How to change wind turbine gearbox oil based on oil properties and not on time intervall. Also about cupper corrosion with aging oil. Published at VGB Powertech, O&M conference in Hamburg march 2017
The crude oil assay is the collection of the results of physical tests that are performed to determine the key properties (boiling point, density, viscosity, heteroatom contents, acid number, etc.) of crude oil and its fractions. It is the procedure based on laboratory and pilot plant testing for determining the general distillation and quality characteristics of crude oil. Crude oil assay is important for determining the value and processability of crude oil. This is the preliminary step before processing the crude oil in the refinery. . In order to utilize the crude oil assay data, it is necessary to understand the results and significance of some of the laboratory tests.
The crude oil assay is the collection of the results of physical tests that are performed to determine the key properties (boiling point, density, viscosity, heteroatom contents, acid number, etc.) of crude oil and its fractions. It is the procedure based on laboratory and pilot plant testing for determining the general distillation and quality characteristics of crude oil. Crude oil assay is important for determining the value and processability of crude oil. This is the preliminary step before processing the crude oil in the refinery. . In order to utilize the crude oil assay data, it is necessary to understand the results and significance of some of the laboratory tests.
TERCOSCO This newly developed procedure is based on a twofold exchange chemical reaction between the crude oil organic Sulphur components and TERCOSCO additive, which results in the annihilation of C-S chemical link, releasing the various Sulphur compounds. Once released, those Sulphur compounds, using the heavy metals already present in the sour crude oil, will form Metallic Sulphur Salts which are later (10 min.) washed out by adding 5% water. Full process takes place at low temperature (50°C) and atmospheric pressure.
TERCOSCO This newly developed procedure is based on a twofold exchange chemical reaction between the crude oil organic Sulphur components and TERCOSCO additive, which results in the annihilation of C-S chemical link, releasing the various Sulphur compounds. Once released, those Sulphur compounds, using the heavy metals already present in the sour crude oil, will form Metallic Sulphur Salts which are later (10 min.) washed out by adding 5% water. Full process takes place at low temperature (50°C) and atmospheric pressure.
2 ijaems sept-2015-2-experimental investigation of waste transformer oil as a...INFOGAIN PUBLICATION
This paper reports on the Waste transformer oil fuel is blended with diesel fuel in different percentage and the effects of their operational characteristics and performance and emission characteristics of the DI diesel engine. In this study, the tested fuels were obtained through catalytic cracking process. Experimental results showed that the flash points and cetane number of the WTO blended diesel have increased with higher concentration of WTO. Based on the experimental results, HC, CO and NOx emissions noticeably decrease, while smoke emissions dramatically increase with increasing the dosing level of WTO. At the full load, the magnitude of HC, CO and NOx emissions for the neat diesel was 120 ppm, 0.36 (%by volume) and 1130ppm, whereas it was 68 ppm, 0.17 (%by volume) and 410ppm for the WTO20 fuel, respectively. The results also showed a significant enhancement in brake thermal efficiency and heat release rate due to the influence of the WTO20 in diesel blend.
Oils and their relationship to refrigeration systems -RETA conference 2015Manuel Muñoz Alonso
These are the slides of the technical paper presented in the RETA Conference 2015 (www.reta.com), used during my lecture. A good review of the latest lubricant technology available for natural refrigerants.
Estas son las transparencias utilizadas en el Congreso anual de RETA (www.reta.com) durante mi presentación. Un buen resumen de las úlitimas tenologías de lubricantes disponibles para los refrigerantes naturales.
Toxic effects of heavy metals : Lead and Arsenicsanjana502982
Heavy metals are naturally occuring metallic chemical elements that have relatively high density, and are toxic at even low concentrations. All toxic metals are termed as heavy metals irrespective of their atomic mass and density, eg. arsenic, lead, mercury, cadmium, thallium, chromium, etc.
Comparing Evolved Extractive Text Summary Scores of Bidirectional Encoder Rep...University of Maribor
Slides from:
11th International Conference on Electrical, Electronics and Computer Engineering (IcETRAN), Niš, 3-6 June 2024
Track: Artificial Intelligence
https://www.etran.rs/2024/en/home-english/
This presentation explores a brief idea about the structural and functional attributes of nucleotides, the structure and function of genetic materials along with the impact of UV rays and pH upon them.
Earliest Galaxies in the JADES Origins Field: Luminosity Function and Cosmic ...Sérgio Sacani
We characterize the earliest galaxy population in the JADES Origins Field (JOF), the deepest
imaging field observed with JWST. We make use of the ancillary Hubble optical images (5 filters
spanning 0.4−0.9µm) and novel JWST images with 14 filters spanning 0.8−5µm, including 7 mediumband filters, and reaching total exposure times of up to 46 hours per filter. We combine all our data
at > 2.3µm to construct an ultradeep image, reaching as deep as ≈ 31.4 AB mag in the stack and
30.3-31.0 AB mag (5σ, r = 0.1” circular aperture) in individual filters. We measure photometric
redshifts and use robust selection criteria to identify a sample of eight galaxy candidates at redshifts
z = 11.5 − 15. These objects show compact half-light radii of R1/2 ∼ 50 − 200pc, stellar masses of
M⋆ ∼ 107−108M⊙, and star-formation rates of SFR ∼ 0.1−1 M⊙ yr−1
. Our search finds no candidates
at 15 < z < 20, placing upper limits at these redshifts. We develop a forward modeling approach to
infer the properties of the evolving luminosity function without binning in redshift or luminosity that
marginalizes over the photometric redshift uncertainty of our candidate galaxies and incorporates the
impact of non-detections. We find a z = 12 luminosity function in good agreement with prior results,
and that the luminosity function normalization and UV luminosity density decline by a factor of ∼ 2.5
from z = 12 to z = 14. We discuss the possible implications of our results in the context of theoretical
models for evolution of the dark matter halo mass function.
Deep Behavioral Phenotyping in Systems Neuroscience for Functional Atlasing a...Ana Luísa Pinho
Functional Magnetic Resonance Imaging (fMRI) provides means to characterize brain activations in response to behavior. However, cognitive neuroscience has been limited to group-level effects referring to the performance of specific tasks. To obtain the functional profile of elementary cognitive mechanisms, the combination of brain responses to many tasks is required. Yet, to date, both structural atlases and parcellation-based activations do not fully account for cognitive function and still present several limitations. Further, they do not adapt overall to individual characteristics. In this talk, I will give an account of deep-behavioral phenotyping strategies, namely data-driven methods in large task-fMRI datasets, to optimize functional brain-data collection and improve inference of effects-of-interest related to mental processes. Key to this approach is the employment of fast multi-functional paradigms rich on features that can be well parametrized and, consequently, facilitate the creation of psycho-physiological constructs to be modelled with imaging data. Particular emphasis will be given to music stimuli when studying high-order cognitive mechanisms, due to their ecological nature and quality to enable complex behavior compounded by discrete entities. I will also discuss how deep-behavioral phenotyping and individualized models applied to neuroimaging data can better account for the subject-specific organization of domain-general cognitive systems in the human brain. Finally, the accumulation of functional brain signatures brings the possibility to clarify relationships among tasks and create a univocal link between brain systems and mental functions through: (1) the development of ontologies proposing an organization of cognitive processes; and (2) brain-network taxonomies describing functional specialization. To this end, tools to improve commensurability in cognitive science are necessary, such as public repositories, ontology-based platforms and automated meta-analysis tools. I will thus discuss some brain-atlasing resources currently under development, and their applicability in cognitive as well as clinical neuroscience.
(May 29th, 2024) Advancements in Intravital Microscopy- Insights for Preclini...Scintica Instrumentation
Intravital microscopy (IVM) is a powerful tool utilized to study cellular behavior over time and space in vivo. Much of our understanding of cell biology has been accomplished using various in vitro and ex vivo methods; however, these studies do not necessarily reflect the natural dynamics of biological processes. Unlike traditional cell culture or fixed tissue imaging, IVM allows for the ultra-fast high-resolution imaging of cellular processes over time and space and were studied in its natural environment. Real-time visualization of biological processes in the context of an intact organism helps maintain physiological relevance and provide insights into the progression of disease, response to treatments or developmental processes.
In this webinar we give an overview of advanced applications of the IVM system in preclinical research. IVIM technology is a provider of all-in-one intravital microscopy systems and solutions optimized for in vivo imaging of live animal models at sub-micron resolution. The system’s unique features and user-friendly software enables researchers to probe fast dynamic biological processes such as immune cell tracking, cell-cell interaction as well as vascularization and tumor metastasis with exceptional detail. This webinar will also give an overview of IVM being utilized in drug development, offering a view into the intricate interaction between drugs/nanoparticles and tissues in vivo and allows for the evaluation of therapeutic intervention in a variety of tissues and organs. This interdisciplinary collaboration continues to drive the advancements of novel therapeutic strategies.
Seminar of U.V. Spectroscopy by SAMIR PANDASAMIR PANDA
Spectroscopy is a branch of science dealing the study of interaction of electromagnetic radiation with matter.
Ultraviolet-visible spectroscopy refers to absorption spectroscopy or reflect spectroscopy in the UV-VIS spectral region.
Ultraviolet-visible spectroscopy is an analytical method that can measure the amount of light received by the analyte.
Nutraceutical market, scope and growth: Herbal drug technologyLokesh Patil
As consumer awareness of health and wellness rises, the nutraceutical market—which includes goods like functional meals, drinks, and dietary supplements that provide health advantages beyond basic nutrition—is growing significantly. As healthcare expenses rise, the population ages, and people want natural and preventative health solutions more and more, this industry is increasing quickly. Further driving market expansion are product formulation innovations and the use of cutting-edge technology for customized nutrition. With its worldwide reach, the nutraceutical industry is expected to keep growing and provide significant chances for research and investment in a number of categories, including vitamins, minerals, probiotics, and herbal supplements.
Observation of Io’s Resurfacing via Plume Deposition Using Ground-based Adapt...Sérgio Sacani
Since volcanic activity was first discovered on Io from Voyager images in 1979, changes
on Io’s surface have been monitored from both spacecraft and ground-based telescopes.
Here, we present the highest spatial resolution images of Io ever obtained from a groundbased telescope. These images, acquired by the SHARK-VIS instrument on the Large
Binocular Telescope, show evidence of a major resurfacing event on Io’s trailing hemisphere. When compared to the most recent spacecraft images, the SHARK-VIS images
show that a plume deposit from a powerful eruption at Pillan Patera has covered part
of the long-lived Pele plume deposit. Although this type of resurfacing event may be common on Io, few have been detected due to the rarity of spacecraft visits and the previously low spatial resolution available from Earth-based telescopes. The SHARK-VIS instrument ushers in a new era of high resolution imaging of Io’s surface using adaptive
optics at visible wavelengths.
DERIVATION OF MODIFIED BERNOULLI EQUATION WITH VISCOUS EFFECTS AND TERMINAL V...Wasswaderrick3
In this book, we use conservation of energy techniques on a fluid element to derive the Modified Bernoulli equation of flow with viscous or friction effects. We derive the general equation of flow/ velocity and then from this we derive the Pouiselle flow equation, the transition flow equation and the turbulent flow equation. In the situations where there are no viscous effects , the equation reduces to the Bernoulli equation. From experimental results, we are able to include other terms in the Bernoulli equation. We also look at cases where pressure gradients exist. We use the Modified Bernoulli equation to derive equations of flow rate for pipes of different cross sectional areas connected together. We also extend our techniques of energy conservation to a sphere falling in a viscous medium under the effect of gravity. We demonstrate Stokes equation of terminal velocity and turbulent flow equation. We look at a way of calculating the time taken for a body to fall in a viscous medium. We also look at the general equation of terminal velocity.
2. Confidentiality - Medium (C2)
Oil Exchange
• Oil should be changed based on Oil Quality Properties
- Instead of exchanging an oil based on yearly intervals
- Dialog with turbine manufacturers, gearbox suppliers and oil
companies
• After five years the oil sample should be sent in for full analyze
- If Quality is acceptable good, the oil should be used for another
1year/6 months.
- When Oil reaches end of life it should be tested every 6 months.
3. Cost Savings
• SRL and SOH
- 40 + 9 Vestas V90 2/1.8 MW with each 300 liters
- Oil bath temperature +55 degrees Celsius
- HSS bearing temperature 62 to 68 degrees Celsius
- >10 degrees lower operating temperature than 80 degrees =>2X life
- Cost of exchanging oil 5 000 Euro/turbine + production loss
- Cost of extra oil sampling 35 Euro + workmanship
- Total positive cash flow 245 000 Euro, during 20 years of operation
one oil exchange saved
• Offshore even larger savings
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4. Test of new and used oil
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Figure 5.2: Overall assessment normalized to one by dividing through the sum of the weighing coefficients.
All test data is included and multiplied with the weighing coefficient obtained above
Two of our most used synthetic oils; brown and green, showed stable tribological values
after 5 years. Mineral oil red showed decreased values after 3 years.Note: Lower is better.
5. Viscosity and aging
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C
C
H
H
H
H
C
C
Polyalphaolefin
Monomer
Dimer
Trimer
Polyalkylene glycol
Lifetime
Viscosity
Brown
Yellow
Red
Green
Viscosity nearly never shows bad values for synthetic oils after 5 years.
6. Test Results Used Oil Analysis, FUCHS Spain
Dark blue fresh oil:
No. 12-2494
RENOLIN UNISYN CLP 320
Green used Oil:
No. 12-2365
RENOLIN UNISYN CLP 320
Machine A 3.3
Weight loss very low: GFKT high !!
Excellent wear protection after 5 - 6 years !!
Micro Pitting short test: DGMK FZG (after 5 - 6 years)
GFKT – C 8,3/ 90 (16 h / load stage)
January 2017 - FS, Product Management Industrial Oils, W. Bock, R. Ambrosi; Research & Development Industrial Oils, Dr. J. Braun, T. Schuermann
7. Weight loss: 14 mg, 10 mg !!
Excellent wear protection after 8 years !!
January 2017 - FS, Product Management Industrial Oils, W. Bock, R. Ambrosi; Research & Development Industrial Oils, Dr. J. Braun, T. Schuermann
Test Results Used Oil Analysis, FUCHS Spain
8. Life Time
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Mineral oils, CLP-M: 2 years or 10.000 h
Synth. Ester („Bio“), CLP-E: 2 years or 10.000 h
Polyglycol, CLP-PG: 4 years or 20.000 h
Polyalphaolefins, CLP-PAO: 4 years or 20.000 h
Lifetime at an average oil sump temperature of 80 °C
(according to Flender)
Contaminations
(e.g. water, dirt, abrasion / wear products, acid gases, etc.) have a negative influence on the lifetime.
Lifetime depends on operating conditions
9. Oil Temperatures
Confidentiality - Medium (C2)
• Oil bath temperature +55 degrees
• High speed shaft bearing temperature 62 degrees
• Temperatures well below 70 degrees and 2X lifetime to be assumed
• Differs 5 degrees between turbines.
10. 2X lifetime = 10 degrees lower temperature
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11. Arrenius Rate Rule
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The Arrhenius equation, named for 19th-century Swedish
chemist Svante Arrhenius. In 1903, Arrhenius won a
Nobel Prize when he figured out the relationship between
temperature and most chemical reaction rates. Often
called the Arrhenius Rate Rule, it relates to the fact that
lubricants, once they've exceeded their base activation
temperature, will degrade (oxidize) twice as fast for every
10 degrees C (18 degrees F) increase in temperature
12. FTIR Analyses and TAN
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Infra red analyses can show if antioxidants are depleted.
If curve remarkably lower oil is aged.
Total Acid Number <2.0 mgKOH/g
13. Prediction of remaining lifetime, Additives
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Trend the decrease of additives.
Limit values is needed. Many times stable values.
15. Interpretation of results, Limit values
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Demand to get limit values at time of purchase
Note: It is not this oil that is used in the samples presented
22. Cracking oil on heaters, low oil level
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Check oil level to avoid cracking. Look at sight glasses.
Low oil level destroys the oil and clogs filters.
23. General observatíon
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A) High cupper values 20 to 80 ppm rapidly increasing over
one year.
B) Tar products as precipitated sludge found in offline filter
and on gearbox walls
C) Black large tar particles found in the inline filter and at
other places in the gearbox
D) Black tar on brass casings in the bearings
E) Corrosion of the brass cages
F) Black oil
Found on aged oil +5 years and <5% of samples
No failed gearboxes observed
24. Recommendation
Confidentiality - Medium (C2)
• Take sample every 6 months when oil older than 5 years
• Look on tar inside gearbox, filters, sight glasses
• Be observant
• If Cu level >5 ppm take new sample within 3 months
• If Cu level >10 ppm prepare for oil exchange
• Use flush oil
• Unsolved questions
• Are tar on brass disappearing? After new fill.
• Is brass corrosion on brass cages lowered by early exchange of oil
• Endoscopy investigations needed
• Is this a general problem with more oil formulas?
25. More information
• Can be found in the report :
- Tar and brass corrosion problems
If you have any problems or notice this phenomena
Please contact Operational Support, Thomas Stalin.
Thomas.stalin@vattenfall.com
Thanks for your Cooperation! This work was possible with combined
information from several sites.
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