This document summarizes research on developing Pt/V2O5-C composite catalysts for methanol oxidation in direct methanol fuel cells (DMFCs). Pt nanoparticles were dispersed on a V2O5-C composite support through chemical reduction. The catalyst was characterized using XRD and TEM, which showed the formation of small Pt nanoparticles (~3 nm) on the support. Electrochemical testing showed that the Pt/V2O5-C composite catalyst had higher catalytic activity for methanol oxidation compared to a commercial Pt/C catalyst, as indicated by a more positive onset potential and higher forward/reverse peak current ratios. The composite catalyst also demonstrated comparable stability during chronoamperometry testing. The improved performance is attributed to
Maiyalagan,Electrochemical oxidation of methanol on pt v2 o5–c composite cata...kutty79
Platinum nanoparticles have been supported on V2O5–C composite through the reduction of chloroplatinic
acid with formaldehyde. The catalyst was characterized by X-ray diffraction and transmission electron
microscopy. Catalytic activity and stability for the oxidation of methanol were studied by using
cyclic voltammetry and chronoamperometry. Pt/V2O5–C composite anode catalyst on glassy carbon electrode
show higher electro-catalytic activity for the oxidation of methanol. High electro-catalytic activities
and good stabilities could be attributed to the synergistic effect between Pt and V2O5, avoiding the electrodes
being poisoned.
Three dimensional cubic ordered mesoporous carbon (cmk-8) as highly efficient...suresh800
This document describes a study comparing palladium (Pd) nanoparticles supported on two types of three-dimensional cubic ordered mesoporous carbon (CMK-8) as electrocatalysts for formic acid oxidation. The Pd/CMK-8 catalysts were synthesized using sodium borohydride reduction and characterized using techniques such as TEM, XRD, and cyclic voltammetry. Cyclic voltammetry results showed that Pd/CMK-8 with larger pores had the highest mass specific activity of 486.4 mA/mg Pd, exceeding the activities of commercial Pd/C and other recently reported Pd catalysts. Chronoamperometry testing also demonstrated this P
Visible light driven photocatalytic oxidation of thiols to disulfides using i...Pawan Kumar
The present paper describes the synthesis of graphene oxide immobilized iron phthalocyanine (FePc) for
the photocatalytic oxidation of thiols to disulfides under alkaline free conditions. Iron phthalocyanine
tetrasulfonamide was immobilized on carboxylated graphene oxide supports via covalent attachment.
The loading of FePc on GO nanosheets was confirmed by FTIR, Raman, ICP-AES, UV-Vis and elemental
analyses. The synthesized catalyst was found to be highly efficient for the photo-oxidation of thiols to
disulfides in aqueous medium using molecular oxygen as oxidant under visible light irradiation. The
identification of photo-oxidation products and their quantitative determination was done using GC-MS.
After completion of the reaction, the catalyst was easily recovered by filtration and reused for several
runs without loss in activity and no leaching was observed during the reaction
This document summarizes a research article that studied the selective oxidation of styrene using Mg-Co-Al hydrotalcite-like catalysts with air as the oxidant. Several Mg-Co-Al catalysts with varying Co content were synthesized and characterized. The catalysts were tested for styrene oxidation and showed good activity and stability. Both styrene conversion and product selectivity depended on the cobalt substitution level. Cobalt ions within the hydrotalcite lattice acted as active sites for styrene epoxidation.
Magnetic Fe3O4@MgAl–LDH composite grafted with cobalt phthalocyanine as an ef...Pawan Kumar
Magnetically separable layered double hydroxide MgAl–LDH@Fe3O4 composite supported cobalt
phthalocyanine catalyst was synthesized and used for the aerobic oxidation of mercaptans to corresponding
disulfides under alkali free conditions. The catalyst exhibited excellent activity for the oxidation of
mercaptans using molecular oxygen as an oxidant which can be effectively recovered by using an external
magnetic field. In addition, the covalent immobilization of cobalt phthalocyanine to MgAl–LDH@Fe3O4
support prevents the leaching of the catalyst and improves its activity and stability
Studies of transition metal ion - 5- Sulphosalicylic acid doped PolyanilinesIOSR Journals
This document summarizes a study on transition metal ion-5-sulphosalicylic acid complexes used as dopants for polyaniline. Polyaniline was doped with various transition metal carbonates both with and without 5-sulphosalicylic acid. The doped polyanilines were characterized through various tests. Conductivity was found to increase with increasing acid concentration in the doping solution. Magnetic susceptibility measurements showed paramagnetic behavior for transition metal-doped polyanilines and diamagnetic behavior for polyaniline doped with only 5-sulphosalicylic acid. The polymers were found to be amorphous by XRD. SEM showed small
Organic inorganic hybrid cobalt phthalocyanine/polyaniline as efficient catal...Pawan Kumar
Organic inorganic hybrid catalyst synthesized by doping of cobalt phthalocyanine (CoPc) on polyaniline
support (CoPc/PANI) exhibited higher activity for the oxidation of various alcohols to the corresponding
carbonyl compounds in high to excellent yield using molecular oxygen as oxidant and isobutyraldehyde
as a sacrificial agent. Notably, the synthesized catalyst was found to be truly heterogeneous in nature and
could be easily recovered, recycled for several recycling runs without loss of catalytic activity
The project will focus on synthesis of hexagonal structured pure phases of compositions: BaM1/3Ti2/3O3-δ and BaM1/6Ti5/6O3-δ, where M= Sc, In and Fe via different methods such as Solid state sintering and wet chemical route. The ultimate goal is to finding structure – functionality relationships within these proton and mixed conducting systems. A substantial effort will focus on search for and fabrication of new materials although the main part of the work will concentrate on detailed structural characterisation (rietveld refinement), impedance spectroscopy, infrared spectroscopy and thermogravimetric analysis.
Maiyalagan,Electrochemical oxidation of methanol on pt v2 o5–c composite cata...kutty79
Platinum nanoparticles have been supported on V2O5–C composite through the reduction of chloroplatinic
acid with formaldehyde. The catalyst was characterized by X-ray diffraction and transmission electron
microscopy. Catalytic activity and stability for the oxidation of methanol were studied by using
cyclic voltammetry and chronoamperometry. Pt/V2O5–C composite anode catalyst on glassy carbon electrode
show higher electro-catalytic activity for the oxidation of methanol. High electro-catalytic activities
and good stabilities could be attributed to the synergistic effect between Pt and V2O5, avoiding the electrodes
being poisoned.
Three dimensional cubic ordered mesoporous carbon (cmk-8) as highly efficient...suresh800
This document describes a study comparing palladium (Pd) nanoparticles supported on two types of three-dimensional cubic ordered mesoporous carbon (CMK-8) as electrocatalysts for formic acid oxidation. The Pd/CMK-8 catalysts were synthesized using sodium borohydride reduction and characterized using techniques such as TEM, XRD, and cyclic voltammetry. Cyclic voltammetry results showed that Pd/CMK-8 with larger pores had the highest mass specific activity of 486.4 mA/mg Pd, exceeding the activities of commercial Pd/C and other recently reported Pd catalysts. Chronoamperometry testing also demonstrated this P
Visible light driven photocatalytic oxidation of thiols to disulfides using i...Pawan Kumar
The present paper describes the synthesis of graphene oxide immobilized iron phthalocyanine (FePc) for
the photocatalytic oxidation of thiols to disulfides under alkaline free conditions. Iron phthalocyanine
tetrasulfonamide was immobilized on carboxylated graphene oxide supports via covalent attachment.
The loading of FePc on GO nanosheets was confirmed by FTIR, Raman, ICP-AES, UV-Vis and elemental
analyses. The synthesized catalyst was found to be highly efficient for the photo-oxidation of thiols to
disulfides in aqueous medium using molecular oxygen as oxidant under visible light irradiation. The
identification of photo-oxidation products and their quantitative determination was done using GC-MS.
After completion of the reaction, the catalyst was easily recovered by filtration and reused for several
runs without loss in activity and no leaching was observed during the reaction
This document summarizes a research article that studied the selective oxidation of styrene using Mg-Co-Al hydrotalcite-like catalysts with air as the oxidant. Several Mg-Co-Al catalysts with varying Co content were synthesized and characterized. The catalysts were tested for styrene oxidation and showed good activity and stability. Both styrene conversion and product selectivity depended on the cobalt substitution level. Cobalt ions within the hydrotalcite lattice acted as active sites for styrene epoxidation.
Magnetic Fe3O4@MgAl–LDH composite grafted with cobalt phthalocyanine as an ef...Pawan Kumar
Magnetically separable layered double hydroxide MgAl–LDH@Fe3O4 composite supported cobalt
phthalocyanine catalyst was synthesized and used for the aerobic oxidation of mercaptans to corresponding
disulfides under alkali free conditions. The catalyst exhibited excellent activity for the oxidation of
mercaptans using molecular oxygen as an oxidant which can be effectively recovered by using an external
magnetic field. In addition, the covalent immobilization of cobalt phthalocyanine to MgAl–LDH@Fe3O4
support prevents the leaching of the catalyst and improves its activity and stability
Studies of transition metal ion - 5- Sulphosalicylic acid doped PolyanilinesIOSR Journals
This document summarizes a study on transition metal ion-5-sulphosalicylic acid complexes used as dopants for polyaniline. Polyaniline was doped with various transition metal carbonates both with and without 5-sulphosalicylic acid. The doped polyanilines were characterized through various tests. Conductivity was found to increase with increasing acid concentration in the doping solution. Magnetic susceptibility measurements showed paramagnetic behavior for transition metal-doped polyanilines and diamagnetic behavior for polyaniline doped with only 5-sulphosalicylic acid. The polymers were found to be amorphous by XRD. SEM showed small
Organic inorganic hybrid cobalt phthalocyanine/polyaniline as efficient catal...Pawan Kumar
Organic inorganic hybrid catalyst synthesized by doping of cobalt phthalocyanine (CoPc) on polyaniline
support (CoPc/PANI) exhibited higher activity for the oxidation of various alcohols to the corresponding
carbonyl compounds in high to excellent yield using molecular oxygen as oxidant and isobutyraldehyde
as a sacrificial agent. Notably, the synthesized catalyst was found to be truly heterogeneous in nature and
could be easily recovered, recycled for several recycling runs without loss of catalytic activity
The project will focus on synthesis of hexagonal structured pure phases of compositions: BaM1/3Ti2/3O3-δ and BaM1/6Ti5/6O3-δ, where M= Sc, In and Fe via different methods such as Solid state sintering and wet chemical route. The ultimate goal is to finding structure – functionality relationships within these proton and mixed conducting systems. A substantial effort will focus on search for and fabrication of new materials although the main part of the work will concentrate on detailed structural characterisation (rietveld refinement), impedance spectroscopy, infrared spectroscopy and thermogravimetric analysis.
Electro catalytic performance of pt-supported poly (o-phenylenediamine) micro...sunitha81
Poly (o-phenylenediamine) (PoPD) microrods were obtained by interfacial
polymerization using ferric chloride as oxidant and without any template or
functional dopant. Pt/PoPD nanocatalysts were prepared by the reduction of chloroplatinic
acid with sodium borohydride, and the composite catalysts formed were
characterized by X-ray diffraction and electrochemical methods. The nanocomposite
of Pt/PoPD microrods has been explored for their electro-catalytic performance
towards oxidation of methanol. The electro-catalytic activity of Pt/PoPD was
found to be much higher (current density 1.96 mA/cm2 at 0.70 V) in comparison to
Pt/Vulcan electrodes (the current density values of 1.56 mA/cm2 at 0.71 V) which
may be attributed to the microrod morphology of PoPD that facilitate the effective
dispersion of Pt particles and easier access of methanol towards the catalytic sites.
synthesis and characterization of hydrazone ligand and their metal complexesMUBASHIRA M
This slide mainly contain the synthesis, characterization of a few hydrazine based heterocyclic ligand such as hydralazone and phenyl hydralazone and also their metal complexes. so in this work, my aim is to synthesise the ligands; 2-thiophenecarboxylaldehydehydralazone and 2,3-butanedionephenylhydrazone. also to characterized the synthesised hydrazones by different physiochemical techniques.
Review of platinum degradation mechanisms in proton exchange membrane fuel ce...Himasree Viswanadhapalli
This document summarizes platinum degradation mechanisms in proton exchange membrane fuel cells. It discusses how platinum catalysts degrade over time through processes like particle migration, dissolution, and agglomeration. Microscopic analysis has revealed evidence of particle migration when potential cycling. Various approaches have been studied to improve platinum stability, such as using core-shell nanoparticles, alloying platinum with gold, and reducing particle size. Understanding platinum degradation mechanisms is an ongoing challenge for improving the efficiency and longevity of fuel cells.
A study on photocatalytic activity of micro arc oxidation ti o2 filmsssuser195344
This document discusses a study on the photocatalytic activity of micro-arc oxidation (MAO) TiO2 films and Ag+/MAO-TiO2 composite films. MAO-TiO2 films were prepared on titanium substrates using a phosphate-based electrolyte. The films were then impregnated with silver ions (Ag+) to create Ag+/MAO-TiO2 composite films. The films were characterized using SEM, XRD, and EDS. Their photocatalytic activity was evaluated by measuring the degradation of methylene blue dye under simulated sunlight irradiation. The results showed that Ag+ impregnation enhanced the photocatalytic activity of the MAO-TiO2 films.
This document provides an overview of metal complexes and organometallics. It discusses the structure, bonding, and applications of inorganic complexes and coordination compounds. Key topics covered include ligands, isomerism, crystal field theory, and the spectrochemical series. Organometallics such as metal carbonyls, ferrocene, and Grignard reagents are also introduced. Important applications of coordination compounds are highlighted in areas like extraction of metals, analytical chemistry, biology, medicine, and industry.
Graphene oxide immobilized copper phthalocyanine tetrasulphonamide: the first...Pawan Kumar
The first successful synthesis of DMC directly from methanol and carbon dioxide using a heterogenized
homogeneous graphene oxide immobilized copper phthalocyanine tetrasulphonamide catalyst in the
presence of N,N0-dicyclohexylcarbodiimide (DCC) as a dehydrating agent is described. The presence of a
dehydrating agent was found to be vital and in its absence the yield of DMC was found to be decreased
significantly. Under the optimized reaction conditions, the maximum yield of DMC reaches up to 13.3%.
Although the homogeneous copper phthalocyanine tetrasulphonamide catalyst provided a little higher
yield of DMC (14.2%), the facile recovery and recycling ability of the heterogeneous catalyst make the
developed method more attractive from environmental and economical viewpoints.
This document discusses solvent extraction, which is a versatile separation method used in analytical chemistry. It can be used to separate, purify, enrich, and analyze both tracer and macro amounts of metal ions. The key principles discussed include the phase rule, which describes solvent extraction as a two-phase system, and the Nernst distribution law, which defines the partition or distribution coefficient. Different types of extraction systems are classified, including chelate extraction involving complex formation, extraction by solvation, and ion-pair formation. Factors that affect metal complex stability such as ligand basicity and ring size are also outlined.
A highly efficient, recyclable and magnetically separable core-shell structured CuZnO@Fe3O4 microsphere
wrapped with reduced graphene oxide (rGO@CuZnO@Fe3O4) photocatalyst has been developed and used
for the photoreduction of carbon dioxide with water to produce methanol under visible light irradiation.
Owing to the synergistic effect of the components and to the presence of a thin Fe2O3 layer on Fe3O4,
rGO@CuZnO@Fe3O4 4 exhibited higher catalytic activity as compared to the other possible combinations
such as CuZnO@Fe3O4 2 and GO@CuZnO@Fe3O4 3 microspheres. The yield of methanol in case of using
2 and 3 as photocatalyst was found to be 858 and 1749 mol g−1 cat, respectively. However, the yield
was increased to 2656 mol g−1 cat when rGO@CuZnO@Fe3O4 4 was used as photocatalyst under similar
experimental conditions. This superior photocatalytic activity of 4 was assumed to be due to the
restoration of the sp2 hybridized aromatic system in rGO, which facilitated the movement of electrons
and resulted in better charge separation. The synthesized heterogeneous photocatalyst could readily be
recovered by external magnet and successfully reused for six subsequent cycles without significant loss
in the product yield
This document discusses the production process of polypropylene fibers. It begins with an introduction to polypropylene and its uses. It then describes the two main polymerization methods used - Ziegler-Natta catalyst polymerization and metallocene catalyst polymerization. The final section discusses the melt spinning process used to produce polypropylene fibers from the polymer, including extrusion of the melt, quenching and drawing of the fibers.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...suresh899
Carbon Supported PtRu nanocatalysts have been prepared by simple impregnation reduction method in which Pt and Ru precursors are reduced by ethanol under reflux conditions for different reaction times. The prepared nanocatalysts were characterized by means of XRD, EDAX, ICP-AAS, FESEM and TEM. XRD analyses showed that all nanocatalysts exhibited f.c.c crystal structure, the structure characteristic for pure Pt, except for that reduced at prolonged reaction time of 4h which showed the presence of characteristic peak for Ru metal. The lattice constant calculations indicate that all catalysts are present in unalloyed phase and the average particle size as determined by TEM was in the range of 3.7 nm. The electrocatalytic activities and stability for the prepared nanocatalysts methanol electro-oxidation reaction (MOR) were studied by cyclic voltammetry. The catalysts prepared at 2h reduction time showed higher electrocatalytic activity in terms of mass specific activity and good stability over potential sweep for 100 cycles for methanol electro-oxidation. The results showed that the prepared nanocatalysts are considered as promising electrode catalyst (anode catalyst) for electro-oxidation of methanol in direct methanol fuel cells.
The document describes using reversible addition-fragmentation chain transfer (RAFT) polymerization to synthesize novel block copolymers containing both a polyolefin block and a poly(styrene-co-maleic anhydride) block. Specifically, it details:
1) Using a commercially available polyolefin (Kraton L-1203) modified with a dithioester group to serve as a macroinitiator for RAFT polymerization and form the polyolefin block.
2) Conducting RAFT polymerizations of styrene and styrene-co-maleic anhydride using this macroinitiator and a small molecule RAFT agent to form the second block and yield polyolefin
Study of electrical properties of Polythiophene and its compositesIOSR Journals
Conducting polymers are known to have significant electrical properties which can be improved by strong oxidizing power of oxidizing agents like V2O5. In the current study oxidative polymerization of the thiophene monomers was done to obtain Polythiophene for converting it into its composites with V2O5 to study their improved electrical nature. The electrical properties of pure Polythiophene, pure V2O5, PTh- V2O5 composite 1:2 (thiophene: V2O5) and PTh- V2O5 composite 2:1(thiophene: V2O5) were studied by carrying out current voltage measurements. It can be stated that the increased concentration of V2O5 is responsible for the increased current flow through the polymer matrix. The study is explained on the basis of fact that oxidizing power leads to removal of higher number of charge carriers from the backbone thereby causing increases in current flow. Such conducting polymers have wide range of applications in the field of Metal ions detectors, molecular electronics, conductive adhesive, electrical displays, electromagnetic shields, chemical, biochemical and thermal sensors, rechargeable batteries, solid electrolytes, optical computers and ion exchange membrane
Photo-induced reduction of CO2 using a magnetically separable Ru-CoPc@TiO2@Si...Pawan Kumar
An efficient photo-induced reduction of CO2 using magnetically separable Ru-CoPc@TiO2@SiO2@Fe3O4
as a heterogeneous catalyst in which CoPc and Ru(bpy)2phene complexes were attached to a solid
support via covalent attachment under visible light is described. The as-synthesized catalyst was characterized
by a series of techniques including FTIR, UV-Vis, XRD, SEM, TEM, etc. and subsequently tested for
the photocatalytic reduction of carbon dioxide using triethylamine as a sacrificial donor and water as a
reaction medium. The developed photocatalyst exhibited a significantly higher catalytic activity to give a
methanol yield of 2570.78 μmol per g cat after 48 h.
This document summarizes a study investigating the initialization behavior of reversible addition-fragmentation chain transfer (RAFT)-mediated styrene-maleic anhydride copolymerizations using in situ 1H NMR spectroscopy. The results indicate specificity of addition of the RAFT agent leaving groups for either styrene or maleic anhydride. Analysis of the NMR spectra also showed that monomers are added individually, favoring the penultimate unit model of polymer propagation over other proposed mechanisms. Stereoselectivity was observed during monomer addition to the RAFT agent.
Carbon based catalysts for oxygen reduction reaction (ORR) Lav Kumar Kasaudhan
The document discusses carbon-based catalysts for oxygen reduction reaction (ORR). It summarizes three journal papers on this topic. The first paper discusses the need for non-precious metal catalysts to replace platinum in fuel cells and issues with stability and durability. The second paper examines nitrogen and metal-containing catalysts and their activity. The third paper analyzes ORR activity on different fullerene molecules and active sites. Overall, the document reviews research gaps and findings on developing durable, non-precious metal catalysts for ORR.
Green synthesis of well dispersed nanoparticles using leaf extract of medicin...tshankar20134
Green synthesis of gold nanoparticles was achieved using an extract of the medicinal plant Adhatoda vasica.
The nanoparticles formed were predominantly spherical and monodisperse, with sizes ranging from 22 to 47 nm as determined through transmission electron microscopy analysis. Ultraviolet-visible spectroscopy and X-ray diffraction data confirmed the formation and crystalline nature of the gold nanoparticles. Functional groups present in the plant extract, such as hydroxyl and carboxyl groups, were found to play a role in both the reduction of gold ions and stabilization of the resulting nanoparticles. This green synthesis method using A. vasica extract could provide a means of producing biocompatible gold nanoparticles for applications such as drug delivery.
Effects of heat treatment on the catalytic activity and methanol tolerance of...tshankar20134
This document studies the effects of heat treatment on the catalytic activity and methanol tolerance of carbon-supported platinum alloys. Platinum (Pt), platinum-cobalt (Pt-Co), platinum-copper (Pt-Cu), platinum-iron (Pt-Fe), and platinum-nickel (Pt-Ni) catalysts were heat treated at different temperatures and their properties were analyzed. Heat treatment was found to increase particle size but also improved catalytic activity in most cases. The optimum heat treatment temperature depended on the specific catalyst. Pt-Cu/C and Pt-Fe/C catalysts heat treated at 350°C showed the highest oxygen reduction reaction activity and best methanol tolerance. Overall, Pt-
Components of pem_fuel_cells_an_overviewtshankar20134
The document provides an overview of the key components of proton exchange membrane fuel cells (PEMFCs). PEMFCs consist of a membrane electrode assembly (MEA) with a proton-conducting membrane sandwiched between two electrode layers. Perfluorinated sulfonic acid membranes like Nafion are most widely used as they have high proton conductivity while preventing fuel/oxidant mixing. Efforts are ongoing to develop alternative membranes and electrocatalysts to reduce costs and improve durability in order to facilitate PEMFC commercialization for applications like transportation.
Hepatoblastoma is a rare liver tumor that affects children under 3 years old. It typically presents as a golf ball sized tumor in the right lobe of the liver. While the cause is unknown, genetic disorders like Beckwith-Wiedemann syndrome can increase the risk. Treatment depends on the stage, ranging from surgery alone for early stages to chemotherapy and surgery for advanced cases. Without treatment, hepatoblastoma has a 100% fatality rate.
Hepatoblastoma and hepatocellular carcinoma in children Fanny Yeh
This document discusses hepatoblastoma (HB) in children, including surgical strategies and outcomes. The key points are:
1. Between 1996-2012, 14 HB patients underwent surgery at a Taiwanese hospital, with 12 receiving fresh resection and 2 recurrent cases. Aggressive resection resulted in long-term survival in 91.7% of fresh cases.
2. For resectable HB (PRETEXT I-II), chemotherapy before resection is unnecessary. Some image-unresectable cases may be cured with skilled resection.
3. For unresectable HB, primary liver transplant should be arranged after 4-6 rounds of chemotherapy. Rescue transplant after recurrence also results in
care of children with Hepatoblastoma and bone tumorNimmy Tomy
This document discusses hepatoblastoma, a type of liver cancer that primarily affects young children. It defines hepatoblastoma and other types of childhood liver cancer. Risk factors include genetic conditions and hepatitis B infection. Symptoms may include an abdominal mass, vomiting, and jaundice. Diagnostic tests include blood tests, imaging scans, and biopsy. Staging evaluates how far the cancer has spread. Treatment involves chemotherapy, surgery such as partial hepatectomy, and sometimes liver transplant. Prognosis has improved in recent decades with overall survival rates now around 70%.
Electro catalytic performance of pt-supported poly (o-phenylenediamine) micro...sunitha81
Poly (o-phenylenediamine) (PoPD) microrods were obtained by interfacial
polymerization using ferric chloride as oxidant and without any template or
functional dopant. Pt/PoPD nanocatalysts were prepared by the reduction of chloroplatinic
acid with sodium borohydride, and the composite catalysts formed were
characterized by X-ray diffraction and electrochemical methods. The nanocomposite
of Pt/PoPD microrods has been explored for their electro-catalytic performance
towards oxidation of methanol. The electro-catalytic activity of Pt/PoPD was
found to be much higher (current density 1.96 mA/cm2 at 0.70 V) in comparison to
Pt/Vulcan electrodes (the current density values of 1.56 mA/cm2 at 0.71 V) which
may be attributed to the microrod morphology of PoPD that facilitate the effective
dispersion of Pt particles and easier access of methanol towards the catalytic sites.
synthesis and characterization of hydrazone ligand and their metal complexesMUBASHIRA M
This slide mainly contain the synthesis, characterization of a few hydrazine based heterocyclic ligand such as hydralazone and phenyl hydralazone and also their metal complexes. so in this work, my aim is to synthesise the ligands; 2-thiophenecarboxylaldehydehydralazone and 2,3-butanedionephenylhydrazone. also to characterized the synthesised hydrazones by different physiochemical techniques.
Review of platinum degradation mechanisms in proton exchange membrane fuel ce...Himasree Viswanadhapalli
This document summarizes platinum degradation mechanisms in proton exchange membrane fuel cells. It discusses how platinum catalysts degrade over time through processes like particle migration, dissolution, and agglomeration. Microscopic analysis has revealed evidence of particle migration when potential cycling. Various approaches have been studied to improve platinum stability, such as using core-shell nanoparticles, alloying platinum with gold, and reducing particle size. Understanding platinum degradation mechanisms is an ongoing challenge for improving the efficiency and longevity of fuel cells.
A study on photocatalytic activity of micro arc oxidation ti o2 filmsssuser195344
This document discusses a study on the photocatalytic activity of micro-arc oxidation (MAO) TiO2 films and Ag+/MAO-TiO2 composite films. MAO-TiO2 films were prepared on titanium substrates using a phosphate-based electrolyte. The films were then impregnated with silver ions (Ag+) to create Ag+/MAO-TiO2 composite films. The films were characterized using SEM, XRD, and EDS. Their photocatalytic activity was evaluated by measuring the degradation of methylene blue dye under simulated sunlight irradiation. The results showed that Ag+ impregnation enhanced the photocatalytic activity of the MAO-TiO2 films.
This document provides an overview of metal complexes and organometallics. It discusses the structure, bonding, and applications of inorganic complexes and coordination compounds. Key topics covered include ligands, isomerism, crystal field theory, and the spectrochemical series. Organometallics such as metal carbonyls, ferrocene, and Grignard reagents are also introduced. Important applications of coordination compounds are highlighted in areas like extraction of metals, analytical chemistry, biology, medicine, and industry.
Graphene oxide immobilized copper phthalocyanine tetrasulphonamide: the first...Pawan Kumar
The first successful synthesis of DMC directly from methanol and carbon dioxide using a heterogenized
homogeneous graphene oxide immobilized copper phthalocyanine tetrasulphonamide catalyst in the
presence of N,N0-dicyclohexylcarbodiimide (DCC) as a dehydrating agent is described. The presence of a
dehydrating agent was found to be vital and in its absence the yield of DMC was found to be decreased
significantly. Under the optimized reaction conditions, the maximum yield of DMC reaches up to 13.3%.
Although the homogeneous copper phthalocyanine tetrasulphonamide catalyst provided a little higher
yield of DMC (14.2%), the facile recovery and recycling ability of the heterogeneous catalyst make the
developed method more attractive from environmental and economical viewpoints.
This document discusses solvent extraction, which is a versatile separation method used in analytical chemistry. It can be used to separate, purify, enrich, and analyze both tracer and macro amounts of metal ions. The key principles discussed include the phase rule, which describes solvent extraction as a two-phase system, and the Nernst distribution law, which defines the partition or distribution coefficient. Different types of extraction systems are classified, including chelate extraction involving complex formation, extraction by solvation, and ion-pair formation. Factors that affect metal complex stability such as ligand basicity and ring size are also outlined.
A highly efficient, recyclable and magnetically separable core-shell structured CuZnO@Fe3O4 microsphere
wrapped with reduced graphene oxide (rGO@CuZnO@Fe3O4) photocatalyst has been developed and used
for the photoreduction of carbon dioxide with water to produce methanol under visible light irradiation.
Owing to the synergistic effect of the components and to the presence of a thin Fe2O3 layer on Fe3O4,
rGO@CuZnO@Fe3O4 4 exhibited higher catalytic activity as compared to the other possible combinations
such as CuZnO@Fe3O4 2 and GO@CuZnO@Fe3O4 3 microspheres. The yield of methanol in case of using
2 and 3 as photocatalyst was found to be 858 and 1749 mol g−1 cat, respectively. However, the yield
was increased to 2656 mol g−1 cat when rGO@CuZnO@Fe3O4 4 was used as photocatalyst under similar
experimental conditions. This superior photocatalytic activity of 4 was assumed to be due to the
restoration of the sp2 hybridized aromatic system in rGO, which facilitated the movement of electrons
and resulted in better charge separation. The synthesized heterogeneous photocatalyst could readily be
recovered by external magnet and successfully reused for six subsequent cycles without significant loss
in the product yield
This document discusses the production process of polypropylene fibers. It begins with an introduction to polypropylene and its uses. It then describes the two main polymerization methods used - Ziegler-Natta catalyst polymerization and metallocene catalyst polymerization. The final section discusses the melt spinning process used to produce polypropylene fibers from the polymer, including extrusion of the melt, quenching and drawing of the fibers.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...suresh899
Carbon Supported PtRu nanocatalysts have been prepared by simple impregnation reduction method in which Pt and Ru precursors are reduced by ethanol under reflux conditions for different reaction times. The prepared nanocatalysts were characterized by means of XRD, EDAX, ICP-AAS, FESEM and TEM. XRD analyses showed that all nanocatalysts exhibited f.c.c crystal structure, the structure characteristic for pure Pt, except for that reduced at prolonged reaction time of 4h which showed the presence of characteristic peak for Ru metal. The lattice constant calculations indicate that all catalysts are present in unalloyed phase and the average particle size as determined by TEM was in the range of 3.7 nm. The electrocatalytic activities and stability for the prepared nanocatalysts methanol electro-oxidation reaction (MOR) were studied by cyclic voltammetry. The catalysts prepared at 2h reduction time showed higher electrocatalytic activity in terms of mass specific activity and good stability over potential sweep for 100 cycles for methanol electro-oxidation. The results showed that the prepared nanocatalysts are considered as promising electrode catalyst (anode catalyst) for electro-oxidation of methanol in direct methanol fuel cells.
The document describes using reversible addition-fragmentation chain transfer (RAFT) polymerization to synthesize novel block copolymers containing both a polyolefin block and a poly(styrene-co-maleic anhydride) block. Specifically, it details:
1) Using a commercially available polyolefin (Kraton L-1203) modified with a dithioester group to serve as a macroinitiator for RAFT polymerization and form the polyolefin block.
2) Conducting RAFT polymerizations of styrene and styrene-co-maleic anhydride using this macroinitiator and a small molecule RAFT agent to form the second block and yield polyolefin
Study of electrical properties of Polythiophene and its compositesIOSR Journals
Conducting polymers are known to have significant electrical properties which can be improved by strong oxidizing power of oxidizing agents like V2O5. In the current study oxidative polymerization of the thiophene monomers was done to obtain Polythiophene for converting it into its composites with V2O5 to study their improved electrical nature. The electrical properties of pure Polythiophene, pure V2O5, PTh- V2O5 composite 1:2 (thiophene: V2O5) and PTh- V2O5 composite 2:1(thiophene: V2O5) were studied by carrying out current voltage measurements. It can be stated that the increased concentration of V2O5 is responsible for the increased current flow through the polymer matrix. The study is explained on the basis of fact that oxidizing power leads to removal of higher number of charge carriers from the backbone thereby causing increases in current flow. Such conducting polymers have wide range of applications in the field of Metal ions detectors, molecular electronics, conductive adhesive, electrical displays, electromagnetic shields, chemical, biochemical and thermal sensors, rechargeable batteries, solid electrolytes, optical computers and ion exchange membrane
Photo-induced reduction of CO2 using a magnetically separable Ru-CoPc@TiO2@Si...Pawan Kumar
An efficient photo-induced reduction of CO2 using magnetically separable Ru-CoPc@TiO2@SiO2@Fe3O4
as a heterogeneous catalyst in which CoPc and Ru(bpy)2phene complexes were attached to a solid
support via covalent attachment under visible light is described. The as-synthesized catalyst was characterized
by a series of techniques including FTIR, UV-Vis, XRD, SEM, TEM, etc. and subsequently tested for
the photocatalytic reduction of carbon dioxide using triethylamine as a sacrificial donor and water as a
reaction medium. The developed photocatalyst exhibited a significantly higher catalytic activity to give a
methanol yield of 2570.78 μmol per g cat after 48 h.
This document summarizes a study investigating the initialization behavior of reversible addition-fragmentation chain transfer (RAFT)-mediated styrene-maleic anhydride copolymerizations using in situ 1H NMR spectroscopy. The results indicate specificity of addition of the RAFT agent leaving groups for either styrene or maleic anhydride. Analysis of the NMR spectra also showed that monomers are added individually, favoring the penultimate unit model of polymer propagation over other proposed mechanisms. Stereoselectivity was observed during monomer addition to the RAFT agent.
Carbon based catalysts for oxygen reduction reaction (ORR) Lav Kumar Kasaudhan
The document discusses carbon-based catalysts for oxygen reduction reaction (ORR). It summarizes three journal papers on this topic. The first paper discusses the need for non-precious metal catalysts to replace platinum in fuel cells and issues with stability and durability. The second paper examines nitrogen and metal-containing catalysts and their activity. The third paper analyzes ORR activity on different fullerene molecules and active sites. Overall, the document reviews research gaps and findings on developing durable, non-precious metal catalysts for ORR.
Green synthesis of well dispersed nanoparticles using leaf extract of medicin...tshankar20134
Green synthesis of gold nanoparticles was achieved using an extract of the medicinal plant Adhatoda vasica.
The nanoparticles formed were predominantly spherical and monodisperse, with sizes ranging from 22 to 47 nm as determined through transmission electron microscopy analysis. Ultraviolet-visible spectroscopy and X-ray diffraction data confirmed the formation and crystalline nature of the gold nanoparticles. Functional groups present in the plant extract, such as hydroxyl and carboxyl groups, were found to play a role in both the reduction of gold ions and stabilization of the resulting nanoparticles. This green synthesis method using A. vasica extract could provide a means of producing biocompatible gold nanoparticles for applications such as drug delivery.
Effects of heat treatment on the catalytic activity and methanol tolerance of...tshankar20134
This document studies the effects of heat treatment on the catalytic activity and methanol tolerance of carbon-supported platinum alloys. Platinum (Pt), platinum-cobalt (Pt-Co), platinum-copper (Pt-Cu), platinum-iron (Pt-Fe), and platinum-nickel (Pt-Ni) catalysts were heat treated at different temperatures and their properties were analyzed. Heat treatment was found to increase particle size but also improved catalytic activity in most cases. The optimum heat treatment temperature depended on the specific catalyst. Pt-Cu/C and Pt-Fe/C catalysts heat treated at 350°C showed the highest oxygen reduction reaction activity and best methanol tolerance. Overall, Pt-
Components of pem_fuel_cells_an_overviewtshankar20134
The document provides an overview of the key components of proton exchange membrane fuel cells (PEMFCs). PEMFCs consist of a membrane electrode assembly (MEA) with a proton-conducting membrane sandwiched between two electrode layers. Perfluorinated sulfonic acid membranes like Nafion are most widely used as they have high proton conductivity while preventing fuel/oxidant mixing. Efforts are ongoing to develop alternative membranes and electrocatalysts to reduce costs and improve durability in order to facilitate PEMFC commercialization for applications like transportation.
Hepatoblastoma is a rare liver tumor that affects children under 3 years old. It typically presents as a golf ball sized tumor in the right lobe of the liver. While the cause is unknown, genetic disorders like Beckwith-Wiedemann syndrome can increase the risk. Treatment depends on the stage, ranging from surgery alone for early stages to chemotherapy and surgery for advanced cases. Without treatment, hepatoblastoma has a 100% fatality rate.
Hepatoblastoma and hepatocellular carcinoma in children Fanny Yeh
This document discusses hepatoblastoma (HB) in children, including surgical strategies and outcomes. The key points are:
1. Between 1996-2012, 14 HB patients underwent surgery at a Taiwanese hospital, with 12 receiving fresh resection and 2 recurrent cases. Aggressive resection resulted in long-term survival in 91.7% of fresh cases.
2. For resectable HB (PRETEXT I-II), chemotherapy before resection is unnecessary. Some image-unresectable cases may be cured with skilled resection.
3. For unresectable HB, primary liver transplant should be arranged after 4-6 rounds of chemotherapy. Rescue transplant after recurrence also results in
care of children with Hepatoblastoma and bone tumorNimmy Tomy
This document discusses hepatoblastoma, a type of liver cancer that primarily affects young children. It defines hepatoblastoma and other types of childhood liver cancer. Risk factors include genetic conditions and hepatitis B infection. Symptoms may include an abdominal mass, vomiting, and jaundice. Diagnostic tests include blood tests, imaging scans, and biopsy. Staging evaluates how far the cancer has spread. Treatment involves chemotherapy, surgery such as partial hepatectomy, and sometimes liver transplant. Prognosis has improved in recent decades with overall survival rates now around 70%.
Anemia, thalassemia and hemophilia in childrenNimmy Tomy
This document defines and discusses different types of anemia, including hemolytic anemia. It notes that anemia is a low red blood cell or hemoglobin level, reducing oxygen delivery. Causes include decreased or ineffective red blood cell production, increased red blood cell destruction (hemolytic anemia), and blood loss. Hemolytic anemia specifically refers to the premature breakdown of red blood cells, either inside or outside blood vessels. Causes can be genetic defects affecting red blood cells or acquired factors like immune system attacks or infections. Symptoms range from none in mild cases to fatigue, palpitations, and jaundice in more severe cases.
Art is a creative expression that stimulates the senses or imagination according to Felicity Hampel. Picasso believed that every child is an artist but growing up can stop that creativity. Aristotle defined art as anything requiring a maker and not being able to create itself.
Interior Effects is a design and construction company that focuses on meeting client goals through architectural and interior design services. They provide building construction, renovation, interior design, and furniture design. Some of their projects include constructing a luxury gym for a tennis club and renovating a kitchen and conference room. They have experience in residential and commercial projects, including constructing warehouses, offices, and apartments. Their team includes architects, engineers, and project managers with between 8-15 years of experience to deliver design and construction services.
JerusalemL practical immuno for hepatobiliary neoplasiaNeil Theise
This document discusses immunohistochemistry markers that can be used to differentiate various hepatobiliary neoplasms and lesions. It begins with an overview of markers that can help distinguish benign from malignant hepatocytes, such as CD34 and reticulin staining. The document then covers marker panels useful for specific diagnoses, such as distinguishing hepatocellular carcinoma from metastatic tumors. Several case examples are presented to demonstrate the application of immunohistochemistry in accurately diagnosing difficult hepatobiliary cases.
Protons Compared to Photons in Pediatric PatientsDanielle Buswell
Proton radiation therapy may reduce risks of late side effects compared to photon therapy for pediatric patients with medulloblastoma. Proton therapy decreases exit dose which can cause toxicities like heart problems, hearing loss, and neurocognitive deficits. Studies found proton therapy resulted in fewer neurocognitive deficits and lower risks of secondary cancers. While proton therapy may have better outcomes, its higher cost must be considered compared to photon therapy for each patient.
El documento describe diferentes tipos de tumores pediátricos, sus características y sistemas de clasificación. Menciona que es importante determinar si las lesiones son quísticas, sólidas o mixtas, y que generalmente las lesiones sólidas o mixtas representan malignidad. También presenta diferentes sistemas de estadificación y clasificación de tumores como el neuroblastoma, tumor de Wilms y linfoma de Hodgkin.
Fran Rafferty's thesis project aims to raise awareness and money for childhood cancer. The document outlines the project, which will provide facts about childhood cancers, different types of cancers that affect children, signs and symptoms, treatment options, and long-term effects of treatment. It also describes class activities where students will find songs to uplift children with cancer and create a slideshow presentation on childhood cancer applications.
The document describes various types of rodent liver lesions including neoplastic lesions such as hepatocellular adenomas and carcinomas, cholangiomas and cholangiocarcinomas, hepatoblastomas, hepatocholangiomas and hepatocholangiocarcinomas, Ito cell tumors, histiocytic sarcomas, hemangiomas and hemangiosarcomas, as well as lymphomas, erythroleukemia, and mononuclear cell leukemia. Photomicrographs are provided to illustrate characteristics such as nodular growth patterns, cellular pleomorphism, and infiltrative properties of these rodent liver tumors and cancers.
This document provides guidance on performing suprapubic bladder catheterization. It describes the indications, contraindications, necessary equipment, patient preparation, techniques, tips, aftercare, and potential complications of the procedure. Suprapubic bladder catheterization involves inserting a catheter through the abdominal wall and into the bladder to drain urine when transurethral catheterization is not possible or advisable. It is commonly used for patients with urinary retention, obstructive uropathies, or iatrogenic urethral injuries.
Apple Inc. is an American technology company founded in 1976 by Steve Jobs and Steve Wozniak. It specializes in consumer electronics, computer software, and online services. Some of Apple's most popular products include the Macintosh line of computers, the iPod, iPhone, iPad, and Apple Watch. Apple operates over 300 retail stores worldwide and has experienced significant growth, becoming one of the largest companies in the world as of 2010.
This document discusses Wilms' tumor, a type of childhood kidney cancer. It accounts for about 6% of pediatric cancers and develops from immature kidney tissue. Survival rates have improved from 30% in the 1930s to over 85% currently. Treatment typically involves surgery to remove the kidney along with chemotherapy and sometimes radiation therapy. Prognosis depends on factors like tumor stage, histology, and presence of anaplasia. Coordinated treatment protocols through organizations like the National Wilms Tumor Study Group have helped increase survival rates by standardizing treatment.
El documento describe el cáncer de hígado en niños. Existen dos tipos principales: hepatoblastoma y carcinoma hepatocelular. El hepatoblastoma es más común y ocurre en niños menores de 3 años, mientras que el carcinoma hepatocelular es raro en niños menores de 14 años. La supervivencia general es de 70% para el hepatoblastoma pero solo 25% para el carcinoma hepatocelular. El diagnóstico y tratamiento dependen del tipo y grado de cáncer.
Pitfalls in diagnosis of soft tissue tumors of childhoodSonic V S
The document discusses several potential pitfalls in the diagnosis of soft tissue tumors in children. It covers:
1) Misclassification of specific sarcomas like rhabdomyosarcoma subtypes and non-rhabdomyosarcoma soft tissue sarcomas.
2) Benign lesions that can be misdiagnosed as sarcomas, and sarcomas that can be misdiagnosed as benign.
3) Misgrading the aggressiveness of sarcomas.
4) Non-soft tissue tumors that are sometimes misdiagnosed as soft tissue sarcomas. Careful histology, immunohistochemistry, cytogenetics and molecular analysis are needed to arrive at
This document discusses various malignant liver lesions including primary and secondary tumors. For primary liver cancers, it describes hepatocellular carcinoma (HCC) as the most common type, risk factors such as hepatitis, and imaging features. It also discusses cholangiocarcinoma, hepatoblastoma, and rare tumors such as fibrolamellar carcinoma. Secondary cancers and criteria for staging HCC are also summarized.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...suresh800
This document summarizes a study that prepared carbon-supported platinum-ruthenium (PtRu) nanocatalysts for methanol electrooxidation using a simple ethanol reduction method. Pt and Ru precursors were impregnated on carbon support and reduced by refluxing in ethanol at 80°C for different times. The prepared nanocatalysts were characterized using various techniques and tested for their electrocatalytic activity and stability for methanol oxidation via cyclic voltammetry. The catalyst reduced for 2 hours showed higher mass activity and good stability over 100 cycles, indicating it is a promising anode catalyst for direct methanol fuel cells.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...madlovescience
The document describes a study that prepared carbon-supported PtRu nanocatalysts using an ethanol reduction method for different reaction times. The catalysts were characterized using various techniques and tested for their electrocatalytic activity in methanol oxidation. XRD and TEM analysis showed the catalysts had an FCC structure with an average particle size of 3.7 nm. Cyclic voltammetry tests found that the catalyst prepared at a 2h reduction time had higher electrocatalytic activity and stability for methanol electrooxidation compared to the other samples. The results suggest these catalysts could be promising anode catalysts for direct methanol fuel cells.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...tshankar20134
The document describes a study that prepared carbon-supported PtRu nanocatalysts using an ethanol reduction method for different reaction times. The catalysts were characterized using various techniques and tested for their electrocatalytic activity in methanol oxidation. XRD and TEM analysis showed the catalysts had an FCC structure with an average particle size of 3.7 nm. Cyclic voltammetry tests found that the catalyst prepared at a 2h reduction time had higher electrocatalytic activity and stability for methanol electrooxidation compared to the other catalysts. The results suggest these catalysts could be promising anode catalysts for direct methanol fuel cells.
Nitrogen containing carbon nanotubes as supports fortshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a commercial platinum on carbon catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...tshankar20134
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Nitrogen containing carbon nanotubes as supports for pt–alternate anodes for ...madlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotubes with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had significantly higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon catalyst.
Nitrogen containing carbon nanotubes as supports formadlovescience
1) Nitrogen-containing carbon nanotubes were synthesized and used to support platinum nanoparticles as an alternative anode catalyst for direct methanol fuel cells.
2) The platinum nanoparticles were uniformly distributed on the nitrogen-containing carbon nanotube surface with an average particle size of 3 nm.
3) Cyclic voltammetry studies showed that the platinum nanoparticles supported on nitrogen-containing carbon nanotubes had higher catalytic activity for methanol oxidation compared to a conventional platinum on carbon black catalyst.
Effects of heat treatment on the catalytic activity and methanol tolerance of...sunidevi
This document summarizes a study on the effects of heat treatment on the catalytic activity and methanol tolerance of carbon-supported platinum alloys. Carbon-supported platinum (Pt/C) and platinum alloy (Pt-Co/C, Pt-Cu/C, Pt-Fe/C, Pt-Ni/C) catalysts were subjected to heat treatments at different temperatures. X-ray diffraction, transmission electron microscopy, and electrochemical measurements were used to characterize the catalysts and evaluate their oxygen reduction reaction activity and methanol tolerance. The results showed that heat treatment improved catalytic activity by increasing particle size but the optimal temperature depended on the catalyst. Pt-Cu/C treated at 350°C showed the highest activity and
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...sunidevi
This document summarizes a study that prepared carbon-supported Pt-Ru nanocatalysts for methanol electrooxidation using a simple ethanol reduction method. The catalysts were characterized using various techniques and tested for their electrocatalytic activity and stability via cyclic voltammetry. The catalyst prepared with a 2-hour reduction time showed higher mass activity and good stability over 100 cycles for methanol electrooxidation compared to other reduction times. The results indicate these catalysts prepared via a low-cost ethanol reduction method have potential as anode catalysts for direct methanol fuel cells.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...sunilove
This document summarizes a study that prepared carbon-supported Pt-Ru nanocatalysts for methanol electrooxidation using a simple ethanol reduction method. The catalysts were characterized using various techniques and tested for their electrocatalytic activity via cyclic voltammetry. The key findings were:
1) Pt-Ru nanoparticles were successfully synthesized on carbon support using ethanol as a reducing agent without any stabilizers or heat treatment.
2) Characterization showed the catalysts had an FCC crystal structure and particle size around 3.7 nm.
3) Electrochemical testing found the catalyst reduced for 2 hours had the highest mass activity and stability for methanol electrooxidation over 100 cycles.
Electrooxidation of methanol on carbon supported pt ru nanocatalysts prepared...Science Padayatchi
This document summarizes a study that prepared carbon-supported Pt-Ru nanocatalysts for methanol electrooxidation using a simple ethanol reduction method. The catalysts were characterized using various techniques and tested for their electrocatalytic activity and stability via cyclic voltammetry. The catalyst prepared with a 2-hour reduction time showed higher mass activity and good stability over 100 cycles for methanol electrooxidation compared to other reduction times. The results indicate these catalysts prepared via a low-cost ethanol reduction method have potential as anode catalysts for direct methanol fuel cells.
Electro oxidation of methanol on ti o2 nanotube supported platinum electrodestshankar20134
This document summarizes research on using TiO2 nanotubes as a support for platinum nanoparticles for use as an electrocatalyst in methanol fuel cells. TiO2 nanotubes were synthesized using anodic aluminum oxide as a template. Platinum nanoparticles 3-4 nm in size were uniformly dispersed on the TiO2 nanotube supports. Electrochemical testing found that platinum nanoparticles supported on TiO2 nanotubes had higher catalytic activity for methanol oxidation compared to commercial Pt/C catalysts, with mass activity over 33 mA/mg Pt versus 3.25 mA/mg Pt for Pt/C. The improved activity is attributed to the TiO2 support preventing CO poisoning of platinum sites and possible electronic interactions between
Electro oxidation of methanol on ti o2 nanotube supported platinum electrodesmadlovescience
This document summarizes research on using TiO2 nanotubes as a support for platinum nanoparticles for use as an electrocatalyst in methanol fuel cells. TiO2 nanotubes were synthesized using anodic aluminum oxide as a template. Platinum nanoparticles 3-4 nm in size were uniformly dispersed on the TiO2 nanotube supports. Electrochemical testing found that platinum nanoparticles supported on TiO2 nanotubes had higher catalytic activity for methanol oxidation compared to commercial Pt/C catalysts, with mass activity over 33 mA/mg Pt versus 3.25 mA/mg Pt for Pt/C. The improved activity is attributed to the TiO2 support preventing CO poisoning of platinum sites and possible electronic interactions between
Highly stable pt–ru nanoparticles supported on three dimensional cubic ordere...tshankar20134
This document describes the synthesis and characterization of Pt-Ru nanoparticles supported on cubic ordered mesoporous carbon (Pt-Ru/CMK-8) and their evaluation as electrocatalysts for methanol oxidation in direct methanol fuel cells. Two types of CMK-8 carbon with different pore sizes were synthesized using two different mesoporous silica templates. Pt-Ru was deposited on the CMK-8 using sodium borohydride reduction. Characterization showed the CMK-8 had high surface areas over 1000 m2/g and pore volumes over 1.26 cm3/g. Electrochemical testing found the Pt-Ru/CMK-8-I catalyst had a high specific mass activity of 487
A facile synthesis method produced highly active Pd nanoparticle catalysts for oxygen reduction reaction (ORR) in under 5 minutes. An electrode was dipped in separate solutions of reducing agent and Pd ions to deposit amorphous Pd nanoparticles. Repeatedly dipping the electrode increased catalytic activity, with the highest activity achieved after 12 cycles of 20 seconds each. The Pd nanoparticles produced using sodium hypophosphite as the reducing agent showed superior ORR activity compared to commercial Pt/C catalysts.
The document describes the synthesis and characterization of a new heterogeneous photocatalyst consisting of an octahedral rhenium cluster (K4[Re6S8(CN)6]) grafted onto copper hydroxide (Cu(OH)2) modified titanium dioxide (TiO2) nanoparticles. Scanning electron microscopy images showed the Cu(OH)2/TiO2 nanoparticles were spherical and around 100-250 nm in diameter. Grafting the rhenium cluster did not significantly change the particle morphology. The synthesized photocatalyst was found to be highly active for the visible light-driven reduction of carbon dioxide to methanol, achieving a higher methanol yield than either the Cu(OH)2/TiO2 or rhen
Octahedral rhenium K4[Re6S8(CN)6] and Cu(OH)2cluster modifiedTiO2for the phot...Pawan Kumar
tOctahedral hexacyano rhenium K4[Re6S8(CN)6] cluster complexes were grafted onto photoactive Cu(OH)2cluster modified TiO2{Cu(OH)2/TiO2} support. The rhenium and copper cluster modified TiO2photocata-lyst combines the advantages of heterogeneous catalyst (facile recovery, recycling ability of the catalyst)with the reactivity, selectivity of the soluble molecular catalyst. The synthesized heterogeneous cata-lyst was found to be highly efficient photoredox catalyst for the reduction of CO2under visible lightirradiation. Methanol was found to be the major liquid product with the formation of hydrogen as a byproduct as determined with GC-FID and GC-TCD, respectively. The methanol yield after 24 h irradiationwas found to be 149 mol/0.1 g cat. for Re-cluster@Cu(OH)2/TiO2photocatalyst that is much higher than35 mol/0.1 g cat. for Cu(OH)2/TiO2and 75 mol/0.1 g cat. for equimolar rhenium cluster in the presenceof triethanolamine (TEOA) as a sacrificial donor. The quantum yields (MeOH) of Re-cluster@Cu(OH)2/TiO2and Cu(OH)2/TiO2were found to be 0.018 and 0.004 mol einstein−1, respectively. These values are muchhigher than those reported for other heterogeneous catalysts for six electron transfer reaction
Similar to Electrochemical oxidation of_methanol_on_pt-v2_o5-c_composite_catalysts (20)
Deposition of ni ti n coatings by a plasma assisted mocvd using an organometa...tshankar20134
Titanium nitride (TiN)/nickel (Ni) composite coatings were synthesized by plasma assisted metal-organic
chemical vapour deposition (PAMOCVD) using organo-metallic and metal-organic complexes namely dichlorobis(5-
cyclopentadienyl)titanium (IV) for titanium and N,N'-ethylene-bis(2,4-pentanedion-iminoato)nickel(II) for nickel. The
growth of such films was investigated in nitrogen (N2) plasma environment in the substrate temperature range of 450-
550ºC at a deposition pressure of 0.5-1 mbar. Prior to the deposition of films, the Ti precursor was subjected to the
equilibrium vapour pressure measurements by employing TG/DTA in transpiration mode, which led to the value of 109.2
± 5.6 kJ mol-1 for the standard enthalpy of sublimation (Ho
sub). The phase identification using glancing incidence x-ray
diffraction showed Ni/TiN is a nanocomposite coating containing nanocrystals of Ni and TiN with face centered cubic
structure. Scanning electron microscopy revealed a uniform surface morphology of the films, while chemical analysis by
energy dispersive analysis confirmed the presence of titanium, nickel and nitrogen in the composite films.
Template synthesis and characterization of well aligned nitrogen containing c...tshankar20134
This document describes the synthesis and characterization of nitrogen-containing carbon nanotubes produced through the pyrolysis of polyvinyl pyrrolidone on an alumina membrane template. The nanotubes were analyzed using various techniques which showed they had a hollow, vertically aligned structure with a significant amount of nitrogen incorporated into the carbon framework, as evidenced by elemental analysis, Raman spectroscopy, IR spectroscopy, and XPS. The template synthesis method allowed production of well-aligned nitrogen-containing carbon nanotubes with controlled morphology and composition.
Synthesis, characterization and electrocatalytic activity of silver nanorods ...tshankar20134
This document describes the synthesis of silver nanorods using a polyol process. Silver nitrate and polyvinylpyrrolidone (PVP) are reduced by propylene glycol at high temperature, allowing control over the diameter and length of the nanorods. Characterization with SEM, TEM, XRD and UV-vis spectroscopy confirms the formation of crystalline silver nanorods. Electrochemical testing shows that a glassy carbon electrode coated with silver nanorods exhibits high catalytic activity for the reduction of benzyl chloride, with a more positive reduction potential than bulk silver or plain glassy carbon electrodes. The extraordinary catalytic effect of the silver nanorods is likely due to their morphology and high affinity for chloride ions.
Synthesis and optimisation of ir o2 electrocatalysts by adams fusion method f...tshankar20134
The document summarizes research into optimizing IrO2 as an electrocatalyst for oxygen evolution in solid polymer electrolyte electrolyzers. IrO2 was synthesized using the Adams fusion method, varying synthesis duration from 0.5-4 hours and temperature from 250-500°C. Characterization showed that increasing duration and temperature increased crystallinity and particle size. Electrochemical testing found that IrO2 synthesized for 2 hours at 350°C had the best catalytic activity for oxygen evolution, outperforming a commercial IrO2. Higher temperatures favored formation of the active IrO2 phase but also led to larger particle sizes which decreased activity. Lower than 350°C did not favor IrO2 formation.
Synthesis and electro catalytic activity of methanol oxidation on nitrogen co...tshankar20134
The document summarizes research on synthesizing nitrogen-containing carbon nanotubes using different nitrogen-containing polymers as templates. Platinum particles were then supported on these nitrogen-containing carbon nanotubes and on regular carbon nanotubes and carbon for comparison. Characterization showed the nitrogen-containing carbon nanotube supported platinum catalyst had higher catalytic activity for methanol oxidation than the other catalysts. This was attributed to the existence of additional active sites on the nitrogen-containing carbon nanotube surface, which improved platinum particle dispersion and metal-support interaction.
This document describes a study where Pt-Ru nanoparticles were supported on functionalized carbon nanofibers (CNF) using polyamidoamine (PAMAM) dendrimers. PAMAM dendrimers were anchored to carboxylated CNF and then used to encapsulate and disperse Pt-Ru nanoparticles on the CNF surface. The composite catalyst (20% Pt-Ru/PAMAM-CNF) showed better performance for methanol oxidation than a commercial 20% Pt-Ru/C catalyst based on cyclic voltammetry tests. Characterization with XRD, SEM and TEM showed the Pt-Ru nanoparticles were uniformly dispersed and small in size (2.6 nm) on the PA
The document summarizes research on nano-structured lanthanum (La)-doped zinc oxide (ZnO) prepared using a combustion method. Coral-shaped ZnO nanostructures with pore sizes of 10-50 nm were successfully synthesized. Transmission electron microscopy showed the coral shape and porous nature increased with higher La doping concentrations. X-ray diffraction analysis confirmed the wurtzite structure of pure and doped ZnO. Optical studies showed absorbance in the UV region decreased and band gap increased with higher La doping levels. Photoluminescence spectra exhibited La characteristic emission and a shift in emission with doping. The La-doped ZnO nanostructures showed potential for applications in chemical sensing,
One pot synthesis of chain-like palladium nanocubes and their enhanced electr...tshankar20134
This document describes a one-pot synthesis of chain-like palladium nanocubes and their enhanced electrocatalytic activity. A simple aqueous approach is used to produce anisotropic cubic chain-like Pd nanostructures using the neurotransmitter 5-hydroxytryptamine. Scanning electron microscopy images show the nanocubes have sizes between 140-210 nm and form chain-like branched structures. Testing shows the cubic chain-like nanostructures have over 11 times greater electrocatalytic activity for oxidizing formic acid, methanol, and ethanol compared to spherical nanoparticles and commercial Pd/C catalysts. The enhanced performance makes them promising multipurpose catalysts for direct fuel cells.
Nitrogen review on recent progress in nitrogen-doped graphene synthesis, cha...tshankar20134
This document reviews recent progress in nitrogen-doped graphene. It discusses various synthesis methods for nitrogen-doped graphene including chemical vapor deposition, segregation growth, solvothermal synthesis, and arc discharge. It describes common nitrogen bonding configurations in nitrogen-doped graphene of pyridinic nitrogen, pyrrolic nitrogen, and graphitic nitrogen. The document also reviews potential applications of nitrogen-doped graphene in areas like electrocatalysis, field-effect transistors, and energy storage based on experimental and theoretical studies.
Nanostructured fe2 o3 platform for the electrochemical sensing of folic acidtshankar20134
The document describes the synthesis of alpha-iron oxide (α-Fe2O3) nanofibers using a simple electrospinning method and their application for the electrochemical sensing of folic acid (FA). The α-Fe2O3 nanofiber-modified glassy carbon electrode showed good selectivity for detecting FA even in the presence of ascorbic acid, achieving a detection limit of 60 nM for FA. The α-Fe2O3 nanofibers provided a high surface area platform and enhanced the oxidation current and separation of voltammetric signals for FA and ascorbic acid compared to an unmodified electrode. The modified electrode was successfully used to determine FA concentrations in human blood serum samples.
Film pore diffusion modeling for sorption of azo dye on to exfoliated graphit...tshankar20134
This document summarizes a study on the adsorption of the azo dye Acid Orange 7 onto exfoliated graphitic nanoplatelets (xGnPs) as a potential adsorbent. The effects of temperature, initial dye concentration, and pH on the adsorption process were investigated. Kinetic models including pseudo-first order, pseudo-second order and Elovich equation were applied and the data fit best with the pseudo-second order model, indicating chemisorption. Equilibrium studies showed the adsorption data fit well with both Langmuir and Freundlich isotherm models. The maximum adsorption capacity was found to increase with decreasing temperature, indicating an exothermic process.
Fabrication, morphology and structural characterization of tungsten oxide nan...tshankar20134
The document describes a method for synthesizing tungsten oxide nanorods. Phosphotungstic acid is infiltrated into an alumina membrane template and then calcined to form WO3 nanorods inside the template. The nanorods are characterized using SEM, TEM, AFM, XRD, Raman and IR spectroscopy. SEM and TEM images show the nanorods have a diameter of around 200nm, matching the pore size of the template. XRD and Raman patterns confirm the nanorods have a monoclinic crystalline structure. The nanorods also show superior electrochemical cycling ability compared to bulk WO3 materials.
Equilibrium and kinetic studies on the adsorption of methylene blue from aqueoustshankar20134
The document summarizes a study on the adsorption of the dye methylene blue from aqueous solution using activated carbon prepared from Murraya koenigii stems. Some key findings:
1) The activated carbon was characterized and found to have a specific surface area of 508 m2/g and pore structure consisting of micro and mesopores suitable for adsorption.
2) Batch adsorption experiments showed that adsorption capacity increased with increasing adsorbent dosage, reaching 98.99% dye removal at 0.12g dosage.
3) Equilibrium data fitted well to Langmuir and Temkin isotherm models, indicating monolayer adsorption occurred with a maximum adsorption capacity of 123
Electrodeposited pt on three dimensional interconnected graphene as a free st...tshankar20134
The document summarizes research on using a three-dimensional interconnected graphene structure as an electrode support for platinum nanoparticles for fuel cell applications. Key points:
1) Graphene was grown into a 3D foam-like structure using chemical vapor deposition on a nickel foam template, creating a seamless porous structure with high surface area and conductivity.
2) Platinum nanoparticles were deposited on the 3D graphene using pulsed electrodeposition, allowing control over particle size and uniform dispersion.
3) The 3D graphene with platinum nanoparticles showed improved catalytic activity for methanol oxidation compared to carbon fibers, due to the unique 3D structure, high surface area, and high conductivity of the graphene support.
Electro catalytic performance of pt-supported poly (o-phenylenediamine) micro...tshankar20134
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1. Catalysis Communications 10 (2009) 433–436
Contents lists available at ScienceDirect
Catalysis Communications
journal homepage: www.elsevier.com/locate/catcom
Electrochemical oxidation of methanol on Pt/V2O5–C composite catalysts
T. Maiyalagan *, F. Nawaz Khan
Department of Chemistry, School of Science and Humanities, VIT University, Vellore 632 014, India
a r t i c l e
i n f o
Article history:
Received 5 June 2008
Received in revised form 26 September
2008
Accepted 2 October 2008
Available online 22 October 2008
Keywords:
Pt nanoparticles
Methanol oxidation
DMFC
Electro-catalyst
a b s t r a c t
Platinum nanoparticles have been supported on V2O5–C composite through the reduction of chloroplatinic acid with formaldehyde. The catalyst was characterized by X-ray diffraction and transmission electron microscopy. Catalytic activity and stability for the oxidation of methanol were studied by using
cyclic voltammetry and chronoamperometry. Pt/V2O5–C composite anode catalyst on glassy carbon electrode show higher electro-catalytic activity for the oxidation of methanol. High electro-catalytic activities
and good stabilities could be attributed to the synergistic effect between Pt and V2O5, avoiding the electrodes being poisoned.
Ó 2008 Elsevier B.V. All rights reserved.
1. Introduction
Since the last decade, fuel cells have been receiving an increased
attention due to the depletion of fossil fuels and rising environmental pollution. Fuel cells have been demonstrated as interesting and
very promising alternatives to solve the problem of clean electric
power generation with high efficiency. Among the different types
of fuel cells, direct methanol fuel cells (DMFCs) are excellent power
sources for portable applications owing to its high energy density,
ease of handling liquid fuel, low operating temperatures (60
À100 °C) and quick start up [1,2]. Furthermore, methanol fuel cell
seems to be highly promising for large-scale commercialization in
contrast to hydrogen-fed cells, especially in transportation [3].
The limitation of methanol fuel cell system is due to low catalytic
activity of the electrodes, especially the anodes and at present,
there is no practical alternative to Pt based catalysts. High noble
metal loadings on the electrode [4,5] and the use of perfluorosulfonic acid membranes significantly contribute to the cost of the devices. An efficient way to decrease the loadings of precious
platinum metal catalysts and higher utilization of Pt particles is
by better dispersion of the desired metal on the suitable support [6].
In order to reduce the amount of Pt loading on the electrodes,
there have been considerable efforts to increase the dispersion of
the metal on the support. Pt nanoparticles have been dispersed on
a wide variety of substrates such as carbon nanomaterials [7,8] polymers nanotubules, [9] polymer-oxide nanocomposites [10], three
dimensional organic matrices [11], and oxide matrices [12–22].
* Corresponding author. Tel.: +91 0416 2202465; fax: +91 0416 2243092.
E-mail address: maiyalagan@gmail.com (T. Maiyalagan).
1566-7367/$ - see front matter Ó 2008 Elsevier B.V. All rights reserved.
doi:10.1016/j.catcom.2008.10.011
Most often the catalyst is dispersed on a conventional carbon
support and the support material influences the catalytic activity
through metal support interaction. Dispersion of Pt particles on
an oxide matrix can lead, depending mainly on the nature of support, to Pt supported oxide system that shows better behaviour
than pure Pt. On the other hand, if the oxide is not involved in
the electrochemical reactions taking place on the Pt sites, it might
just provide a convenient matrix to produce a high surface area
catalyst [23,24].
Recently metal oxides like CeO2 [25], ZrO2 [26], MgO [17], TiO2
[18] and WO3 [27] were used as electro-catalysts for direct oxidation of alcohol which significantly improve the electrode performance for alcohols oxidation, in terms of the enhanced reaction
activity and the poisoning resistance.
V2O5 has been extensively used as cathode in lithium ion batteries [28]. Vanadium (IV)/vanadium (III) redox couple has been
used to construct a redox type of fuel cell [29]. V2O5 has been
tested as anode for electro-oxidation of toluene [30]. Furthermore,
V2O5 is a strong oxidant, V2O5 acts as a good oxidation catalyst for
methanol [31,32].
The present report focuses on the efforts undertaken to develop
metal oxide supports based platinum catalysts for methanol oxidation. In this communication the preparation of highly dispersed platinum supported on V2O5–carbon composites, the evaluation of the
activity for the methanol oxidation of these electrodes and comparison with the activity of conventional 20% Pt/C electrodes are reported. These materials are characterized and studied, using XRD,
TEM and cyclic voltammetry. The electrochemical properties of the
composite electrode were compared to those of the commercial electrode, using cyclic voltammetry. The Pt Supported V2O5–C composite
2. T. Maiyalagan, F.N. Khan / Catalysis Communications 10 (2009) 433–436
2.2. Preparation of electro-catalysts
The V2O5/C composite used in this study was prepared by a solid-state reaction under the microwave irradiation. The aqueous
solution of V2O5 was well dispersed with carbon black (Vulcan
XC-72R, Cabot Corp., USA) and precipitate was dried in oven at
100 °C. The mixture was then introduced into a microwave oven
and heated 10 s and paused 40 s for ten times alternately.
Pt nanoparticles supported on V2O5–C composite was prepared
through the reduction of chloroplatinic acid with formaldehyde.
The V2O5/C composite powder (ca. 100 mg) was ground gently
with a mortar and pestle then suspended in about 20 ml H2O.
H2PtCl6 solution was used (Aldrich) for deposition of Pt was then
added in an amount slightly greater than the desired loading.
The suspension was stirred at around 80 °C for 30 min to allow dispersion and aqueous formaldehyde (BDH, 37%) was added followed by heating at reflux for 1 h. The composite catalyst were
collected by filtration, washed thoroughly with water, and then
dried under vacuum (25–50 °C).
The same procedure as the above was repeated for the preparation of Pt/C catalyst. The same procedure and conditions were used
to make a comparison between the Pt/C and Pt/V2O5–C system.
2.3. Preparation of working electrode
Glassy carbon (GC) (Bas electrode, 0.07 cm2) was polished to a
mirror finish with 0.05 lm alumina suspensions before each
experiment and served as an underlying substrate of the working
electrode. In order to prepare the composite electrode, the catalysts were dispersed ultrasonically in water at a concentration of
1 mg mlÀ1 and 20 ll aliquot was transferred on to a polished glassy
carbon substrate. After the evaporation of water, the resulting thin
catalyst film was covered with 5 wt% Nafion solution. Then the
electrode was dried at 353 K and used as the working electrode.
2.4. Characterization methods
The phases and lattice parameters of the catalyst were characterized by X-ray diffraction (XRD) patterns employing Shimadzu
XD-D1 diffractometer using Cu Ka radiation (k = 1.5418 Å) operating at 40 kV and 48 mA. XRD samples were obtained by depositing
carbon-supported nanoparticles on a glass slide and drying the later in a vacuum overnight. For transmission electron microscopic
studies, the composite dispersed in ethanol were placed on the
copper grid and the images were obtained using JEOL JEM-3010
model, operating at 300 keV.
2.5. Electrochemical measurements
All electrochemical studies were carried out using a BAS 100
electrochemical analyzer. A conventional three-electrode cell con-
3. Results and discussion
The Pt/V2O5–C composite catalysts were characterized by XRD.
The XRD pattern of as-synthesized Pt/C and Pt/V2O5–C catalysts is
given in Fig. 1. The diffraction peak at 24–27° observed is attributed to the hexagonal graphite structure (002) of Vulcan carbon.
The peaks can be indexed at 2h = 39.8° (1 1 1), 46.6° (2 0 0) and
67.9° (2 2 0) reflections of a Pt face-centered cubic (FCC) crystal
structure. The diffraction peak at 2h = 39.8° for Pt (1 1 1) corresponds well to the inter-planer spacing of d111 = 0.226 nm and
the lattice constant of 3.924 Å. The facts agree well with the standard powder diffraction file of Pt (JCPDS number 1-1311). From the
isolated Pt (2 2 0) peak, the mean particle size was about 3.1 nm
and 2.8 nm for the Pt/C and Pt/V2O5–C catalysts samples respectively, calculated with the Scherrer formula [33]. This suggests that
very small Pt nanoparticles dispersed on the Pt/V2O5–C composite.
The formation of broad peaks in V2O5-modified Pt/C catalysts indicated the presence of smaller Pt nanoparticles. But the diffraction
peaks of Pt–V2O5/C are slightly shifted to lower values when compared to Pt/C. This is an indication that an alloy between Pt and
V2O5 is being formed on the Pt–V2O5/C catalysts. Moreover, in
the XRD patterns of the V2O5-modified Pt catalysts, the peaks associated with pure V2O5 did not appear prominently. This might be
due to the presence of very small amount of V2O5 in catalysts.
However, XRD measurements cannot supply exact information
of crystallite size when it is less than 3.0 nm, for this reason, the
figures obtained by the above equation will be slightly smaller
than true ones. Fig. 2 shows TEM images of Pt/C and Pt/V2O5–C catalysts. The mean size was estimated to be 2.9 nm for Pt/C and
3.4 nm for Pt/V2O5–C, which was in good agreement with the results from XRD.
The electro-catalytic activities for methanol oxidation of Pt/C
and Pt/V2O5–C electro-catalysts were analyzed by cyclic voltam-
(c)
(a) Vulcan XC-72
(b) 20% Pt/C
(c) 20% Pt/V2O5- C
Pt (220)
All the chemicals used were of analytical grade. V2O5 obtained
from Merck was used. Hexachloroplatinic acid was obtained from
Aldrich. Vulcan XC-72 carbon black was purchased from Cabot
Inc., Methanol and sulphuric acid were obtained from Fischer
chemicals. Nafion 5 wt% solution was obtained from Dupont and
was used as received.
Pt (200)
2.1. Materials
Pt (111)
2. Experimental
sisting of the GC (0.07 cm2) working electrode, Pt plate (5 cm2) as
counter electrode and Ag/AgCl reference electrode were used for
the cyclic voltammetry (CV) studies. The CV experiments were performed using 1 M H2SO4 solution in the absence and presence of
1 M CH3OH at a scan rate of 50 mV/s. All the solutions were prepared by using ultra pure water (Millipore, 18 MX). The electrolytes were degassed with nitrogen gas before the electrochemical
measurements.
C (002)
electrode exhibited excellent catalytic activity and stability compared to the 20 wt% Pt supported on the Vulcan XC-72R carbon.
Intensity (a.u)
434
(b)
(a)
20
30
40
50
60
70
80
2θ (degrees)
Fig. 1. XRD spectra of (a) Vulcan XC-72 (b) Pt/Vulcan XC-72 and (c) Pt–V2O5/Vulcan
XC-72.
3. 435
T. Maiyalagan, F.N. Khan / Catalysis Communications 10 (2009) 433–436
(a)
(a) 20%Pt/V O5- C
2
Current density (mA/cm2 )
15
(b) 20% Pt/C
(b)
10
5
0
-0.2
0.0
0.2
0.4
0.6
0.8
1.0
Potential (V) vs Ag/AgCl
Fig. 3. Cyclic voltammograms of (a) Pt/V2O5–C and (b) Pt/C in 1 M H2SO4/1 M
CH3OH run at 50 mV/s.
Fig. 2. TEM images of (a) Pt/C and (b) Pt/V2O5–C electro-catalysts.
metry in an electrolyte of 1 M H2SO4 and 1 M CH3OH at 50 mV/s.
The cyclic voltammograms of Pt/C and Pt based V2O5 composite
electrodes are shown in Fig. 3, respectively. The data obtained from
the cyclic voltammograms of the composite electrodes were compared in Table 1.
The onset for methanol oxidation on Pt/C was found to be
0.31 V, which is 100 mV more positive than Pt/V2O5–C electrode
(0.21 V). This gives clear evidence for the superior electro-catalytic
activity of Pt/V2O5–C composite electrodes for methanol oxidation.
The ratio of the forward anodic peak current (If) to the reverse
anodic peak current (Ib) can be used to describe the catalyst tolerance to accumulation of carbonaceous species [34–38]. A higher
ratio indicates more effective removal of the poisoning species
on the catalyst surface. The If/Ib ratios of Pt/V2O5–C and Pt/C are
1.06 and 0.90, respectively, which are higher than that of Pt/C
(0.90), showing better catalyst tolerance of Pt/V2O5–C composites.
Chronoamperometric experiments were carried out to observe
the stability and possible poisoning of the catalysts under shorttime continuous operation. Fig. 4 shows the evaluation of activity
of Pt/C and Pt/V2O5–C composite electrodes with respect to time
at constant potential of +0.6 V. It is clear from Fig. 4 when the electrodes are compared under identical experimental conditions; the
Pt/V2O5–C composite electrodes show a comparable stability to the
20% Pt/C electrodes.
The higher activity of composite electrodes demonstrates the
better utilization of the catalyst. Also the redox potential of vanadium oxide (VO2+/V3+) is +337 mV (vs. SHE) which lying on the
electrode potential of methanol oxidation favours oxidation of
methanol. Enhancement in catalytic activity of Pt–Ru compared
to pure platinum can be attributed to a bifunctional mechanism:
platinum accomplishes the dissociative chemisorption of methanol
whereas ruthenium forms a surface oxy-hydroxide which subsequently oxidizes the carbonaceous adsorbate to CO2 [39,40]. Based
on most accepted bifunctional mechanism of Pt–Ru, similar type of
mechanism has been interpreted for enhancement in the catalytic
activity of Pt–V2O5 [41]. First, methanol is preferred to bind with Pt
surface atoms, and dehydrogenated to form CO adsorbed species.
The COad intermediates are thought as the main poisoning species
during electro-oxidation of methanol. Thus how to oxidize COad
intermediates as quickly as possible is very important to methanol
oxidation. Due to the higher affinity of vanadium oxides towards
Table 1
Comparison of activity of methanol oxidation between Pt/V2O5–C and Pt/C electrodes.
S. No.
Electrode
Onset potential (V)
Activitya
If/Ib
Forward sweep
Reverse sweep
E (V)
1
2
Pt/C (J.M.)
Pt–V2O5/C
a
0.31
0.21
I (mA cmÀ2)
E (V)
I (mA cmÀ2)
0.76
0.811
12.25
17.4
0.62
0.63
13.49
16.52
Activity evaluated from cyclic voltammogram run in 1 M H2SO4/1 M CH3OH.
0.9
1.06
4. 436
T. Maiyalagan, F.N. Khan / Catalysis Communications 10 (2009) 433–436
60
(a) 20% Pt/VO5- C
2
(b) 20% Pt/C
2
Current density (mA/cm )
50
intermediates. Easier formation of the oxygen-containing species
on the surface of V2O5 favours the oxidation of CO intermediates
to CO2 and releasing the active sites on Pt for further electrochemical reaction.
References
40
[1]
[2]
[3]
[4]
[5]
[6]
30
20
(a)
[7]
10
[8]
[9]
[10]
(b)
0
[11]
0
500
1000
1500
Time (Sec)
Fig. 4. Current density vs. time curves at (a) Pt/V2O5–C (b) Pt/C measured in 1 M
H2SO4 + 1 M CH3OH. The potential was stepped from the rest potential to 0.6 V vs.
Ag/AgCl.
[12]
[13]
[14]
[15]
[16]
oxygen-containing species, sufficient amounts of OHad to support
reasonable CO oxidation rates are formed at lower potential on
V2O5 composite sites than on Pt sites. The OHad species are necessary for the oxidative removal of COad intermediates. This effect
leads to the higher activity and longer lifetime for the overall
methanol oxidation process on Pt/V2O5–C composite. Based on
the experimental results, to illustrate the enhanced activity of
methanol electro-oxidation a similar promotional reaction model
is proposed as follows,
CH3 OHad ! COad þ 4Hþ þ 4eÀ
V2 O5 þ 2Hþ ! 2VOþ þ H2 O
2
4VOþ þ 4Hþ ! 4VO2þ þ O2 þ 2H2 O
2
VO2þ þ H2 O ! VOOHþ þ Hþ
COad þ VOOHþ ! CO2 þ VO2þ þ Hþ þ eÀ
4. Conclusion
Highly dispersed nanosized Pt particles on V2O5–C composite
have been prepared by formaldehyde reduction.Pt/V2O5–C composite catalyst exhibits higher catalytic activity for the methanol
oxidation reaction than Pt/C, which is attributed to the synergetic effects due to formation of an interface between the platinum and V2O5, and by spillover due to diffusion of the CO
[17]
[18]
[19]
[20]
[21]
[22]
[23]
[24]
[25]
[26]
[27]
[28]
[29]
[30]
[31]
[32]
[33]
[34]
[35]
[36]
[37]
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