This study investigated the effectiveness of using laboratory experiments and demonstration methods to teach solubility and solubility product to high school students in Medan, Indonesia. The results showed that using innovated laboratory experiments increased student achievement more than conventional teaching methods, with achievement increases of 109% versus 104%. However, using innovated demonstration methods resulted in lower achievement increases compared to conventional methods, at 104% versus 135%. Student motivation was also found to be positively correlated with achievement when using innovated teaching methods. The study concludes that chemistry teachers should use laboratory experiments when teaching solubility and solubility product as it leads to higher student achievement and interest compared to only conventional methods.