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Copyright © 2011 PETRONAS IONIC LIQUIDS CENTRE (PILC)
All right reserved. No part of this document may be reproduced, stored in retrieval system, or transmitted in any form or by means (electronic, mechanical, photocopying,
recording, or otherwise) without permission of the copyright owner
Fuel and Energy
Dr Zakir Khan
Department of Chemical Engineering
CUI Lahore Campus, Lahore
Introduction to Gaseous Fuels and their
Sources
2
Objectives
Course Learning Outcomes (CLOs)
• CLO-1 Describe the industrial fuels, combustion phenomena and fuel processing
• CLO-2 Explain the industrial combustion system and renewable and alternative
energy sources
• CLO-3 Demonstrate the knowledge of combustion through calculations
 Introduction to gaseous fuels
 Gas heating values
 Sources of gaseous fuels
• Methane from coal bed/mines
• Gobar gas (Dung gas)
• Coal gas from Coal gasification
Objectives and Related CLOs
Gaseous fuel
• Fuel which are burnt in gaseous state in the presence of air or oxygen (pure) to
give heat utilization in homes and industry.
Sources
• Methane from coal bed/mines (Coal mines)
• Dung gas (Gobar gas) (Fermentation of biodegradable)
• Coal/biomass gas from gasification (gasification at atmosphere pressure)
• Gas from underground coal gasification (underground gasification)
• Sewage gas (Gas produced by sewage disposal through anaerobic decomposition)
• Liquified petroleum gas (LPG) (Mixture of propane (80-90 %) and Butane (10-20 %) extracted
from oil well)
• Refinery gas (produced during distillation of crude oil or treatment of oil products (e.g.
cracking) in refineries contains H2, CH4 and C2H6)
Gaseous fuel
Sources (continue……….)
• Producer gas (Mixture of CO and N2 produces in a furnace by blowing air or mixture of
air/steam in a furnace through coal/coke).
• Blast furnace gas (Generated in Blast furnace when the iron ore is reduced with coke to
metallic iron)
• Water gas (Reaction of superheated steam with bed of hot coke/coal producing CO and H2
mainly)
• Coke oven gas (is produced during the manufacture of metallurgical coke by heating
bituminous coal)
• Oil gas from oil gasification process ( Gasification of light/middle distillate and heavy oils (low
CH ratio) from refinery to produce synthesis gas for Ammonia production to used in
Fertilizers)
• Hydrogen and Acetylene
Gas fuel heating values
What is Calorific value (CV) or Heating value
The heat produced by a fuel for its complete combustion
Wobbe Index=CV/(specific gravity)0.5
Gas group Wobbe index (CV in kcal/Nm3
1 Rich fuel gas (>4000 kcal/Nm3)
2
3 7650+380
4 6970+285
5 6400+285
6 5870+240
7 5340+285
Lean fuel gas
(<1500 kcal/Nm3)
• Gross heating values or High
heating values
(With water heating values
In exhaust gas)
• Net heating values or lower
heating values
(without water heating values)
This index is helpful in comparing energy generation from
different fuel gases while using a burner. When the Wobbe
index for two fuel gases is identical or very close (less than 5%),
then for a specified gas pressure and burner valves settings the
energy generation would be nearly identical.
Methane from coal bed/mines
• Methane is formed and adsorbed on the surface of coal during
“coalification process”
[CH4=93-99%], C2H6=0-3%, CO2=0-4%, N2=2-6%]
• Methane is desorbed during coal
mining and extremely danger if
not properly handled
Most of the coal we use
now was formed about
300 million years ago. As
plants and trees died,
their remains sank to
the bottom of the
swampy areas, making
layers and layers of
plant material and
eventually forming a
soggy, thick material
called coal (PEAT).
Gobar gas (Dung gas)
Temperature 30-40 ℃
Methane rich gas
Fermentation
The chemical breakdown of a substance by bacteria, yeasts, or other microorganisms and the giving off of heat.
• To convert solid carbonaceous fuel (biomass and coal etc.) into a
gaseous mixture i.e. H2, CO CO2 and CH4.
8
What is Gasification
Coal
Gasification Steps
Solid
Liquid
Coal gas from coal gasification
Difference between Combustion and
Gasification???
9
Reactors for Coal Gasification

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Lecture 16- Gaseous fuels and thier sources.pptx

  • 1. Copyright © 2011 PETRONAS IONIC LIQUIDS CENTRE (PILC) All right reserved. No part of this document may be reproduced, stored in retrieval system, or transmitted in any form or by means (electronic, mechanical, photocopying, recording, or otherwise) without permission of the copyright owner Fuel and Energy Dr Zakir Khan Department of Chemical Engineering CUI Lahore Campus, Lahore Introduction to Gaseous Fuels and their Sources
  • 2. 2 Objectives Course Learning Outcomes (CLOs) • CLO-1 Describe the industrial fuels, combustion phenomena and fuel processing • CLO-2 Explain the industrial combustion system and renewable and alternative energy sources • CLO-3 Demonstrate the knowledge of combustion through calculations  Introduction to gaseous fuels  Gas heating values  Sources of gaseous fuels • Methane from coal bed/mines • Gobar gas (Dung gas) • Coal gas from Coal gasification Objectives and Related CLOs
  • 3. Gaseous fuel • Fuel which are burnt in gaseous state in the presence of air or oxygen (pure) to give heat utilization in homes and industry. Sources • Methane from coal bed/mines (Coal mines) • Dung gas (Gobar gas) (Fermentation of biodegradable) • Coal/biomass gas from gasification (gasification at atmosphere pressure) • Gas from underground coal gasification (underground gasification) • Sewage gas (Gas produced by sewage disposal through anaerobic decomposition) • Liquified petroleum gas (LPG) (Mixture of propane (80-90 %) and Butane (10-20 %) extracted from oil well) • Refinery gas (produced during distillation of crude oil or treatment of oil products (e.g. cracking) in refineries contains H2, CH4 and C2H6)
  • 4. Gaseous fuel Sources (continue……….) • Producer gas (Mixture of CO and N2 produces in a furnace by blowing air or mixture of air/steam in a furnace through coal/coke). • Blast furnace gas (Generated in Blast furnace when the iron ore is reduced with coke to metallic iron) • Water gas (Reaction of superheated steam with bed of hot coke/coal producing CO and H2 mainly) • Coke oven gas (is produced during the manufacture of metallurgical coke by heating bituminous coal) • Oil gas from oil gasification process ( Gasification of light/middle distillate and heavy oils (low CH ratio) from refinery to produce synthesis gas for Ammonia production to used in Fertilizers) • Hydrogen and Acetylene
  • 5. Gas fuel heating values What is Calorific value (CV) or Heating value The heat produced by a fuel for its complete combustion Wobbe Index=CV/(specific gravity)0.5 Gas group Wobbe index (CV in kcal/Nm3 1 Rich fuel gas (>4000 kcal/Nm3) 2 3 7650+380 4 6970+285 5 6400+285 6 5870+240 7 5340+285 Lean fuel gas (<1500 kcal/Nm3) • Gross heating values or High heating values (With water heating values In exhaust gas) • Net heating values or lower heating values (without water heating values) This index is helpful in comparing energy generation from different fuel gases while using a burner. When the Wobbe index for two fuel gases is identical or very close (less than 5%), then for a specified gas pressure and burner valves settings the energy generation would be nearly identical.
  • 6. Methane from coal bed/mines • Methane is formed and adsorbed on the surface of coal during “coalification process” [CH4=93-99%], C2H6=0-3%, CO2=0-4%, N2=2-6%] • Methane is desorbed during coal mining and extremely danger if not properly handled Most of the coal we use now was formed about 300 million years ago. As plants and trees died, their remains sank to the bottom of the swampy areas, making layers and layers of plant material and eventually forming a soggy, thick material called coal (PEAT).
  • 7. Gobar gas (Dung gas) Temperature 30-40 ℃ Methane rich gas Fermentation The chemical breakdown of a substance by bacteria, yeasts, or other microorganisms and the giving off of heat.
  • 8. • To convert solid carbonaceous fuel (biomass and coal etc.) into a gaseous mixture i.e. H2, CO CO2 and CH4. 8 What is Gasification Coal Gasification Steps Solid Liquid Coal gas from coal gasification Difference between Combustion and Gasification???
  • 9. 9 Reactors for Coal Gasification