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Chapter 39
Chapter 39 -
- Nuclear Physics
Nuclear Physics
A PowerPoint Presentation by
Paul E. Tippens, Professor of Physics
Southern Polytechnic State University
A PowerPoint Presentation by
A PowerPoint Presentation by
Paul E. Tippens, Professor of Physics
Paul E. Tippens, Professor of Physics
Southern Polytechnic State University
Southern Polytechnic State University
© 2007
Objectives:
Objectives: After completing this
After completing this
module, you should be able to:
module, you should be able to:
•
• Define and apply the concepts of
Define and apply the concepts of mass
mass
number
number,
, atomic number
atomic number, and
, and isotopes
isotopes.
.
•
• Define and apply concepts of
Define and apply concepts of radioactive decay
radioactive decay
and
and nuclear reactions
nuclear reactions.
.
•
• Calculate the
Calculate the mass defect
mass defect and the
and the binding
binding
energy per nucleon
energy per nucleon for a particular isotope.
for a particular isotope.
•
• State the various
State the various conservation laws
conservation laws, and
, and
discuss their application for nuclear reactions.
discuss their application for nuclear reactions.
Composition of Matter
Composition of Matter
All of matter is composed of at least three
fundamental particles (approximations):
All of matter is composed of at least three
fundamental particles (approximations):
Particle
Particle Fig.
Fig. Sym
Sym Mass
Mass Charge
Charge Size
Size
The mass of the proton and neutron are close, but
The mass of the proton and neutron are close, but
they are about 1840 times the mass of an electron.
they are about 1840 times the mass of an electron.
Electron
Electron e
e-
- 9.11 x 10
9.11 x 10-
-31
31 kg
kg -
-1.6 x 10
1.6 x 10-
-19
19 C
C 

Proton
Proton p
p 1.673 x 10
1.673 x 10-
-27
27 kg +1.6 x 10
kg +1.6 x 10-
-19
19 C 3 fm
C 3 fm
Neutron
Neutron n
n 1.675 x 10
1.675 x 10-
-31
31 kg
kg 0
0 3 fm
3 fm
The Atomic Nucleus
The Atomic Nucleus
Beryllium Atom
Beryllium Atom
Compacted nucleus:
Compacted nucleus:
4 protons
4 protons
5 neutrons
5 neutrons
Since atom is
Since atom is electri
electri-
-
cally
cally neutral, there
neutral, there
must be 4 electrons.
must be 4 electrons.
4 electrons
4 electrons
Modern Atomic Theory
Modern Atomic Theory
The Bohr atom, which is
The Bohr atom, which is
sometimes shown with
sometimes shown with
electrons as planetary
electrons as planetary
particles, is no longer a valid
particles, is no longer a valid
representation of an atom, but
representation of an atom, but
it is used here to simplify our
it is used here to simplify our
discussion of energy levels.
discussion of energy levels.
The uncertain position of an
The uncertain position of an
electron is now described as a
electron is now described as a
probability distribution
probability distribution—
—loosely
loosely
referred to as an
referred to as an electron cloud
electron cloud.
.
Definitions
Definitions
A
A nucleon
nucleon is a general term to denote a nuclear
is a general term to denote a nuclear
particle
particle -
- that is, either a proton or a neutron.
that is, either a proton or a neutron.
The
The atomic number
atomic number Z
Z of an element is equal to the
of an element is equal to the
number of protons in the nucleus of that element.
number of protons in the nucleus of that element.
The
The mass number
mass number A
A of an element is equal to the
of an element is equal to the
total number of nucleons (protons + neutrons).
total number of nucleons (protons + neutrons).
The mass number A of any element is equal to
the sum of the atomic number Z and the number
of neutrons N :
A = N + Z
Symbol Notation
Symbol Notation
A convenient way of describing an element is by
giving its mass number and its atomic number,
along with the chemical symbol for that element.
A convenient way of describing an element is by
A convenient way of describing an element is by
giving its mass number and its atomic number,
giving its mass number and its atomic number,
along with the chemical symbol for that element.
along with the chemical symbol for that element.
 
A Mass number
Z Atomic number
X Symbol

For example, consider beryllium (Be):
9
4 Be
Example 1:
Example 1: Describe the nucleus of a lithium
Describe the nucleus of a lithium
atom which has a mass number of 7 and an
atom which has a mass number of 7 and an
atomic number of 3.
atomic number of 3.
Lithium Atom
Lithium Atom
N = A
N = A –
– Z =
Z = 7
7 -
- 3
3
A =
A = 7; Z = 3;
7; Z = 3; N
N = ?
= ?
Protons: Z = 3
Protons: Z = 3
neutrons:
neutrons: N
N = 4
= 4
Electrons:
Electrons: Same as Z
Same as Z
7
3 Li
Isotopes of Elements
Isotopes of Elements
Isotopes
Isotopes are atoms that have the same number
are atoms that have the same number
of protons (
of protons (Z
Z1
1= Z
= Z2
2), but a different number of
), but a different number of
neutrons (N). (
neutrons (N). (A
A1
1 
 A
A2
2)
)
Helium
Helium -
- 4
4
4
2 He
Helium
Helium -
- 3
3
3
2 He Isotopes
Isotopes
of helium
of helium
Nuclides
Nuclides
Because of the existence of so many
Because of the existence of so many
isotopes, the term
isotopes, the term element
element is sometimes
is sometimes
confusing. The term
confusing. The term nuclide
nuclide is better.
is better.
A nuclide is an atom that has a definite
mass number A and Z-number. A list
of nuclides will include isotopes.
The following are best described as nuclides:
The following are best described as nuclides:
3
2 He 4
2 He 12
6 C 13
6 C
Atomic Mass Unit, u
Atomic Mass Unit, u
One
One atomic mass unit
atomic mass unit (1 u)
(1 u) is equal to one
is equal to one-
-
twelfth of the mass of the most abundant
twelfth of the mass of the most abundant
form of the carbon atom
form of the carbon atom--
--carbon
carbon-
-12
12.
.
Atomic mass unit: 1 u = 1.6606 x 10-27 kg
Common atomic masses:
Proton: 1.007276 u Neutron: 1.008665 u
Electron: 0.00055 u Hydrogen: 1.007825 u
Exampe
Exampe 2:
2: The average atomic mass of
The average atomic mass of
Boron
Boron-
-11 is 11.009305 u. What is the mass
11 is 11.009305 u. What is the mass
of the nucleus of one boron atom in kg?
of the nucleus of one boron atom in kg?
Electron: 0.00055 u
Electron: 0.00055 u
11
5 B = 11.009305
= 11.009305
The mass of the nucleus is the atomic mass
The mass of the nucleus is the atomic mass
less the mass of Z = 5 electrons:
less the mass of Z = 5 electrons:
Mass = 11.009305 u
Mass = 11.009305 u –
– 5(0.00055 u)
5(0.00055 u)
1 boron nucleus = 11.00656 u
1 boron nucleus = 11.00656 u
-27
1.6606 x 10 kg
11.00656 u
1 u
m
 
  
 
m = 1.83 x 10-26 kg
m = 1.83 x 10-26 kg
2 8
; 3 x 10 m/s
E mc c
 
Mass and Energy
Mass and Energy
Recall Einstein
Recall Einstein’
’s equivalency formula for m and E:
s equivalency formula for m and E:
The energy of a mass of 1 u can be found:
The energy of a mass of 1 u can be found:
E
E = (1 u)
= (1 u)c
c2
2 =
= (1.66 x 10
(1.66 x 10-
-27
27 kg)(3 x 10
kg)(3 x 108
8 m/s)
m/s)2
2
E = 1.49 x 10-10 J Or
Or E = 931.5 MeV
When converting
When converting
amu
amu to energy:
to energy:
2 MeV
u
931.5
c 
Example 3:
Example 3: What is the rest mass energy of
What is the rest mass energy of
a proton (1.007276 u)?
a proton (1.007276 u)?
E
E =
= mc
mc2
2 =
= (1.00726
(1.00726 u)(931.5
u)(931.5 MeV/u
MeV/u)
)
Proton: E = 938.3 MeV
Proton: E = 938.3 MeV
Similar conversions show other
Similar conversions show other
rest mass energies:
rest mass energies:
Electron: E = 0.511 MeV
Electron:
Electron: E
E = 0.511
= 0.511 MeV
MeV
Neutron: E = 939.6 MeV
Neutron: E = 939.6 MeV
The Mass Defect
The Mass Defect
The mass defect is the difference between
the rest mass of a nucleus and the sum of
the rest masses of its constituent nucleons.
The
The mass defect
mass defect is the difference between
is the difference between
the rest mass of a nucleus and the sum of
the rest mass of a nucleus and the sum of
the rest masses of its constituent nucleons.
the rest masses of its constituent nucleons.
The whole is less than the sum of the parts!
The whole is less than the sum of the parts!
Consider the carbon
Consider the carbon-
-12 atom (12.00000 u):
12 atom (12.00000 u):
Nuclear mass = Mass of atom
Nuclear mass = Mass of atom –
– Electron masses
Electron masses
= 12.00000 u
= 12.00000 u –
– 6(0.00055 u)
6(0.00055 u)
= 11.996706 u
= 11.996706 u
The
The nucleus
nucleus of the carbon
of the carbon-
-12 atom has this mass.
12 atom has this mass.
(Continued . . .)
(Continued . . .)
Mass Defect (Continued)
Mass Defect (Continued)
Mass of carbon
Mass of carbon-
-12 nucleus:
12 nucleus: 11.996706
11.996706
Proton: 1.007276 u
Proton: 1.007276 u Neutron: 1.008665 u
Neutron: 1.008665 u
The nucleus contains 6 protons and 6 neutrons:
The nucleus contains 6 protons and 6 neutrons:
6 p = 6(1.007276 u) = 6.043656 u
6 p = 6(1.007276 u) = 6.043656 u
6 n = 6(1.008665 u) = 6.051990 u
6 n = 6(1.008665 u) = 6.051990 u
Total mass of parts: =
Total mass of parts: = 12.095646 u
12.095646 u
Mass defect
Mass defect m
mD
D = 12.095646 u
= 12.095646 u –
– 11.996706 u
11.996706 u
mD = 0.098940 u
mD = 0.098940 u
The Binding Energy
The Binding Energy
The binding energy EB of a nucleus is the
energy required to separate a nucleus into
its constituent parts.
The
The binding energy
binding energy E
EB
B of a nucleus is the
of a nucleus is the
energy required to separate a nucleus into
energy required to separate a nucleus into
its constituent parts.
its constituent parts.
EB = mDc2 where c2 = 931.5 MeV/u
The binding energy for the carbon
The binding energy for the carbon-
-12 example is:
12 example is:
E
EB
B = (
= (0.098940 u)(931.5 MeV/u)
EB = 92.2 MeV
Binding EB for C-12:
Binding Energy per Nucleon
Binding Energy per Nucleon
An important way of comparing the nuclei of
atoms is finding their binding energy per nucleon:
An important way of comparing the nuclei of
An important way of comparing the nuclei of
atoms is finding their binding energy per nucleon:
atoms is finding their binding energy per nucleon:
Binding energy
per nucleon
MeV
=
nucleon
B
E
A
 
 
 
For our C
For our C-
-12 example A = 12 and:
12 example A = 12 and:
MeV
nucleon
92.2 MeV
7.68
12
B
E
A
 
Formula for Mass Defect
Formula for Mass Defect
The following formula is useful for mass defect:
The following formula is useful for mass defect:
 
D H n
m Zm Nm M
  
 
 
Mass defect
Mass defect
m
mD
D
m
mH
H = 1.007825 u;
= 1.007825 u; m
mn
n = 1.008665 u
= 1.008665 u
Z is atomic number; N is neutron number;
Z is atomic number; N is neutron number;
M is mass of atom (including electrons).
M is mass of atom (including electrons).
By using the mass of the hydrogen atom, you
avoid the necessity of subtracting electron masses.
By using the mass of the hydrogen atom, you
avoid the necessity of subtracting electron masses.
Example 4:
Example 4: Find the mass defect for the
Find the mass defect for the
nucleus of helium
nucleus of helium-
-4. (
4. (M =
M = 4.002603 u)
4.002603 u)
 
D H n
m Zm Nm M
  
 
 
Mass defect
Mass defect
m
mD
D
Zm
ZmH
H = (2)(1.007825 u) = 2.015650 u
= (2)(1.007825 u) = 2.015650 u
Nm
Nmn
n = (2)(1.008665 u) = 2.017330 u
= (2)(1.008665 u) = 2.017330 u
M
M = 4.002603 u (From nuclide tables)
= 4.002603 u (From nuclide tables)
m
mD
D = (2.015650 u + 2.017330 u)
= (2.015650 u + 2.017330 u) -
- 4.002603 u
4.002603 u
mD = 0.030377 u
mD = 0.030377 u
4
2 He
Example 4 (Cont.)
Example 4 (Cont.) Find the binding energy per
Find the binding energy per
nucleon for helium
nucleon for helium-
-4. (
4. (m
mD
D = 0.030377 u)
= 0.030377 u)
EB = mDc2 where c2 = 931.5 MeV/u
EB = mDc2 where c2 = 931.5 MeV/u
E
EB
B =
= (0.030377 u)(931.5
(0.030377 u)(931.5 MeV/u
MeV/u) =
) = 28.3
28.3 MeV
MeV
MeV
nucleon
28.3 MeV
7.07
4
B
E
A
 
A total of 28.3 MeV is required To tear apart
the nucleons from the He-4 atom.
A total of 28.3 MeV is required To tear apart
the nucleons from the He-4 atom.
Since there are four nucleons, we find that
Since there are four nucleons, we find that
Binding Energy Vs. Mass Number
Binding Energy Vs. Mass Number
Mass number A
Binding
Energy
per
nucleon
50 100 150 250
200
2
6
8
4
Curve shows that
Curve shows that
E
EB
B increases with
increases with
A
A and peaks at
and peaks at
A
A = 60
= 60. Heavier
. Heavier
nuclei are less
nuclei are less
stable.
stable.
Green region is for
Green region is for
most stable atoms.
most stable atoms.
For heavier nuclei, energy is released when they
For heavier nuclei, energy is released when they
break up (
break up (fission
fission). For lighter nuclei, energy is
). For lighter nuclei, energy is
released when they fuse together (
released when they fuse together (fusion
fusion).
).
Stability Curve
Stability Curve
Atomic number Z
Neutron
number
N
Stable
Stable
nuclei
nuclei
Z = N
Z = N
20 40 60 80 100
40
100
140
20
60
80
120
Nuclear particles are
held together by a
nuclear strong force.
Nuclear particles are
Nuclear particles are
held together by a
held together by a
nuclear strong force.
nuclear strong force.
A stable nucleus remains
A stable nucleus remains
forever, but as the ratio
forever, but as the ratio
of
of N/Z
N/Z gets larger, the
gets larger, the
atoms decay.
atoms decay.
Elements with Z > 82
are all unstable.
Elements with Z > 82
Elements with Z > 82
are all unstable.
are all unstable.
Radioactivity
Radioactivity
As the heavier atoms become
more unstable, particles and
photons are emitted from the
nucleus and it is said to be
radioactive. All elements with
A > 82 are radioactive.
As the heavier atoms become
more unstable, particles and
photons are emitted from the
nucleus and it is said to be
radioactive. All elements with
A > 82 are radioactive.
Examples are:
Examples are:
Alpha particles
Alpha particles 
 

 particles (electrons)
particles (electrons)


 particles (positrons)
particles (positrons)
Gamma rays
Gamma rays 











The Alpha Particle
The Alpha Particle
An
An alpha particle
alpha particle 
 is the nucleus of a helium
is the nucleus of a helium
atom consisting of two protons and two
atom consisting of two protons and two
neutrons tightly bound.
neutrons tightly bound.
Charge = +2
Charge = +2e
e-
- =
= 3.2 x 10
3.2 x 10-
-19
19 C
C
Mass = 4.001506 u
Mass = 4.001506 u
Relatively low speeds (
Relatively low speeds (
 0.1c )
0.1c )
Not very penetrating
Not very penetrating
The Beta
The Beta-
-minus Particle
minus Particle
A
A beta
beta-
-minus particle
minus particle 

 is simply an electron
is simply an electron
that has been expelled from the nucleus.
that has been expelled from the nucleus.
Charge =
Charge = e
e-
- =
= -
-1.6 x 10
1.6 x 10-
-19
19 C
C
-
High speeds (near
High speeds (near c
c)
)
-
Mass = 0.00055 u
Mass = 0.00055 u
-
Very penetrating
Very penetrating
-
The Positron
The Positron
A
A beta positive particle
beta positive particle 

 is essentially an
is essentially an
electron with positive charge. The mass and
electron with positive charge. The mass and
speeds are similar.
speeds are similar.
Charge = +
Charge = +e
e-
- =
= 1.6 x 10
1.6 x 10-
-19
19 C
C
+
High speeds (near
High speeds (near c
c)
)
+
Mass = 0.00055 u
Mass = 0.00055 u
+
Very penetrating
Very penetrating
+
The Gamma Photon
The Gamma Photon
A
A gamma ray
gamma ray 
 has very high electromagnetic
has very high electromagnetic
radiation carrying energy away from the
radiation carrying energy away from the
nucleus.
nucleus.
Charge = Zero (0)
Charge = Zero (0)


Mass = zero (0)
Mass = zero (0)


Speed = c (3 x 10
Speed = c (3 x 108
8 m/s)
m/s)


Most penetrating radiation
Most penetrating radiation


Radioactive Decay
Radioactive Decay
As discussed, when the ratio of N/Z gets very
As discussed, when the ratio of N/Z gets very
large, the nucleus becomes unstable and often
large, the nucleus becomes unstable and often
particles and/or photons are emitted.
particles and/or photons are emitted.
Alpha decay
Alpha decay results in the loss of two
results in the loss of two
protons and two neutrons from the nucleus.
protons and two neutrons from the nucleus.
4
2
4 4
2 2
A A
Z Z
X Y energy



  
X
X is
is parent
parent atom and
atom and Y
Y is
is daughter
daughter atom
atom
The energy is carried away primarily
The energy is carried away primarily
by the K.E. of the alpha particle.
by the K.E. of the alpha particle.
Example 5:
Example 5: Write the reaction that occurs
Write the reaction that occurs
when radium
when radium-
-226 decays by alpha emission.
226 decays by alpha emission.
4 4
2 2
A A
Z Z
X Y energy



  
226 226 4 4
88 88 2 2
Ra Y energy



  
From tables, we find Z and A for nuclides.
From tables, we find Z and A for nuclides.
The daughter atom: Z = 86, A = 222
The daughter atom: Z = 86, A = 222
226 222 4
88 86 2
Ra Rn energy

  
Radium-226 decays into radon-222.
Radium-226 decays into radon-222.
Beta
Beta-
-minus Decay
minus Decay
Beta
Beta-
-minus
minus 

 decay
decay results when a neutron
results when a neutron
decays into a proton and an electron. Thus,
decays into a proton and an electron. Thus,
the Z
the Z-
-number
number increases
increases by one.
by one.
0
1 1
A A
Z Z
X Y energy

 
  
X
X is
is parent
parent atom and
atom and Y
Y is
is daughter
daughter atom
atom
The energy is carried away primarily
The energy is carried away primarily
by the K.E. of the electron.
by the K.E. of the electron.
-
Beta
Beta-
-plus Decay
plus Decay
Beta
Beta-
-plus
plus 

 decay
decay results when a proton
results when a proton
decays into a neutron and a positron. Thus,
decays into a neutron and a positron. Thus,
the Z
the Z-
-number
number decreases
decreases by one.
by one.
0
1 1
A A
Z Z
X Y energy

 
  
X
X is
is parent
parent atom and
atom and Y
Y is
is daughter
daughter atom
atom
The energy is carried away primarily
The energy is carried away primarily
by the K.E. of the positron.
by the K.E. of the positron.
+
Radioactive Materials
Radioactive Materials
The rate of decay for radioactive substances is
The rate of decay for radioactive substances is
expressed in terms of the activity
expressed in terms of the activity R
R, given by:
, given by:
N
R
t



Activity N =
N = Number of
Number of
undecayed nuclei
undecayed nuclei
One curie (Ci) is the activity of a radioactive
material that decays at the rate of 3.7 x 1010 Bq
or 3.7 x 1010 disintegrations per second.
One curie (
One curie (Ci
Ci)
) is the activity of a radioactive
is the activity of a radioactive
material that decays at the rate of 3.7 x 10
material that decays at the rate of 3.7 x 1010
10 Bq
Bq
or 3.7 x 10
or 3.7 x 1010
10 disintegrations per second.
disintegrations per second.
One becquerel (Bq) is an activity equal to one
disintegration per second (1 s-1).
One
One becquerel
becquerel (
(Bq
Bq)
) is an activity equal to one
is an activity equal to one
disintegration per second (1 s
disintegration per second (1 s-
-1
1).
).
The Half
The Half-
-Life
Life
The
The half
half-
-life T
life T1/2
1/2 of
of
an isotope is the
an isotope is the
time in which one
time in which one-
-
half of its unstable
half of its unstable
nuclei will decay.
nuclei will decay.
No
0
2
N
0
4
N
Number of Half-lives
Number
Undecayed
Nuclei
1 4
3
2
0
1
2
n
N N
 
  
 
Where
Where n
n is number
is number
of half
of half-
-lives
lives
Half
Half-
-Life (Cont.)
Life (Cont.)
The same reasoning will apply to
The same reasoning will apply to activity R
activity R or to
or to
amount of material
amount of material. In general, the following
. In general, the following
three equations can be applied to radioactivity:
three equations can be applied to radioactivity:
Nuclei Remaining
Nuclei Remaining
0
1
2
n
N N
 
  
 
Activity R
Activity R
0
1
2
n
R R
 
  
 
Mass Remaining
Mass Remaining
0
1
2
n
m m
 
  
 
Number of Half
Number of Half-
-lives:
lives:
1
2
t
n
T

Example 6:
Example 6: A sample of
A sample of iodine
iodine-
-131
131 has an
has an
initial activity of
initial activity of 5
5 mCi
mCi. The half
. The half-
-life of I
life of I-
-131
131
is
is 8
8 days
days. What is the activity of the sample
. What is the activity of the sample
32
32 days
days later?
later?
First we determine the number of half
First we determine the number of half-
-lives:
lives:
1/2
32 d
8 d
t
n
T
  n =
n = 4 half
4 half-
-lives
lives
4
0
1 1
5 mCi
2 2
n
R R
   
 
   
    R = 0.313 mCi
R = 0.313 mCi
There would also be 1/16 remaining of the
mass and 1/16 of the number of nuclei.
There would also be 1/16 remaining of the
mass and 1/16 of the number of nuclei.
Nuclear Reactions
Nuclear Reactions
It is possible to alter the structure of a nucleus
It is possible to alter the structure of a nucleus
by bombarding it with small particles. Such
by bombarding it with small particles. Such
events are called nuclear reactions:
events are called nuclear reactions:
General Reaction: x + X  Y + y
For example, if an alpha particle bombards
For example, if an alpha particle bombards
a nitrogen
a nitrogen-
-14 nucleus it produces a
14 nucleus it produces a
hydrogen atom and oxygen
hydrogen atom and oxygen-
-17:
17:
4 14 1 17
2 7 1 8
N H O
   
Conservation Laws
Conservation Laws
For any nuclear reaction, there are three
conservation laws which must be obeyed:
For any nuclear reaction, there are three
conservation laws which must be obeyed:
Conservation of Charge:
Conservation of Charge: The total charge of a
The total charge of a
system can neither be increased nor decreased.
system can neither be increased nor decreased.
Conservation of Nucleons:
Conservation of Nucleons: The total number of
The total number of
nucleons in a reaction must be unchanged.
nucleons in a reaction must be unchanged.
Conservation of Mass Energy:
Conservation of Mass Energy: The total mass
The total mass-
-
energy of a system must not change in a
energy of a system must not change in a
nuclear reaction.
nuclear reaction.
Example 7:
Example 7: Use conservation criteria to
Use conservation criteria to
determine the unknown element in the
determine the unknown element in the
following nuclear reaction:
following nuclear reaction:
1 7 4
1 3 2
A
Z
H Li He X energy
   
Charge before = +1 + 3 = +4
Charge before = +1 + 3 = +4
Charge after = +2 + Z = +4
Charge after = +2 + Z = +4
Z = 4
Z = 4 –
– 2 = 2
2 = 2
Nucleons before = 1 + 7 = 8
Nucleons before = 1 + 7 = 8
Nucleons after = 4 + A = 8
Nucleons after = 4 + A = 8
(Helium has
(Helium has Z = 2
Z = 2)
)
(Thus,
(Thus, A =
A = 4
4)
)
1 7 4 4
1 3 2 2
H Li He He energy
   
Conservation of Mass
Conservation of Mass-
-Energy
Energy
There is always mass
There is always mass-
-energy associated with any
energy associated with any
nuclear reaction. The energy released or absorbed
nuclear reaction. The energy released or absorbed
is called the Q
is called the Q-
-value and can be found if the
value and can be found if the
atomic masses are known before and after.
atomic masses are known before and after.
1 7 4 4
1 3 2 2
H Li He He Q
   
   
1 7 4 4
1 3 2 2
Q H Li He He
   
Q
Q is the energy
is the energy released
released in the reaction. If
in the reaction. If Q
Q
is
is positive
positive, it is
, it is exothermic
exothermic. If
. If Q
Q is
is negative
negative, it
, it
is
is endothermic
endothermic.
.
Example 8:
Example 8: Calculate the energy released in the
Calculate the energy released in the
bombardment of lithium
bombardment of lithium-
-7 with hydrogen
7 with hydrogen-
-1.
1.
1 7 4 4
1 3 2 2
H Li He He Q
   
   
1 7 4 4
1 3 2 2
Q H Li He He
   
7
3 7.016003 u
Li 
4
2 4.002603 u
He 
1
1 1.007825 u
H 
Substitution of these masses gives:
Substitution of these masses gives:
Q
Q = 0.018622 u(931.5
= 0.018622 u(931.5 MeV/u
MeV/u)
) Q =17.3 MeV
Q =17.3 MeV
4
2 4.002603 u
He 
The positive Q means the reaction is exothermic.
The positive Q means the reaction is exothermic.
Summary
Summary
Particle
Particle Fig.
Fig. Sym
Sym Mass
Mass Charge
Charge Size
Size
Electron e 9.11 x 10
Electron e 9.11 x 10-
-31
31 kg
kg -
-1.6 x 10
1.6 x 10-
-19
19 C
C 

Proton
Proton p
p 1.673 x 10
1.673 x 10-
-27
27 kg +1.6 x 10
kg +1.6 x 10-
-19
19 C 3 fm
C 3 fm
Neutron
Neutron n
n 1.675 x 10
1.675 x 10-
-31
31 kg 0 3 fm
kg 0 3 fm
Fundamental atomic and nuclear particles
Fundamental atomic and nuclear particles
The mass number A of any element is equal to
the sum of the protons (atomic number Z) and
the number of neutrons N : A = N + Z
Summary Definitions:
Summary Definitions:
A
A nucleon
nucleon is a general term to denote a nuclear
is a general term to denote a nuclear
particle
particle -
- that is, either a proton or a neutron.
that is, either a proton or a neutron.
The
The mass number
mass number A
A of an element is equal to the
of an element is equal to the
total number of nucleons (protons + neutrons).
total number of nucleons (protons + neutrons).
Isotopes
Isotopes are atoms that have the same number
are atoms that have the same number
of protons (
of protons (Z
Z1
1= Z
= Z2
2), but a different number of
), but a different number of
neutrons (N). (
neutrons (N). (A
A1
1 
 A
A2
2)
)
A
A nuclide
nuclide is an atom that has a definite mass
is an atom that has a definite mass
number
number A
A and
and Z
Z-
-number. A list of nuclides
number. A list of nuclides
will include isotopes.
will include isotopes.
Summary (Cont.)
Summary (Cont.)
 
A Mass number
Z Atomic number
X Symbol

Symbolic notation
Symbolic notation
for atoms
for atoms
 
D H n
m Zm Nm M
  
 
 
Mass defect
Mass defect
m
mD
D
Binding Energy
per nucleon
MeV
=
nucleon
B
E
A
 
 
 
EB = mDc2 where c2 = 931.5 MeV/u
Binding
Binding
energy
energy
Summary (Decay Particles)
Summary (Decay Particles)
An
An alpha particle
alpha particle 
 is the nucleus of a helium
is the nucleus of a helium
atom consisting of two protons and two tightly
atom consisting of two protons and two tightly
bound neutrons.
bound neutrons.
A
A beta
beta-
-minus particle
minus particle 

 is simply an electron
is simply an electron
that has been expelled from the nucleus.
that has been expelled from the nucleus.
A
A beta positive particle
beta positive particle 

 is essentially an
is essentially an
electron with positive charge. The mass and
electron with positive charge. The mass and
speeds are similar.
speeds are similar.
A
A gamma ray
gamma ray 
 has very high electromagnetic
has very high electromagnetic
radiation carrying energy away from the
radiation carrying energy away from the
nucleus.
nucleus.
Summary (Cont.)
Summary (Cont.)
4 4
2 2
A A
Z Z
X Y energy



  
Alpha Decay:
Alpha Decay:
0
1 1
A A
Z Z
X Y energy

 
  
Beta
Beta-
-minus Decay:
minus Decay:
0
1 1
A A
Z Z
X Y energy

 
  
Beta
Beta-
-plus Decay:
plus Decay:
Summary (Radioactivity)
Summary (Radioactivity)
Nuclei Remaining
Nuclei Remaining
0
1
2
n
N N
 
  
 
Activity R
Activity R
0
1
2
n
R R
 
  
 
Mass Remaining
Mass Remaining
0
1
2
n
m m
 
  
 
Number of Half
Number of Half-
-lives:
lives:
1
2
t
n
T

The half-life T1/2 of an isotope is the time in
which one-half of its unstable nuclei will decay.
The
The half
half-
-life T
life T1/2
1/2 of an isotope is the time in
of an isotope is the time in
which one
which one-
-half of its unstable nuclei will decay.
half of its unstable nuclei will decay.
Summary (Cont.)
Summary (Cont.)
Conservation of Charge:
Conservation of Charge: The total charge of a
The total charge of a
system can neither be increased nor decreased.
system can neither be increased nor decreased.
Conservation of Nucleons:
Conservation of Nucleons: The total number of
The total number of
nucleons in a reaction must be unchanged.
nucleons in a reaction must be unchanged.
Conservation of Mass Energy:
Conservation of Mass Energy: The total mass
The total mass-
-
energy of a system must not change in a
energy of a system must not change in a
nuclear reaction. (Q
nuclear reaction. (Q-
-value = energy released)
value = energy released)
Nuclear Reaction: x + X  Y + y + Q
CONCLUSION: Chapter 39
CONCLUSION: Chapter 39
Nuclear Physics
Nuclear Physics

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Nuclear_Physics: A Guide to chemistry and nuclear physics

  • 1. Chapter 39 Chapter 39 - - Nuclear Physics Nuclear Physics A PowerPoint Presentation by Paul E. Tippens, Professor of Physics Southern Polytechnic State University A PowerPoint Presentation by A PowerPoint Presentation by Paul E. Tippens, Professor of Physics Paul E. Tippens, Professor of Physics Southern Polytechnic State University Southern Polytechnic State University © 2007
  • 2. Objectives: Objectives: After completing this After completing this module, you should be able to: module, you should be able to: • • Define and apply the concepts of Define and apply the concepts of mass mass number number, , atomic number atomic number, and , and isotopes isotopes. . • • Define and apply concepts of Define and apply concepts of radioactive decay radioactive decay and and nuclear reactions nuclear reactions. . • • Calculate the Calculate the mass defect mass defect and the and the binding binding energy per nucleon energy per nucleon for a particular isotope. for a particular isotope. • • State the various State the various conservation laws conservation laws, and , and discuss their application for nuclear reactions. discuss their application for nuclear reactions.
  • 3. Composition of Matter Composition of Matter All of matter is composed of at least three fundamental particles (approximations): All of matter is composed of at least three fundamental particles (approximations): Particle Particle Fig. Fig. Sym Sym Mass Mass Charge Charge Size Size The mass of the proton and neutron are close, but The mass of the proton and neutron are close, but they are about 1840 times the mass of an electron. they are about 1840 times the mass of an electron. Electron Electron e e- - 9.11 x 10 9.11 x 10- -31 31 kg kg - -1.6 x 10 1.6 x 10- -19 19 C C   Proton Proton p p 1.673 x 10 1.673 x 10- -27 27 kg +1.6 x 10 kg +1.6 x 10- -19 19 C 3 fm C 3 fm Neutron Neutron n n 1.675 x 10 1.675 x 10- -31 31 kg kg 0 0 3 fm 3 fm
  • 4. The Atomic Nucleus The Atomic Nucleus Beryllium Atom Beryllium Atom Compacted nucleus: Compacted nucleus: 4 protons 4 protons 5 neutrons 5 neutrons Since atom is Since atom is electri electri- - cally cally neutral, there neutral, there must be 4 electrons. must be 4 electrons. 4 electrons 4 electrons
  • 5. Modern Atomic Theory Modern Atomic Theory The Bohr atom, which is The Bohr atom, which is sometimes shown with sometimes shown with electrons as planetary electrons as planetary particles, is no longer a valid particles, is no longer a valid representation of an atom, but representation of an atom, but it is used here to simplify our it is used here to simplify our discussion of energy levels. discussion of energy levels. The uncertain position of an The uncertain position of an electron is now described as a electron is now described as a probability distribution probability distribution— —loosely loosely referred to as an referred to as an electron cloud electron cloud. .
  • 6. Definitions Definitions A A nucleon nucleon is a general term to denote a nuclear is a general term to denote a nuclear particle particle - - that is, either a proton or a neutron. that is, either a proton or a neutron. The The atomic number atomic number Z Z of an element is equal to the of an element is equal to the number of protons in the nucleus of that element. number of protons in the nucleus of that element. The The mass number mass number A A of an element is equal to the of an element is equal to the total number of nucleons (protons + neutrons). total number of nucleons (protons + neutrons). The mass number A of any element is equal to the sum of the atomic number Z and the number of neutrons N : A = N + Z
  • 7. Symbol Notation Symbol Notation A convenient way of describing an element is by giving its mass number and its atomic number, along with the chemical symbol for that element. A convenient way of describing an element is by A convenient way of describing an element is by giving its mass number and its atomic number, giving its mass number and its atomic number, along with the chemical symbol for that element. along with the chemical symbol for that element.   A Mass number Z Atomic number X Symbol  For example, consider beryllium (Be): 9 4 Be
  • 8. Example 1: Example 1: Describe the nucleus of a lithium Describe the nucleus of a lithium atom which has a mass number of 7 and an atom which has a mass number of 7 and an atomic number of 3. atomic number of 3. Lithium Atom Lithium Atom N = A N = A – – Z = Z = 7 7 - - 3 3 A = A = 7; Z = 3; 7; Z = 3; N N = ? = ? Protons: Z = 3 Protons: Z = 3 neutrons: neutrons: N N = 4 = 4 Electrons: Electrons: Same as Z Same as Z 7 3 Li
  • 9. Isotopes of Elements Isotopes of Elements Isotopes Isotopes are atoms that have the same number are atoms that have the same number of protons ( of protons (Z Z1 1= Z = Z2 2), but a different number of ), but a different number of neutrons (N). ( neutrons (N). (A A1 1   A A2 2) ) Helium Helium - - 4 4 4 2 He Helium Helium - - 3 3 3 2 He Isotopes Isotopes of helium of helium
  • 10. Nuclides Nuclides Because of the existence of so many Because of the existence of so many isotopes, the term isotopes, the term element element is sometimes is sometimes confusing. The term confusing. The term nuclide nuclide is better. is better. A nuclide is an atom that has a definite mass number A and Z-number. A list of nuclides will include isotopes. The following are best described as nuclides: The following are best described as nuclides: 3 2 He 4 2 He 12 6 C 13 6 C
  • 11. Atomic Mass Unit, u Atomic Mass Unit, u One One atomic mass unit atomic mass unit (1 u) (1 u) is equal to one is equal to one- - twelfth of the mass of the most abundant twelfth of the mass of the most abundant form of the carbon atom form of the carbon atom-- --carbon carbon- -12 12. . Atomic mass unit: 1 u = 1.6606 x 10-27 kg Common atomic masses: Proton: 1.007276 u Neutron: 1.008665 u Electron: 0.00055 u Hydrogen: 1.007825 u
  • 12. Exampe Exampe 2: 2: The average atomic mass of The average atomic mass of Boron Boron- -11 is 11.009305 u. What is the mass 11 is 11.009305 u. What is the mass of the nucleus of one boron atom in kg? of the nucleus of one boron atom in kg? Electron: 0.00055 u Electron: 0.00055 u 11 5 B = 11.009305 = 11.009305 The mass of the nucleus is the atomic mass The mass of the nucleus is the atomic mass less the mass of Z = 5 electrons: less the mass of Z = 5 electrons: Mass = 11.009305 u Mass = 11.009305 u – – 5(0.00055 u) 5(0.00055 u) 1 boron nucleus = 11.00656 u 1 boron nucleus = 11.00656 u -27 1.6606 x 10 kg 11.00656 u 1 u m        m = 1.83 x 10-26 kg m = 1.83 x 10-26 kg
  • 13. 2 8 ; 3 x 10 m/s E mc c   Mass and Energy Mass and Energy Recall Einstein Recall Einstein’ ’s equivalency formula for m and E: s equivalency formula for m and E: The energy of a mass of 1 u can be found: The energy of a mass of 1 u can be found: E E = (1 u) = (1 u)c c2 2 = = (1.66 x 10 (1.66 x 10- -27 27 kg)(3 x 10 kg)(3 x 108 8 m/s) m/s)2 2 E = 1.49 x 10-10 J Or Or E = 931.5 MeV When converting When converting amu amu to energy: to energy: 2 MeV u 931.5 c 
  • 14. Example 3: Example 3: What is the rest mass energy of What is the rest mass energy of a proton (1.007276 u)? a proton (1.007276 u)? E E = = mc mc2 2 = = (1.00726 (1.00726 u)(931.5 u)(931.5 MeV/u MeV/u) ) Proton: E = 938.3 MeV Proton: E = 938.3 MeV Similar conversions show other Similar conversions show other rest mass energies: rest mass energies: Electron: E = 0.511 MeV Electron: Electron: E E = 0.511 = 0.511 MeV MeV Neutron: E = 939.6 MeV Neutron: E = 939.6 MeV
  • 15. The Mass Defect The Mass Defect The mass defect is the difference between the rest mass of a nucleus and the sum of the rest masses of its constituent nucleons. The The mass defect mass defect is the difference between is the difference between the rest mass of a nucleus and the sum of the rest mass of a nucleus and the sum of the rest masses of its constituent nucleons. the rest masses of its constituent nucleons. The whole is less than the sum of the parts! The whole is less than the sum of the parts! Consider the carbon Consider the carbon- -12 atom (12.00000 u): 12 atom (12.00000 u): Nuclear mass = Mass of atom Nuclear mass = Mass of atom – – Electron masses Electron masses = 12.00000 u = 12.00000 u – – 6(0.00055 u) 6(0.00055 u) = 11.996706 u = 11.996706 u The The nucleus nucleus of the carbon of the carbon- -12 atom has this mass. 12 atom has this mass. (Continued . . .) (Continued . . .)
  • 16. Mass Defect (Continued) Mass Defect (Continued) Mass of carbon Mass of carbon- -12 nucleus: 12 nucleus: 11.996706 11.996706 Proton: 1.007276 u Proton: 1.007276 u Neutron: 1.008665 u Neutron: 1.008665 u The nucleus contains 6 protons and 6 neutrons: The nucleus contains 6 protons and 6 neutrons: 6 p = 6(1.007276 u) = 6.043656 u 6 p = 6(1.007276 u) = 6.043656 u 6 n = 6(1.008665 u) = 6.051990 u 6 n = 6(1.008665 u) = 6.051990 u Total mass of parts: = Total mass of parts: = 12.095646 u 12.095646 u Mass defect Mass defect m mD D = 12.095646 u = 12.095646 u – – 11.996706 u 11.996706 u mD = 0.098940 u mD = 0.098940 u
  • 17. The Binding Energy The Binding Energy The binding energy EB of a nucleus is the energy required to separate a nucleus into its constituent parts. The The binding energy binding energy E EB B of a nucleus is the of a nucleus is the energy required to separate a nucleus into energy required to separate a nucleus into its constituent parts. its constituent parts. EB = mDc2 where c2 = 931.5 MeV/u The binding energy for the carbon The binding energy for the carbon- -12 example is: 12 example is: E EB B = ( = (0.098940 u)(931.5 MeV/u) EB = 92.2 MeV Binding EB for C-12:
  • 18. Binding Energy per Nucleon Binding Energy per Nucleon An important way of comparing the nuclei of atoms is finding their binding energy per nucleon: An important way of comparing the nuclei of An important way of comparing the nuclei of atoms is finding their binding energy per nucleon: atoms is finding their binding energy per nucleon: Binding energy per nucleon MeV = nucleon B E A       For our C For our C- -12 example A = 12 and: 12 example A = 12 and: MeV nucleon 92.2 MeV 7.68 12 B E A  
  • 19. Formula for Mass Defect Formula for Mass Defect The following formula is useful for mass defect: The following formula is useful for mass defect:   D H n m Zm Nm M        Mass defect Mass defect m mD D m mH H = 1.007825 u; = 1.007825 u; m mn n = 1.008665 u = 1.008665 u Z is atomic number; N is neutron number; Z is atomic number; N is neutron number; M is mass of atom (including electrons). M is mass of atom (including electrons). By using the mass of the hydrogen atom, you avoid the necessity of subtracting electron masses. By using the mass of the hydrogen atom, you avoid the necessity of subtracting electron masses.
  • 20. Example 4: Example 4: Find the mass defect for the Find the mass defect for the nucleus of helium nucleus of helium- -4. ( 4. (M = M = 4.002603 u) 4.002603 u)   D H n m Zm Nm M        Mass defect Mass defect m mD D Zm ZmH H = (2)(1.007825 u) = 2.015650 u = (2)(1.007825 u) = 2.015650 u Nm Nmn n = (2)(1.008665 u) = 2.017330 u = (2)(1.008665 u) = 2.017330 u M M = 4.002603 u (From nuclide tables) = 4.002603 u (From nuclide tables) m mD D = (2.015650 u + 2.017330 u) = (2.015650 u + 2.017330 u) - - 4.002603 u 4.002603 u mD = 0.030377 u mD = 0.030377 u 4 2 He
  • 21. Example 4 (Cont.) Example 4 (Cont.) Find the binding energy per Find the binding energy per nucleon for helium nucleon for helium- -4. ( 4. (m mD D = 0.030377 u) = 0.030377 u) EB = mDc2 where c2 = 931.5 MeV/u EB = mDc2 where c2 = 931.5 MeV/u E EB B = = (0.030377 u)(931.5 (0.030377 u)(931.5 MeV/u MeV/u) = ) = 28.3 28.3 MeV MeV MeV nucleon 28.3 MeV 7.07 4 B E A   A total of 28.3 MeV is required To tear apart the nucleons from the He-4 atom. A total of 28.3 MeV is required To tear apart the nucleons from the He-4 atom. Since there are four nucleons, we find that Since there are four nucleons, we find that
  • 22. Binding Energy Vs. Mass Number Binding Energy Vs. Mass Number Mass number A Binding Energy per nucleon 50 100 150 250 200 2 6 8 4 Curve shows that Curve shows that E EB B increases with increases with A A and peaks at and peaks at A A = 60 = 60. Heavier . Heavier nuclei are less nuclei are less stable. stable. Green region is for Green region is for most stable atoms. most stable atoms. For heavier nuclei, energy is released when they For heavier nuclei, energy is released when they break up ( break up (fission fission). For lighter nuclei, energy is ). For lighter nuclei, energy is released when they fuse together ( released when they fuse together (fusion fusion). ).
  • 23. Stability Curve Stability Curve Atomic number Z Neutron number N Stable Stable nuclei nuclei Z = N Z = N 20 40 60 80 100 40 100 140 20 60 80 120 Nuclear particles are held together by a nuclear strong force. Nuclear particles are Nuclear particles are held together by a held together by a nuclear strong force. nuclear strong force. A stable nucleus remains A stable nucleus remains forever, but as the ratio forever, but as the ratio of of N/Z N/Z gets larger, the gets larger, the atoms decay. atoms decay. Elements with Z > 82 are all unstable. Elements with Z > 82 Elements with Z > 82 are all unstable. are all unstable.
  • 24. Radioactivity Radioactivity As the heavier atoms become more unstable, particles and photons are emitted from the nucleus and it is said to be radioactive. All elements with A > 82 are radioactive. As the heavier atoms become more unstable, particles and photons are emitted from the nucleus and it is said to be radioactive. All elements with A > 82 are radioactive. Examples are: Examples are: Alpha particles Alpha particles      particles (electrons) particles (electrons)    particles (positrons) particles (positrons) Gamma rays Gamma rays            
  • 25. The Alpha Particle The Alpha Particle An An alpha particle alpha particle   is the nucleus of a helium is the nucleus of a helium atom consisting of two protons and two atom consisting of two protons and two neutrons tightly bound. neutrons tightly bound. Charge = +2 Charge = +2e e- - = = 3.2 x 10 3.2 x 10- -19 19 C C Mass = 4.001506 u Mass = 4.001506 u Relatively low speeds ( Relatively low speeds (  0.1c ) 0.1c ) Not very penetrating Not very penetrating
  • 26. The Beta The Beta- -minus Particle minus Particle A A beta beta- -minus particle minus particle    is simply an electron is simply an electron that has been expelled from the nucleus. that has been expelled from the nucleus. Charge = Charge = e e- - = = - -1.6 x 10 1.6 x 10- -19 19 C C - High speeds (near High speeds (near c c) ) - Mass = 0.00055 u Mass = 0.00055 u - Very penetrating Very penetrating -
  • 27. The Positron The Positron A A beta positive particle beta positive particle    is essentially an is essentially an electron with positive charge. The mass and electron with positive charge. The mass and speeds are similar. speeds are similar. Charge = + Charge = +e e- - = = 1.6 x 10 1.6 x 10- -19 19 C C + High speeds (near High speeds (near c c) ) + Mass = 0.00055 u Mass = 0.00055 u + Very penetrating Very penetrating +
  • 28. The Gamma Photon The Gamma Photon A A gamma ray gamma ray   has very high electromagnetic has very high electromagnetic radiation carrying energy away from the radiation carrying energy away from the nucleus. nucleus. Charge = Zero (0) Charge = Zero (0)   Mass = zero (0) Mass = zero (0)   Speed = c (3 x 10 Speed = c (3 x 108 8 m/s) m/s)   Most penetrating radiation Most penetrating radiation  
  • 29. Radioactive Decay Radioactive Decay As discussed, when the ratio of N/Z gets very As discussed, when the ratio of N/Z gets very large, the nucleus becomes unstable and often large, the nucleus becomes unstable and often particles and/or photons are emitted. particles and/or photons are emitted. Alpha decay Alpha decay results in the loss of two results in the loss of two protons and two neutrons from the nucleus. protons and two neutrons from the nucleus. 4 2 4 4 2 2 A A Z Z X Y energy       X X is is parent parent atom and atom and Y Y is is daughter daughter atom atom The energy is carried away primarily The energy is carried away primarily by the K.E. of the alpha particle. by the K.E. of the alpha particle.
  • 30. Example 5: Example 5: Write the reaction that occurs Write the reaction that occurs when radium when radium- -226 decays by alpha emission. 226 decays by alpha emission. 4 4 2 2 A A Z Z X Y energy       226 226 4 4 88 88 2 2 Ra Y energy       From tables, we find Z and A for nuclides. From tables, we find Z and A for nuclides. The daughter atom: Z = 86, A = 222 The daughter atom: Z = 86, A = 222 226 222 4 88 86 2 Ra Rn energy     Radium-226 decays into radon-222. Radium-226 decays into radon-222.
  • 31. Beta Beta- -minus Decay minus Decay Beta Beta- -minus minus    decay decay results when a neutron results when a neutron decays into a proton and an electron. Thus, decays into a proton and an electron. Thus, the Z the Z- -number number increases increases by one. by one. 0 1 1 A A Z Z X Y energy       X X is is parent parent atom and atom and Y Y is is daughter daughter atom atom The energy is carried away primarily The energy is carried away primarily by the K.E. of the electron. by the K.E. of the electron. -
  • 32. Beta Beta- -plus Decay plus Decay Beta Beta- -plus plus    decay decay results when a proton results when a proton decays into a neutron and a positron. Thus, decays into a neutron and a positron. Thus, the Z the Z- -number number decreases decreases by one. by one. 0 1 1 A A Z Z X Y energy       X X is is parent parent atom and atom and Y Y is is daughter daughter atom atom The energy is carried away primarily The energy is carried away primarily by the K.E. of the positron. by the K.E. of the positron. +
  • 33. Radioactive Materials Radioactive Materials The rate of decay for radioactive substances is The rate of decay for radioactive substances is expressed in terms of the activity expressed in terms of the activity R R, given by: , given by: N R t    Activity N = N = Number of Number of undecayed nuclei undecayed nuclei One curie (Ci) is the activity of a radioactive material that decays at the rate of 3.7 x 1010 Bq or 3.7 x 1010 disintegrations per second. One curie ( One curie (Ci Ci) ) is the activity of a radioactive is the activity of a radioactive material that decays at the rate of 3.7 x 10 material that decays at the rate of 3.7 x 1010 10 Bq Bq or 3.7 x 10 or 3.7 x 1010 10 disintegrations per second. disintegrations per second. One becquerel (Bq) is an activity equal to one disintegration per second (1 s-1). One One becquerel becquerel ( (Bq Bq) ) is an activity equal to one is an activity equal to one disintegration per second (1 s disintegration per second (1 s- -1 1). ).
  • 34. The Half The Half- -Life Life The The half half- -life T life T1/2 1/2 of of an isotope is the an isotope is the time in which one time in which one- - half of its unstable half of its unstable nuclei will decay. nuclei will decay. No 0 2 N 0 4 N Number of Half-lives Number Undecayed Nuclei 1 4 3 2 0 1 2 n N N        Where Where n n is number is number of half of half- -lives lives
  • 35. Half Half- -Life (Cont.) Life (Cont.) The same reasoning will apply to The same reasoning will apply to activity R activity R or to or to amount of material amount of material. In general, the following . In general, the following three equations can be applied to radioactivity: three equations can be applied to radioactivity: Nuclei Remaining Nuclei Remaining 0 1 2 n N N        Activity R Activity R 0 1 2 n R R        Mass Remaining Mass Remaining 0 1 2 n m m        Number of Half Number of Half- -lives: lives: 1 2 t n T 
  • 36. Example 6: Example 6: A sample of A sample of iodine iodine- -131 131 has an has an initial activity of initial activity of 5 5 mCi mCi. The half . The half- -life of I life of I- -131 131 is is 8 8 days days. What is the activity of the sample . What is the activity of the sample 32 32 days days later? later? First we determine the number of half First we determine the number of half- -lives: lives: 1/2 32 d 8 d t n T   n = n = 4 half 4 half- -lives lives 4 0 1 1 5 mCi 2 2 n R R               R = 0.313 mCi R = 0.313 mCi There would also be 1/16 remaining of the mass and 1/16 of the number of nuclei. There would also be 1/16 remaining of the mass and 1/16 of the number of nuclei.
  • 37. Nuclear Reactions Nuclear Reactions It is possible to alter the structure of a nucleus It is possible to alter the structure of a nucleus by bombarding it with small particles. Such by bombarding it with small particles. Such events are called nuclear reactions: events are called nuclear reactions: General Reaction: x + X  Y + y For example, if an alpha particle bombards For example, if an alpha particle bombards a nitrogen a nitrogen- -14 nucleus it produces a 14 nucleus it produces a hydrogen atom and oxygen hydrogen atom and oxygen- -17: 17: 4 14 1 17 2 7 1 8 N H O    
  • 38. Conservation Laws Conservation Laws For any nuclear reaction, there are three conservation laws which must be obeyed: For any nuclear reaction, there are three conservation laws which must be obeyed: Conservation of Charge: Conservation of Charge: The total charge of a The total charge of a system can neither be increased nor decreased. system can neither be increased nor decreased. Conservation of Nucleons: Conservation of Nucleons: The total number of The total number of nucleons in a reaction must be unchanged. nucleons in a reaction must be unchanged. Conservation of Mass Energy: Conservation of Mass Energy: The total mass The total mass- - energy of a system must not change in a energy of a system must not change in a nuclear reaction. nuclear reaction.
  • 39. Example 7: Example 7: Use conservation criteria to Use conservation criteria to determine the unknown element in the determine the unknown element in the following nuclear reaction: following nuclear reaction: 1 7 4 1 3 2 A Z H Li He X energy     Charge before = +1 + 3 = +4 Charge before = +1 + 3 = +4 Charge after = +2 + Z = +4 Charge after = +2 + Z = +4 Z = 4 Z = 4 – – 2 = 2 2 = 2 Nucleons before = 1 + 7 = 8 Nucleons before = 1 + 7 = 8 Nucleons after = 4 + A = 8 Nucleons after = 4 + A = 8 (Helium has (Helium has Z = 2 Z = 2) ) (Thus, (Thus, A = A = 4 4) ) 1 7 4 4 1 3 2 2 H Li He He energy    
  • 40. Conservation of Mass Conservation of Mass- -Energy Energy There is always mass There is always mass- -energy associated with any energy associated with any nuclear reaction. The energy released or absorbed nuclear reaction. The energy released or absorbed is called the Q is called the Q- -value and can be found if the value and can be found if the atomic masses are known before and after. atomic masses are known before and after. 1 7 4 4 1 3 2 2 H Li He He Q         1 7 4 4 1 3 2 2 Q H Li He He     Q Q is the energy is the energy released released in the reaction. If in the reaction. If Q Q is is positive positive, it is , it is exothermic exothermic. If . If Q Q is is negative negative, it , it is is endothermic endothermic. .
  • 41. Example 8: Example 8: Calculate the energy released in the Calculate the energy released in the bombardment of lithium bombardment of lithium- -7 with hydrogen 7 with hydrogen- -1. 1. 1 7 4 4 1 3 2 2 H Li He He Q         1 7 4 4 1 3 2 2 Q H Li He He     7 3 7.016003 u Li  4 2 4.002603 u He  1 1 1.007825 u H  Substitution of these masses gives: Substitution of these masses gives: Q Q = 0.018622 u(931.5 = 0.018622 u(931.5 MeV/u MeV/u) ) Q =17.3 MeV Q =17.3 MeV 4 2 4.002603 u He  The positive Q means the reaction is exothermic. The positive Q means the reaction is exothermic.
  • 42. Summary Summary Particle Particle Fig. Fig. Sym Sym Mass Mass Charge Charge Size Size Electron e 9.11 x 10 Electron e 9.11 x 10- -31 31 kg kg - -1.6 x 10 1.6 x 10- -19 19 C C   Proton Proton p p 1.673 x 10 1.673 x 10- -27 27 kg +1.6 x 10 kg +1.6 x 10- -19 19 C 3 fm C 3 fm Neutron Neutron n n 1.675 x 10 1.675 x 10- -31 31 kg 0 3 fm kg 0 3 fm Fundamental atomic and nuclear particles Fundamental atomic and nuclear particles The mass number A of any element is equal to the sum of the protons (atomic number Z) and the number of neutrons N : A = N + Z
  • 43. Summary Definitions: Summary Definitions: A A nucleon nucleon is a general term to denote a nuclear is a general term to denote a nuclear particle particle - - that is, either a proton or a neutron. that is, either a proton or a neutron. The The mass number mass number A A of an element is equal to the of an element is equal to the total number of nucleons (protons + neutrons). total number of nucleons (protons + neutrons). Isotopes Isotopes are atoms that have the same number are atoms that have the same number of protons ( of protons (Z Z1 1= Z = Z2 2), but a different number of ), but a different number of neutrons (N). ( neutrons (N). (A A1 1   A A2 2) ) A A nuclide nuclide is an atom that has a definite mass is an atom that has a definite mass number number A A and and Z Z- -number. A list of nuclides number. A list of nuclides will include isotopes. will include isotopes.
  • 44. Summary (Cont.) Summary (Cont.)   A Mass number Z Atomic number X Symbol  Symbolic notation Symbolic notation for atoms for atoms   D H n m Zm Nm M        Mass defect Mass defect m mD D Binding Energy per nucleon MeV = nucleon B E A       EB = mDc2 where c2 = 931.5 MeV/u Binding Binding energy energy
  • 45. Summary (Decay Particles) Summary (Decay Particles) An An alpha particle alpha particle   is the nucleus of a helium is the nucleus of a helium atom consisting of two protons and two tightly atom consisting of two protons and two tightly bound neutrons. bound neutrons. A A beta beta- -minus particle minus particle    is simply an electron is simply an electron that has been expelled from the nucleus. that has been expelled from the nucleus. A A beta positive particle beta positive particle    is essentially an is essentially an electron with positive charge. The mass and electron with positive charge. The mass and speeds are similar. speeds are similar. A A gamma ray gamma ray   has very high electromagnetic has very high electromagnetic radiation carrying energy away from the radiation carrying energy away from the nucleus. nucleus.
  • 46. Summary (Cont.) Summary (Cont.) 4 4 2 2 A A Z Z X Y energy       Alpha Decay: Alpha Decay: 0 1 1 A A Z Z X Y energy       Beta Beta- -minus Decay: minus Decay: 0 1 1 A A Z Z X Y energy       Beta Beta- -plus Decay: plus Decay:
  • 47. Summary (Radioactivity) Summary (Radioactivity) Nuclei Remaining Nuclei Remaining 0 1 2 n N N        Activity R Activity R 0 1 2 n R R        Mass Remaining Mass Remaining 0 1 2 n m m        Number of Half Number of Half- -lives: lives: 1 2 t n T  The half-life T1/2 of an isotope is the time in which one-half of its unstable nuclei will decay. The The half half- -life T life T1/2 1/2 of an isotope is the time in of an isotope is the time in which one which one- -half of its unstable nuclei will decay. half of its unstable nuclei will decay.
  • 48. Summary (Cont.) Summary (Cont.) Conservation of Charge: Conservation of Charge: The total charge of a The total charge of a system can neither be increased nor decreased. system can neither be increased nor decreased. Conservation of Nucleons: Conservation of Nucleons: The total number of The total number of nucleons in a reaction must be unchanged. nucleons in a reaction must be unchanged. Conservation of Mass Energy: Conservation of Mass Energy: The total mass The total mass- - energy of a system must not change in a energy of a system must not change in a nuclear reaction. (Q nuclear reaction. (Q- -value = energy released) value = energy released) Nuclear Reaction: x + X  Y + y + Q
  • 49. CONCLUSION: Chapter 39 CONCLUSION: Chapter 39 Nuclear Physics Nuclear Physics