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R.A.D.E 2017|www.rade.co.in
A SINGLE SOLUTION TO MYRIAD PROBLEMS :
- POLLUTION
- EXCESS CONSUMPTION
- BREAKDOWNS
EMULSIFIED HEAVY FUEL OIL
R.A.D.E 2017|www.rade.co.in
Problems Of Furnace Oil/HFO
• Comprise of Residual & Waste Oils from the Petroleum refining process.
• Suffers from Incomplete Combustion due to Poor Atomization.
• Burner, Strainer Blockages due to Asphaltenes & Sludge.
• Very Hydroscopic, which also helps forms Tank Sludge.
• Black Smoke and Sulfur smell, Pollutants like NOx & SOx in Flue Gas.
• No Uniform Quality Standards maintained even by Manufacturers.
• Very Often Adulterated by Dealers and Transporters.
• Vague Metering Practices.
R.A.D.E 2017|www.rade.co.in
One Solution: Emulsified Heavy Fuel Oil
• Additional Fuel Economy by 3-10 % over Normal F.O .
• Doesn’t require any Major Equipment changes.
• Completely Homogenized.
• Zero Sludge, Free Water & Impurities.
• Reduced Un-burnt Carbon, Smoke and Particulate Matter .
• Total Fuel Utilization & Complete Combustion.
• Clean & Economical Alternative to normal F.O. & Diesel.
R.A.D.E 2017|www.rade.co.in
Emulsified F.O. : Characteristics
• Emulsions are stable blends of immiscible liquids like Oil & Water.
• Fuel Emulsions contain suspended micron sized water droplets.
• The water droplets are inserted by a special High Shear process.
• Special additives and surfactants stabilize the Fuel Emulsion.
• The Emulsifying process can also reduce the Sulfur in F.O.
• Can be used in Boilers, Furnaces, IC Engines and even Gas Turbines.
R.A.D.E 2017|www.rade.co.in
Furnace Oil vs. Emulsified F.O.
Normal F.O. Emulsified F.O.
Under Microscope 100x Magnification
R.A.D.E 2017|www.rade.co.in
How It Works
• Emulsified Fuel is embedded with micron sized water droplets.
• Fuel Emulsion’s water droplets bursts into steam during combustion in a series of
micro-explosions called Secondary Atomization.
• This shatters the atomized fuel drops into a nano-fuel-mist, with 100 times more surface
area causing Instant Gasification and Complete Combustion.
• Increased combustion efficiency reduces Auxiliary and Excess Air requirement.
• Reduction of Excess Air improves Thermal efficiency and reduces Waste-heat.
• The free carbon strips hydrogen from the steam, forming traces of SynGas.
R.A.D.E 2017|www.rade.co.in
Emulsified F. O.: Flame Diagram
R.A.D.E 2017|www.rade.co.in
Secondary Atomization in Flames
R.A.D.E 2017|www.rade.co.in
The Kilocalorie Question
• Bomb Calorimeters cannot be used for measuring Fuel emulsions.
• However the NCV of the Emulsions can be measured in actual use.
• Low Excess Air levels possible only in Fuel Emulsions, reduces Waste Heat.
• Improved Combustion Efficiency + Less Excess Air offset the effects of water.
• Steam released during combustion helps transfer the heat better.
• Fuel Emulsions actually release more usable energy then stock F.O.
• Hence burning of Fuel Emulsions reduce fuel consumption.
R.A.D.E 2017|www.rade.co.in
Emulsified F.O. – Essentials for Success
• One size doesn’t fit all – Equipment and settings have to be customised.
• Water Droplets must be 2-5 microns and never exceed 10 microns.
• Water Droplets should be uniformly sized & dispersed.
• Fuel Emulsion should be Thermo-dynamically stable up-to 90 Degrees.
• The Burners should ideally have separate controls for Auxiliary air.
• Excess Air levels must be reduced as per the recommendation.
• Fuel Emulsion shouldn’t be pre-heated above prescribed levels.
R.A.D.E 2017|www.rade.co.in
Good Emulsion Vs. Bad Emulsion
Under 100x
Magnification
Our FO Emulsion
100% Homogenised
Uniform Dispersal
Uniform Droplet Size
Droplets < 5 microns
Poor FO Emulsion
Un-homogenized
Uneven Dispersal
Uneven Droplet Size
Droplets 5 - 50 microns
R.A.D.E 2017|www.rade.co.in
Advantages of our Batch Process
• Our design of Fuel Emulsifiers utilize a 5-Stage batch process.
• Our batch process provides complete control of all the parameters.
• Our batch process is extremely flexible towards Oil quality.
• Our batch process requires very little surfactants.
• Our batch process guarantees uniform water droplet size and dispersal.
• Our batch process homogenizes the Oil shredding sludge and asphalteen.
• Our batch process utilizes cavitation, static and dynamic mixing.
• Our Emulsifier units come in two sizes 3.5Kl & 5 Kl per hour.
• Our process is undergoing two patent applications.
R.A.D.E 2017|www.rade.co.in
Our Batch Vs. Online Processes
• 5 - Stage process.
• Multi Pass recirculation.
• Water drop <10 microns.
• Uniform droplet size.
• Uniform droplet dispersal.
• Complete homogenization.
• Handles dirty or adulterated fuel.
• Low Additive Requirement.
• Single Stage Process
• Single Pass Process.
• Uneven droplet sizes 10-50 microns.
• Uneven dispersal.
• Incomplete homogenization.
• Cannot Handle dirty Fuel.
• High Additive requirement.
• Unstable Emulsion.
R.A.D.E 2017|www.rade.co.in
Our Emulsion under Microscope
A 100x microscope image of an Emulsified HFO droplet created in our 5-stage batch
emulsifying process. Each dark speck on the screen is a droplet of water.
R.A.D.E 2017|www.rade.co.in
Fuel Emulsifying - Process Blocks.
• Water Filtration and Treatment.
• Oil Filtration and Testing.
• Fuel Transfer.
• Fuel Preheating Section.
• Water pumping and Infusion.
• Fuel Emulsification Section.
• Emulsion Testing Section.
R.A.D.E 2017|www.rade.co.in
Fully CAD Designed.
• Fully designed in 3D CAD programs.
• Complete computer simulation of process.
• All flow calculations made in specialized apps.
• All sections precision Laser cut and welded.
• Only DC arc and MIG welding on the tank.
• TIG Welding on Stainless Steel Parts.
R.A.D.E 2017|www.rade.co.in
Laser Cut Precision.
• All critical parts shaped with CNC Laser.
• Machined with 0.05% precession.
• All Cavitator & Static Mixer parts from SS.
• Only SS 304 & 316 used in critical sections
• Only TIG welding on SS parts.
R.A.D.E 2017|www.rade.co.in
Our HFO Emulsifiers at Work.
R.A.D.E 2017|www.rade.co.in
Benefits: For Boilers
• Complete Combustion: Fuel economy of 5-10%.
• No Equipment changes needed.
• Clean burners and Strainers : Reduced maintenance.
• Requires Less Excess Air : Reduced Waste Heat Loss.
• Low Carbon and Soot deposits on Tubes: Reduced downtime.
• Enhanced Thermal efficiency.
• Cleaner Emissions.
R.A.D.E 2017|www.rade.co.in
Benefits: For Furnaces
• Complete Combustion: Fuel economy 3 - 10 %.
• Drastic Reduction of Metal Oxide Losses like Dross & Furnace Scale.
• Increased Refractory / Reccuperator / Stack Lifespan.
• Clean burners and Strainers : Reduced maintenance.
• No major Equipment changes needed.
• Requires Less Excess Air : Reduced Waste Heat losses.
• Enhanced Thermal Transfer.
• Cleaner Emissions.
R.A.D.E 2017|www.rade.co.in
Benefits: For IC (Generator) Engines
• Can be used in most H.F.O. Generator engines without any changes.
• Low Carbon and Soot deposits on Pistons: Reduced maintenance.
• No Wastage of Fuel in Filters and Centrifuges.
• Lean-Burn due to reduced Hydrocarbon content in Fuel: Economy.
• Peak Temperature Reduction: Longer Engine Life.
• Very Clean Emissions.
R.A.D.E 2017|www.rade.co.in
Ecological Benefits: All Segments
• Emulsified F.O. combustion uses almost 20% less Oxygen.
• Emulsified F.O. generates 10-30% less waste-heat.
• Emulsified F.O. Combustion released up to 30% less NOx .
• Particulate Matter(PM) reduction by 30-50%.
• Drastic reduction of CO, CO2 & even SOx(with special additives).
• Reduces pollution even when fired along with Pulverized Coal.
R.A.D.E 2017|www.rade.co.in
Other Benefits: Zero Wastage Fuel
Normal H.F.O Tank
Oil
Sludge
Water
Emul H.F.O Tank
Zero Waste fully-
Homogenized &
Emulsified Oil
R.A.D.E 2017|www.rade.co.in
Case Study - Kobe University(Japan)
R.A.D.E 2017|www.rade.co.in
Enel S.p.a (Italy) - Case Study
Company Enel S.p.a.
Plant Type Thermal Power Station
Turbine Manufacturer Ansaldo Energia
Model AE94.2
Rating 180 MW
Fuel Emulsified HFO
Emulsion Ratio 30% Water
Economy 9.7%
NOx - 28%
PM -56%
Smoke - 64%
* Source: Enel S.P.a, Italy
R.A.D.E 2017|www.rade.co.in
Case Study 1- EPA, USA (Thermal Output)
According to the study of NRMRL (National Risk Management Research Laboratory) on behalf of EPA (Environment
Protection Agency, USA),Emulsified Class 6 Heavy Oil (Furnace Oil),containing 10% water released 16,604 BTU/LB
while normal Oil released only 10,390 BTU/LB.*
* Source: EPA-600/R-02-093
R.A.D.E 2017|www.rade.co.in
Case Study 2 – EPA, USA (Emissions)
* Source: U.S. EPA AP-42 Section 1.3
R.A.D.E 2017|www.rade.co.in
Case Study – Boiler (Consumption)
MONTH HOURS F.O. TYPE STEAM KG
FUEL CONS.
LITRES
STEAM kg/LTR
F.O DIFF. IMPROVEMENT
Apr-15 380.20 F.O.-BPCL 9,78,510.57 56,021.00 17.467
May-15 410.23 EMUL.F.O 9,46,013.00 59,948.00 16.380 +1.087
Actual F.O. Consumption minus 12.5% Water 49,596.80 19.074 -1.61 + 9.20%
COMPARISON OF FUEL CONSUMPTION
OF Bharat Petroleum F.O vs. EMUL.FO. WITH 12.5% WATER
IN A THERMAX 6TON BOILER.
R.A.D.E 2017|www.rade.co.in
Case Study – Steel Furnace (Consumption)
R.A.D.E 2017|www.rade.co.in
Case Study – Aluminum (Emissions)
Emissions with normal F. O.
Date: 6/12/14
CO(ppm):240
CO2 %: 13
SO2 (mg/Nm3) : 984
NOx (mg/Nm3): 600
Emissions with Emulsified F.O.
Date: 10/12/14
CO(ppm): 4
CO2 %: 4
SO2 (mg/Nm3) : 334
NOx (mg/Nm3): 40
R.A.D.E 2017|www.rade.co.in
About Fuel Emulsions in the Global Press
R.A.D.E 2017|www.rade.co.in
Articles Featuring our Work
FORTUNE India
June 2015
MANUFACTURING
TODAY
June 2015
Moneycontrol.com
March 2015
Chemical Engineering
World
April 2016
* With Creatnet Technology Pvt Ltd
R.A.D.E 2017|www.rade.co.in
About Us
• RADE Initiative is a India based Energy Efficiency Technology Developer.
• Pioneer in introducing Fuel Emulsification concepts & Technology in India.
• Invited by UNDP-GEF on numerous occasions to speak in their Seminars.
• Since 2013 we have partnered with Creatnet Technology in Delhi.
• We have been operating our Proof-Of-Concept Plant for one year in NCR.
• We have an In-House testing Laboratory and Firing Facility.
• Covered by publications like Fortune, Money Control, Manufacturing Today.
R.A.D.E 2017|www.rade.co.in
Contact Us
For Queries :
R.A.DE INITIATIVE
Please leave a message in the Contact Page:
www.rade.co.in
610, Shiv Towers
Patto Plaza, Panaji
Goa 403001
Tel: +91-9953007470

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02 petrochemical processes
02 petrochemical processes02 petrochemical processes
02 petrochemical processes
 

new-rade-emulsions

  • 1. R.A.D.E 2017|www.rade.co.in A SINGLE SOLUTION TO MYRIAD PROBLEMS : - POLLUTION - EXCESS CONSUMPTION - BREAKDOWNS EMULSIFIED HEAVY FUEL OIL
  • 2. R.A.D.E 2017|www.rade.co.in Problems Of Furnace Oil/HFO • Comprise of Residual & Waste Oils from the Petroleum refining process. • Suffers from Incomplete Combustion due to Poor Atomization. • Burner, Strainer Blockages due to Asphaltenes & Sludge. • Very Hydroscopic, which also helps forms Tank Sludge. • Black Smoke and Sulfur smell, Pollutants like NOx & SOx in Flue Gas. • No Uniform Quality Standards maintained even by Manufacturers. • Very Often Adulterated by Dealers and Transporters. • Vague Metering Practices.
  • 3. R.A.D.E 2017|www.rade.co.in One Solution: Emulsified Heavy Fuel Oil • Additional Fuel Economy by 3-10 % over Normal F.O . • Doesn’t require any Major Equipment changes. • Completely Homogenized. • Zero Sludge, Free Water & Impurities. • Reduced Un-burnt Carbon, Smoke and Particulate Matter . • Total Fuel Utilization & Complete Combustion. • Clean & Economical Alternative to normal F.O. & Diesel.
  • 4. R.A.D.E 2017|www.rade.co.in Emulsified F.O. : Characteristics • Emulsions are stable blends of immiscible liquids like Oil & Water. • Fuel Emulsions contain suspended micron sized water droplets. • The water droplets are inserted by a special High Shear process. • Special additives and surfactants stabilize the Fuel Emulsion. • The Emulsifying process can also reduce the Sulfur in F.O. • Can be used in Boilers, Furnaces, IC Engines and even Gas Turbines.
  • 5. R.A.D.E 2017|www.rade.co.in Furnace Oil vs. Emulsified F.O. Normal F.O. Emulsified F.O. Under Microscope 100x Magnification
  • 6. R.A.D.E 2017|www.rade.co.in How It Works • Emulsified Fuel is embedded with micron sized water droplets. • Fuel Emulsion’s water droplets bursts into steam during combustion in a series of micro-explosions called Secondary Atomization. • This shatters the atomized fuel drops into a nano-fuel-mist, with 100 times more surface area causing Instant Gasification and Complete Combustion. • Increased combustion efficiency reduces Auxiliary and Excess Air requirement. • Reduction of Excess Air improves Thermal efficiency and reduces Waste-heat. • The free carbon strips hydrogen from the steam, forming traces of SynGas.
  • 9. R.A.D.E 2017|www.rade.co.in The Kilocalorie Question • Bomb Calorimeters cannot be used for measuring Fuel emulsions. • However the NCV of the Emulsions can be measured in actual use. • Low Excess Air levels possible only in Fuel Emulsions, reduces Waste Heat. • Improved Combustion Efficiency + Less Excess Air offset the effects of water. • Steam released during combustion helps transfer the heat better. • Fuel Emulsions actually release more usable energy then stock F.O. • Hence burning of Fuel Emulsions reduce fuel consumption.
  • 10. R.A.D.E 2017|www.rade.co.in Emulsified F.O. – Essentials for Success • One size doesn’t fit all – Equipment and settings have to be customised. • Water Droplets must be 2-5 microns and never exceed 10 microns. • Water Droplets should be uniformly sized & dispersed. • Fuel Emulsion should be Thermo-dynamically stable up-to 90 Degrees. • The Burners should ideally have separate controls for Auxiliary air. • Excess Air levels must be reduced as per the recommendation. • Fuel Emulsion shouldn’t be pre-heated above prescribed levels.
  • 11. R.A.D.E 2017|www.rade.co.in Good Emulsion Vs. Bad Emulsion Under 100x Magnification Our FO Emulsion 100% Homogenised Uniform Dispersal Uniform Droplet Size Droplets < 5 microns Poor FO Emulsion Un-homogenized Uneven Dispersal Uneven Droplet Size Droplets 5 - 50 microns
  • 12. R.A.D.E 2017|www.rade.co.in Advantages of our Batch Process • Our design of Fuel Emulsifiers utilize a 5-Stage batch process. • Our batch process provides complete control of all the parameters. • Our batch process is extremely flexible towards Oil quality. • Our batch process requires very little surfactants. • Our batch process guarantees uniform water droplet size and dispersal. • Our batch process homogenizes the Oil shredding sludge and asphalteen. • Our batch process utilizes cavitation, static and dynamic mixing. • Our Emulsifier units come in two sizes 3.5Kl & 5 Kl per hour. • Our process is undergoing two patent applications.
  • 13. R.A.D.E 2017|www.rade.co.in Our Batch Vs. Online Processes • 5 - Stage process. • Multi Pass recirculation. • Water drop <10 microns. • Uniform droplet size. • Uniform droplet dispersal. • Complete homogenization. • Handles dirty or adulterated fuel. • Low Additive Requirement. • Single Stage Process • Single Pass Process. • Uneven droplet sizes 10-50 microns. • Uneven dispersal. • Incomplete homogenization. • Cannot Handle dirty Fuel. • High Additive requirement. • Unstable Emulsion.
  • 14. R.A.D.E 2017|www.rade.co.in Our Emulsion under Microscope A 100x microscope image of an Emulsified HFO droplet created in our 5-stage batch emulsifying process. Each dark speck on the screen is a droplet of water.
  • 15. R.A.D.E 2017|www.rade.co.in Fuel Emulsifying - Process Blocks. • Water Filtration and Treatment. • Oil Filtration and Testing. • Fuel Transfer. • Fuel Preheating Section. • Water pumping and Infusion. • Fuel Emulsification Section. • Emulsion Testing Section.
  • 16. R.A.D.E 2017|www.rade.co.in Fully CAD Designed. • Fully designed in 3D CAD programs. • Complete computer simulation of process. • All flow calculations made in specialized apps. • All sections precision Laser cut and welded. • Only DC arc and MIG welding on the tank. • TIG Welding on Stainless Steel Parts.
  • 17. R.A.D.E 2017|www.rade.co.in Laser Cut Precision. • All critical parts shaped with CNC Laser. • Machined with 0.05% precession. • All Cavitator & Static Mixer parts from SS. • Only SS 304 & 316 used in critical sections • Only TIG welding on SS parts.
  • 18. R.A.D.E 2017|www.rade.co.in Our HFO Emulsifiers at Work.
  • 19. R.A.D.E 2017|www.rade.co.in Benefits: For Boilers • Complete Combustion: Fuel economy of 5-10%. • No Equipment changes needed. • Clean burners and Strainers : Reduced maintenance. • Requires Less Excess Air : Reduced Waste Heat Loss. • Low Carbon and Soot deposits on Tubes: Reduced downtime. • Enhanced Thermal efficiency. • Cleaner Emissions.
  • 20. R.A.D.E 2017|www.rade.co.in Benefits: For Furnaces • Complete Combustion: Fuel economy 3 - 10 %. • Drastic Reduction of Metal Oxide Losses like Dross & Furnace Scale. • Increased Refractory / Reccuperator / Stack Lifespan. • Clean burners and Strainers : Reduced maintenance. • No major Equipment changes needed. • Requires Less Excess Air : Reduced Waste Heat losses. • Enhanced Thermal Transfer. • Cleaner Emissions.
  • 21. R.A.D.E 2017|www.rade.co.in Benefits: For IC (Generator) Engines • Can be used in most H.F.O. Generator engines without any changes. • Low Carbon and Soot deposits on Pistons: Reduced maintenance. • No Wastage of Fuel in Filters and Centrifuges. • Lean-Burn due to reduced Hydrocarbon content in Fuel: Economy. • Peak Temperature Reduction: Longer Engine Life. • Very Clean Emissions.
  • 22. R.A.D.E 2017|www.rade.co.in Ecological Benefits: All Segments • Emulsified F.O. combustion uses almost 20% less Oxygen. • Emulsified F.O. generates 10-30% less waste-heat. • Emulsified F.O. Combustion released up to 30% less NOx . • Particulate Matter(PM) reduction by 30-50%. • Drastic reduction of CO, CO2 & even SOx(with special additives). • Reduces pollution even when fired along with Pulverized Coal.
  • 23. R.A.D.E 2017|www.rade.co.in Other Benefits: Zero Wastage Fuel Normal H.F.O Tank Oil Sludge Water Emul H.F.O Tank Zero Waste fully- Homogenized & Emulsified Oil
  • 24. R.A.D.E 2017|www.rade.co.in Case Study - Kobe University(Japan)
  • 25. R.A.D.E 2017|www.rade.co.in Enel S.p.a (Italy) - Case Study Company Enel S.p.a. Plant Type Thermal Power Station Turbine Manufacturer Ansaldo Energia Model AE94.2 Rating 180 MW Fuel Emulsified HFO Emulsion Ratio 30% Water Economy 9.7% NOx - 28% PM -56% Smoke - 64% * Source: Enel S.P.a, Italy
  • 26. R.A.D.E 2017|www.rade.co.in Case Study 1- EPA, USA (Thermal Output) According to the study of NRMRL (National Risk Management Research Laboratory) on behalf of EPA (Environment Protection Agency, USA),Emulsified Class 6 Heavy Oil (Furnace Oil),containing 10% water released 16,604 BTU/LB while normal Oil released only 10,390 BTU/LB.* * Source: EPA-600/R-02-093
  • 27. R.A.D.E 2017|www.rade.co.in Case Study 2 – EPA, USA (Emissions) * Source: U.S. EPA AP-42 Section 1.3
  • 28. R.A.D.E 2017|www.rade.co.in Case Study – Boiler (Consumption) MONTH HOURS F.O. TYPE STEAM KG FUEL CONS. LITRES STEAM kg/LTR F.O DIFF. IMPROVEMENT Apr-15 380.20 F.O.-BPCL 9,78,510.57 56,021.00 17.467 May-15 410.23 EMUL.F.O 9,46,013.00 59,948.00 16.380 +1.087 Actual F.O. Consumption minus 12.5% Water 49,596.80 19.074 -1.61 + 9.20% COMPARISON OF FUEL CONSUMPTION OF Bharat Petroleum F.O vs. EMUL.FO. WITH 12.5% WATER IN A THERMAX 6TON BOILER.
  • 29. R.A.D.E 2017|www.rade.co.in Case Study – Steel Furnace (Consumption)
  • 30. R.A.D.E 2017|www.rade.co.in Case Study – Aluminum (Emissions) Emissions with normal F. O. Date: 6/12/14 CO(ppm):240 CO2 %: 13 SO2 (mg/Nm3) : 984 NOx (mg/Nm3): 600 Emissions with Emulsified F.O. Date: 10/12/14 CO(ppm): 4 CO2 %: 4 SO2 (mg/Nm3) : 334 NOx (mg/Nm3): 40
  • 31. R.A.D.E 2017|www.rade.co.in About Fuel Emulsions in the Global Press
  • 32. R.A.D.E 2017|www.rade.co.in Articles Featuring our Work FORTUNE India June 2015 MANUFACTURING TODAY June 2015 Moneycontrol.com March 2015 Chemical Engineering World April 2016 * With Creatnet Technology Pvt Ltd
  • 33. R.A.D.E 2017|www.rade.co.in About Us • RADE Initiative is a India based Energy Efficiency Technology Developer. • Pioneer in introducing Fuel Emulsification concepts & Technology in India. • Invited by UNDP-GEF on numerous occasions to speak in their Seminars. • Since 2013 we have partnered with Creatnet Technology in Delhi. • We have been operating our Proof-Of-Concept Plant for one year in NCR. • We have an In-House testing Laboratory and Firing Facility. • Covered by publications like Fortune, Money Control, Manufacturing Today.
  • 34. R.A.D.E 2017|www.rade.co.in Contact Us For Queries : R.A.DE INITIATIVE Please leave a message in the Contact Page: www.rade.co.in 610, Shiv Towers Patto Plaza, Panaji Goa 403001 Tel: +91-9953007470