P. Harsha,Häger,K. Friedrich Wear,2002,252,9 92–1000 Solid particle erosion of unidirectional carbon fibre reinforced polyetheretherketone composite The composites exhibited a maximum erosion rate at an impingement angle of 60◦ under the present experimental condition.The fibre orientation has a significant influence on the erosion rate of
  • 24. 24 SL No Author Name Journal name & Yr. of Publication Topic Summary of work 7 Manish Roy, G.Sundararajan, B. Vishvvanathan Wear, (1994) 171,149-161 The solid particle erosion of polymer matrix composites Theglass-reinforced epoxy resin composite exhibits the lowest erosion rate and glass- reinforced phenolic resin (modified) shows the highest erosion rate (at α=30° and 90°, for V=38 and 45 m/ s). The erosion rates of glass-polyester resin and glass- (unmodified) phenolic resin exhibit intermediatevalues.Composites having thermoset matrix (epoxy and phenolic) behave in a brittle way while the composites with thermoplastic matrix (polyester) respond in a ductile manner. Reinforcing fibres reduces the erosion efficiencies and hence the erosion rates of the composites most probably by arresting the crack and controlling the spread of deformation. 8 A.P.Harsha,Avin ash A.Thakre Wear (2007),262 807–818 Investigation on solid particle erosion behaviour of polyetherimide and its composites The present investigation reports about, the solid particle erosion behaviour of randomly oriented short E-glass, carbon fibre and solid lubricants (PTFE, graphite, MoS2) filled polyetherimide (PEI) composites.The erosion rates (ERs) of these composites have been evaluated at different impingement angles (15–90◦) and impact velocities (30–88 m/s). Polyetherimide and its glass, carbon fibre
  • 25.  Impingement of solid particle against a target surface causes material removal due to local damage which is generally known as erosive wear.  Polymer composites demands in various engineering fields are increasing day by day because of their high specific mechanical properties compared to conventional materials.  These composites are also being used in areas where the components encounter impact of lot of abrasions from dust, sand, splinters of materials, slurry of solid particle and the consequence is the material finally undergoes erosive wear.  Visualising the importance of polymeric composites,lot of work has been done to evaluate various types of polymers and their composites to solid particle erosion (Harsha and Thakre, 2007;Tiwari et al, 2003;Bijwe et al,2001; Bijwe et al,2002).The effect of stacking sequence on mechanical properties of natural fiber jute, hemp with glass fiber has been studied in detailed by Sabeel and Vijayarangan (2008),Santulli and Caruso (2009).  Recently the erosive wear of woven jute and glass fiber has been studied by Patel etal(2011).  In their work they have considered woven bi-directional fiber (0-90º) for both jute and glass fiber.In this present investigation keeping the glass fiber direction as constant (0-90º) the jute fiber orientation has been changed to (45º-450) for preparation of the layered composite.  The erosive wear experiment has been conducted to find out the effect of this changed orientation.
  • 27.  Study of mechanical properties of jute-glass hybrid epoxy composite with specific orientation of fiber at different stacking sequence(JJJJ,GJGJ,JGGJ,GJJG).  Erosive wear behavior of all composites developed under different parameters like, •Percentage of fiber content •Impact angle •Impact velocity •Stand-off distance (SOD)  SEM analysis for structure,property co-relationship.
  • 28.  In this present work the effect of stacking sequence on erosive wear behavior of untreated woven jute and glass fabric reinforced epoxy hybrid composites has been investigated experimentally.  The position of glass and jute fabric has been kept as 00-900 and 450-450 for all stacking sequences.  All the laminates were made with a total of 4 plies, by varying the number and position of glass layers so as to obtain four different stacking sequences.  The erosion rates of these composites have been evaluated at different impingement angles (30°-90°) and at three different particle speeds (V=48, 70,82m/s).  The erodent used is silica sand. The impingement angle was found to have a significant influence on the erosion rate.  The composite material showed semi ductile behavior with maximum erosion at 60° impingement angle.  The morphologies of eroded surface were examined by the scanning electron microscope (SEM).Possible erosion mechanism were discussed.
  • 30.  Jute fiber.  E-Glass fiber.  Cenosphere  Epoxy resin: LY-556 and  Hardener HY-951 Materials Required
  • 31. 31 Materials Preparation: Jute fiber of 90°(a) and 45°(b) orientation (a) (b) (c) (d) Glass fiber of 90°(c)and 45°(d)orientation
  • 32. E-GLASS ADVANTAGES  High strength  Low cost  High chemical resistance  Good insulating properties DRAW BACKS Low elastic modulus. Poor adhesion to polymer. Low fatigue strength
  • 33. EPOXY Epoxy resin (Araldite LY 556) having properties :- • Excellent Mechanical Properties • Good Fatigue Resistance • Low Shrinkage • Negligible shrinkage. Hardener  In the present work Hardener (araldite) HY 951 is used.  This has viscosity of 10-20 poise at 25 °c.  The hardener is taken 10 % of volume of polymer .
  • 34. 34 Preparation of test specimen:  Hybrid laminates of woven jute and glass mat were prepared by hand lay-up technique. The type of epoxy resin used in the present investigation is LY 556 and corresponding hardener is (HY951).  Epoxy is mixed with hardener in the ratio 10:1 by weight.  A wooden mold of dimension (140 x 130 x5) mm was used for casting the composite sheet.  A coat of gel was applied on the inner side of the mold and mold release spray was used for quick and easy removal of the composite sheet.  Usual hand lay-up technique was used to manufacture the composite sheet of 5 mm thickness at room temperature.  Suitable pieces of the above were cut from the composite plates for erosion studies. Four groups of laminate composite samples with total 4 plies were manufactured by varying stacking sequence of jute and glass fabrics as presented in Table-1  The composites were cured for 72h at room temperature.
  • 36. Micro-hardness  A diamond indenter, in the form of a right pyramid with a square base and an angle 1360between opposite faces, is forced into the material under a load F.  The two diagonals X and Y of the indentation left on the surface of the material after removal of the load are measured and their arithmetic mean L is calculated.  In the present study, the load considered F = 10N and Vickers hardness number is calculated using the following equation
  • 37. Micro-hardness measurement is done using a Leco Vickers Hardness tester (LV 700). The present investigation reveals that the by varying the number and position of glass and jute layers four different stacking sequences are obtained as shown in Figure. Its maximum value is for sequence S4. Where F is the applied load (N) X is the horizontal length (mm) Y is the vertical length (mm) L is the diagonal of square impression (mm) and
  • 38. 38 Test for Erosive wear Details of erosion test rig. (1) Sand hopper. (2) Conveyor belt system for sand flow. (3) Pressure transducer. (4) Particle-air mixing chamber. (5) Nozzle. (6) X–Y axes assembly. (7) Sample holder
  • 39. 39 The operating parameters were as follows:- Test parameters value Erodent Silica sand Erodent size(µm) 200±50 Erodent shape irregular Impact velocity(m/s) 48,70,82 Erodent feed rate(gm/min) 10 Test temp 27° Nozzle to sample distance(mm) 20
  • 40. 40 Test procedure:  Erosion test rig confirming to ASTM G 76.  It consists of an air compressor, an air particle mixing chamber and accelerating chamber.  Dry compressed air is mixed with the particles which are fed at constant rate from a sand flow control knob through the nozzle tube and then accelerated by passing the mixture through a convergent tungsten carbide nozzle of 4 mm internal diameter. These particles impact the specimen which can be held at different angles with respect to the direction of erodent flow using a swivel and an adjustable sample clip.  The velocity of the eroding particles is determined using standard double disc method.
  • 41. 41  In the present study, dry silica sand (irregular) of different particle sizes (200 ± 50 µm ) are used as erodent.  The samples are cleaned in acetone, dried and weighed to an accuracy of +/- 1×10‾³ gm before and after the erosion trials using a precision electronic balance.  The weight loss is recorded for subsequent calculation of erosion rate.  The process is repeated till the erosion rate attains a constant value called steady state erosion rate. The erosion rate (Er) is then calculated by using the following equation Er= ΔW / We where ΔW is the mass loss of test sample in gm and We is the mass of eroding particles (i.e., testing time × particle feed rate ).
  • 43. 43 2. Erosion of Jute-Glass hybrid Epoxy composite: Influence of impingement angle (α) on erosion wear behaviour Variation of erosion rate with different impingement angle at velocity (a) 48m/s (b)70m/s and (c) 82 m/s
  • 44.  Figure 4(a-c) shows the result of the erosion rate for different stacking sequence of reinforced hybrid composite as function of angle of impingement. It is evident from the plot that the erosion rate attains peak value at impingement angle either at 45º or at 60º for all stacking sequence. It is known that impingement angle is one of the most important parameters for the erosion behavior of materials.  In the literature materials as classified as ductile or brittle based on the dependence of their erosion rate with impingement angle.The ductile behavior is characterized by maximum erosion rate at low impingement angle typically 15° < α < 300.  On the other hand, if the maximum erosion rate occurs at normal impact (α=900) the behavior of the material is brittle. Reinforced composites have been found to exhibit semi ductile behavior with maximum erosion rate at intermediate impingement angles; typically (450 < α <600).
  • 45.  However the above classification is not absolute on the erosion behavior of materials which strongly depends upon the experimental conditions and the composition of target materials .  Therefore maximum erosion rate between 45º-60º in the present case indicates that these composites are neither behaving in a purely ductile nor in a purely brittle manner. So this behavior of these composites can be termed as semi-ductile in nature.  Figures 5 Shows the result of the erosion rate for different stacking sequence of reinforced hybrid composite as function of angle of impingement. It is found that the erosion rate of the composite for the sequence GJJG is minimum and is maximum for all layers of jute fibers .  Maximum erosion rate between 45º-60º in the present case indicates that these composites are neither behaving in a purely ductile nor in a purely brittle manner. So this behavior of these composites can be termed as semi ductile in nature.
  • 46. Surface morphology of eroded surface Figure 5(a): GJGJ (45°) Figure 5(b): GJJG 45° Figure 5(c): JGGJ 60° Figure 5(a) shows the crater formed and the damage caused to the composite.It shows extensive damage of fibers.  Fig (b) also shows the damage of fibers but still fibers are not pull- out from the matrix.This might have happened due to lower impact velocity .  Fig 5(c) shows the chipping out of jute fibers but there is no damage found to the glass layers.  It can be justified from this fact that erosion resistance of the natural fiber jute can be improved significantly by hybridising with synthetic fiber glass.  It can be seen from the surface of the samples that material removal is mainly due to micro-cutting and micro-ploughing.
  • 47. 47 CONCLUSION The following conclusions are drawn from this study. 1.Incorporation of glass in jute fiber composite enhances the erosive properties of resulting hybrid composite. 2. SEM studies of worn surfaces support the involved mechanism and indicated micro-cracking, exposure of fibers, fiber cracking,removal of the fibers and sand particle embedment. 3. For the same relative weight fraction of jute and glass fiber, layering sequence has significant effect on erosive wear properties. 5. The influence of impingement angle on erosive wear of all composites under consideration exhibit semi ductile behavior with maximum wear rate at 45º-600 impingement angle.
  • 48. 48 REFERENCES 1. B.C. Patel, S.K. Acharya et al 2011.Effect of stacking sequence on the erosive wear behavior of jute and jute glass fabric reinforced epoxy composite, International Journal of Engineering, Science and Technology Vol. 3, No. 1, 2011, pp. 213-219. 2. Bijwe J.,Indumathi J.,John Rajesh J.Fahim M. 2001.Friction and wear behavior of polyetherimide composites in various wear modes, Wear, Vol.249, pp. 715-726. 3. BijweJ.Indumathi J., Ghose A.K. 2002. On the abrasive wear behavior of fabric- reinforced polyetherimide composites, Wear, Vol.253, pp. 768-777. 4. Harsha A. P.Thakre A.A. 2007.Investigation on solid particle erosion behavior, wear, Vol.262pp. 8:7-18. 5. Sabeel A.K.,Vijayarangan S. 2008.Tensile, flexuralproperties of woven jute and jute-glass fabric reinforced polyester composites, Journal of Materials Processing Technology, Vol.207, No.1-3, pp. 330-335. 6. Santulli A.P. 2009. A Comparative Study on Falling Weight Impact Properties of Jute/Epoxy and Hemp/Epoxy Laminates, Malaysian Polymer Journal, Vol.4, No.1, pp. 19-29. 7. Tewari U.S.Harsha A. P.Solid particle erosion of glass fiber epoxy composite,Com Sci Tech, Vol.63, pp. 549-557