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Chemical characteristics and health risk assessment of traffic related particles
St. Pateraki1
, K. Bairachtari1,2
, C. Markellou3
, G. Chousos1
, Α. Stamatelopoulou1
, N. Mihalopoulos3,4
,
Ch.Vasilakos1
and Th. Maggos1
1
Environmental Research Laboratory/ I.N.RA.S.T.E.S., National Centre for Scientific Research
“DEMOKRITOS”, 153 10 Aghia Paraskevi, Athens, Greece
2
Hellenic Army Academy, Division of Physical Sciences & Applications, Vari Attica 16673, Greece
3
Environmental Chemical Processes Laboratory, Chemistry Department, University of Crete, 2208, 71003
Heraklion, Greece
4
Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Palaia
Penteli, 152 36, Athens, Greece
Keywords: Fine particles, roadside, chemical composition, health risk assessment
Presenting author email: stella@ipta.demokritos.gr
Roadside air quality in cities is an environmental and
simultaneously health issue of increasing concern,
especially in urban areas where many roadways are lined
by dense and high-rise buildings forming street canyon
that greatly limits the dispersion of mobile emissions.
Recently, the WHO classified diesel exhaust as Group I
Carcinogen (Rakowska et al., 2014) while aerosol
samples taken in urban areas show that motor vehicular
emissions, especially diesel exhausts, constitute the most
significant source of ultrafine and fine particles (Lee et
al., 2006). Despite the implementation of emission
control programs, roadway transport is still a major
source of PM pollution (Rakowska et al., 2014).
In general, horizontal aerosols profile in a roadside
microenvironment has been studied extensively.
Unfortunately, there are only limited studies observing
the vertical characteristics of traffic originated particles
(Tian et al., 2013). Therefore, a roadside monitoring
campaign in terms of PM2.5 and PM1 concentrations and
chemical components took place within the urban
atmosphere of Athens (ions, OC, EC, PAHs).
Being considered as traffic hot spot due to its
location next to one of the busiest roads of the capital,
the selected roadside allows the thorough investigation
of the behavior of different, traffic-impacted, diameter
particles. The placement of the experimental equipment
on different heights of a 19m high building (1st
and 5th
floor) i) along the open road and ii) at the street canyon
(H/W ratio~1.5), allocates the parallel analysis of the
configured vertical and horizontal PM status. Moreover,
taking into consideration the toxic and mutagenic
equivalency factor (TEF and MEF, respectively) method,
will be evaluated the carcinogenic and mutagenic
potential of PM2.5 and PM1- bound PAHs, both
horizontally and vertically. The particle mass
determination was conducted according to EN 12341.
The water-soluble ions and the carbon elements will be
detected using suppressed ion chromatography and a
carbon analyzer, respectively while the analysis of the
PAHs will be performed according to ISO 12884.
During the fieldwork (8-12/9/14 & 22-26/9/14), a total
of 60 samples were collected.
In total, the daily PM2.5 and PM1 values did not
exceed 32.4 and 27.5μg/m3
, respectively. As it was
expected, the obtained average load, was higher along
the open road, than the one at the street canyon. In both
investigated cases it should be highlighted the fact that
i) the average PM2.5 peak occurred at the 1st
floor while
the maximum PM1 average value was recorded at the 5th
one and ii) the PM1 partitioning at the PM2.5 mass was
increased on the 5th
floor (90% and 92% at the open road
and the street canyon, respectively). It is worthy to note
the significant vertical differentiation, at the street
canyon, between the PM1/PM2.5 ratio on 22/9; 43% and
96% on the 1st
and 5th
floor, respectively.
Fig. 1 Average PM concentration on the vertical
and the horizontal axis
This work was supported by thefinancial supported from
the EnTeC FP7 Capacities programme (REGPOT-2012-
2013-1, FP7, ID: 316173)
Lee, SC., Cheng, Y., Ho, K.F., Cao, J.J., Louie, PK.-K,
Chow J.C. and Watson J.G. (2006) Aerosol Sci.
Technol. 40, 157-165.
Rakowska, A., Wong, K.C., Townsend, T., Chan, K. L.,
Westerdahl, D., Ng, S., Mocnik, G., Drinovec, L. and
Ning Z. (2014) Atmos Environ 98, 260-270.
Tian, Y.-Z., Shi, G.-L., Han, S.-Q., Zhang, Y.-F., Feng,
Y.-C., Liu, G.-R., Gao, L.-J., Wu, J.-H. and Zhu, T.
(2013) Sci Total Environ 447, 1–9.
0
10
20
30
PM2.5 PM1 PM2.5 PM1
Concentration(μg/m^3)
Along the open road
Street Canyon
5
th
floor1
st
floor

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PATERAKI ABSTRACT 1(1)

  • 1. Chemical characteristics and health risk assessment of traffic related particles St. Pateraki1 , K. Bairachtari1,2 , C. Markellou3 , G. Chousos1 , Α. Stamatelopoulou1 , N. Mihalopoulos3,4 , Ch.Vasilakos1 and Th. Maggos1 1 Environmental Research Laboratory/ I.N.RA.S.T.E.S., National Centre for Scientific Research “DEMOKRITOS”, 153 10 Aghia Paraskevi, Athens, Greece 2 Hellenic Army Academy, Division of Physical Sciences & Applications, Vari Attica 16673, Greece 3 Environmental Chemical Processes Laboratory, Chemistry Department, University of Crete, 2208, 71003 Heraklion, Greece 4 Institute for Environmental Research and Sustainable Development, National Observatory of Athens, Palaia Penteli, 152 36, Athens, Greece Keywords: Fine particles, roadside, chemical composition, health risk assessment Presenting author email: stella@ipta.demokritos.gr Roadside air quality in cities is an environmental and simultaneously health issue of increasing concern, especially in urban areas where many roadways are lined by dense and high-rise buildings forming street canyon that greatly limits the dispersion of mobile emissions. Recently, the WHO classified diesel exhaust as Group I Carcinogen (Rakowska et al., 2014) while aerosol samples taken in urban areas show that motor vehicular emissions, especially diesel exhausts, constitute the most significant source of ultrafine and fine particles (Lee et al., 2006). Despite the implementation of emission control programs, roadway transport is still a major source of PM pollution (Rakowska et al., 2014). In general, horizontal aerosols profile in a roadside microenvironment has been studied extensively. Unfortunately, there are only limited studies observing the vertical characteristics of traffic originated particles (Tian et al., 2013). Therefore, a roadside monitoring campaign in terms of PM2.5 and PM1 concentrations and chemical components took place within the urban atmosphere of Athens (ions, OC, EC, PAHs). Being considered as traffic hot spot due to its location next to one of the busiest roads of the capital, the selected roadside allows the thorough investigation of the behavior of different, traffic-impacted, diameter particles. The placement of the experimental equipment on different heights of a 19m high building (1st and 5th floor) i) along the open road and ii) at the street canyon (H/W ratio~1.5), allocates the parallel analysis of the configured vertical and horizontal PM status. Moreover, taking into consideration the toxic and mutagenic equivalency factor (TEF and MEF, respectively) method, will be evaluated the carcinogenic and mutagenic potential of PM2.5 and PM1- bound PAHs, both horizontally and vertically. The particle mass determination was conducted according to EN 12341. The water-soluble ions and the carbon elements will be detected using suppressed ion chromatography and a carbon analyzer, respectively while the analysis of the PAHs will be performed according to ISO 12884. During the fieldwork (8-12/9/14 & 22-26/9/14), a total of 60 samples were collected. In total, the daily PM2.5 and PM1 values did not exceed 32.4 and 27.5μg/m3 , respectively. As it was expected, the obtained average load, was higher along the open road, than the one at the street canyon. In both investigated cases it should be highlighted the fact that i) the average PM2.5 peak occurred at the 1st floor while the maximum PM1 average value was recorded at the 5th one and ii) the PM1 partitioning at the PM2.5 mass was increased on the 5th floor (90% and 92% at the open road and the street canyon, respectively). It is worthy to note the significant vertical differentiation, at the street canyon, between the PM1/PM2.5 ratio on 22/9; 43% and 96% on the 1st and 5th floor, respectively. Fig. 1 Average PM concentration on the vertical and the horizontal axis This work was supported by thefinancial supported from the EnTeC FP7 Capacities programme (REGPOT-2012- 2013-1, FP7, ID: 316173) Lee, SC., Cheng, Y., Ho, K.F., Cao, J.J., Louie, PK.-K, Chow J.C. and Watson J.G. (2006) Aerosol Sci. Technol. 40, 157-165. Rakowska, A., Wong, K.C., Townsend, T., Chan, K. L., Westerdahl, D., Ng, S., Mocnik, G., Drinovec, L. and Ning Z. (2014) Atmos Environ 98, 260-270. Tian, Y.-Z., Shi, G.-L., Han, S.-Q., Zhang, Y.-F., Feng, Y.-C., Liu, G.-R., Gao, L.-J., Wu, J.-H. and Zhu, T. (2013) Sci Total Environ 447, 1–9. 0 10 20 30 PM2.5 PM1 PM2.5 PM1 Concentration(μg/m^3) Along the open road Street Canyon 5 th floor1 st floor