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IUPAC Nomenclature
General rules for IUPAC Nomenclature
1)word root 2)suffix 3)prefix
IUPAC Nomenclature
Word root
IUPAC Nomenclature
Suffix
1)primary suffix 2)secondary suffix
IUPAC Nomenclature
Prefixes
1)Alkyl group
IUPAC Nomenclature
2)Functional group named as substituents 3)Functional group in polyfunctional compounds
IUPAC Nomenclature
Complete IUPAC Name
prefixes + word root + primary suffix + secondary suffix
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
1)Straight chain alkanes
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
2)Branched chain alkanes
a) Longest chain rule
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
b) Lowest sum rule
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
c) Identifying the word root
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
d) Naming the alkyl group (side chain)
i) When only one alkyl group is present
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
ii) When similar alkyl groups are present at different position
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
iii) When similar alkyl groups are at same position
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
iv)When different alkyl groups are present
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
v) When side chain is complex
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
3)Hydrocarbons containing multiple bonds
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
Nomenclature of compounds containing function groups
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
a)Compound containing only one functional group
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
b)Compounds containing two or more similar functional groups
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
c)Compounds containing two or more different function groups
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
d) Compounds containing multiple bonds and functional groups
IUPAC Nomenclature
Nomenclature of open chain hydrocarbons
Bond line notations and nomenclature
IUPAC Nomenclature
Alicyclic compounds
1)A saturatetd alicyclic compound is named by adding the prefix cyclo to the name of the corresponding straight chain alkanes.
IUPAC Nomenclature
Alicyclic compounds
2)If side chains are present then they are named exactly in the same way as discussed earlier for open chain compound.
IUPAC Nomenclature
Alicyclic compounds
3)When an alicyclic compound contains a multiple bond or a functional group , the corresponding primary and secondary suffixes
Or prefixes attached to the word root and their positions are indicated by the appropriate numbers . The numbering of carbon
Atoms present in the ring is done in such a way so as to assign the minimum possible numbers to the functional group or
Multiple bonds exactly in the same way as we discussed earlier.
IUPAC Nomenclature
Alicyclic compounds
4)When a cyclic ring is attached to a chain containing number of carbon atoms or more than one cyclic rings are attached to
A single chain , the compound is named as cycloalkyl alkane.
IUPAC Nomenclature
Alicyclic compounds
5) If chain attached to a cyclic ring contains lesser carbon atoms , the compound is named as a derivative of cycloalkane.
IUPAC Nomenclature
Alicyclic compounds
6) If the chain attached to cyclic ring contains multiple bonds.
IUPAC Nomenclature
Alicyclic compounds
7) If the benzene ring attached to cyclic ring .
IUPAC Nomenclature
Structural formula from IUPAC name
1)Identify word root
2)Attach functional group
3)Number the carbon atom from either end ie functional group or multiple bonds.
4)Fill multiple bonds
5)Satisfy the remaining valencies of carbon atoms with single bonded H atoms.
Nomenclature of aromatic compounds
1)Mono substituted derivatives
Nomenclature of aromatic compounds
2)Di substituted derivatives
Nomenclature of aromatic compounds
3)Tri substituted derivatives
Nomenclature of aromatic compounds
4)Side chain substituted
Nomenclature of aromatic compounds
Aryl group
Nomenclature of aromatic compounds
Nomenclature of aromatic compounds
Nomenclature of aromatic compounds
iupac chemistry tsh                           .pptx

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iupac chemistry tsh .pptx