Topic 8 Plastics Learning Outcomes
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Polymerization (Condensation Polymerization)
Primary Discussion on Mechanism of Condensation Polymerization
1 Name .docx
1
Name: Chem 9, Section:
Lab Partner: Experiment Date:
Synthetic Polymers and Plastics
Part A: Physical Characteristics
Find or choose one type of each of the following plastic polymers, and report the following
characteristics:
Plastic
number
Short Name
(HDPE,
LDPE, etc)
Clear
(yes or no)
Opaque
(yes or no)
Flexibility
(can be
bent?)
Durability
(hard or
soft)
Breakability
(can be
cracked?)
Recyclable
(yes or no)
1
2
3
4
5
6
7
Part B: Density Tests
Report for plastic samples in each liquid: sinks rapidly, sinks slowly, floats on top, floats below surface
Plastic
number
1:1 ethanol/water
density = 0.94 g/cm
3
Water
density = 1.0 g/cm
3
10% NaCl solution
density = 1.08 g/cm
3
1
2
3
4
5
6
Relative Plastic Densities:
Less than 0.94 g/cm
3
Less than 1.0 g/cm
3
Less than 1.08 g/cm
3
More than 1.08 g/cm
3
Ranking of densities:
(lowest) _______ _______ _______ _______ _______ _______ (highest)
2
Part C: Polymer Bouncy Balls
Polymer Ball composition Approximate height bounced Physical characteristics
Ball #1:
Ball #2
Ball #3
Questions
1. Which of the Big Six plastics was the most flexible?
2. Which of the Big Six plastics would be the best material for each of the following examples?
Use short names to identify each plastic (e.g. HDPE).
a replacement for a glass window ?
a take-out container for food?
a flexible, expandable bag for carrying items?
a lightweight bottle cap?
3. An unknown plastic floats in a 10% NaCl solution but sinks in water. What is the range of
possible density values this plastic may have? Suggest the composition of this plastic.
3
4. Why is it important to dislodge any adhering bubbles in the density tests?
5. PET plastic (number 1) is the most valuable waste plastic at the present time. Suggest a way
to separate it commercially from other waste plastics.
6. Sometimes plastic containers are made from two polymers and not just one. What would
happen to the water density test if HDPE and PVC were mixed?
7. Why are plastic recyclers very concerned about identifying the different polymers and not
mixing them together?
8. The figure below depicts polymerization of polystyrene (PS). Circle the original monomers
and determine how many monomers are present.
4
9. Polyvinylchloride (PVC) is composed of the vinyl chloride monomer. The monomer
structure and general reaction are shown at right.
Draw a polyvinyl chloride polymer composed of five
monomers arrange ...
Plastic's use and abuse
Main point of this slide
01. Introduction
02. There are some types of plastic materials such as
03. History
04. Organic Structure of Plastic
05. Mechanism of Organic Structure
06. The molecule Ethene
07. The molecule Polyvinyl chloride
08. Uses
09. Benefits
10. Uses Statistics
11. Pollutants of plastic
12. Disadvantage of plastic
13. Plastic Waste management
14. Alternative of Plastic
15. Conclusion
Thank you
Polymers Meyer (2014) suggests that a contemporary culture could n.docx
Polymers Meyer (2014) suggests that a contemporary culture could not long endure without the goods or products that the polymer industry provides (p. 607). These polymeric products include clothing, household/office, indoor and outdoor gadgets, and furnishings that are manufactured from natural and synthetic polymers. Polymers are not ordinarily considered hazardous materials since they are stable at ambient conditions; however, most of the products burn and produce toxic gases (Meyer, 2014). Because of their widespread use, it is of benefit to understand why and how they can pose hazards, especially during fires. For this unit, we will study the features and structural characteristics of commonly encountered polymers as well as the hazards that they pose when they burn. What are polymers? The International Union of Pure and Applied Chemistry (IUPAC) education website defines polymers as substances or macromolecules that “are composed of very large molecules with molecular weights ranging from a few thousand to as high as millions of grams/mole” (n.d., para. 1). For additional information on polymers, visit http://www.iupac.org/polyedu/page33/page33.html. The structure of a macromolecule is essentially comprised of multiple repetitions of units derived, actually or conceptually, from molecules of low molecular mass. Polymers can be natural or synthetic, but most of us probably associate polymers with the synthetic ones such as plastic. Examples of natural polymers include protein, starch, cellulose, and DNA that make up most of the structures of living tissue. Synthetic polymers include polyvinyl chloride (PVC), polycarbonate, and polyethylene. UNIT VII STUDY GUIDE Chemistry of Toxic Substances BOS 3640, Interactions of Hazardous Materials 2 UNIT x STUDY GUIDE Title Types of synthetic polymers: Synthetic polymers are often referred to as plastics, and most of them can be classified into the categories of elastomers, thermoplastics, and thermosets: Thermoplastics are polymers that soften when heated but return to their original condition on cooling to ambient temperature (e.g., polyvinyl chloride (PVC), polyethylene). Thermosets are polymers that cannot be remolded once they have solidified, such as polyurethane. Elastomers have elasticity like rubber (Polymer Science Learning Center, 2005). Polymerization is the chemical reaction during which monomers are linked and cross-linked to form polymers. The polymerization reaction is characterized by the macromolecule/polymer that is produced (see Figures 14.1 and 14.2 of the textbook). According to Meyer (2014), chemists have found when they examined the three-dimensional structure of polymers that the chains of repeating units are invariably cross-linked as shown in Figure 14.3 of the textbook. Note the following information about polymers: Intentional cross-linking technique for polymers is used during the production of thermoset plastics to make the polymer denser, stronger, and even elastic.
Plastic processing
Presentation Deals with the various Aspects and parameters related to Plastic Processing, its Application, Advancement and Limitations.
GREEN COMPOSITES
Green composites( Polymer Matrix composites only; Including wood plastic composites)
POLYMERS
Introduction
Types of polymer
Classification of Polymer
Polymerization
Biodegradable Polymer
Application of biodegradable polymer
Natural polymer
They occur naturally and are found in plants and animals. For example, proteins, starch, cellulose, and rubber. To add up, we also have biodegradable polymers called biopolymers.
Semi-synthetic Polymers:
They are derived from naturally occurring polymers and undergo further chemical modification. For example, cellulose nitrate, and cellulose acetate.
Synthetic Polymers
These are man-made polymers. Plastic is the most common and widely used synthetic polymer. It is used in industries and various dairy products. For example, nylon-6, 6, polyether’s etc.
Thermosetting polymers These polymers greatly improve the material’s mechanical properties. It provides enhanced chemical and heat resistance. For example, phenolics, epoxies, and silicones. Addition Polymerization: For Example, poly ethane, Teflon, Polyvinyl chloride (PVC) Condensation Polymerization: Example, Nylon -6, 6, perylene, polyesters.
Polymer
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Similar to Topic 8 Plastics Learning Outcomes
Polymerization (Condensation Polymerization)
Primary Discussion on Mechanism of Condensation Polymerization
1 Name .docx
1
Name: Chem 9, Section:
Lab Partner: Experiment Date:
Synthetic Polymers and Plastics
Part A: Physical Characteristics
Find or choose one type of each of the following plastic polymers, and report the following
characteristics:
Plastic
number
Short Name
(HDPE,
LDPE, etc)
Clear
(yes or no)
Opaque
(yes or no)
Flexibility
(can be
bent?)
Durability
(hard or
soft)
Breakability
(can be
cracked?)
Recyclable
(yes or no)
1
2
3
4
5
6
7
Part B: Density Tests
Report for plastic samples in each liquid: sinks rapidly, sinks slowly, floats on top, floats below surface
Plastic
number
1:1 ethanol/water
density = 0.94 g/cm
3
Water
density = 1.0 g/cm
3
10% NaCl solution
density = 1.08 g/cm
3
1
2
3
4
5
6
Relative Plastic Densities:
Less than 0.94 g/cm
3
Less than 1.0 g/cm
3
Less than 1.08 g/cm
3
More than 1.08 g/cm
3
Ranking of densities:
(lowest) _______ _______ _______ _______ _______ _______ (highest)
2
Part C: Polymer Bouncy Balls
Polymer Ball composition Approximate height bounced Physical characteristics
Ball #1:
Ball #2
Ball #3
Questions
1. Which of the Big Six plastics was the most flexible?
2. Which of the Big Six plastics would be the best material for each of the following examples?
Use short names to identify each plastic (e.g. HDPE).
a replacement for a glass window ?
a take-out container for food?
a flexible, expandable bag for carrying items?
a lightweight bottle cap?
3. An unknown plastic floats in a 10% NaCl solution but sinks in water. What is the range of
possible density values this plastic may have? Suggest the composition of this plastic.
3
4. Why is it important to dislodge any adhering bubbles in the density tests?
5. PET plastic (number 1) is the most valuable waste plastic at the present time. Suggest a way
to separate it commercially from other waste plastics.
6. Sometimes plastic containers are made from two polymers and not just one. What would
happen to the water density test if HDPE and PVC were mixed?
7. Why are plastic recyclers very concerned about identifying the different polymers and not
mixing them together?
8. The figure below depicts polymerization of polystyrene (PS). Circle the original monomers
and determine how many monomers are present.
4
9. Polyvinylchloride (PVC) is composed of the vinyl chloride monomer. The monomer
structure and general reaction are shown at right.
Draw a polyvinyl chloride polymer composed of five
monomers arrange ...
Plastic's use and abuse
Main point of this slide
01. Introduction
02. There are some types of plastic materials such as
03. History
04. Organic Structure of Plastic
05. Mechanism of Organic Structure
06. The molecule Ethene
07. The molecule Polyvinyl chloride
08. Uses
09. Benefits
10. Uses Statistics
11. Pollutants of plastic
12. Disadvantage of plastic
13. Plastic Waste management
14. Alternative of Plastic
15. Conclusion
Thank you
Polymers Meyer (2014) suggests that a contemporary culture could n.docx
Polymers Meyer (2014) suggests that a contemporary culture could not long endure without the goods or products that the polymer industry provides (p. 607). These polymeric products include clothing, household/office, indoor and outdoor gadgets, and furnishings that are manufactured from natural and synthetic polymers. Polymers are not ordinarily considered hazardous materials since they are stable at ambient conditions; however, most of the products burn and produce toxic gases (Meyer, 2014). Because of their widespread use, it is of benefit to understand why and how they can pose hazards, especially during fires. For this unit, we will study the features and structural characteristics of commonly encountered polymers as well as the hazards that they pose when they burn. What are polymers? The International Union of Pure and Applied Chemistry (IUPAC) education website defines polymers as substances or macromolecules that “are composed of very large molecules with molecular weights ranging from a few thousand to as high as millions of grams/mole” (n.d., para. 1). For additional information on polymers, visit http://www.iupac.org/polyedu/page33/page33.html. The structure of a macromolecule is essentially comprised of multiple repetitions of units derived, actually or conceptually, from molecules of low molecular mass. Polymers can be natural or synthetic, but most of us probably associate polymers with the synthetic ones such as plastic. Examples of natural polymers include protein, starch, cellulose, and DNA that make up most of the structures of living tissue. Synthetic polymers include polyvinyl chloride (PVC), polycarbonate, and polyethylene. UNIT VII STUDY GUIDE Chemistry of Toxic Substances BOS 3640, Interactions of Hazardous Materials 2 UNIT x STUDY GUIDE Title Types of synthetic polymers: Synthetic polymers are often referred to as plastics, and most of them can be classified into the categories of elastomers, thermoplastics, and thermosets: Thermoplastics are polymers that soften when heated but return to their original condition on cooling to ambient temperature (e.g., polyvinyl chloride (PVC), polyethylene). Thermosets are polymers that cannot be remolded once they have solidified, such as polyurethane. Elastomers have elasticity like rubber (Polymer Science Learning Center, 2005). Polymerization is the chemical reaction during which monomers are linked and cross-linked to form polymers. The polymerization reaction is characterized by the macromolecule/polymer that is produced (see Figures 14.1 and 14.2 of the textbook). According to Meyer (2014), chemists have found when they examined the three-dimensional structure of polymers that the chains of repeating units are invariably cross-linked as shown in Figure 14.3 of the textbook. Note the following information about polymers: Intentional cross-linking technique for polymers is used during the production of thermoset plastics to make the polymer denser, stronger, and even elastic.
Plastic processing
Presentation Deals with the various Aspects and parameters related to Plastic Processing, its Application, Advancement and Limitations.
GREEN COMPOSITES
Green composites( Polymer Matrix composites only; Including wood plastic composites)
POLYMERS
Introduction
Types of polymer
Classification of Polymer
Polymerization
Biodegradable Polymer
Application of biodegradable polymer
Natural polymer
They occur naturally and are found in plants and animals. For example, proteins, starch, cellulose, and rubber. To add up, we also have biodegradable polymers called biopolymers.
Semi-synthetic Polymers:
They are derived from naturally occurring polymers and undergo further chemical modification. For example, cellulose nitrate, and cellulose acetate.
Synthetic Polymers
These are man-made polymers. Plastic is the most common and widely used synthetic polymer. It is used in industries and various dairy products. For example, nylon-6, 6, polyether’s etc.
Thermosetting polymers These polymers greatly improve the material’s mechanical properties. It provides enhanced chemical and heat resistance. For example, phenolics, epoxies, and silicones. Addition Polymerization: For Example, poly ethane, Teflon, Polyvinyl chloride (PVC) Condensation Polymerization: Example, Nylon -6, 6, perylene, polyesters.
Polymer
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Topic 8 Plastics Learning Outcomes
- 1. Plastics and Synthetic Fibres Learning outcomes for Topic 8