Particleboard is widely used for panelling, partitioning and ceiling in buildings. The treatment of this material to improve fire performance is not an exception. A study was carried out to determine the fire performance of kenaf particleboard treated with phosphorous-based fire retardants. Kenaf core particles were first treated separately with 8 and 10% solutions of monoammonium phosphate (MAP), diammonium phosphate (DAP) and a mixture of boric acid, guanylurea phosphate and phosphoric acid (BP®) using hot and cold bath processes. The soaking time needed to achieve the standard dry salt retention, i.e. 50 kg m-3 was determined. Particleboards from these treated kenaf particles were fabricated and their fire performance evaluated. Using 8% treating solution, it took about 36, 21 and 48 min of immersing in cold bath to achieve the standard retention requirement for MAP, DAP and BP® respectively but for 10% concentration, the times were slightly shorter, i.e. 15, 20 and 35 min respectively. Among the three phosphorous formulations, BP® showed the best performance in improving the insulation and integrity of kenaf particleboard when exposed to fire. This is followed by MAP and DAP. BP® treated board was the last to ignite compared with the other two boards.
a prediction of thermal properties of epoxy composites filled with pine appl...Ijripublishers Ijri
The document discusses research on predicting the thermal properties of epoxy composites filled with pine apple leaf fiber. Pine apple leaf fiber was used to reinforce epoxy resin composites at various volume fractions ranging from 0% to 20.1% fiber content. The composites were fabricated using hand layup and their thermal conductivity, specific heat, and thermal diffusivity were measured experimentally. The results showed that the thermal conductivity and thermal diffusivity decreased with increasing fiber content, while specific heat increased with increasing temperature. The composites exhibited low densities and thermal properties, indicating potential as lightweight insulating materials.
investigation on thermal properties of epoxy composites filled with pine app...Ijripublishers Ijri
he present paper deals with the effect of volume fraction of fillers on the thermal Properties of polymer composites. This work sees an opportunity of enhancement on insulation capability of a typical fiber reinforced polymer composite. To validate this mathematical model, a set of epoxy based composites, with fiber content ranging 4.38 to 20.10% of volume fractions have been prepared by simple hand lay-up technique. For preparing the composite, natural fiber i.e. Pine apple leaf fibers are incorporated in Epoxy Resin. Thermal conductivities of these composite samples are measured as per ASTM standard E-1530 by using the Unitherm™ Model 2022 tester, which operates on the double guarded heat flow principle at the temperature ranging from 30˚C to 150˚C. And also the Specific Heat of the powdered samples are measured by using Differential Scanning Calorimeter (DSC). By using the MATLAB the numerical analysis is carried out to find the value of Thermal Diffusivity with varying temperatures. It was observed that the thermal diffusivity varies with fiber concentration, but the variation of thermal diffusivity with varying temperature was not so significant.
KEYWORDS: Pine Apple Leaf fiber, Epoxy Composites, Volume Fraction, Thermal Properties.
The document summarizes a study on the effect of In, Ce, and Bi dopings on sintering and dielectric properties of Ba(Zn1/3Nb2/3)O3 (BZN) ceramics. In doping between 0.2-4.0% increased density at 1300°C. Ce doping decreased density at 1250°C. Bi doping up to 1.0% negatively affected densification, while higher levels improved it. XRD showed single phase formation for all dopant levels except 0.5% Bi. In and Ce doping increased dielectric constant from 41 to around 66 at 1 MHz. Bi doping initially decreased then increased dielectric constant with higher levels.
Ultra low dielectric constant (k 1⁄4 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 1⁄4 38) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers.
Torrefaction is a pretreatment process for biomass that increases its energy density and improves its properties for combustion and gasification. It involves heating biomass to 200-300°C in the absence of oxygen, which makes the biomass more hydrophobic, brittle, and increases its energy content from 18-23 MJ/kg. Several reactor concepts have been tested at the lab scale but no commercial plants yet. The process results in a 70% mass yield but 90% energy yield along with significantly reduced grinding requirements. Further research is still needed but torrefaction shows promise for more efficient biomass utilization.
A Study on Thermal behavior of Nano film as thermal interface layerIJASCSE
Increase in thermal design power and re-duce in manufacturing cost of the processor chip has pushes the need for high performance and durable test fixture design in future. Test fixture with efficient themal management has lowest resistance possible to maintain the accuracy of the device temperature when it makes contact with processor chip’s silicon during test. High thermal conductivity and mechanical relia-bility of text fixures are desired for high volume test environment. Nano film materials such as Aluminum Titanium Nitride (AlTiN), Titanium carbide (TiC), Ti-tanium on Titanium nitride (Ti on TiN), Titanium ni-tride on Titanium (TiN on Ti) and Aluminum(III) Ox-ide (Al2O3) are coated over copper substrates by Fil-tered Cathodic Vacuum Arc (FCVA) deposition method and tested for their thermal conductivity behavior for high volume test (HVM) environment. Thermal con-ductivity of the prepared films is tested by using the ASTM 5470 Thermal Interface Material (TIM) Tester. Titanium on Titanium nitride (Ti on TiN) and Alumi-num (III) Oxide (Al2O3) observed with highest thermal conductivity of 117.68 W/mk and 128.34 W/mk respec-tively among the prepared nano thin films. Thickness of the film and stack configuration influenced the thermal conductivity of the prepared film.
1. A melt spinning and spark plasma sintering (MS-SPS) process was used to prepare n-type Bi2(Te1-xSex)3 (x = 0.0-1.0) solid solutions from high purity elemental chunks.
2. Substitution of tellurium with selenium significantly impacted the electrical and thermal transport properties in a way that can be understood using valence bond rules and changes in band gap.
3. The Bi2(Se0.2Te0.8)3 sample achieved the highest ZT of 1.05 at 420K, with an average ZT of around 0.97 in the entire measurement temperature range from 300-500K, representing
Enhanced thermal conductivity of epoxy matrix composites filled with boron ni...IAEME Publication
This document summarizes research on enhancing the thermal conductivity of epoxy composites by adding boron nitride (BN) microparticles. Epoxy composites containing 0-11.3% BN by volume were prepared and their thermal conductivities were measured experimentally. Numerical simulations using ANSYS found the effective thermal conductivity increased by 27.82% for 11.3% BN and 440% for 30% BN, compared to neat epoxy. The results showed BN particles exhibited a percolation behavior, with a sudden jump in thermal conductivity occurring at 20% BN volume.
a prediction of thermal properties of epoxy composites filled with pine appl...Ijripublishers Ijri
The document discusses research on predicting the thermal properties of epoxy composites filled with pine apple leaf fiber. Pine apple leaf fiber was used to reinforce epoxy resin composites at various volume fractions ranging from 0% to 20.1% fiber content. The composites were fabricated using hand layup and their thermal conductivity, specific heat, and thermal diffusivity were measured experimentally. The results showed that the thermal conductivity and thermal diffusivity decreased with increasing fiber content, while specific heat increased with increasing temperature. The composites exhibited low densities and thermal properties, indicating potential as lightweight insulating materials.
investigation on thermal properties of epoxy composites filled with pine app...Ijripublishers Ijri
he present paper deals with the effect of volume fraction of fillers on the thermal Properties of polymer composites. This work sees an opportunity of enhancement on insulation capability of a typical fiber reinforced polymer composite. To validate this mathematical model, a set of epoxy based composites, with fiber content ranging 4.38 to 20.10% of volume fractions have been prepared by simple hand lay-up technique. For preparing the composite, natural fiber i.e. Pine apple leaf fibers are incorporated in Epoxy Resin. Thermal conductivities of these composite samples are measured as per ASTM standard E-1530 by using the Unitherm™ Model 2022 tester, which operates on the double guarded heat flow principle at the temperature ranging from 30˚C to 150˚C. And also the Specific Heat of the powdered samples are measured by using Differential Scanning Calorimeter (DSC). By using the MATLAB the numerical analysis is carried out to find the value of Thermal Diffusivity with varying temperatures. It was observed that the thermal diffusivity varies with fiber concentration, but the variation of thermal diffusivity with varying temperature was not so significant.
KEYWORDS: Pine Apple Leaf fiber, Epoxy Composites, Volume Fraction, Thermal Properties.
The document summarizes a study on the effect of In, Ce, and Bi dopings on sintering and dielectric properties of Ba(Zn1/3Nb2/3)O3 (BZN) ceramics. In doping between 0.2-4.0% increased density at 1300°C. Ce doping decreased density at 1250°C. Bi doping up to 1.0% negatively affected densification, while higher levels improved it. XRD showed single phase formation for all dopant levels except 0.5% Bi. In and Ce doping increased dielectric constant from 41 to around 66 at 1 MHz. Bi doping initially decreased then increased dielectric constant with higher levels.
Ultra low dielectric constant (k 1⁄4 1.53) materials with self-cleansing properties were synthesized via incorporation of fluorodecyl-polyhedral oligomeric silsesquioxane (FD-POSS) into recently synthesized perfluorocyclopentenyl (PFCP) aryl ether polymers. Incorporation of fluorine rich, high free volume, and low surface energy POSS into a semifluorinated PFCP polymer matrix at various weight percentages resulted in a dramatic drop in dielectric constant, as well as a significant increase in hydrophobicity and oleophobicity of the system. These ultra-low dielectric self-cleansing materials (qtilt 1⁄4 38) were fabricated into electrospun mats from a solvent blend of fluorinated FD-POSS with PFCP polymers.
Torrefaction is a pretreatment process for biomass that increases its energy density and improves its properties for combustion and gasification. It involves heating biomass to 200-300°C in the absence of oxygen, which makes the biomass more hydrophobic, brittle, and increases its energy content from 18-23 MJ/kg. Several reactor concepts have been tested at the lab scale but no commercial plants yet. The process results in a 70% mass yield but 90% energy yield along with significantly reduced grinding requirements. Further research is still needed but torrefaction shows promise for more efficient biomass utilization.
A Study on Thermal behavior of Nano film as thermal interface layerIJASCSE
Increase in thermal design power and re-duce in manufacturing cost of the processor chip has pushes the need for high performance and durable test fixture design in future. Test fixture with efficient themal management has lowest resistance possible to maintain the accuracy of the device temperature when it makes contact with processor chip’s silicon during test. High thermal conductivity and mechanical relia-bility of text fixures are desired for high volume test environment. Nano film materials such as Aluminum Titanium Nitride (AlTiN), Titanium carbide (TiC), Ti-tanium on Titanium nitride (Ti on TiN), Titanium ni-tride on Titanium (TiN on Ti) and Aluminum(III) Ox-ide (Al2O3) are coated over copper substrates by Fil-tered Cathodic Vacuum Arc (FCVA) deposition method and tested for their thermal conductivity behavior for high volume test (HVM) environment. Thermal con-ductivity of the prepared films is tested by using the ASTM 5470 Thermal Interface Material (TIM) Tester. Titanium on Titanium nitride (Ti on TiN) and Alumi-num (III) Oxide (Al2O3) observed with highest thermal conductivity of 117.68 W/mk and 128.34 W/mk respec-tively among the prepared nano thin films. Thickness of the film and stack configuration influenced the thermal conductivity of the prepared film.
1. A melt spinning and spark plasma sintering (MS-SPS) process was used to prepare n-type Bi2(Te1-xSex)3 (x = 0.0-1.0) solid solutions from high purity elemental chunks.
2. Substitution of tellurium with selenium significantly impacted the electrical and thermal transport properties in a way that can be understood using valence bond rules and changes in band gap.
3. The Bi2(Se0.2Te0.8)3 sample achieved the highest ZT of 1.05 at 420K, with an average ZT of around 0.97 in the entire measurement temperature range from 300-500K, representing
Enhanced thermal conductivity of epoxy matrix composites filled with boron ni...IAEME Publication
This document summarizes research on enhancing the thermal conductivity of epoxy composites by adding boron nitride (BN) microparticles. Epoxy composites containing 0-11.3% BN by volume were prepared and their thermal conductivities were measured experimentally. Numerical simulations using ANSYS found the effective thermal conductivity increased by 27.82% for 11.3% BN and 440% for 30% BN, compared to neat epoxy. The results showed BN particles exhibited a percolation behavior, with a sudden jump in thermal conductivity occurring at 20% BN volume.
This document discusses the burning characteristics of six selected structural timber species from Southwestern Nigeria. Eighteen timber samples of dimensions 510mm x 150mm x 150mm from the six species were exposed to fire for 0-29 minutes, 30-60 minutes, and 0-60 minutes. The species tested were Afara, Iroko, Mahogany, Mansonia, Opepe, and Teak. Charring rates were determined by measuring char depth and comparing to exposure time. Results showed charring rates increased with longer exposure times and higher densities and moisture contents reduced charring rates. Exposure time, density, and moisture content were found to influence timber burning characteristics.
Chemical modifications of natural fibres for composite applicationsketki chavan
This seminar report discusses chemical modifications of natural fibres for composite applications. It introduces composites and their constituents such as reinforcement, matrix and interface. It then classifies fibre reinforced composites and discusses market trends for natural fibre reinforced composites in automotive and construction industries. The report examines advantages and disadvantages of natural plant fibres such as flax, hemp and jute compared to conventional fibres. It describes the structure of plant fibres and various physical, biological, nanotechnology and chemical modification techniques to improve mechanical properties and interface bonding of natural fibres in composites. Specific chemical treatments including alkali, silane, acetylation and permanganate treatments are explained along with reaction mechanisms. Case studies on jute
Experimental Investigation of Flow Pattern on Rectangular Fin Arrays under Na...IJMER
Abstract: In Natural convection heat transfer with the help of fin arrays, parameter are fin length to height ratio, spacing
and orientation of geometry. In the longitudinally short fin array, where single chimney flow pattern is present hence heat
transfer coefficient is high. In long rectangular fin arrays, air is stagnant at central zone hence it is not so much contributed
in heat dissipation. In present study experimental setup is developed to studying the effect of natural convection over
rectangular fin array. Fin spacing, height and heater input are the parameter study during experimentation. Lampblack
coating is used to black fin surface. Flow patterns of various spacing’s are investigated using smoke flow visualization
techniques.
Keyword: Fin Arrays, Flow Visualization, Flow Pattern, Heat Transfer Coefficient, Natural convection.
PBO fibers (Zylon) provide high strength and modulus. They are manufactured by spinning a solution of the polymer in polyphosphoric acid. Zylon fibers have higher strength, modulus, and decomposition temperature than aramid fibers. They also have excellent flame resistance and stability in heat and chemicals. Common applications of PBO fibers include ballistic protection fabrics, reinforcement in composites, and heat/flame resistant work wear.
Graphene is synthesized from graphite through chemical reactions and thermal reduction to create a single layer of carbon atoms. Transmission electron microscopy is used to characterize the structure of graphene oxide and graphene, showing they are thin, crystalline flakes. Graphene nanosheets can then be incorporated into polymers as a nanocomposite to enhance the polymer's properties, such as increasing its thermal conductivity for applications in thermal management.
PERFORMANCE STUDY ON HYBRID GLASS FIBER EPOXY COMPOSITEIjorat1
1) The document discusses a study on hybrid glass fiber-epoxy composites with the addition of chemically treated natural fibers like jute and bagasse.
2) Jute and bagasse fibers were treated with sodium hydroxide, potassium permanganate, and stearic acid solutions. Composite specimens with treated and untreated fibers were fabricated by compression molding with layers of natural and glass fibers in epoxy resin.
3) The study aims to identify the optimal chemically treated natural fiber material to enhance the tensile and flexural strength of the hybrid composites. Mechanical properties of specimens will be compared to determine the effect of fiber treatment.
1) The document reports on a study that examined how the concentration of graphene nanofiller within polypropylene nanocomposites affects flame retardancy, impact strength resistance, and melting point.
2) The study found that increasing the graphene concentration improved flame retardancy but reduced impact strength resistance and lowered the melting point.
3) This is because the mismatch between polypropylene and graphene properties introduced stresses that weakened the nanocomposite structure at the nanoscale.
A REVIEW ON CHEMICAL AND PHYSICAL PROPERTIES OF NATURAL FIBER REINFORCED COMP...IAEME Publication
This review paper examines the chemical properties of natural fiber reinforced polymer bonded composites and the processing techniques are compared for the reinforced composite materials. The chemical properties of the different natural fibers composites were compared. Present days natural fibers are attracting many scholars and researchers due to its cost and largely available in nature also processing of these fibers is not hard in comparison to the conventional fibres production. Also, Environmental awareness and a growing concern with the greenhouse effect have triggered the construction, automotive, and packing industries to watch out for eco-friendly materials that can replace conventional synthetic polymeric fibres. Natural fibers seem to be a good alternate because they are readily available in fibrous form and can be extracted from herb leaves at very low costs. By these reasons the natural fibers are trusted over the regular fibers.
The document summarizes research on improving the properties of low-density wood through impregnation with phenolic resin admixed with urea. Key findings include:
1) Impregnation increased wood density by 2-3 times and weight percent gain by 50-100%, indicating successful penetration of the resin into the cellular structure.
2) Formaldehyde emission was reduced to a minimum of 8.38 ppm for jelutong and 23.59 ppm for sesenduk with addition of urea, though still above standards.
3) Fourier transform infrared spectroscopy analysis showed bands corresponding to urea-formaldehyde and phenol-urea formaldehyde confirming reaction and co-condensation with
Polymer composites are materials made by combining polymers with fibers or fillers. Natural fiber composites are an environmentally friendly type of polymer composite that uses plant-derived fibers like wood, sisal, hemp or cotton instead of fibers like fiberglass. They have been investigated since the 1960s for uses like repairing existing structures. Natural fiber composites are lightweight, can be produced with low energy, and sequester carbon dioxide. They provide benefits like strength enhancement, durability, and a replacement for steel with lower stiffness. However, there are challenges to wider adoption like a lack of experienced designers and higher short term costs. The construction industry is a major consumer of polymer composites, especially for non-load bearing
An experimental studies on heat sink using screw thread with and without perf...IJARIIT
The fins increase the effective area of the surface thereby increase the heat transfer by convection. In this project, an
experimental investigation on threaded pin fin solid and hollow with and without perforated. The pin fin is made out of copper
having dimension of 40 mm length, 16 mm diameter and rectangular base of required dimensions. The number of pin fin used
in inline arrangement 2, 4 and 6 respectively. The heat transfer takes place through a rectangular base plate with fin held in
the rectangular tunnel. The Nusselts number and Reynolds numbers considered as a performance parameter. By concluding
all the result, perforated solid thread inline pin fin has higher rate heat transfer capacity.
This document summarizes the results of a study on the effects of adding recycled nylon fish net fibres to laterite brick mixes. Tests were conducted on bricks with 0-5% nylon fibre content to determine the impacts on density, compressive strength, and water absorption. The results showed that as nylon fibre content increased, the density and compressive strength of the bricks decreased while water absorption increased. Bricks with 1% fibre content performed best in tests for density and compressive strength. The reductions were likely due to the lighter nylon replacing heavier materials, and fibre clustering weakening the structure.
The document analyzes the materials used in various parts of a low-end hairdryer. The heating wire was found to be made of Kanthal alloy, which is commonly used for heating elements due to its resistance and conductivity. The back of the case was determined to be injection molded ABS plastic through testing of its properties, structure, and infrared spectroscopy. Other parts included PVC insulated wires, a bimetallic temperature switch made of copper and steel, and ceramic magnets containing strontium hexaferrite in the electric motor.
Vanadium doped zinc telluride (ZnTe:V) thin films (containing 2.5 to 10wt% V) were deposited onto glass
substrates by e-beam evaporation technique in vacuum at a pressure of 8×10-4
Pa. Thermoelectric power of these
films have been measured from room temperature up to 413 K with reference to pure copper material. The
deposition rate of the films was maintained at 2.05 nms-1
. The composition and temperature dependence
thermopower and its related parameters have been studied in detail for a particular thickness of 150 nm. The
Fermi levels were determined using a non-degenerate semiconducting model. The carrier scattering index,
activation energy and temperature coefficient of activation energy have all been obtained at different ranges of
compositions and temperatures. The results of thermopower of ZnTe:V thin films obey an activated conduction
mechanism and also suggest that the simultaneous bipolar conduction of both (n- and p-types) carriers (mixed
carriers) take place. All these samples are optically transparent and mixed crystalline in structure
Ultrasonic bonding of flexible substrates and rigid boards using anisotropic conductive films (ACFs) was investigated as an alternative to traditional thermo-compression bonding. The study found that ultrasonic ACF bonding can be done at room temperature in only 5 seconds, significantly faster than the conventional 15 seconds at 190°C. Bond strength and electrical continuity of ultrasonic ACF bonds were comparable to thermo-compression bonds. Reliability testing showed ultrasonic ACF bonds maintained stable electrical resistance over 1000 hours at high temperature and humidity and 1000 thermal cycles from -55°C to 125°C.
fabrication and testing of palm fiber reinforced composite magarajothi sam
Composite materials are a mixture of two or more materials that provide improved properties over the individual components. They consist of a continuous matrix phase reinforced with a discontinuous phase. Natural fiber composites are gaining popularity due to their low cost, low density, high strength, and biodegradability. This document discusses different types of composites, fibers, and resins used in composites. It provides examples of various natural fibers like jute, flax, sisal and their properties. Different resins discussed include polyester, vinyl ester, epoxy and phenolic. The document also lists several applications of composites in industries like construction, transportation, marine etc.
This document discusses the development and characterization of poly(methyl methacrylate) (PMMA)/thermally reduced graphene oxide (TRG) composite coatings with TRGs of varying carboxylic group content for anticorrosion applications. Graphene oxide was thermally reduced at different temperatures (300, 1000, 1400°C) to produce TRGs with high, medium and low carboxylic group contents. These TRGs were then incorporated into PMMA matrices using UV curing to form composite coatings. Electrochemical measurements showed that coatings with TRGs of higher carboxylic group content provided better corrosion protection for steel, due to their enhanced oxygen barrier properties.
Dielectric, Electric and Thermal Behavior of La3+ doped Co-Zn NanoferriteIOSRJAP
Dielectric, Electric and Thermal properties of rare earth La3+ material doped in Co0.5Zn0.5 Lax Fe(2- x)O4 (where x=0.025, 0.050, 0.075, 0.100, 0.125) reaction nanocrystalline ferrites were synthesized by sol-gel auto combustion method. The electric, dielectric constant and Thermal properties were investigated. The dielectric constants and dielectric loss of the samples was observed between the 100Hz and 5 MHz. The resistivities of the prepared samples were measured from 0 Volt to 550 Volts at the constant temperature 2000C using the Two Probe method. The Thermal properties were characterized by Thermo Gravimetric and Differential Thermal Analysis (TGDTA).
IRJET- Investigation on Mechanical Behaviour of Sugarcane Bagasse Fiber R...IRJET Journal
This document investigates the mechanical behavior of sugarcane bagasse fiber reinforcement in polymer matrix composites. It begins by providing background on composite materials and the advantages of natural fibers like sugarcane bagasse. The document then reviews previous literature on composites using bagasse reinforcement. The methodology section outlines the fabrication process, including preparing the bagasse fibers and using an epoxy resin matrix. Mechanical tests will be performed to study the composites' tensile, flexural, and impact properties.
Chemical mechanism of fire retardance of boric acid on woodMohamed Tahoun, PMP
1) Thermogravimetric analysis of boric acid, guanylurea phosphate (GUP), and a mixture of the two (FRW) showed that each decomposed independently without interacting, as the curve for the mixture was a linear combination of the individual curves.
2) Differential thermal analysis of boric acid-treated wood showed an exothermic peak at 420°C, indicating an exothermic polymerization reaction during charring.
3) Cone calorimetry results demonstrated a considerable synergistic fire retardant effect between boric acid and GUP on wood.
Study of the Thermal Behavior of the Plaster Reinforced Vegetable Fiberinventionjournals
This study focused on the characterization of a heat insulating material, aims to determine the thermal characteristics of the plaster reinforced with vegetable fibers. It intends to replace the fibers of sisal generally used in practice to strengthen the plaster is replaced by those of the RheckthophyllumCamerunense (RC), a fiber of humid equatorial forests, in applications such as the manufacture of the staff, separating walls of dwellings. The objective of this work is to make a comparative assessment of the thermal diffusivity using a material composed of high porous plaster, non-reinforced and strengthened with the new plant fiber. It also aims to study the influence of the architecture of the RC fibers. The testing of thermal transfer by infrared thermography without contact are conducted on the composite plates. The resolution of the heat equation by finite difference with Matlab program permit the identification of the thermal diffusivity by fitting the theoretical thermogramme representation on the measures curve. The results reveal that the vegetable fibers increase the thermal performance of the plaster; that the RC fibers favor the isolation function better than the fibers of sisal and that their random distribution in the material proved to be more favorable.
This document discusses the burning characteristics of six selected structural timber species from Southwestern Nigeria. Eighteen timber samples of dimensions 510mm x 150mm x 150mm from the six species were exposed to fire for 0-29 minutes, 30-60 minutes, and 0-60 minutes. The species tested were Afara, Iroko, Mahogany, Mansonia, Opepe, and Teak. Charring rates were determined by measuring char depth and comparing to exposure time. Results showed charring rates increased with longer exposure times and higher densities and moisture contents reduced charring rates. Exposure time, density, and moisture content were found to influence timber burning characteristics.
Chemical modifications of natural fibres for composite applicationsketki chavan
This seminar report discusses chemical modifications of natural fibres for composite applications. It introduces composites and their constituents such as reinforcement, matrix and interface. It then classifies fibre reinforced composites and discusses market trends for natural fibre reinforced composites in automotive and construction industries. The report examines advantages and disadvantages of natural plant fibres such as flax, hemp and jute compared to conventional fibres. It describes the structure of plant fibres and various physical, biological, nanotechnology and chemical modification techniques to improve mechanical properties and interface bonding of natural fibres in composites. Specific chemical treatments including alkali, silane, acetylation and permanganate treatments are explained along with reaction mechanisms. Case studies on jute
Experimental Investigation of Flow Pattern on Rectangular Fin Arrays under Na...IJMER
Abstract: In Natural convection heat transfer with the help of fin arrays, parameter are fin length to height ratio, spacing
and orientation of geometry. In the longitudinally short fin array, where single chimney flow pattern is present hence heat
transfer coefficient is high. In long rectangular fin arrays, air is stagnant at central zone hence it is not so much contributed
in heat dissipation. In present study experimental setup is developed to studying the effect of natural convection over
rectangular fin array. Fin spacing, height and heater input are the parameter study during experimentation. Lampblack
coating is used to black fin surface. Flow patterns of various spacing’s are investigated using smoke flow visualization
techniques.
Keyword: Fin Arrays, Flow Visualization, Flow Pattern, Heat Transfer Coefficient, Natural convection.
PBO fibers (Zylon) provide high strength and modulus. They are manufactured by spinning a solution of the polymer in polyphosphoric acid. Zylon fibers have higher strength, modulus, and decomposition temperature than aramid fibers. They also have excellent flame resistance and stability in heat and chemicals. Common applications of PBO fibers include ballistic protection fabrics, reinforcement in composites, and heat/flame resistant work wear.
Graphene is synthesized from graphite through chemical reactions and thermal reduction to create a single layer of carbon atoms. Transmission electron microscopy is used to characterize the structure of graphene oxide and graphene, showing they are thin, crystalline flakes. Graphene nanosheets can then be incorporated into polymers as a nanocomposite to enhance the polymer's properties, such as increasing its thermal conductivity for applications in thermal management.
PERFORMANCE STUDY ON HYBRID GLASS FIBER EPOXY COMPOSITEIjorat1
1) The document discusses a study on hybrid glass fiber-epoxy composites with the addition of chemically treated natural fibers like jute and bagasse.
2) Jute and bagasse fibers were treated with sodium hydroxide, potassium permanganate, and stearic acid solutions. Composite specimens with treated and untreated fibers were fabricated by compression molding with layers of natural and glass fibers in epoxy resin.
3) The study aims to identify the optimal chemically treated natural fiber material to enhance the tensile and flexural strength of the hybrid composites. Mechanical properties of specimens will be compared to determine the effect of fiber treatment.
1) The document reports on a study that examined how the concentration of graphene nanofiller within polypropylene nanocomposites affects flame retardancy, impact strength resistance, and melting point.
2) The study found that increasing the graphene concentration improved flame retardancy but reduced impact strength resistance and lowered the melting point.
3) This is because the mismatch between polypropylene and graphene properties introduced stresses that weakened the nanocomposite structure at the nanoscale.
A REVIEW ON CHEMICAL AND PHYSICAL PROPERTIES OF NATURAL FIBER REINFORCED COMP...IAEME Publication
This review paper examines the chemical properties of natural fiber reinforced polymer bonded composites and the processing techniques are compared for the reinforced composite materials. The chemical properties of the different natural fibers composites were compared. Present days natural fibers are attracting many scholars and researchers due to its cost and largely available in nature also processing of these fibers is not hard in comparison to the conventional fibres production. Also, Environmental awareness and a growing concern with the greenhouse effect have triggered the construction, automotive, and packing industries to watch out for eco-friendly materials that can replace conventional synthetic polymeric fibres. Natural fibers seem to be a good alternate because they are readily available in fibrous form and can be extracted from herb leaves at very low costs. By these reasons the natural fibers are trusted over the regular fibers.
The document summarizes research on improving the properties of low-density wood through impregnation with phenolic resin admixed with urea. Key findings include:
1) Impregnation increased wood density by 2-3 times and weight percent gain by 50-100%, indicating successful penetration of the resin into the cellular structure.
2) Formaldehyde emission was reduced to a minimum of 8.38 ppm for jelutong and 23.59 ppm for sesenduk with addition of urea, though still above standards.
3) Fourier transform infrared spectroscopy analysis showed bands corresponding to urea-formaldehyde and phenol-urea formaldehyde confirming reaction and co-condensation with
Polymer composites are materials made by combining polymers with fibers or fillers. Natural fiber composites are an environmentally friendly type of polymer composite that uses plant-derived fibers like wood, sisal, hemp or cotton instead of fibers like fiberglass. They have been investigated since the 1960s for uses like repairing existing structures. Natural fiber composites are lightweight, can be produced with low energy, and sequester carbon dioxide. They provide benefits like strength enhancement, durability, and a replacement for steel with lower stiffness. However, there are challenges to wider adoption like a lack of experienced designers and higher short term costs. The construction industry is a major consumer of polymer composites, especially for non-load bearing
An experimental studies on heat sink using screw thread with and without perf...IJARIIT
The fins increase the effective area of the surface thereby increase the heat transfer by convection. In this project, an
experimental investigation on threaded pin fin solid and hollow with and without perforated. The pin fin is made out of copper
having dimension of 40 mm length, 16 mm diameter and rectangular base of required dimensions. The number of pin fin used
in inline arrangement 2, 4 and 6 respectively. The heat transfer takes place through a rectangular base plate with fin held in
the rectangular tunnel. The Nusselts number and Reynolds numbers considered as a performance parameter. By concluding
all the result, perforated solid thread inline pin fin has higher rate heat transfer capacity.
This document summarizes the results of a study on the effects of adding recycled nylon fish net fibres to laterite brick mixes. Tests were conducted on bricks with 0-5% nylon fibre content to determine the impacts on density, compressive strength, and water absorption. The results showed that as nylon fibre content increased, the density and compressive strength of the bricks decreased while water absorption increased. Bricks with 1% fibre content performed best in tests for density and compressive strength. The reductions were likely due to the lighter nylon replacing heavier materials, and fibre clustering weakening the structure.
The document analyzes the materials used in various parts of a low-end hairdryer. The heating wire was found to be made of Kanthal alloy, which is commonly used for heating elements due to its resistance and conductivity. The back of the case was determined to be injection molded ABS plastic through testing of its properties, structure, and infrared spectroscopy. Other parts included PVC insulated wires, a bimetallic temperature switch made of copper and steel, and ceramic magnets containing strontium hexaferrite in the electric motor.
Vanadium doped zinc telluride (ZnTe:V) thin films (containing 2.5 to 10wt% V) were deposited onto glass
substrates by e-beam evaporation technique in vacuum at a pressure of 8×10-4
Pa. Thermoelectric power of these
films have been measured from room temperature up to 413 K with reference to pure copper material. The
deposition rate of the films was maintained at 2.05 nms-1
. The composition and temperature dependence
thermopower and its related parameters have been studied in detail for a particular thickness of 150 nm. The
Fermi levels were determined using a non-degenerate semiconducting model. The carrier scattering index,
activation energy and temperature coefficient of activation energy have all been obtained at different ranges of
compositions and temperatures. The results of thermopower of ZnTe:V thin films obey an activated conduction
mechanism and also suggest that the simultaneous bipolar conduction of both (n- and p-types) carriers (mixed
carriers) take place. All these samples are optically transparent and mixed crystalline in structure
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fabrication and testing of palm fiber reinforced composite magarajothi sam
Composite materials are a mixture of two or more materials that provide improved properties over the individual components. They consist of a continuous matrix phase reinforced with a discontinuous phase. Natural fiber composites are gaining popularity due to their low cost, low density, high strength, and biodegradability. This document discusses different types of composites, fibers, and resins used in composites. It provides examples of various natural fibers like jute, flax, sisal and their properties. Different resins discussed include polyester, vinyl ester, epoxy and phenolic. The document also lists several applications of composites in industries like construction, transportation, marine etc.
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IRJET- Investigation on Mechanical Behaviour of Sugarcane Bagasse Fiber R...IRJET Journal
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2) Differential thermal analysis of boric acid-treated wood showed an exothermic peak at 420°C, indicating an exothermic polymerization reaction during charring.
3) Cone calorimetry results demonstrated a considerable synergistic fire retardant effect between boric acid and GUP on wood.
Study of the Thermal Behavior of the Plaster Reinforced Vegetable Fiberinventionjournals
This study focused on the characterization of a heat insulating material, aims to determine the thermal characteristics of the plaster reinforced with vegetable fibers. It intends to replace the fibers of sisal generally used in practice to strengthen the plaster is replaced by those of the RheckthophyllumCamerunense (RC), a fiber of humid equatorial forests, in applications such as the manufacture of the staff, separating walls of dwellings. The objective of this work is to make a comparative assessment of the thermal diffusivity using a material composed of high porous plaster, non-reinforced and strengthened with the new plant fiber. It also aims to study the influence of the architecture of the RC fibers. The testing of thermal transfer by infrared thermography without contact are conducted on the composite plates. The resolution of the heat equation by finite difference with Matlab program permit the identification of the thermal diffusivity by fitting the theoretical thermogramme representation on the measures curve. The results reveal that the vegetable fibers increase the thermal performance of the plaster; that the RC fibers favor the isolation function better than the fibers of sisal and that their random distribution in the material proved to be more favorable.
Expanded graphite as thermal conductivity enhancer for paraffin wax being us...Gulfam Raza
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1) Carbon foam was produced with 2-8% aluminum powder added to improve thermal and mechanical properties. During carbonization, aluminum reacted with carbon to form Al4C3 and AlN, increasing conductivity and strength.
2) Samples with 6% aluminum showed a density of 0.5-0.58 g/cm3, porosity of 64-68%, conductivity of 0.043-0.385 W/mK, and compressive strength of 17-32 MPa.
3) Carbon foam with 8% aluminum self-destructed after 2 weeks due to formation of Al4C3 and Al(OH)3 from reaction with atmospheric moisture, starting from the core and proceeding out
Preparation and characterization JAAP SCI-3shameel farhan
The document describes a method for preparing carbon foam from a mixture of phenolic resin and coal tar pitch using polyurethane foam as a soft template. The polyurethane foam was impregnated with the resin/pitch mixture through multiple cycles, then cured and carbonized to remove the template. The resulting carbon foam had a density of 0.48-0.60 g/cm3, porosity of 63-67%, compressive strength of 13.3-19.5 MPa, and pore sizes ranging from 10-500 micrometers. Testing showed the carbon foam has potential as a high-temperature thermal insulation material.
An experimental and analytical study to show the effect of theOzyegin University
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Silicate coatings are environmentally friendly inorganic-based products that have long
been used for mineral substrates and protection of steel against corrosion. The development and
acceptance of these coatings in the wood sector require some adjustments in formulations or special
preparation of the surface to be coated to obtain durable finishes. In this work, the adhesion of
various silicate-based formulations to a beech wood substrate (Fagus sylvatica L.), was assessed with
the main objective to study relevant parameters and potential improvements. Adhesion strength
was determined by pull-off and cross-cut tests. Other coating properties such as scratch, impact,
and water resistance were also determined. Surface roughness and interface were analyzed using
confocal laser scanning microscopy (CLSM) and scanning electron microscopy (SEM), and coating
curing was studied by attenuated total reflection-infrared spectroscopy (ATR FTIR). The results
showed that adhesion was highly dependent on formulation, penetration of the coatings into wood,
and mechanical anchoring. Increasing the content of solid particles in the coating formulations or
adding a polyol (glycerol, xylose), which probably acted as a coalescent, considerably decreased the
adhesion strength, probably by blocking penetration into the wood by forming aggregates. Adhesion
was improved by pre-mineralization of the surface, and substitution of a part of the potassium silicate
binder with potassium methyl siliconate reduced the formation of cracks caused by dimensional
instability of the wood.
Chemical Modification of Wood Using Vinegar and Benzoic Acid against Termites...Premier Publishers
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This research paper investigates the thermal properties of beeswax/graphene as a phase change material for energy storage applications in buildings. Differential scanning calorimetry was used to measure the melting temperature, thermal capacity, and latent heat of beeswax and beeswax/graphene samples. Thermal conductivity was measured using a thermal conductivity apparatus. Viscosity was also tested to analyze the effect of nanoparticles. Results showed that the addition of 0.3 wt% graphene increased the latent heat of beeswax by 22.5% and increased the thermal conductivity to 2.8 W/m K. Scanning electron microscopy, Fourier transform infrared spectroscopy and X-ray diffraction analysis confirmed compatibility between the beeswax
This document evaluates the combustion characteristics of charcoal produced from five tropical wood species: Iroko, Obeche, Oak, Afara, and Mahogany. Physical properties and proximate analyses were conducted on the charcoal samples. Results showed densities ranged from 0.453 to 0.620 g/cm3. Heating values ranged from 3.2149 to 3.3236 x 104 kJ/kg. Chemical analyses found moisture contents ranged from 2.110 to 4.823%. Charcoal from Afara wood had the highest heating value and lowest moisture content. Overall, properties varied between wood species and met criteria for quality charcoal.
This document summarizes research on developing a phosphoric acid doped poly(2,5-benzimidazole) membrane for use in high temperature fuel cells. Key points:
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Inherent flame retardant polyester fibre using organophosporous compounds as ...iosrjce
Flame retardant polyester fibres have been produced using various organo-phosphorous compounds
as melt additives. To ensure proper blending at the molecular level and stability at the spinning temperatures,
four organo-phosphorous compounds with melting point lower than that of polyethylene terephthalate (PET)
and boiling point higher than the processing temperature were selected. These compounds are
triphenylphosphine oxide (TPPO), diphenylchloro phosphate (DPCP), phenyl phosphonic acid (PPA), and 2,4-
diterbutylphenyl phosphite (DTBPP). The flame retardant polyester fibres are melt spun at 80 m/min on a
laboratory melt-spinning unit and subsequently drawn-heatset. The limiting oxygen index (LOI) has been found
to be in the range 25-27 at 2.5 -10.0% loading. The effect of additives on mechanical properties of fibres has
been investigated and correlated with the structure of the fibres. The TPPO is found to be most appropriate
additive among the selected compounds for providing adequate flame retardancy with very small loss in
mechanical properties. The, flame retardant PET fibres containing 10% TPPO showed tenacity comparable to
control sample. The study suggests the possibility of developing mechanically strong flame retardant polyester
fibres using a more economical dope additive route
Banana fiber-reinforced polypropylene composites: A study of the physico-mech...Thùy Linh
This document summarizes a study on banana fiber-reinforced polypropylene composites. The composites were prepared by compression molding banana fibers with polypropylene matrix. Both fibers and matrix were irradiated with UV radiation at different intensities to improve mechanical properties. The fibers were also treated with 2-hydroxyethyl methacrylate solutions and cured at different temperatures and times. The treated composites showed better mechanical properties than untreated ones. The composites' water uptake and weathering performance were also evaluated.
IJCER (www.ijceronline.com) International Journal of computational Engineerin...ijceronline
This document summarizes a study that evaluated the thermal and fire resistance properties of epoxy composites filled with different materials. E-glass fiber reinforced epoxy composites were fabricated with varying amounts of aluminum oxide, magnesium hydroxide, silicon carbide, and hematite powder using hand layup. Thermal conductivity, coefficient of thermal expansion, time to ignition, and flame propagation rate were measured. Composites filled with aluminum oxide and magnesium hydroxide exhibited low thermal conductivity. Silicon carbide filled composites had a lower thermal expansion coefficient than other composites. Increasing amounts of aluminum oxide, magnesium hydroxide, and hematite powder increased ignition time and decreased flame propagation rate.
This document discusses gas diffusion electrodes containing sulfonated polyether ionomers for use in polymer electrolyte fuel cells (PEFCs). It describes a novel process for preparing the gas diffusion electrodes using an autoclave treatment that allows the sulfonated polyether ionomer to uniformly coat the platinum catalyst particles on carbon black supports. The performance of the gas diffusion electrodes containing varying amounts of the sulfonated polyether ionomer was evaluated in PEFCs. Higher ionomer content and humidification conditions improved the proton conductivity and catalyst utilization, leading to better fuel cell performance at low currents. The optimal ionomer content and humidification conditions depended on the specific ion exchange capacity of the sulfonated polyether ionomer used.
Development of Nanocomposite from Epoxy/PDMS-Cyanate/Nanoclay for Materials w...IJMER
Dicyanate monomer viz bis-4-cyanato-polydimethylsiloxane(PDMS-CY) containing
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The document studies the microstructure of pure hydroxyapatite (HAp) and a 20% alumina-reinforced HAp bioceramic composite sintered at different temperatures. Scanning electron microscopy revealed that pure HAp sintered at 1250°C had an irregular bubbly surface and well-distributed pores, indicating decomposition. The composite sintered up to 1250°C maintained a dense microstructure with small pores (<3 μm), explaining its higher strength compared to pure HAp. The addition of alumina prevented pore growth at high temperatures, negating the negative effects of HAp decomposition.
Effect of modified graphene and microwave irradiation on the mechanical and t...Mukarram Zubair
The effect of modified graphene (MG) and microwave irradiation on the interaction between graphene (G) and poly(styrene-comethyl meth acrylate) [P(S-co-MMA)] polymer matrix has been studied in this article. Modification of graphene was performed
using nitric acid. P(S-co-MMA) polymer was blended via melt blending with pristine and MG. The resultant nanocomposites were irradiated under microwave at three different time intervals (5, 10, and 20 min). Compared to pristine graphene, MG showed
improved interaction with P(S-co-MMA) polymer (P) after melt mixing and microwave irradiation. The mechanism of improved
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This document discusses a study on modifying carbon fiber surfaces with nitric acid treatment and measuring the effects on mechanical and tribological properties when used to reinforce polyimide composites. Carbon fibers were treated with nitric acid and analyzed with XPS to show increased nitrogen and oxygen concentrations and different chemical functionalities on the surface. Composites made with treated fibers showed improved tensile strength and friction/wear performance compared to untreated fibers. The document provides background on carbon fiber composites and different surface treatment techniques before detailing the experimental methods used and presenting results which demonstrated benefits of nitric acid treatment for interfacial adhesion and mechanical properties.
Wood nanofibers from industrial waste have been used as polymeric
material to reinforce the cement paste to a content of up to 2% by weight of
cement. The effect of the wood nanofibre content on the porosity, the
compressive strength and the degree of hydration of the cement was studied. The
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added fiberwood. Chemical modification of nanofiber wood by grafting alkyl
chains to their surface can reduce the amount of water absorbed by the sample.
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hence the water absorption decreases. The degree of hydration of the cement
increased with the cellulose content containing nanofibrils. The analysis revealed
that the presence of nanofibers favored the hydration of the cement by producing
more calcium silicate gel and portlandite, probably the main reason for this
improvement in compressive strength.
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Optimising Treatment System for Kenaf (Hibiscus cannabinus) Particleboard with Fire Retardants
1. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
175
OPTIMIsING TREATMENT SYSTEM for KENAF (Hibiscus
cannabinus) PARTICLEBOARD WITH FIRE RETARDANTS
K Izran1,
*, A Zaidon2
, G Beyer3
, AM Abdul Rashid1
, F Abood2
& S Rahim1
1
Forest Research Institute Malaysia, 52109 Kepong, Selangor Darul Ehsan, Malaysia
2
Faculty of Forestry, Universiti Putra Malaysia, 43400 Serdang, Selangor Darul Ehsan, Malaysia
3
Physical and Mechanical Laboratories, Kabelwerk Eupen Ag, B-47000 Eupen, Belgium
Received March 2009
IZRAN K, ZAIDON A, BEYER G, ABDUL RASHID AM, ABOOD F & RAHIM S. 2010. Optimising treatment
system for kenaf (Hibiscus cannabinus) particleboard with fire retardants. Particleboard is widely used for
panelling, partitioning and ceiling in buildings. The treatment of this material to improve fire performance
is not an exception. A study was carried out to determine the fire performance of kenaf particleboard
treated with phosphorous-based fire retardants. Kenaf core particles were first treated separately with 8
and 10% solutions of monoammonium phosphate (MAP), diammonium phosphate (DAP) and a mixture
of boric acid, guanylurea phosphate and phosphoric acid (BP®) using hot and cold bath processes. The
soaking time needed to achieve the standard dry salt retention, i.e. 50 kg m-3
was determined. Particleboards
from these treated kenaf particles were fabricated and their fire performance evaluated. Using 8% treating
solution, it took about 36, 21 and 48 min of immersing in cold bath to achieve the standard retention
requirement for MAP, DAP and BP® respectively but for 10% concentration, the times were slightly shorter,
i.e. 15, 20 and 35 min respectively. Among the three phosphorous formulations, BP® showed the best
performance in improving the insulation and integrity of kenaf particleboard when exposed to fire. This is
followed by MAP and DAP. BP®-treated board was the last to ignite compared with the other two boards.
Keywords: MAP, DAP, BP, hot and cold bath, fire resistance, early burning performance
IZRAN K, ZAIDON A, BEYER G, ABDUL RASHID AM, ABOOD F & RAHIM S. 2010. Pengoptimuman
sistem rawatan papan serpai kenaf (Hibiscus cannabinus) dengan bahan perencat api. Papan serpai
contohnya yang dijadikan panel, pembahagi dan siling telah digunakan secara meluas dalam pembinaan
bangunan. Rawatan bahan ini untuk meningkatkan prestasi api bukanlah sesuatu yang asing. Kajian telah
dijalankan untuk menentukan prestasi api papan serpai kenaf yang dirawat dengan menggunakan bahan
perencat api yang berasaskan fosforus. Partikel teras kenaf telah dirawat secara berasingan menggunakan
monoammonium fosfat (MAP), diammonium fosfat (DAP) dan campuran asid borik, guanilurea fosfat
dan asid fosforik (BP®) pada kepekatan 8% dan 10% melalui proses rendaman panas dan sejuk. Sistem
rawatan yang optimum untuk mendapatkan retensi garam kering yang diperlukan iaitu 50 kg m-3
juga telah
dikenal pasti. Papan serpai dihasilkan daripada partikel kenaf yang telah dirawat ini dan prestasi apinya
telah diuji. Pada kepekatan 8%, partikel kenaf memerlukan tempoh rendaman sejuk masing-masing selama
lebih kurang 36 min, 21 min dan 48 min untuk mencapai retensi garam kering bagi MAP, DAP dan BP®.
Bagaimanapun, pada kepekatan 10%, tempohnya lebih singkat iaitu 15 min untuk MAP, 20 min untuk
DAP dan 35 min untuk BP®. Antara tiga formulasi fosforus ini, BP® menunjukkan prestasi terbaik dalam
memperbaiki insulasi dan integriti papan serpai kenaf apabila didedahkan kepada api. Ini diikuti oleh MAP
dan DAP. Papan serpai yang dirawat dengan BP® paling sukar terbakar berbanding papan yang dirawat
dengan bahan perencat yang lain.
*E-mail: izran_kamal@yahoo.com
INTRODUCTION
Kenafhasbeenfoundtobeapotentialrawmaterial
for wood composites. Mechanical properties of
kenaf particleboard and fibreboard surpass the
EN standard requirements (Mohamad Jani et al.
2004, Izran et al. 2009b, c). It was also reported that
particleboard made from kenaf core has superior
physical and mechanical properties than those
of rubberwood (Paridah et al. 2007). Kenaf core
particles can also be treated with fire retardants
to produce particleboards which have abilities to
reduce the spread of flame and the release of heat
when exposed to fire (Izran et al. 2009a).
2. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
176
Particleboards for the building industry come
in many sizes and densities which are suitable
for many uses such as ceilings, partitioning
and panelling. In order to be used in high rise
buildings, particleboard must comply with
the fire resistance requirements of building
regulation, i.e. the Uniform Buildings by Laws
1984. Therefore, treatment to improve the fire
performance of these boards is necessary to
comply with the building regulation. Attempts to
treat particleboard with fire retardants have been
carried out through brushing, spraying, dipping,
soaking, pressure treatment, hot and cold bath,
and diffusion treatments (Abdul Rashid & Chew
1990, Baharuddin 2002). A 50-mm or thinner solid
sawn lumber must achieve a standard chemical
loadingof50kgm-3
withaminimumpenetrationof
12 mm (Anonymous 1963). The fire performance
of a material for building construction is assessed
through fire resistance and early burning tests.
Fire resistance provides a means of quantifying
the ability of an element to withstand exposure
to high temperatures based on insulation which is
influenced by integrity criteria (British Standard
1987). Once a particleboard has achieved integrity
failure, automatically the insulation evaluation
will be stopped. However, the insulation failure
can happen before integrity failure, therefore, it
is best to assess the failure too. For early burning
test, the three important variables measured are
ignition time of an element, percentage of weight
loss and char formation after exposure to source
of heat.
The aim of this study was to evaluate the fire
resistance and early burning performances of
particleboards made from kenaf core particles
treated with phosphorous-based fire retardants.
The optimum treatment system so as to meet
the standard retention requirement for the
fire retardants was first studied. For this, kenaf
particles were treated separately with 8 and 10%
solutions using hot and cold bath treatments.
The optimum time of cold soaking to obtain
the desired minimum retention requirement
for each treating solution was determined. This
is to ensure that the required amount of fire
retardants is determined and to avoid excessive
or insufficient amounts of fire retardant in the
treatment. Excessive amount of fire retardant
will only unnecessarily add cost to the treatment.
On the other hand, if a small amount is used,
the dry salt standard retention (DSR) will
be very low and may not meet the standard
requirement.
MATERIALS AND METHODS
Chips from kenaf core were used as raw material
and these were obtained from the National
Tobacco Board, Malaysia. Fire retardants
used were diammonium phosphate (DAP),
monoammonium phosphate (MAP) and a
mixture of guanylurea phosphate, phosphoric
acid and boric acid (BP®). Urea formaldehyde
resin obtained from the Malayan Adhesive &
Chemicals Sdn Bhd was used as the binder.
Kenaf chips were flaked using a ring flaker and
screened to obtain particles with sizes of 1–2 mm.
The particles were dried in a standard industrial
oven at approximately 80 °C until a moisture
content of 3 to 5% was reached. Fire retardant
solutions of 8 and 10% concentrations (w/v)
were prepared separately.
Hot and cold bath treatments
Kenaf particles were treated separately with fire
retardant solutions using hot and cold bath
treatments. The time required to immerse
particles to achieve the minimum DSR in each
board, i.e. 50 kg m-3
, was determined. Particles
(5 g) (Wi) were placed on a piece of cloth which
was then tied using a rubber band. Four packs
were prepared for each treatment. The packs
were then immersed into a beaker filled with
hot fire retardant solution. The beaker was then
heated using a hot plate at 70 °C for 10 min after
which the beaker was placed in a fume hood
until the solution reached ambient temperature.
An hour later, one pack of each treatment was
taken out of the beaker, dried and its weight (Wf)
measured. This was repeated for the rest of the
packs at hourly intervals. The DSR was calculated
using equation 1.
DSR (%) =[(Wf – Wi)/(Wi)] ×
concentration (%) (1)
The DSR was then converted to kg m-3
to obtain
the standard minimum retention, i.e. 50 kg m-3
.
From the graph of DSR (%) versus time of
soaking (h), it was determined that 997 g of dried
particles were needed to produce a particleboard
of 350 × 350 × 12 mm. Subsequently, the amount
of dry salt (kg) required for each board was
calculated using equation 2.
DSR(50kgm-3
)=drysaltweight/particleboard
volume (2)
3. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
177
From the above equation, the weight of dry salt
required for each board was 74 g (i.e. 7.42%).
Having found this, the soaking time of particles
to achieve the desired requirement retention for
each solution was estimated through the plotted
graph.
Board fabrication
Single-layer treated and untreated particleboards
were fabricated using specifications shown in
Table 1. The treated furnish was blended with
12% urea formaldehyde for approximately
15 min to ensure uniform distribution of the
adhesive. Moisture content of the furnish was
maintained at 12% to avoid blistering during hot
pressing and also because fire retardants used
in the treatment were hygroscopic. Furnish with
excess moisture was dried again in an oven at
80 °C. The furnish was then formed in a wood
deckle, pre-pressed and subsequently hot pressed
at 180 °C. The time for pressing was determined
by gelation time of the admixture of adhesive
and fire retardants (Zaidon et al. 1998, Zaidon et
al. 2008, Izran et al. 2009d). It was found that the
pressing time of DAP-treated furnish was 12 min,
BP 10 min, MAP 9 min and untreated furnish,
10 min. The hot press was performed stepwise
using four cycles of pressure starting from 130,
followed by 90, 70 and 50 kg cm-2
.
Fire resistance test
The test was conducted in a fire furnace based
on BS 476: Part 22 (British Standards Institution
1987). Samples of 350 × 350 × 12 mm were used
in this test. Before testing, the weight, thickness,
length and width of the boards were measured.
Cement was used to attach the board to the
frame of the furnace. One board was tested at
a time. Three thermocouples were attached to
each board and the ends of the thermocouples
were connected to a recorder which measured
the temperature of the unexposed (i.e. the part
of the board which was not exposed to the fire
source in the furnace) face of the board. The
temperature of the furnace was also recorded
using thermocouples in the furnace.
The initial temperatures of the furnace were
27–30 °C and temperature increments were
recordedatintervalsof5minuntilthetemperature
of the unexposed face achieved 183 °C (insulation
failure) or the board collapsed (integrity failure).
The temperature–time relationship during the
test was calculated using equation 3 (British
Standards Institution 1987).
Raw material Kenaf core particles
Targeted board density 700 kg m-3
Targeted board moisture content 12%
Board size 350 × 350 × 12 mm
Adhesive
UF resin
Hardener (NH4Cl)
Wax
12% (w/w of board)
3% (based on resin)
1% (based on oven-dried particles)
Fire retardant
Diammonium phosphate (DAP)•
Monoammonium phosphate (MAP)•
Mixture of (BP®): 67–73% guanylurea•
phosphate, 27–33% boric acid and 0–4.2%
phosphoric acid
DSR 7.42% (w/w particles)
Hot press temperature 180 °C
Hot pressing time 9–12 min, dependent on the
treated particles
Table 1 Description of the fabricated particleboard
4. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
178
T = 345 log (8t + 1) + To (3)
where
T = furnace temperature at time t min
To = ambient temperature
After burning, physical changes of the exposed
and unexposed faces of boards were examined to
evaluate the failure of integrity and insulation.
Early burning performance
All samples (200 × 200 × 12 mm) were oven
dried at 103 ± 2 °C overnight and their oven-dry
weights (Wb) were determined. Prior to testing,
1 ml ethanol was dispersed at the centre of each
untreated and treated boards. Each board was
then placed inclined at 45°, 3 cm above a Bunsen
burner and the time taken for the board to ignite
was recorded. The combustion on the surface of
the board was left for 2 min after which the char
area was measured and the sample reweighed
(Wa). These data were used to calculate the
percentages of burnt area and weight loss
(equations 4 and 5).
Wb – Wa
Weight loss (%) = ------------------------ × 100 (4)
Wb
Char area
Burnt area (%) = --------------------------- × 100 (5)
Sample area
RESULTS AND DISCUSSION
Hot and cold bath treatments of kenaf
particleboard
The DSR versus the time of cold soaking is
illustrated in Figures 1 and 2. Results showed
that during the first hour, for 8% solution, DAP
was the highest amount of retardant absorbed by
particles, followed by MAP and BP®. On the other
hand, for 10% solution, particles absorbed MAP
the most, followed by DAP and BP®. Soaking
times required to reach the standard retention
requirement of 7.42% DSR were 36, 21 and
48 min for MAP, DAP and BP® respectively (Figure
1) for treatments using 8% solutions and 15, 20
and 35 min respectively for the 10% treatment
solution (Figure 2). These showed that shorter
cold soaking time could be achieved from the 10%
concentration compared with the 8%. Therefore,
particles soaked in the 10% concentration were
chosen for board fabrication.
Fire resistance performance of kenaf
particleboard
Tables 2 and 3 summarise the fire properties
of treated and untreated boards. Figures 3 to
6 show temperature curves of the furnace for
each tested board. The furnace temperature
curves can be used to observe the relationship
between temperature increment and time in
Figure 1 Dry salt retention (DSR) of kenaf particles treated with 8% solutions of MAP, DAP and BP using
hot and cold bath processes
DSR(%)
Soaking in cold bath (hours)
5. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
179
Particleboard CTEF
(min)
CTUF
(min)
Insulation
(min)
Integrity
(min)
TIAF
(°C)
Untreated 7 11 13 13 182
DAP-treated 8 12 15 15 183
MAP-treated 13 16 18 19 244
BP®-treated 15 17 18 18 331
Table 2 Fire resistance performance of treated kenaf particleboard
CTEF = Charring time at the exposed face; CTUF = charring time at the unexposed face;
Insulation = time at insulation failure; Integrity = time at integrity failure
TIAF = temperature at integrity failure
Particleboard Ignition time (s) Burnt area
± SD
(%)
Weight loss
± SD
(%)
Board density
(kg m-3
)
Untreated 50 18.43 ± 3.9 0.99 ± 0.3 586
DAP-treated 100 15.83 ± 2.0 0.97 ± 0.4 447
MAP-treated 100 14.28 ± 1.3 0.55 ± 0.2 472
BP®-treated 120 8.52 ± 2.6 0.69 ± 0.3 537
Table 3 Early burning performance test of treated kenaf particleboard
Data are averages of three samples
the furnace during the tests. Four curves were
generated for each test; three curves were
calibrated curves, namely, specified upper
limit temperature (SULT), specified standard
temperature (SST) and specified lower limit
temperature (SLLT) and one curve was the actual
burning temperature (ABT), i.e. temperature of
the furnace during the test. To ensure accuracy
of assessment, ABT should be between SULT and
SLLT and needs to be almost similar with the SST
and this was observed in this study. This indicated
that the temperatures of the furnace were not
influencing the accuracy of the fire resistance
results obtained.
Figure 2 DSR of kenaf particles treated with 10% solutions of MAP, DAP and BP using hot and cold bath
processes
DSR(%)
Soaking in cold bath (hours)
6. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
180
Untreated board could only maintain
insulation and integrity for 13 min after exposure
to fire. The temperature at integrity failure was
182 °C (Table 2). The exposed part of the board
started to darken within 7 min of exposure and
was completely burnt at the 11th min. By this
time, char started to establish on unexposed
surface at the top of the board and after 13 min,
the surface started to ignite and continuous
flaming was observed for more than 10 s.
The DAP-treated board experienced integrity
failure after 15 min of exposure to fire (Table 2).
The board collapsed as the temperature of the
unexposed surface increased to 183 °C. Darkening
at the exposed surface started after 8 min, while
charring at the unexposed surface began after
12 min. Flaming on the unexposed surface
also continued for more than 10 s. Insulation
(18 min) and integrity (19 min) performances
of MAP-treated board were higher than the
Figure 3 The furnace temperature for the DAP particleboard; ABT = actual burning temperature; SULT
= specified upper limit temperature; SST = specified standard temperature; SLLT = specified lower
limit temperature
Figure 4 The furnace temperature for the BP®-treated particleboard; ABT = actual burning temperature;
SULT = specified upper limit temperature; SST = specified standard temperature; SLLT = specified
lower limit temperature
Temperature(°C)
Time (min)
Time (min)
Temperature(°C)
7. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
181
untreated and DAP-treated boards. At 244 °C,
the temperature at integrity failure for MAP-
treated board was also higher than DAP- and
untreated boards but inferior to BP®-treated
boards. Char started to form at the centre of the
board after 16 min and ignition occurred after
19 min with continuous flaming for more than
10 s. For BP®-treated board, both insulation and
integrity criteria were maintained up to 18 min
of exposure to flame. However, integrity failure
was observed at a much higher temperature, i.e.
331 °C. Charring at the unexposed surface
occurred after 17 min exposure to fire.
In the early burning performance, MAP- and
DAP-treated boards each took 100 s to ignite
whereas for BP®-treated board, 120 s (Table
3). Ignition time for untreated board was 50 s.
BP-treated board had the smallest burnt area,
i.e. 8.5% of the total exposed area, while for
MAP- and DAP-treated boards, the burnt areas
Figure 5 The furnace temperature for the untreated particleboard; ABT = actual burning temperature;
SULT = specified upper limit temperature; SST = specified standard temperature; SLLT = specified
lower limit temperature
Figure 6 The furnace temperature for the MAP-treated particleboard; ABT = actual burning temperature;
SULT = specified upper limit temperature; SST = specified standard temperature; SLLT = specified
lower limit temperature
Time (min)
Temperature(°C)
Time (min)
Temperature(°C)
8. Journal of Tropical Forest Science 22(2): 175–183 (2010) Izran K et al.
182
were 14.3 and 15.8% respectively. Untreated
board had 18.4% of burnt area (Table 3). With
regard to weight loss due to burning, there was no
difference between DAP-treated and untreated
boards (~1%) but the other two boards showed
lesser weight loss, i.e. 0.6% for MAP- and 0.7%
for BP®-treated boards.
The tests revealed that fire performance of
kenaf particleboard improved when treated with
phosphorous-based fire retardants. BP® showed
the highest efficacy followed by MAP and DAP
indicating that boron formulated fire retardants
performed better than phosphorous-based fire
retardants. This is in agreement with findings
by Abdul Rashid and Chew (1990). Boron
compound is able to penetrate into particles of
boards and provide complete protection of the
material, thus, prolonging the time taken for heat
to transfer through the cross-section of the board
(Kolowski & Wladyka 2001).
Results of this study also showed that a shorter
time is needed to cause charring in the board that
had a higher percentage of phosphorous. Char
formed faster on DAP- and MAP-treated boards
compared with the BP®-treated board. This is
because phosphorous accelerates the formation
of char mass from cellulosic material and
suppresses flammable volatiles (Grexa & Kiosk
1992, Ishihara 1992). Thus, the higher content
of phosphorous in MAP-treated and DAP-treated
boards compared with BP®-treated board may
contribute to the shorter time for charring. Boron
compound reacts with combustible gases and tar
generated by kenaf particles and converts them
into carbon char. The by-products generated
from this process, namely, carbon dioxide and
water will dilute the combustible gases, resulting
in reduction of flame spread (Levan & Tran
1990).
CONCLUSIONS
Fire retardant can be successfully incorporated
in kenaf particleboard through treatment of
particles using hot and cold bath treatments.
Using 8% treating solutions, it took about 21 to
48 min of immersing in the cold bath to achieve
standard retention requirement but for 10%
concentration, it took slightly shorter time, i.e. 15
to 35 min. The three fire retardants studied were
effective in improving fire resistance and early
burning performance of kenaf particleboards.
Treated boards had insulation and integrity
performances between 15 and 19 min compared
with 13 min for untreated board. BP® and
MAP performed better than DAP in improving
insulation and integrity of the board. BP®-treated
board ignited least readily when compared with
the rest of the boards. MAP and DAP aggravated
the formation of char on the surface of the
boards when exposed to fire compared with
BP®. MAP formulation is better than BP® only
in terms of weight loss after burning.
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