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International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194
www.rsisinternational.org Page 57
Production and Evaluation of Impact Strength of
Snail Shell Reinforced Epoxy Composite
Nkin Gift Kiisi
Department of Industrial Chemistry, University Of Abuja, Pmb 117 Gwagwalada, Abuja, Nigeria
Abstract: Particulate-filled polymer composites are becoming
quite attractive because of their low cost and wide application.
Nowadays shells of arthropods and mollusks are widely used as
reinforced materials due to their availability and impact
mechanical properties. This study focused on the production and
evaluation of impact strength of snail shell reinforced epoxy
composite and as well given concrete information and
recommendation on usage with respect to appropriate filler
concentration and impact strength resistance. Production was
carried out according to the percentages of filler which are 0%,
10%, 20%, 30%, 40% and 50% respectively. ASTM standard
method forcharpy impact strength tests was used to determine
the impact resistance of samples. From the result, the neat epoxy
gave 11.344 while 10% and 20% filler concentration gave 7.519
and 7.056 KJ/m² respectively. The results showed that the impact
strength of snail shell reinforced epoxy composite, decreases with
increase in filler concentration. Composite materials are
generally used for building, bridges and structures such as boat,
hulls, swimming pool panels and shower stalls.
Key words: production, evaluation, impact, strength, snail shell,
epoxy, composite.
I. INTRODUCTION
odern technologies require materials which have
unusual combinations of properties that cannot be
provided by any single material.
Composite materials are materials made from two or more
constituent materials significantly different physical or
chemical properties, that when combined, produce a material
with characteristics different from the individual
components.[1
]
Fig 1.0 REPRESENTATION OF A COMPOSITE MATERIAL
1
Waterman and Pamela (2007)
The individual components remain separate and distinct
within the finished structure.
One of the earliest use of composite materials was by the
ancient Mesopotamians around 3400 B.C, when they glued
wood strips at different angles to create plywood[2
].
The earliest man-made composite materials were straw and
mud combined to form bricks for building construction[3
].
Ancient brick paint making was documented by Egyptian
tomb paintings. Water and daub is one of the oldest man-made
composite materials at over 600 years old[4
].
In the early 1900’s, plastic such as vinyl, polystyrene,
phenolic and polyester were developed. As important as these
innovations were, reinforcement was needed to provide the
strength and rigidity. The first artificial fiber reinforced was
Bakelite which dated to 1907[5
].
Although other Nigerian researchers have used snail shell and
other different materials as filler in polymer composite
production, but snail shell of the species[Aspersa] has not
been used. One of the major problems associated with snail
shell reinforced epoxy composite production and evaluation in
many research work done in Nigeria is lack of concrete
information on impact resistance or energy absorbing property
with reference to appropriate filler concentration and usage.
Due to the availability and low cost of snail shell in Nigeria, it
is high time we focus on the use of snail shell as a reinforced
material in polymer composite production to enable our local
industries function to their optimum production.
Therefore, this research seeks to produce and evaluate the
impact strength of snail shell reinforced epoxy composite and
as well, given concrete information and recommendation on
usage, with respect to filler concentration and impact strength
resistance.
1.1 Snail shell as a reinforced material
2
Housecraft and Catherine E (2008). Composite and reinforcement. 2nd
edition pp 437-443
3
John W. Benson (1980). Application of composite materials p.44
4
Miller and Marvin J. (2007). Classification of plastics and molding
techniques. 1st
edition. Pp 77-79
5
May and Clayton A.91987). epoxy resins: chemistry and technology 2nd
edition pp 795-797
M
International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194
www.rsisinternational.org Page 58
Fig 1.1 garden/land snail
Below is the taxonomic classification of common garden/land
snails in Nigeria[6
].
Kingdom: Animalia
Class: Mollusca
Order: Stylommatophora
Family: Helicidae
Genus: Helix
Species: Aspersa
II. MATERIALS AND METHODS
2.1 Apparatus and Material
Mortar and pestle, oven, wire sieve, take away plastic plate,
moulds (size: L=17cm. W=13cm), foil [paper, razor blade,
hypodermic syringes, spatula, weighing balance [OHAUS],
measuring cylinder [50,100(cm3
)], composite cutting machine,
impact 15 [DTS-15], filler (grounded sieve snail shell).
2.2 Regent
Epoxy resin, and hardener
III. METHODOLOGY
3.1 Sample collection
The snail shells were obtained from Gwagwalada market
while the epoxy resin and hardeners were purchased from a
chemical shop in Lagos, Lagos State.
3.2 Sample preparation
The snail shells were thoroughly cleaned, washed and dried in
an oven temperature to remove water. Furthermore, they were
pounded using mortar and pestle to powder form. Wire sieve
was used to sieve the sample. The collected sample was stored
in two cleaned, dried takeaway plastic plates tightly covered
and was finally used for composite production.
6
Peter H. Raven, George B. Johnson (2002). The diversity of mollusks and
Athropods. 3rd
edition .
3.3 Method of production
Open molding method was adopted.
Appropriate measured amount of both resin and the reinforced
material was mixed completely and placed in an open mould
of the sizes, L, 17cm and W 13cm covered at the bottom with
aluminum foil which was allowed to cure or harden while
exposed to air.
Below are the photographs of the produced polymer
composite at various filler level i.e. 0, 10, 20, 30, 40 & 50%.
Fig 3.4 showing impact 15 [DTS-15] Used for impact strength Determination
NOTE: (SS) represent snail shell (filler)
(EP) Represent Epoxy Resin
3.4 Charpy Impact Strength Test Procedures
Charpy impact test is an ATSM standard method of
determining the impact resistance of materials. A hammer-like
International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194
www.rsisinternational.org Page 59
pendulum with a massive striking edge was allowed to hit the
sample. From the travel of the pendulum after breaking the
specimen, the energy absorbed by the sample was determined
[7
]. Values for the energy (KJ/m2
) required to break each of
the samples was calculated by the machine [impact-15] as
shown on the result sheet, the testing temperature was
maintained at 22.
IV. RESULT, DISCUSSION, CONCLUSION AND
RECOMMENDATION
4.1 Result
The results are presented in table 4.1 and figure 4.1. Table
4.1shows the values of energy in KJ/m2
required to break the
various samples produced at zero filler level [100%EP] to 50
filler level [50% SS/EP] in percentages and figure 4.1
presented the result in bar chart.
Table 4.1: showing the result of the impact test of snail shell epoxy composite
S/N FILLER LEVEL (%)
IMPACT
ENERGY (KJ/m2
)
1 0 11.344
2 10 7.519
3 20 7.056
4 30 6.737
5 40 5.107
6 50 3.613
Figure 4.1: the interpretation of results in bar chart
7
Charpy impact test(1998). Testing of mechanical properties of polymer.
P432
4.2 Discussion
It is obvious from figure 4.1 that the impact strength of snail
shell reinforced epoxy composite decreases with increase in
filler concentration. The decreased observed between 30 - 50
percentages is significant compared to decrease observed
between 10 - 20 percentages.
4.3 Conclusion
Snail shell contains calcium carbonate and can be considered
as a good source of filler material in polymer composite
production due to its impact mechanical properties,
availability and low cost. The impact strength of snail shell
reinforced epoxy composite decreases with increase in filler
concentration.Information obtained from impact test can be
used to determine whether a given composite has sufficient
energy – absorbing properties to be used for a particular
application.
4.4 Recommendation
Since the impact strength of snail shell reinforced epoxy
composite decreases with increase in filler concentration, it is
recommendable that, snail shell polymer composite which
usage demanded high impact strength should be produced at
low filler concentration while those which usage demanded
low impact strength should be produced at high filler
concentration.
REFERENCE
[1] Waterman, Pamela J (2007). The life of composite material,
desktop Engineering Magazine.
[2] Housecraft and Catherine E (2008). Composite and
reinforcement. 2nd edition P. 437-443
[3] John W. Benson (1980). Application of composite materials
P.44
[4] Miller and Marvin J. (2007). Classification of plastics and
molding techniques. 1st Edition. P. 77-79
[5] May and ClaytonA. (1987). Epoxy Resins: chemistry and
technology 2nd edition P. 795-797
[6] Peter H Raven, George B. Johnson (2002). The diversity of
mollusks and Athropods. 3rd edition. P.379
[7] Charpy impact test (1998). Testing of mechanical properties
of polymer. P. 432

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Production and Evaluation of Impact Strength of Snail Shell Reinforced Epoxy Composite

  • 1. International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194 www.rsisinternational.org Page 57 Production and Evaluation of Impact Strength of Snail Shell Reinforced Epoxy Composite Nkin Gift Kiisi Department of Industrial Chemistry, University Of Abuja, Pmb 117 Gwagwalada, Abuja, Nigeria Abstract: Particulate-filled polymer composites are becoming quite attractive because of their low cost and wide application. Nowadays shells of arthropods and mollusks are widely used as reinforced materials due to their availability and impact mechanical properties. This study focused on the production and evaluation of impact strength of snail shell reinforced epoxy composite and as well given concrete information and recommendation on usage with respect to appropriate filler concentration and impact strength resistance. Production was carried out according to the percentages of filler which are 0%, 10%, 20%, 30%, 40% and 50% respectively. ASTM standard method forcharpy impact strength tests was used to determine the impact resistance of samples. From the result, the neat epoxy gave 11.344 while 10% and 20% filler concentration gave 7.519 and 7.056 KJ/m² respectively. The results showed that the impact strength of snail shell reinforced epoxy composite, decreases with increase in filler concentration. Composite materials are generally used for building, bridges and structures such as boat, hulls, swimming pool panels and shower stalls. Key words: production, evaluation, impact, strength, snail shell, epoxy, composite. I. INTRODUCTION odern technologies require materials which have unusual combinations of properties that cannot be provided by any single material. Composite materials are materials made from two or more constituent materials significantly different physical or chemical properties, that when combined, produce a material with characteristics different from the individual components.[1 ] Fig 1.0 REPRESENTATION OF A COMPOSITE MATERIAL 1 Waterman and Pamela (2007) The individual components remain separate and distinct within the finished structure. One of the earliest use of composite materials was by the ancient Mesopotamians around 3400 B.C, when they glued wood strips at different angles to create plywood[2 ]. The earliest man-made composite materials were straw and mud combined to form bricks for building construction[3 ]. Ancient brick paint making was documented by Egyptian tomb paintings. Water and daub is one of the oldest man-made composite materials at over 600 years old[4 ]. In the early 1900’s, plastic such as vinyl, polystyrene, phenolic and polyester were developed. As important as these innovations were, reinforcement was needed to provide the strength and rigidity. The first artificial fiber reinforced was Bakelite which dated to 1907[5 ]. Although other Nigerian researchers have used snail shell and other different materials as filler in polymer composite production, but snail shell of the species[Aspersa] has not been used. One of the major problems associated with snail shell reinforced epoxy composite production and evaluation in many research work done in Nigeria is lack of concrete information on impact resistance or energy absorbing property with reference to appropriate filler concentration and usage. Due to the availability and low cost of snail shell in Nigeria, it is high time we focus on the use of snail shell as a reinforced material in polymer composite production to enable our local industries function to their optimum production. Therefore, this research seeks to produce and evaluate the impact strength of snail shell reinforced epoxy composite and as well, given concrete information and recommendation on usage, with respect to filler concentration and impact strength resistance. 1.1 Snail shell as a reinforced material 2 Housecraft and Catherine E (2008). Composite and reinforcement. 2nd edition pp 437-443 3 John W. Benson (1980). Application of composite materials p.44 4 Miller and Marvin J. (2007). Classification of plastics and molding techniques. 1st edition. Pp 77-79 5 May and Clayton A.91987). epoxy resins: chemistry and technology 2nd edition pp 795-797 M
  • 2. International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194 www.rsisinternational.org Page 58 Fig 1.1 garden/land snail Below is the taxonomic classification of common garden/land snails in Nigeria[6 ]. Kingdom: Animalia Class: Mollusca Order: Stylommatophora Family: Helicidae Genus: Helix Species: Aspersa II. MATERIALS AND METHODS 2.1 Apparatus and Material Mortar and pestle, oven, wire sieve, take away plastic plate, moulds (size: L=17cm. W=13cm), foil [paper, razor blade, hypodermic syringes, spatula, weighing balance [OHAUS], measuring cylinder [50,100(cm3 )], composite cutting machine, impact 15 [DTS-15], filler (grounded sieve snail shell). 2.2 Regent Epoxy resin, and hardener III. METHODOLOGY 3.1 Sample collection The snail shells were obtained from Gwagwalada market while the epoxy resin and hardeners were purchased from a chemical shop in Lagos, Lagos State. 3.2 Sample preparation The snail shells were thoroughly cleaned, washed and dried in an oven temperature to remove water. Furthermore, they were pounded using mortar and pestle to powder form. Wire sieve was used to sieve the sample. The collected sample was stored in two cleaned, dried takeaway plastic plates tightly covered and was finally used for composite production. 6 Peter H. Raven, George B. Johnson (2002). The diversity of mollusks and Athropods. 3rd edition . 3.3 Method of production Open molding method was adopted. Appropriate measured amount of both resin and the reinforced material was mixed completely and placed in an open mould of the sizes, L, 17cm and W 13cm covered at the bottom with aluminum foil which was allowed to cure or harden while exposed to air. Below are the photographs of the produced polymer composite at various filler level i.e. 0, 10, 20, 30, 40 & 50%. Fig 3.4 showing impact 15 [DTS-15] Used for impact strength Determination NOTE: (SS) represent snail shell (filler) (EP) Represent Epoxy Resin 3.4 Charpy Impact Strength Test Procedures Charpy impact test is an ATSM standard method of determining the impact resistance of materials. A hammer-like
  • 3. International Journal of Research and Innovation in Applied Science (IJRIAS) | Volume V, Issue XII, December 2020|ISSN 2454-6194 www.rsisinternational.org Page 59 pendulum with a massive striking edge was allowed to hit the sample. From the travel of the pendulum after breaking the specimen, the energy absorbed by the sample was determined [7 ]. Values for the energy (KJ/m2 ) required to break each of the samples was calculated by the machine [impact-15] as shown on the result sheet, the testing temperature was maintained at 22. IV. RESULT, DISCUSSION, CONCLUSION AND RECOMMENDATION 4.1 Result The results are presented in table 4.1 and figure 4.1. Table 4.1shows the values of energy in KJ/m2 required to break the various samples produced at zero filler level [100%EP] to 50 filler level [50% SS/EP] in percentages and figure 4.1 presented the result in bar chart. Table 4.1: showing the result of the impact test of snail shell epoxy composite S/N FILLER LEVEL (%) IMPACT ENERGY (KJ/m2 ) 1 0 11.344 2 10 7.519 3 20 7.056 4 30 6.737 5 40 5.107 6 50 3.613 Figure 4.1: the interpretation of results in bar chart 7 Charpy impact test(1998). Testing of mechanical properties of polymer. P432 4.2 Discussion It is obvious from figure 4.1 that the impact strength of snail shell reinforced epoxy composite decreases with increase in filler concentration. The decreased observed between 30 - 50 percentages is significant compared to decrease observed between 10 - 20 percentages. 4.3 Conclusion Snail shell contains calcium carbonate and can be considered as a good source of filler material in polymer composite production due to its impact mechanical properties, availability and low cost. The impact strength of snail shell reinforced epoxy composite decreases with increase in filler concentration.Information obtained from impact test can be used to determine whether a given composite has sufficient energy – absorbing properties to be used for a particular application. 4.4 Recommendation Since the impact strength of snail shell reinforced epoxy composite decreases with increase in filler concentration, it is recommendable that, snail shell polymer composite which usage demanded high impact strength should be produced at low filler concentration while those which usage demanded low impact strength should be produced at high filler concentration. REFERENCE [1] Waterman, Pamela J (2007). The life of composite material, desktop Engineering Magazine. [2] Housecraft and Catherine E (2008). Composite and reinforcement. 2nd edition P. 437-443 [3] John W. Benson (1980). Application of composite materials P.44 [4] Miller and Marvin J. (2007). Classification of plastics and molding techniques. 1st Edition. P. 77-79 [5] May and ClaytonA. (1987). Epoxy Resins: chemistry and technology 2nd edition P. 795-797 [6] Peter H Raven, George B. Johnson (2002). The diversity of mollusks and Athropods. 3rd edition. P.379 [7] Charpy impact test (1998). Testing of mechanical properties of polymer. P. 432