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Carbon footprint of pultruded
composite products in
Automotive applications: case
study side panel of a coach
Samer Ziadeh
25.8.2015
Outline
 Introduction
 The aim of the case study
 Life cycle of the side panel
 The modeling and calculations
 Results and discussion
 Further work for improvements
 Conclusion
20.11.2016 2
Introduction
• The increasing demands of the environmental protection
especially in the automotive industry.
• The automotive industry is a major contributor of emitted
greenhouse gas emissions in the world.
20.11.2016
Carbon trust, Carbon Footprinting guide-
Carbon Trust, 2012.
3
”A carbon footprint is the total greenhouse gas (GHG)
emissions caused directly and indirectly by an individual,
organization, event or product, ”
Carbon trust
o Kyoto GHG emissions: (CO2), (CH4), (N2O), (HFCs),
(PFCs), (SF6).
o Carbon dioxide equivalent (CO2e) is a measure used to
compare the emissions from various greenhouse gases
based upon their global warming potential
20.11.2016 4
Emission
factor
CO2e
Activity
data
mass/volu
me/energy
/distance
CF of the
given
activity
Standards and Labels
 Standards: PAS 2050, ISO/TS 14067, The GHG
Protocol: A corporate Accounting and Reporting
Standard.
 Labels:
20.11.2016 5
The aim of the case study
• Calculating the CF and energy consumption for a
pultruded composite profile.
• Comparing the values with other conventional materials.
• Emphasize the benefits of light materials in weight
reduction, less fuel consumption and lower impacts on
environment.
20.11.2016 6
The side panel of a coach
20.11.2016
Exelcomposites.com, 'Exel Composites –
Advanced Pultrusion and Pullwinding
Technologies', 2015.
7
(a) The Body component fixed on coach,
Solidworks drawing of the panel (b) front and (c)
back
The pultruded composite
profile is 43,2% wt of E-glass
fiber (GF) and unsaturated
polyester resin (UP).
Pultruded profiles enviromental
analysis
20.11.2016
J. Anderson, Green guide to composites,
Garston: BRE; Netcomposites, 2004.
8
Sandwich panel 8m x 1m(25mm core) ribs as a
core materials
20.11.2016 9
Fibers for Pultrusion (CSM with glass
rovings) (39%)
Polyester + 50% CaCO3 (45%)
Closed mixing-any matrix (<1%)
Pull fibers through resin - emissions from
resin bath (15%)
Cure through heated die (<1%)
Saw to length (<1%)
Cleaning of pultrusion machine (<1%)
Life cycle of side panel
20.11.2016 10
Data collection
20.11.2016 11
Materials
Thickness
(mm)
Density
(kg/m3)
Weight
(kg)
Stainless steel, ferritic, AISI 405,
wrought, annealed, low nickel
0,9 7,82x103 64,74
Aluminium, 5005, wrought, H14
2,5 2,72x103 62,56
Carbon steel, AISI 1050, annealed
0,75 7,9x103 54,51
E-glass fiber/polyester, pultruded
profile (UD fiber and CSM) 90̊
direction
3 1,9x103 52,44
Eco Audit modeling
20.11.2016Cambridge Engineering Selector Software
(CES 2015). Granta desgin, 2015.
12
CF and energy consumption
calculations
o Transportation phase: 4500 km distance
Transport energy/CO2
= transport energy per unit mass & distance × distance
× product mass CO2 foot print source
o Use phase: product life cycle 12 years, distance 200 km
per day, usage 350 days per year
Life distance = product life years × daysper year × distance per day
Life distance 840000 km
Mobile use energy MJ/CO2kg
= transport energy per unit mass&distance × life distance × mass
× (energy equivalence − CO2footprint source)
20.11.2016
M. Ashby. Materials and environment. 2end
ed. Elsevier,2013. 13
Results and discussion
20.11.2016 14
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
Raw materials
extraction
Manufacturing Transportation Use of the product End-of-life
9680
25100
168000
174000
4050
Energy Consumption MJ
Composite Aluminium Stainless steel Steel
20.11.2016 15
0
2000
4000
6000
8000
10000
12000
14000
Raw materials
extraction
Manufacturing Transportation Use of the product End-of-life
507
10000
1650
11900
12400
237
CO2 footprint kg
Composite Aluminium Stainless steel Steel
20.11.2016 16
0
2000
4000
6000
8000
10000
12000
14000
Total Carbon Footprint
(kg)
10600 10800
Composite Aluminium
Stainless steel Steel
0
50000
100000
150000
200000
Total Energy Consumption
(MJ)
152000 153000
Composite Aluminium
Stainless steel Steel
The equivalent annual environmental burden
(averaged over 12 year of a product life)
20.11.2016 17
12700
16200
15100
12800
Composite Aluminium Stainless steel Steel
Total energy consumptions
per a year (MJ/year)
885
1140
1080
900
Composite Aluminium Stainless steel Steel
Total CO2 footprint per a
year (kg/year)
Transportation phase case
scenarios
20.11.2016 18
278
7080
332
8450
344
8750
286
7270
0
2000
4000
6000
8000
10000
Case scenario 1 (Truck-
diesel)
Case scenario 2 (air
flight -kerosene)
Energy Consumption
(MJ)
Composite Panel Aluminium Panel
Stainless steel Panel Steel Panel
19.8
474
23.6
566
24.4
586
20.3
487
0
100
200
300
400
500
600
700
Case scenario 1 (Truck-
diesel)
Case scenario 2 (Air flight-
kerosene)
CO2 footprint (kg)
Composite Panel Aluminium Panel
Stainles steel Panel Steel Panel
o Case 1: Effect of the transportation is a minor contributor to the total
impacts with only >1% of the prodcut CF
o Case 2 : High impact of transportation in the air flight type with both
energy and CO2 footprint.
Use phase case scenarios
20.11.2016 19
0
50000
100000
150000
200000
250000
Energy Consumption (MJ)
Composite Panel Aluminium Panel
Stainless steel Panel Steel Panel
0
2000
4000
6000
8000
10000
12000
14000
16000
18000
CO2 footprint (kg)
Composite Panel Aluminium Panel
Stainless steel Panel Steel Panel
Further work for improvements
A. Biocomposite:
less CO2 emissions, lower embodied energy of materials,
ease depletion of non-renewable resources and the
possibility for biodegradation taking place as an end-of-life
option.
B. Material recycling
C. Chemical recycling method
D. Co-processing
20.11.2016
European Composites Industry Association
(EuCIA ), "Composites Recycling Made Easy,"
EuCIA , 2011. 20
Conclusion
• The use phase of the vehicle shows the most significant
enviromental impact emissions of the entire life cycle of
the panel.
• By using composite materials, the use phase emissions
from a vehicle were reduced due to lower
weight/improved performance of composites.
• Implementing the recycling methods: (pyrolysis-
hydrolysis-chemical recycling-biodegradation) at the end
of life phase.
20.11.2016 21
Acknowledgement
Prof. Jyrki Vuorinen
Mikko Lassila, Kim Sjödahl,
Eric Moussiaux
20.11.2016 22
Thank you
for kind attention
20.11.2016 23

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Master thesis seminar" Carbon footprint of pultruded composite products in Automotive applications

  • 1. Carbon footprint of pultruded composite products in Automotive applications: case study side panel of a coach Samer Ziadeh 25.8.2015
  • 2. Outline  Introduction  The aim of the case study  Life cycle of the side panel  The modeling and calculations  Results and discussion  Further work for improvements  Conclusion 20.11.2016 2
  • 3. Introduction • The increasing demands of the environmental protection especially in the automotive industry. • The automotive industry is a major contributor of emitted greenhouse gas emissions in the world. 20.11.2016 Carbon trust, Carbon Footprinting guide- Carbon Trust, 2012. 3 ”A carbon footprint is the total greenhouse gas (GHG) emissions caused directly and indirectly by an individual, organization, event or product, ” Carbon trust
  • 4. o Kyoto GHG emissions: (CO2), (CH4), (N2O), (HFCs), (PFCs), (SF6). o Carbon dioxide equivalent (CO2e) is a measure used to compare the emissions from various greenhouse gases based upon their global warming potential 20.11.2016 4 Emission factor CO2e Activity data mass/volu me/energy /distance CF of the given activity
  • 5. Standards and Labels  Standards: PAS 2050, ISO/TS 14067, The GHG Protocol: A corporate Accounting and Reporting Standard.  Labels: 20.11.2016 5
  • 6. The aim of the case study • Calculating the CF and energy consumption for a pultruded composite profile. • Comparing the values with other conventional materials. • Emphasize the benefits of light materials in weight reduction, less fuel consumption and lower impacts on environment. 20.11.2016 6
  • 7. The side panel of a coach 20.11.2016 Exelcomposites.com, 'Exel Composites – Advanced Pultrusion and Pullwinding Technologies', 2015. 7 (a) The Body component fixed on coach, Solidworks drawing of the panel (b) front and (c) back The pultruded composite profile is 43,2% wt of E-glass fiber (GF) and unsaturated polyester resin (UP).
  • 8. Pultruded profiles enviromental analysis 20.11.2016 J. Anderson, Green guide to composites, Garston: BRE; Netcomposites, 2004. 8
  • 9. Sandwich panel 8m x 1m(25mm core) ribs as a core materials 20.11.2016 9 Fibers for Pultrusion (CSM with glass rovings) (39%) Polyester + 50% CaCO3 (45%) Closed mixing-any matrix (<1%) Pull fibers through resin - emissions from resin bath (15%) Cure through heated die (<1%) Saw to length (<1%) Cleaning of pultrusion machine (<1%)
  • 10. Life cycle of side panel 20.11.2016 10
  • 11. Data collection 20.11.2016 11 Materials Thickness (mm) Density (kg/m3) Weight (kg) Stainless steel, ferritic, AISI 405, wrought, annealed, low nickel 0,9 7,82x103 64,74 Aluminium, 5005, wrought, H14 2,5 2,72x103 62,56 Carbon steel, AISI 1050, annealed 0,75 7,9x103 54,51 E-glass fiber/polyester, pultruded profile (UD fiber and CSM) 90̊ direction 3 1,9x103 52,44
  • 12. Eco Audit modeling 20.11.2016Cambridge Engineering Selector Software (CES 2015). Granta desgin, 2015. 12
  • 13. CF and energy consumption calculations o Transportation phase: 4500 km distance Transport energy/CO2 = transport energy per unit mass & distance × distance × product mass CO2 foot print source o Use phase: product life cycle 12 years, distance 200 km per day, usage 350 days per year Life distance = product life years × daysper year × distance per day Life distance 840000 km Mobile use energy MJ/CO2kg = transport energy per unit mass&distance × life distance × mass × (energy equivalence − CO2footprint source) 20.11.2016 M. Ashby. Materials and environment. 2end ed. Elsevier,2013. 13
  • 14. Results and discussion 20.11.2016 14 0 20000 40000 60000 80000 100000 120000 140000 160000 180000 Raw materials extraction Manufacturing Transportation Use of the product End-of-life 9680 25100 168000 174000 4050 Energy Consumption MJ Composite Aluminium Stainless steel Steel
  • 15. 20.11.2016 15 0 2000 4000 6000 8000 10000 12000 14000 Raw materials extraction Manufacturing Transportation Use of the product End-of-life 507 10000 1650 11900 12400 237 CO2 footprint kg Composite Aluminium Stainless steel Steel
  • 16. 20.11.2016 16 0 2000 4000 6000 8000 10000 12000 14000 Total Carbon Footprint (kg) 10600 10800 Composite Aluminium Stainless steel Steel 0 50000 100000 150000 200000 Total Energy Consumption (MJ) 152000 153000 Composite Aluminium Stainless steel Steel
  • 17. The equivalent annual environmental burden (averaged over 12 year of a product life) 20.11.2016 17 12700 16200 15100 12800 Composite Aluminium Stainless steel Steel Total energy consumptions per a year (MJ/year) 885 1140 1080 900 Composite Aluminium Stainless steel Steel Total CO2 footprint per a year (kg/year)
  • 18. Transportation phase case scenarios 20.11.2016 18 278 7080 332 8450 344 8750 286 7270 0 2000 4000 6000 8000 10000 Case scenario 1 (Truck- diesel) Case scenario 2 (air flight -kerosene) Energy Consumption (MJ) Composite Panel Aluminium Panel Stainless steel Panel Steel Panel 19.8 474 23.6 566 24.4 586 20.3 487 0 100 200 300 400 500 600 700 Case scenario 1 (Truck- diesel) Case scenario 2 (Air flight- kerosene) CO2 footprint (kg) Composite Panel Aluminium Panel Stainles steel Panel Steel Panel o Case 1: Effect of the transportation is a minor contributor to the total impacts with only >1% of the prodcut CF o Case 2 : High impact of transportation in the air flight type with both energy and CO2 footprint.
  • 19. Use phase case scenarios 20.11.2016 19 0 50000 100000 150000 200000 250000 Energy Consumption (MJ) Composite Panel Aluminium Panel Stainless steel Panel Steel Panel 0 2000 4000 6000 8000 10000 12000 14000 16000 18000 CO2 footprint (kg) Composite Panel Aluminium Panel Stainless steel Panel Steel Panel
  • 20. Further work for improvements A. Biocomposite: less CO2 emissions, lower embodied energy of materials, ease depletion of non-renewable resources and the possibility for biodegradation taking place as an end-of-life option. B. Material recycling C. Chemical recycling method D. Co-processing 20.11.2016 European Composites Industry Association (EuCIA ), "Composites Recycling Made Easy," EuCIA , 2011. 20
  • 21. Conclusion • The use phase of the vehicle shows the most significant enviromental impact emissions of the entire life cycle of the panel. • By using composite materials, the use phase emissions from a vehicle were reduced due to lower weight/improved performance of composites. • Implementing the recycling methods: (pyrolysis- hydrolysis-chemical recycling-biodegradation) at the end of life phase. 20.11.2016 21
  • 22. Acknowledgement Prof. Jyrki Vuorinen Mikko Lassila, Kim Sjödahl, Eric Moussiaux 20.11.2016 22
  • 23. Thank you for kind attention 20.11.2016 23

Editor's Notes

  1. The main environmental impacts for pultrusion arise from the resin. the emissions from the resin bath are also large due to the high surface area of the resin bath. closed mixing, results in an 8% improvement of environmental impact for the process. Pultrusion. Emissions from the styrene used in polyester resins are a significant source of impact during both the mixing and application of a resin.