Front-end performance optimizing involves optimizing a website's HTML, CSS, JavaScript, and image files to achieve the fastest possible loading speed. This includes minimizing HTTP requests by combining files, compressing files, optimizing code by removing unused code and errors, leveraging browser caching, and parallelizing downloads across domains. The document outlines nine techniques for front-end optimization, such as optimizing file sizes, reducing download size through compression and caching, and minimizing HTTP requests through file combining and CSS sprites.