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Objectives
Describing the Metallic bond.
Relate the electron sea model to the
physical properties of metals.
Define alloys, and categorize them into
two basic types
Metallic Bonds
 Electron Sea Model proposes that all the metal
atoms in a metallic solid share their valence
electrons to form a “sea” of electrons. This sea of
electrons surrounds the metal cations in the
lattice.
 The electrons present in the outer energy levels of the
bonding metallic atoms are not held by any specific
atom and can move easily
 Because they are free to move, they are often referred
to as delocalized electrons.
Metallic bond
 A metallic bond is the attraction of a metallic
cation for delocalized electrons.
Properties of metals
Melting and boiling points
The melting points of metals vary greatly.
For example ;
Mercury is a liquid at room temperature, which makes
it useful in scientific instruments such as thermometers
and barometers.
Tungsten has a melting point of 3422°C. Light bulb
filaments are usually made from tungsten, also in certain
spacecraft parts.
Compare melting points and boiling
points for different elements
melting point does not
take an extreme amount
of energy for
them to be able to move
past each other.
Boiling point
is usually
higher than
Melting point,
why?
However, during boiling,
atoms must be separated
from the group of cations
and electrons, which
requires much more
energy.
Malleability, ductility, and
durability
Metals are malleable, which means
they can be hammered into sheets,
and they are ductile, which means
they can be drawn into wire
How the mobile particles involved in
metallic bonding can be pushed
Thermal Conductivity And
Electrical Conductivity
 Metals are good conductors, explain
 The movement of mobile electrons around positive
metallic cations makes metals good conductors.
 Mobile electrons easily move as part forming electric
current when an electric potential is applied to a metal
Hardness and strength
As the number of delocalized electrons increases, so do the
properties of hardness and strength.
strong metallic bonds are found in transition metals such as
chromium, iron, and nickel
whereas alkali metals are considered soft because they have
only one delocalized electron
number of delocalized
electrons increases
hardness and
strength
strong metallic bonds
Metal Alloys
An alloy is a mixture of elements that has metallic
properties
Properties of alloys
The properties of alloys differ somewhat from the
properties of the elements they contain.
For example, steel is iron mixed with at least one other
element.
Some properties of iron are present, but steel has
additional properties, such as increased strength.
Commercial alloys
Substitutional alloys
 In a substitutional alloy, some of the atoms in the
original metallic solid are replaced by other metals of
similar atomic size.
 Sterling silver is an example of a substitutional alloy.
 In sterling silver, copper atoms replace some of the
silver atoms in the metallic crystal.
 The resulting solid has properties of both silver and
copper.
An interstitial alloy is formed when the small holes
(interstices) in a metallic crystal are filled with
smaller atoms.
The best-known interstitial alloy is carbon steel.
Holes in the iron crystal are filled with carbon
atoms, and the physical properties of iron are
changed.
Iron is relatively soft and malleable. However, the
presence of carbon makes the solid harder, stronger,
and less ductile than pure iron
Interstitial alloys
Metallic Bonding, Properties, and Alloys

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Metallic Bonding, Properties, and Alloys

  • 1.
  • 2. Objectives Describing the Metallic bond. Relate the electron sea model to the physical properties of metals. Define alloys, and categorize them into two basic types
  • 3. Metallic Bonds  Electron Sea Model proposes that all the metal atoms in a metallic solid share their valence electrons to form a “sea” of electrons. This sea of electrons surrounds the metal cations in the lattice.  The electrons present in the outer energy levels of the bonding metallic atoms are not held by any specific atom and can move easily  Because they are free to move, they are often referred to as delocalized electrons.
  • 4. Metallic bond  A metallic bond is the attraction of a metallic cation for delocalized electrons.
  • 5. Properties of metals Melting and boiling points The melting points of metals vary greatly. For example ; Mercury is a liquid at room temperature, which makes it useful in scientific instruments such as thermometers and barometers. Tungsten has a melting point of 3422°C. Light bulb filaments are usually made from tungsten, also in certain spacecraft parts.
  • 6. Compare melting points and boiling points for different elements melting point does not take an extreme amount of energy for them to be able to move past each other. Boiling point is usually higher than Melting point, why? However, during boiling, atoms must be separated from the group of cations and electrons, which requires much more energy.
  • 7. Malleability, ductility, and durability Metals are malleable, which means they can be hammered into sheets, and they are ductile, which means they can be drawn into wire
  • 8. How the mobile particles involved in metallic bonding can be pushed
  • 9. Thermal Conductivity And Electrical Conductivity  Metals are good conductors, explain  The movement of mobile electrons around positive metallic cations makes metals good conductors.  Mobile electrons easily move as part forming electric current when an electric potential is applied to a metal
  • 10. Hardness and strength As the number of delocalized electrons increases, so do the properties of hardness and strength. strong metallic bonds are found in transition metals such as chromium, iron, and nickel whereas alkali metals are considered soft because they have only one delocalized electron number of delocalized electrons increases hardness and strength strong metallic bonds
  • 11. Metal Alloys An alloy is a mixture of elements that has metallic properties Properties of alloys The properties of alloys differ somewhat from the properties of the elements they contain. For example, steel is iron mixed with at least one other element. Some properties of iron are present, but steel has additional properties, such as increased strength.
  • 13. Substitutional alloys  In a substitutional alloy, some of the atoms in the original metallic solid are replaced by other metals of similar atomic size.  Sterling silver is an example of a substitutional alloy.  In sterling silver, copper atoms replace some of the silver atoms in the metallic crystal.  The resulting solid has properties of both silver and copper.
  • 14. An interstitial alloy is formed when the small holes (interstices) in a metallic crystal are filled with smaller atoms. The best-known interstitial alloy is carbon steel. Holes in the iron crystal are filled with carbon atoms, and the physical properties of iron are changed. Iron is relatively soft and malleable. However, the presence of carbon makes the solid harder, stronger, and less ductile than pure iron Interstitial alloys