Stereoisomers are isomeric molecules that have the same molecular formula and
sequence of bonded atoms (constitution), but that differ only in the three-dimensional
orientations of their atoms in space. This contrasts with structural isomers, which share the same
molecular formula, but the bond connections and/or their order differ(s) between different
atoms/groups. In stereoisomers, the order and bond connections of the constituent atoms remain
the same, but their orientation in space differ. stereo isomers are classifides in to two types
(1)enantiomers (2)diastereomers Enantiomers are two stereoisomers that are related to each other
by a reflection: They are mirror images of each other, which are non-superimposable. Human
hands are a macroscopic example of stereoisomerism. Every stereogenic center in one has the
opposite configuration in the other. Two compounds that are enantiomers of each other have the
same physical properties, except for the direction in which they rotate polarized light and how
they interact with different optical isomers of other compounds. As a result, different
enantiomers of a compound may have substantially different biological effects. Pure enantiomers
also exhibit the phenomenon of optical activity and can be separated only with the use of a chiral
agent. In nature, only one enantiomer of most chiral biological compounds, such as amino acids
(except glycine, which is achiral), is present. Diastereomers are stereoisomers not related through
a reflection operation. They are not mirror images of each other. These include meso
compounds, cis-trans (E-Z) isomers, and non-enantiomeric optical isomers. Diastereomers
seldom have the same physical properties. In the example shown below, the meso form of
tartaric acid forms a diastereomeric pair with both levo and dextro tartaric acids, which form an
enantiomeric pair.
Solution
Stereoisomers are isomeric molecules that have the same molecular formula and
sequence of bonded atoms (constitution), but that differ only in the three-dimensional
orientations of their atoms in space. This contrasts with structural isomers, which share the same
molecular formula, but the bond connections and/or their order differ(s) between different
atoms/groups. In stereoisomers, the order and bond connections of the constituent atoms remain
the same, but their orientation in space differ. stereo isomers are classifides in to two types
(1)enantiomers (2)diastereomers Enantiomers are two stereoisomers that are related to each other
by a reflection: They are mirror images of each other, which are non-superimposable. Human
hands are a macroscopic example of stereoisomerism. Every stereogenic center in one has the
opposite configuration in the other. Two compounds that are enantiomers of each other have the
same physical properties, except for the direction in which they rotate polarized light and how
they interact with different optical isomers of other compounds. As a result, different
enantiomer.
Stereoisomers are isomeric molecules that have th.pdf
1. Stereoisomers are isomeric molecules that have the same molecular formula and
sequence of bonded atoms (constitution), but that differ only in the three-dimensional
orientations of their atoms in space. This contrasts with structural isomers, which share the same
molecular formula, but the bond connections and/or their order differ(s) between different
atoms/groups. In stereoisomers, the order and bond connections of the constituent atoms remain
the same, but their orientation in space differ. stereo isomers are classifides in to two types
(1)enantiomers (2)diastereomers Enantiomers are two stereoisomers that are related to each other
by a reflection: They are mirror images of each other, which are non-superimposable. Human
hands are a macroscopic example of stereoisomerism. Every stereogenic center in one has the
opposite configuration in the other. Two compounds that are enantiomers of each other have the
same physical properties, except for the direction in which they rotate polarized light and how
they interact with different optical isomers of other compounds. As a result, different
enantiomers of a compound may have substantially different biological effects. Pure enantiomers
also exhibit the phenomenon of optical activity and can be separated only with the use of a chiral
agent. In nature, only one enantiomer of most chiral biological compounds, such as amino acids
(except glycine, which is achiral), is present. Diastereomers are stereoisomers not related through
a reflection operation. They are not mirror images of each other. These include meso
compounds, cis-trans (E-Z) isomers, and non-enantiomeric optical isomers. Diastereomers
seldom have the same physical properties. In the example shown below, the meso form of
tartaric acid forms a diastereomeric pair with both levo and dextro tartaric acids, which form an
enantiomeric pair.
Solution
Stereoisomers are isomeric molecules that have the same molecular formula and
sequence of bonded atoms (constitution), but that differ only in the three-dimensional
orientations of their atoms in space. This contrasts with structural isomers, which share the same
molecular formula, but the bond connections and/or their order differ(s) between different
atoms/groups. In stereoisomers, the order and bond connections of the constituent atoms remain
the same, but their orientation in space differ. stereo isomers are classifides in to two types
(1)enantiomers (2)diastereomers Enantiomers are two stereoisomers that are related to each other
by a reflection: They are mirror images of each other, which are non-superimposable. Human
hands are a macroscopic example of stereoisomerism. Every stereogenic center in one has the
opposite configuration in the other. Two compounds that are enantiomers of each other have the
same physical properties, except for the direction in which they rotate polarized light and how
they interact with different optical isomers of other compounds. As a result, different
enantiomers of a compound may have substantially different biological effects. Pure enantiomers
2. also exhibit the phenomenon of optical activity and can be separated only with the use of a chiral
agent. In nature, only one enantiomer of most chiral biological compounds, such as amino acids
(except glycine, which is achiral), is present. Diastereomers are stereoisomers not related through
a reflection operation. They are not mirror images of each other. These include meso
compounds, cis-trans (E-Z) isomers, and non-enantiomeric optical isomers. Diastereomers
seldom have the same physical properties. In the example shown below, the meso form of
tartaric acid forms a diastereomeric pair with both levo and dextro tartaric acids, which form an
enantiomeric pair.